CA2762188C - Non-contact medical thermometer with stray radiation shielding - Google Patents
Non-contact medical thermometer with stray radiation shielding Download PDFInfo
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- CA2762188C CA2762188C CA2762188A CA2762188A CA2762188C CA 2762188 C CA2762188 C CA 2762188C CA 2762188 A CA2762188 A CA 2762188A CA 2762188 A CA2762188 A CA 2762188A CA 2762188 C CA2762188 C CA 2762188C
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/06—Arrangements for eliminating effects of disturbing radiation; Arrangements for compensating changes in sensitivity
- G01J5/061—Arrangements for eliminating effects of disturbing radiation; Arrangements for compensating changes in sensitivity by controlling the temperature of the apparatus or parts thereof, e.g. using cooling means or thermostats
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B5/00—Measuring for diagnostic purposes; Identification of persons
- A61B5/01—Measuring temperature of body parts ; Diagnostic temperature sensing, e.g. for malignant or inflamed tissue
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/07—Arrangements for adjusting the solid angle of collected radiation, e.g. adjusting or orienting field of view, tracking position or encoding angular position
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0803—Arrangements for time-dependent attenuation of radiation signals
- G01J5/0804—Shutters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0806—Focusing or collimating elements, e.g. lenses or concave mirrors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0808—Convex mirrors
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/02—Constructional details
- G01J5/08—Optical arrangements
- G01J5/0896—Optical arrangements using a light source, e.g. for illuminating a surface
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J5/00—Radiation pyrometry, e.g. infrared or optical thermometry
- G01J5/0003—Radiation pyrometry, e.g. infrared or optical thermometry for sensing the radiant heat transfer of samples, e.g. emittance meter
- G01J5/0011—Ear thermometers
Abstract
A non-contact infrared (IR) thermometer for measuring temperature from the surface of an object includes an IR radiation sensor attached to a heating element and a thermal shield having an interior surface positioned within the sensor's field of view that has a high emissivity. An electronic circuit controlling the heating element maintains the temperatures of the sensor and shield substantially close to an anticipated surface temperature of the object. The IR radiation sensor is further thermally coupled to a reference temperature sensor. An optical system positioned in front of the shield focuses thermal radiation from the object on the surface of the sensor, while the shield prevents stray radiation from reaching the sensor. Signals from the IR and reference sensors are used to calculate the object's surface temperature.
Description
NON-CONTACT MEDICAL THERMOMETER WITH STRAY RADIATION SHIELDING
[00011 Field of the Invention:
[00011 Field of the Invention:
[0002] The present invention relates to devices for measuring temperature, and more specifically, to non-contact infrared thermometers for medical applications incorporating shielding to reduce the effects of stray radiation.
Background of the Invention
Background of the Invention
[0003] A thermal radiation or infrared (IR) thermometer is a device capable of measuring temperature without physically contacting the object of measurement. Thus, such thermometers are often called "non-contact" or "remote" thermometers. In an IR thermometer, the temperature of an object is taken by detecting an intensity of the IR radiation which is naturally emanated from the object's surface. For objects between 0 and 100 C, this requires the use of lR. sensors for detecting radiation having wavelengths from approximately 3 to 40 micrometers. Typically, IR radiation in this range is referred to as thermal radiation.
[0004] One example of an IR thermometer is an "instant ear" medical thermometer, which is capable of making non-contact temperature measurements of the tympanic membrane and surrounding tissues of the ear canal of a human or animal.
Instant ear thermometers are exemplified by U.S. Patent No. 4,797,840 to Fraden ("the '840 Patent"). Other examples include medical thermometers for measuring surface skin temperatures (for example, a skin surface temperature of the forehead) as exemplified by U.S. Patent No. 6,789,936 to Kraus et al,
Instant ear thermometers are exemplified by U.S. Patent No. 4,797,840 to Fraden ("the '840 Patent"). Other examples include medical thermometers for measuring surface skin temperatures (for example, a skin surface temperature of the forehead) as exemplified by U.S. Patent No. 6,789,936 to Kraus et al,
[0005] In order to measure the surface temperature of an object by its IR
radiation emissions, the IR radiation is detected and converted into electrical signal suitable for processing by conventional electronic circuits. The task of detecting the IR radiation is accomplished by an IR
sensor or detector.
radiation emissions, the IR radiation is detected and converted into electrical signal suitable for processing by conventional electronic circuits. The task of detecting the IR radiation is accomplished by an IR
sensor or detector.
[0006] Conventional thermal IR sensors typically include a housing with an infrared transparent window and at least one sensing element which is responsive to a thermal radiation energy flux 0 emanating from the object's surface to pass through the IR
window of the IR
sensor. The IR sensor functions to generate an electric signal which is representative of the net IR flux 0 existing between the sensing element and the object of measurement.
The electrical signal can be related to the object's temperature by appropriate data processing as is for example further described below.
window of the IR
sensor. The IR sensor functions to generate an electric signal which is representative of the net IR flux 0 existing between the sensing element and the object of measurement.
The electrical signal can be related to the object's temperature by appropriate data processing as is for example further described below.
[0007] Thermal flux 0 is a function of two temperatures: a sensing element surface temperature Ts and a surface temperature of the object Tb (measured in degrees Kelvin).
Theoretically, thermal radiation is known to be governed by Planck' s law.
However, for a broad optical spectral range, which may be determined by an optical system of the IR
thermometer, the relationship between the two temperatures Ts, Tb and the flux 4, may be approximated by a fourth-order parabola. In physics, this approximation is known as the Stefan-Boltzmann law:
= kehe$o-(TL4 Kt) , (1) where eb and es are the surface emissivities of the object and sensing element, respectively, cr is the Stefan-Boltzmann constant, and k is an optical constant which may be determined by measurement during calibration of the IR thermometer.
Theoretically, thermal radiation is known to be governed by Planck' s law.
However, for a broad optical spectral range, which may be determined by an optical system of the IR
thermometer, the relationship between the two temperatures Ts, Tb and the flux 4, may be approximated by a fourth-order parabola. In physics, this approximation is known as the Stefan-Boltzmann law:
= kehe$o-(TL4 Kt) , (1) where eb and es are the surface emissivities of the object and sensing element, respectively, cr is the Stefan-Boltzmann constant, and k is an optical constant which may be determined by measurement during calibration of the IR thermometer.
[0008] For a relatively small difference between the true object's temperature T,, and sensor's temperature T,õ Eq. (1) can be simplified as:
4kEbE,OV(T-1,¨Ts) (2)
4kEbE,OV(T-1,¨Ts) (2)
[0009] An ultimate purpose of an IR thermometer is to determine the surface temperature of the object (Tb), which may be calculated as The from inverted Eq. 2:
Tbf= Ts+ ______________________________________________ (3) 4kebescrTs.3
Tbf= Ts+ ______________________________________________ (3) 4kebescrTs.3
[0010] Ideally, the computed temperature Tt, should be equal to the true temperature Tb.
Practically, these temperatures may differ as the result of error. It can seen from Equation (3) that, in order to calculate temperature Tbe, two values need to be determined: the magnitude of the IR
flux 4) and the IR sensing element's surface temperature T. The accuracy of the temperature computation depends on the measurement accuracy for all variables at the right side of Eq. (3).
The first summand Ts can be measured quite accurately by a number of techniques known in the art, for example, by employing a thermistor or RTD temperature sensor. The second summand can be more problematic, especially due to a generally unknown and unpredictable value of the object's emissivity a. For example, in medical thermometry, the emissivity Eh.
is a skin emissivity that is defined by the skin properties and shape. The skin emissivity may, for example, range from 0.93 to 0.99. To determine how emissivity affects accuracy, a partial derivative of Eq.
(2) may be calculated as:
a(D, T, ) (4) aeb
Practically, these temperatures may differ as the result of error. It can seen from Equation (3) that, in order to calculate temperature Tbe, two values need to be determined: the magnitude of the IR
flux 4) and the IR sensing element's surface temperature T. The accuracy of the temperature computation depends on the measurement accuracy for all variables at the right side of Eq. (3).
The first summand Ts can be measured quite accurately by a number of techniques known in the art, for example, by employing a thermistor or RTD temperature sensor. The second summand can be more problematic, especially due to a generally unknown and unpredictable value of the object's emissivity a. For example, in medical thermometry, the emissivity Eh.
is a skin emissivity that is defined by the skin properties and shape. The skin emissivity may, for example, range from 0.93 to 0.99. To determine how emissivity affects accuracy, a partial derivative of Eq.
(2) may be calculated as:
a(D, T, ) (4) aeb
[0011] The partial derivative represents the measurement error due to an unknown emissivity el, of an object. Eq. (4) shows that the error essentially approaches zero when temperature T., of the sensor approaches temperature Th of the object, that is when Th T,. Thus, to minimize errors, it is desirable to keep the temperature T., of the IR sensor as close as is practical to the object's temperature Tb. For an instant ear thermometer, for example, U.S.
Patent No. 5,645,349 to Fraden teaches a heated sensing element for bringing the temperatures L., Th into proximity U.S. Patent No. 7,014,358 issued to Kraus et al. alternatively teaches a heating element for warming the IR sensor housing.
Patent No. 5,645,349 to Fraden teaches a heated sensing element for bringing the temperatures L., Th into proximity U.S. Patent No. 7,014,358 issued to Kraus et al. alternatively teaches a heating element for warming the IR sensor housing.
[0012] When temperature is measured from a surface, it is important to direct the associated IR
radiation flux (13 to the IR sensor only from the measured surface, and not from any stray objects that may appear in the field of view of the optical system. IR radiation from stray objects alters the measured flux, and thereby contributes to error.
radiation flux (13 to the IR sensor only from the measured surface, and not from any stray objects that may appear in the field of view of the optical system. IR radiation from stray objects alters the measured flux, and thereby contributes to error.
[0013] One way to minimize the chance of picking up flux from stray objects is to narrow the optical field of view of the IR thermometer. One method of using IR lenses to narrow the optical field of view is exemplified by U.S. Patent No. 5,172,978 to Nomura et al.
(radiant thermometer including a lens barrel mounting a condensing lens at one end and an IR
detector at the other end) and U.S. Patent No 5,655,838 to Ridley et al. (radiation thermometer with multi-element focusing lens, eye piece, beam splitter and IR detector).
(radiant thermometer including a lens barrel mounting a condensing lens at one end and an IR
detector at the other end) and U.S. Patent No 5,655,838 to Ridley et al. (radiation thermometer with multi-element focusing lens, eye piece, beam splitter and IR detector).
[0014] Another method for minimizing the chance of picking up flux from stray objects employs curved mirrors to narrow the field of view. This approach is exemplified by U.S.
Patents No 4,494,881 to Everest.
Patents No 4,494,881 to Everest.
[0015] These methods successfully solve the problem of eliminating stray IR
signals from surrounding objects, but remain ineffective in further preventing stray radiation from interior components of the IR thermometer that surround the IR sensor. This source of stray radiation is unaffected by efforts to limit the optical field of view. It would be of significant benefit to develop an IR thermometer having an IR sensor that is unaffected by stray radiation from interior components of the IR thermometer that surround the IR sensor.
Summary of the Invention:
signals from surrounding objects, but remain ineffective in further preventing stray radiation from interior components of the IR thermometer that surround the IR sensor. This source of stray radiation is unaffected by efforts to limit the optical field of view. It would be of significant benefit to develop an IR thermometer having an IR sensor that is unaffected by stray radiation from interior components of the IR thermometer that surround the IR sensor.
Summary of the Invention:
[0016] A non-contact infrared (IR) thermometer according to the present invention includes an IR radiation sensor thermally coupled to a heating element and a thermal shield having an interior surface positioned within the sensor's field of view, such interior surface has a high emissivity. An electronic circuit controlling the heating element maintains the temperatures of the sensor and shield substantially close to an anticipated surface temperature of the object. The IR radiation sensor is further thermally coupled to a reference temperature sensor. An optical system positioned in front of the shield focuses thermal radiation from the object on the surface of the sensor, while the shield prevents stray radiation from reaching the sensor from the thermometer parts. Signals from the IR and reference temperature sensors are used to calculate the object's surface temperature.
[0017] The thermal shield is configured to reduce stray thermal generation emanating from the interior surface positioned within the thermal radiation sensor's field of view, in part by maintaining the temperatures of the thermal radiation sensor and the thermal shield to be substantially equal. In addition, the interior surface may be treated to be non-reflective of IR radiation (for example, by coating the surface with an organic paint having an emissivity of 0.9 or higher).
[0018] The optical system may preferably comprise a lens. Alternatively, the optical system may preferably comprise a curved mirror.
[0019] The thermometer may also comprise a shutter that is movable to shield the interior surface of the thermal shield and thermal radiation sensor from thermal radiation emanating externally from the shield (for example, thermal radiation emanating from the object). When shielded, a baseline output of the thermal radiation sensor can be obtained for calibrating the sensor. In the thermometer comprising the curved mirror, the curved mirror is preferably rotable configured as the movable shutter.
[0020] The thermometer is also preferably provided with an illuminator for illuminating at least a portion of the field of view of the thermal radiation sensor on the surface of the object. In the thermometer comprising the curved mirror, the illuminator may preferably project a light beam that off an ancillary surface of the curved mirror toward the surface of the object.
[0020a] Accordingly, in one aspect, the present invention resides in a thermal radiation thermometer for measuring a surface temperature of an object, the thermometer comprising:
a thermal radiation sensor; an optical device configured for receiving thermal radiation . .
emanated by the object and directing the thermal radiation to the thermal radiation sensor; a reference temperature sensor thermally coupled to the thermal radiation sensor ; a thermal shield including an outer surface and an internal cavity configured for receiving the thermal radiation sensor and thermally coupling the thermal radiation sensor to the thermal shield, such that the internal cavity of the thermal shield is within a field of view of the thermal radiation sensor; a heating element thermally coupled to the thermal radiation sensor and to the thermal shield; an electronic circuit electrically coupled to the thermal radiation sensor and to the reference temperature sensor, the electrical circuit being configured to process signals generated by the thermal radiation sensor and the reference temperature sensor to calculate the surface temperature of the object and to control an amount of energy supplied to the heating element so that a temperature of the thermal radiation sensor is substantially within a range of anticipated surface temperatures of the object; and a housing configured for enclosing and fixedly positioning the thermal radiation sensor, the optical device and the thermal shield relative to one another, wherein the thermal shield is further configured within the housing to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of the housing.
[0020b] In another aspect, the present invention resides in a method of remotely measuring a surface temperature of an object by a thermal radiation thermometer comprising a thermal radiation sensor, the method comprising the steps of: providing the thermal radiation sensor with a thermal shield that is thermally coupled to the thermal radiation sensor, the thermal shield including an interior surface within a field of view of the thermal radiation sensor and being configured to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of a housing of the thermal radiation thermometer; heating the thermal radiation sensor to a temperature that is substantially within a range of anticipated surface temperatures of the object; receiving thermal radiation emanated from the object onto the thermal radiation sensor; determining a thermal flux 4130 of the thermal radiation emanated from the object according to an output signal of the thermal radiation sensor; calculating the surface temperature of the object as a function of the thermal flux and the sensor temperature; and displaying the calculated temperature of the object on a display of the thermal radiation thermometer.
5a Brief Description of the Drawings:
[0020a] Accordingly, in one aspect, the present invention resides in a thermal radiation thermometer for measuring a surface temperature of an object, the thermometer comprising:
a thermal radiation sensor; an optical device configured for receiving thermal radiation . .
emanated by the object and directing the thermal radiation to the thermal radiation sensor; a reference temperature sensor thermally coupled to the thermal radiation sensor ; a thermal shield including an outer surface and an internal cavity configured for receiving the thermal radiation sensor and thermally coupling the thermal radiation sensor to the thermal shield, such that the internal cavity of the thermal shield is within a field of view of the thermal radiation sensor; a heating element thermally coupled to the thermal radiation sensor and to the thermal shield; an electronic circuit electrically coupled to the thermal radiation sensor and to the reference temperature sensor, the electrical circuit being configured to process signals generated by the thermal radiation sensor and the reference temperature sensor to calculate the surface temperature of the object and to control an amount of energy supplied to the heating element so that a temperature of the thermal radiation sensor is substantially within a range of anticipated surface temperatures of the object; and a housing configured for enclosing and fixedly positioning the thermal radiation sensor, the optical device and the thermal shield relative to one another, wherein the thermal shield is further configured within the housing to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of the housing.
[0020b] In another aspect, the present invention resides in a method of remotely measuring a surface temperature of an object by a thermal radiation thermometer comprising a thermal radiation sensor, the method comprising the steps of: providing the thermal radiation sensor with a thermal shield that is thermally coupled to the thermal radiation sensor, the thermal shield including an interior surface within a field of view of the thermal radiation sensor and being configured to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of a housing of the thermal radiation thermometer; heating the thermal radiation sensor to a temperature that is substantially within a range of anticipated surface temperatures of the object; receiving thermal radiation emanated from the object onto the thermal radiation sensor; determining a thermal flux 4130 of the thermal radiation emanated from the object according to an output signal of the thermal radiation sensor; calculating the surface temperature of the object as a function of the thermal flux and the sensor temperature; and displaying the calculated temperature of the object on a display of the thermal radiation thermometer.
5a Brief Description of the Drawings:
[0021] The foregoing and other features of the present invention will be more readily apparent from the following detailed description and drawings of illustrative embodiments of the invention in which:
[0022] Fig. 1 provides a cross-sectional view of an IR thermometer according to an embodiment of the present invention;
5b
5b
[0023] Fig. 2 depicts an optical part of an IR thermometer according to another embodiment of the present invention;
[0024] Fig. 3 provides a schematic view of a sensor shield according to another embodiment of the present invention;
[0025] Fig. 4 depicts a shutter arrangement in combination with an optical part of a remote thermometer according to an embodiment of the present invention;
[0026] Fie. 5 depicts another shutter arrangement according to an embodiment of the present invention;
[0027] Fig. 6 depicts a tilted mirror included in an optical part of an IR
thermometer according to an embodiment of the present invention;
thermometer according to an embodiment of the present invention;
[0028] Fig. 7 shows an illuminator operable with the tilted mirror of FIG. 6;
[0029] Fig. 8 depicts a schematic view of an IR thermometer according to the present invention an illuminator provided on an external surface of a thermometer housing; and
[0030] Fig. 9 provides a cross-sectional view of a sensor for an IR
thermometer according to the present invention having a focusing lens.
thermometer according to the present invention having a focusing lens.
[0031] Like reference numerals are used in the drawing figures to connote like components of the thermometer.
Detailed Description of the Preferred Embodiments:
Detailed Description of the Preferred Embodiments:
[0032] An IR thermometer is disclosed that includes a thermal shield having a surface that is covered by the sensor's field of view. The surface preferably includes a high-emissivity coating that minimizes stray radiation from the shield. For the purpose of illustrating principles of the present invention, several non-limiting embodiments of the IR thermometer and thermal shield are described below. Accordingly, the invention is to be limited only by the scope of the claims and their equivalents.
[0033] Fig. 1 shows a schematic, cross-sectional view of a remote thermometer.
The thermometer of Fig. 1 includes a housing 3 that contains an infrared sensor 7, several optical components which are described further herein, a circuit board 13 with an electronic circuit 14, a power supply 17, a control button 15, and a display 16. The optical components include an aperture 9 that admits IR radiation into the sensor 7, a lens 5 and a thermal shield 10. The sensor 7 may also preferably contain an optical filter (not illustrated) in proximity to aperture 9. The sensor 7 is positioned inside and thermally coupled to a thefinal shield 10 that during operation is in thermal equilibrium with the sensor 7.
The thermometer of Fig. 1 includes a housing 3 that contains an infrared sensor 7, several optical components which are described further herein, a circuit board 13 with an electronic circuit 14, a power supply 17, a control button 15, and a display 16. The optical components include an aperture 9 that admits IR radiation into the sensor 7, a lens 5 and a thermal shield 10. The sensor 7 may also preferably contain an optical filter (not illustrated) in proximity to aperture 9. The sensor 7 is positioned inside and thermally coupled to a thefinal shield 10 that during operation is in thermal equilibrium with the sensor 7.
[0034] As further shown in Fie. 1, the sensor 7 incorporates an IR sensing element 8 that is thermally coupled to a reference temperature sensor 30. A heating element 12 is coupled to the thermal shield 10 and is also thermally coupled to the sensor 7 and all its internal components, including the sensing element 8 and reference sensor 30. In this manner, these components can be brought into a thermal equilibrium with one another. The focusing lens 5 is provided in proximity to an IR radiation-receiving opening 4 of the housing 3, and is configured to converge nearly parallel IR rays 18 from a field of view 2 of an object 1 to be directed to the aperture 9 such that the IR rays 18 are focused on and absorbed by the sensing element 8.
[0035] The button 15 of Fig. 1 is actuated to initiate a temperature measurement of the object 1 by activating the circuit 14 to process data received from the sensing element 8 and the reference sensor 7. The circuit 14 also operates to control the amount of energy supplied to the heating element 12 according to a predetermined algorithm [for example, a Proportional¨Integral¨
Derivative (PID) corrective algorithm], and to provide an output to the display for indicating a measured temperature according to the processed data. The circuit 14 includes an amplifier, multiplexer, microcontroller with a display driver and output transistor that controls electric currents to the heating element 12. The circuit 14 is of design that is well known in art as exemplified by" 840 Patent".
Derivative (PID) corrective algorithm], and to provide an output to the display for indicating a measured temperature according to the processed data. The circuit 14 includes an amplifier, multiplexer, microcontroller with a display driver and output transistor that controls electric currents to the heating element 12. The circuit 14 is of design that is well known in art as exemplified by" 840 Patent".
[0036] Inner surface 11 of the thermal shield 10 is configured to be in the field of view of the sensing element 8. Thermal shield 10 is preferably fabricated using a metal with good thermal conductivity (for example, copper or aluminum), and preferably includes an inner surface 11 coated with a heat absorbing (non-reflecting) coating 19, such as organic paint having an emissivity greater than 0.9, for example KRYLON. The outer surface of the shield 10 may be covered by a thermal insulating layer (not shown), and/or made reflective in the IR spectral range.
The insulating layer maybe a urethane foam and the reflective property can be achieved by polishing the outer surface of the shield 10. The shield 10 is sized to substantially prevent any stray radiation from an interior surface 6 of the housing 3 from reaching the aperture 9. As a result, only the IR rays 18 passing through the focusing optical device (lens 5) and IR rays emanating from the inner surface 11 of the shield 10 are able to reach the sensing element 8.
The insulating layer maybe a urethane foam and the reflective property can be achieved by polishing the outer surface of the shield 10. The shield 10 is sized to substantially prevent any stray radiation from an interior surface 6 of the housing 3 from reaching the aperture 9. As a result, only the IR rays 18 passing through the focusing optical device (lens 5) and IR rays emanating from the inner surface 11 of the shield 10 are able to reach the sensing element 8.
[0037] A preferred embodiment of the present invention operates as follows. IR
rays 18 are naturally emanated from the surface of the object 1 (for example, a human skin surface). The IR
rays 18 are received by the focusing optical device (lens 5). The sensing element 8 is positioned at or near the focal point of the lens 5. As a result, a substantial portion of the thermal IR energy radiated from the field of view 2 toward the lens 5 is focused on the sensing element 8, which converts the thermal IR flux into an electrical signal. In order to calculate a surface temperature of the surface in the field of view 2 (for example, using Equation (3) or an approximation or variation thereof), a reference temperature (that of the sensing element 8) also must be measured.
This may be accomplished by the reference sensor 30 that is thermally coupled to the IR sensing element 8. Such arrangements coupling a sensing element with a reference sensor are well known in art.
rays 18 are naturally emanated from the surface of the object 1 (for example, a human skin surface). The IR
rays 18 are received by the focusing optical device (lens 5). The sensing element 8 is positioned at or near the focal point of the lens 5. As a result, a substantial portion of the thermal IR energy radiated from the field of view 2 toward the lens 5 is focused on the sensing element 8, which converts the thermal IR flux into an electrical signal. In order to calculate a surface temperature of the surface in the field of view 2 (for example, using Equation (3) or an approximation or variation thereof), a reference temperature (that of the sensing element 8) also must be measured.
This may be accomplished by the reference sensor 30 that is thermally coupled to the IR sensing element 8. Such arrangements coupling a sensing element with a reference sensor are well known in art.
[0038] In addition, according to the present invention, the thermal shield 10 is provided and configured to surround the IR rays 18 radiated from the field of view 2 in such a way as to substantially prevent any stray rays from reaching the sensing element 8.
[0039] To further improve measurement accuracy, the temperature of the sensing element 8 is preferably controlled to be substantially equal to an anticipated surface temperature of object 1 within the field of view 2. For example, if object 1 is a human forehead, its surface temperature may range from 31 to 38 C for the group including healthy and febrile patients. In this case, the temperature for the heating element 12 is preferably set near 34-35 C. To reach and maintain this temperature, the reference sensor 30 monitors the temperature of the sensing element 8 and provides feedback to the circuit 14 which, in turn, provides energy to the heating element 12. In effect, this arrangement operates thermostatically. In addition, the thermal shield 10 is preferably maintained at or near the same controlled temperature, which may be significantly different from temperatures of the housing 3 and the inside surface 6.
[0040] By maintaining the temperature of the shield's 10 inner surface 11 close to that of the sensing element 8, in accordance with Equation (2), little or no IR radiation is emanated from the surface 11 toward the sensing element 8. As a result, the thermal shield 10 effectively becomes thermally "invisible" to the sensing element 8.
[0041] The lens 5 may be fabricated of any suitable IR transmissive material, including for example germanium, silicon, and zinc selenide. Surfaces of the lens 5 may preferably be coated with an IR antireflective coatings for the spectral range from 4 to 15 micrometers of wavelength.
Such coatings are well known in art and generally comprise thin multiple layers (5-40 nm) of metal nitrides, such a titanium nitride, niobium nitride and others deposited in vacuum on both sides of the lens. In low cost applications, for example, the lens 5 may be a Fresnel lens molded of a high-density polyethylene (HDPE) sheet having thickness in the range from 0.2 to 0.6 mm.
Such coatings are well known in art and generally comprise thin multiple layers (5-40 nm) of metal nitrides, such a titanium nitride, niobium nitride and others deposited in vacuum on both sides of the lens. In low cost applications, for example, the lens 5 may be a Fresnel lens molded of a high-density polyethylene (HDPE) sheet having thickness in the range from 0.2 to 0.6 mm.
[0042] Alternatively to the configuration depicted in Fig. 1, the lens 5 may be installed inside the shield 10, or built into the housing of the IR sensor 7 as illustrated in Fig. 9. In Fig. 9, an inner space 56 of sensor 7 contains at least one IR sensing element 8 that is thermally coupled to a reference temperature sensor 30. The sensing element 8 is positioned at or near the focal point of lens 55 (illustrated as a Fresnel lens) that is incorporated into the front end of the sensor 7.
[0043] In another embodiment of the present invention, the focusing optical device is provided in the form of a focusing mirror 20 as shown in Fig. 2. The mirror 20 as illustrated in Fig. 2 has a parabolic reflective surface 23 positioned with reference to an optical axis 22 so that a reflection of the IR rays 18 is redirected toward aperture 9. The sensing element 8 is positioned at or near a focal point of the mirror 20. A protective window 21 may preferably be employed in front of mirror 20 in the path of the IR rays 18. The window may be fabricated of a suitable material having relative high transparency in the IR spectral range (for example, such as HDPE, silicon, and the like). For a better reflectivity, the mirror surface 23 may be coated with gold, aluminum or another suitable IR reflective metal. As in Fig. 1, the thermal shield 10 is configured to be in the field of view of the sensing element 8 and is sized to substantially prevent any stray radiation from the interior the housing 3 from reaching the aperture 9.
[0044] In Fig. 2, the heating element 12 is sandwiched between the sensor 7 and thermal shield 10. Such a heating element 12 may be fabricated in form of a flexible film made of polyimide with imbedded copper conductors. Alternatively, the heating element 12 may be at another position on this assembly as long as good thermal coupling of the assembly is maintained. For example, in Fig. 3, the heating element 12 includes two resistors 25, 125 which are thermally coupled to the thermal shield 10 and clamped to its outside walls, for example, by a shrink tubing 28 shown by a broken line for clarity. The resistors are interconnected by wire 27 and connected to the circuit board 13 by terminals 26 and 126. The resistors 25, 125 may be provided in alternative numbers (for example, one resistor only or four resistors circumferentially spaced around the thermal shield 10), and may be provided in a variety of forms including discrete resistors, film resistors, and printed resistors.
[0045] For accurate temperature measurement, it may be desirable to establish a thermal baseline of the IR sensing element 8 response. The baseline is to be established under conditions where no IR flux from any external object reaches the sensing element 8. This can be accomplished by several methods. One preferred method includes the use of shutter 31 as shown in Fig. 4.
[0046] To establish a baseline, the shutter 31 is set in a first position 34 which substantially blocks external IR rays from entering inner space 37 of thermal shield 10 to reach sensor 7. A
surface 32 that faces an interior space 37 is coated with aluminum or gold to be highly reflective in the IR spectral range (that is, having a coefficient of reflectivity be no less than 0.9). After a baseline output of the sensing element 8 is established from temperature measurements made for this configuration, and when a temperature measurement of the object 1 is to be made, shutter 31 is moved in a direction 36 to a second position 35, out of the path of the IR
rays. This action opens the space 37 to allow external IR radiation from the field of view 2 of the object to reach the sensor 7. After the temperature measurement of the object 1 is complete, shutter 31 returns to the closed position that is first position 34. The shutter 31 is preferably moved by a shutter mechanism 33 that is controlled by operation of the button 15 or the circuit 14. Such shutter mechanisms are well known in the art (see, for example, the '840 Patent). As an alternative to the configuration of Fig. 4, the shutter 31 may be positioned inside a slot 38 that, for example, is cut into a side wall of the shield 10 as shown in Fie. 5 to move along the direction 39.
surface 32 that faces an interior space 37 is coated with aluminum or gold to be highly reflective in the IR spectral range (that is, having a coefficient of reflectivity be no less than 0.9). After a baseline output of the sensing element 8 is established from temperature measurements made for this configuration, and when a temperature measurement of the object 1 is to be made, shutter 31 is moved in a direction 36 to a second position 35, out of the path of the IR
rays. This action opens the space 37 to allow external IR radiation from the field of view 2 of the object to reach the sensor 7. After the temperature measurement of the object 1 is complete, shutter 31 returns to the closed position that is first position 34. The shutter 31 is preferably moved by a shutter mechanism 33 that is controlled by operation of the button 15 or the circuit 14. Such shutter mechanisms are well known in the art (see, for example, the '840 Patent). As an alternative to the configuration of Fig. 4, the shutter 31 may be positioned inside a slot 38 that, for example, is cut into a side wall of the shield 10 as shown in Fie. 5 to move along the direction 39.
[0047] An alternative embodiment of the present invention, a baseline of the sensing element 8 may be established by using a rotatable tilted mirror 20 as shown in Fig. 6.
In a first position 41, the mirror 20 is rotated along the direction 42 to optically close an inner space of the thermal shield 10. In this position, substantially no IR rays can reach the sensor 7.
When a temperature measurement of the object 1 is performed, the mirror 20 rotates to a second position 40 (shown by a broken line for clarity) that allows IR rays to arrive from a window 21 and reach the IR
sensing element 8. After the measurement, the mirror 20 returns to the first position 41. A
mechanism for affecting the mirror rotation can be of a conventional design controlled by the electronic circuit 14, and is not further described herein.
In a first position 41, the mirror 20 is rotated along the direction 42 to optically close an inner space of the thermal shield 10. In this position, substantially no IR rays can reach the sensor 7.
When a temperature measurement of the object 1 is performed, the mirror 20 rotates to a second position 40 (shown by a broken line for clarity) that allows IR rays to arrive from a window 21 and reach the IR
sensing element 8. After the measurement, the mirror 20 returns to the first position 41. A
mechanism for affecting the mirror rotation can be of a conventional design controlled by the electronic circuit 14, and is not further described herein.
[0048] For a better identification of the field of view 2, it is preferable to illuminate the area from which temperature is to be measured. One way to accomplish this is shown in Fig. 7. A
light source 44 (for example, a lamp, LED or laser diode) is positioned outside of the shield 10 adjacent to the mirror 20. A surface 45 of the mirror 20 is positioned at an angle for reflecting light from the light source 44 to form a light bean 43 toward the field of view 2 through the window 21 when the mirror 20 is in the first position 41. The light beam 43 is aligned to illuminate the same portion of the filed of view 2 from which temperature will be measured when the mirror rotates to the second position 40. At that moment, the light source 44 preferably extinguishes the illumination.
light source 44 (for example, a lamp, LED or laser diode) is positioned outside of the shield 10 adjacent to the mirror 20. A surface 45 of the mirror 20 is positioned at an angle for reflecting light from the light source 44 to form a light bean 43 toward the field of view 2 through the window 21 when the mirror 20 is in the first position 41. The light beam 43 is aligned to illuminate the same portion of the filed of view 2 from which temperature will be measured when the mirror rotates to the second position 40. At that moment, the light source 44 preferably extinguishes the illumination.
[0049] An alternative method of illuminating the field of view 2 is depicted in Fie. 8. Here, an illuminator 50 (for example, a narrow beam LED) is positioned externally on the housing 3 in proximity to the IR window 21. A beam 51 generated by the illuminator 50 is directed toward the field of view 2, and nearly overlaps with it to form an illuminated spot 52.
[0050] After a value for the surface temperature for the field of view 2 is computed, it is preferably displayed directly on the display 16 and/or used as an input for further data processing.
An example of further data processing in medical thermometry is computing an inner (core) temperature of a patient from the skin temperature by means of a conventional algorithm known in art, which may then be displayed on the display 16.
An example of further data processing in medical thermometry is computing an inner (core) temperature of a patient from the skin temperature by means of a conventional algorithm known in art, which may then be displayed on the display 16.
[0051] With reference to Fig. 8, an exemplary temperature measurement process according to the present invention, for example, contains the following steps:
[0052] 1. Elevate the temperature of the heating element 12 to maintain a temperature of the infrared sensor 7 substantially at a constant level of about 34 C. The thermal shield 10 assures that thermal radiation is received only from the focusing device.
[0053] 2. Turn on the light source 44, directing the light beam 51 toward the field of view 2 of the object 1
[0054] 3. Operate the button 15 to initiate the measurement cycle.
[0055] 4. Turn off the heating element 12 to prevent its interference with the thermal radiation measurement process.
[0056] 5. Process signals provided by the sensing element 8 and reference sensor 30 in the circuit 14 to compute the surface temperature of the object
[0057] 6. Provide the computed surface temperature at the display 16.
[00581 While the invention has been particularly shown and described with reference to a number of preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the scope of the invention. Accordingly, the invention is to be limited only by the scope of the claims and their equivalents.
[00581 While the invention has been particularly shown and described with reference to a number of preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the scope of the invention. Accordingly, the invention is to be limited only by the scope of the claims and their equivalents.
Claims (23)
1. A thermal radiation thermometer for measuring a surface temperature of an object, the thermometer comprising:
a thermal radiation sensor;
an optical device configured for receiving thermal radiation emanated by the object and directing the thermal radiation to the thermal radiation sensor;
a reference temperature sensor thermally coupled to the thermal radiation sensor;
a thermal shield including an outer surface and an internal cavity configured for receiving the thermal radiation sensor and thermally coupling the thermal radiation sensor to the thermal shield, such that the internal cavity of the thermal shield is within a field of view of the thermal radiation sensor;
a heating element thermally coupled to the thermal radiation sensor and to the thermal shield;
an electronic circuit electrically coupled to the thermal radiation sensor and to the reference temperature sensor, the electrical circuit being configured to process signals generated by the thermal radiation sensor and the reference temperature sensor to calculate the surface temperature of the object and to control an amount of energy supplied to the heating element so that a temperature of the thermal radiation sensor is substantially within a range of anticipated surface temperatures of the object; and a housing configured for enclosing and fixedly positioning the thermal radiation sensor, the optical device and the thermal shield relative to one another, wherein the thermal shield is further configured within the housing to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of the housing.
a thermal radiation sensor;
an optical device configured for receiving thermal radiation emanated by the object and directing the thermal radiation to the thermal radiation sensor;
a reference temperature sensor thermally coupled to the thermal radiation sensor;
a thermal shield including an outer surface and an internal cavity configured for receiving the thermal radiation sensor and thermally coupling the thermal radiation sensor to the thermal shield, such that the internal cavity of the thermal shield is within a field of view of the thermal radiation sensor;
a heating element thermally coupled to the thermal radiation sensor and to the thermal shield;
an electronic circuit electrically coupled to the thermal radiation sensor and to the reference temperature sensor, the electrical circuit being configured to process signals generated by the thermal radiation sensor and the reference temperature sensor to calculate the surface temperature of the object and to control an amount of energy supplied to the heating element so that a temperature of the thermal radiation sensor is substantially within a range of anticipated surface temperatures of the object; and a housing configured for enclosing and fixedly positioning the thermal radiation sensor, the optical device and the thermal shield relative to one another, wherein the thermal shield is further configured within the housing to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of the housing.
2. The thermal radiation thermometer of claim 1, wherein the heating element is on an exterior surface of the thermal shield.
3. The thermal radiation thermometer of claim 1, wherein the thermal radiation sensor comprises:
a sensor housing;
an aperture in the sensor housing configured for receiving the thermal radiation directed by the optical device; and an interior cavity in the sensor housing including a thermal sensing element positioned to sense the thermal radiation received by the aperture, wherein the thermal sensing element is thermally coupled to the reference temperature sensor.
a sensor housing;
an aperture in the sensor housing configured for receiving the thermal radiation directed by the optical device; and an interior cavity in the sensor housing including a thermal sensing element positioned to sense the thermal radiation received by the aperture, wherein the thermal sensing element is thermally coupled to the reference temperature sensor.
4. The thermal radiation thermometer of claim 3, wherein the optical device comprises a lens positioned within the aperture in the sensor housing of the thermal radiation sensor.
5. The thermal radiation thermometer of claim 4, wherein the lens is a Fresnel lens.
6. The thermal radiation thermometer of claim 1, wherein the optical device is positioned within the field of view at a distance from the thermal radiation sensor that is substantially equal to a focal distance of the optical device.
7. The thermal radiation thermometer of claim 6, wherein the optical device comprises a lens.
8. The thermal radiation thermometer of claim 7, wherein the lens comprises high-density polyethylene (HDPE).
9. The thermal radiation thermometer of claim 6, wherein the optical device comprises a mirror.
10. The thermal radiation thermometer of claim 9, wherein the mirror is rotatable between a closed position that closes the internal cavity of the thermal shield to the thermal radiation emanated by the object and an open position that opens the internal cavity of the thermal shield to the thermal radiation emanated by the object.
11. The thermal radiation thermometer of claim 10, wherein the mirror includes a parabolic reflective surface for directing the thermal radiation to the thermal radiation sensor when the mirror is in the open position.
12. The thermal radiation thermometer of claim 10, further comprising:
an illuminator for substantially illuminating at least a portion of the field of view on the surface of the object, wherein the mirror includes an angled reflective surface for directing a light beam of the illuminator toward the surface of the object when the mirror is in the closed position.
an illuminator for substantially illuminating at least a portion of the field of view on the surface of the object, wherein the mirror includes an angled reflective surface for directing a light beam of the illuminator toward the surface of the object when the mirror is in the closed position.
13. The thermal radiation thermometer of claim 1, further comprising:
an illuminator for substantially illuminating at least a portion of the field of view on the surface of the object.
an illuminator for substantially illuminating at least a portion of the field of view on the surface of the object.
14. The thermal radiation thermometer of claim 1, further comprising:
a shutter having an inner surface movable within and outside of the field of view, and a shutter control device for moving the inner surface within and outside the field of view;
wherein the inner surface is positioned adjacent to the internal cavity when said shutter is within the field of view.
a shutter having an inner surface movable within and outside of the field of view, and a shutter control device for moving the inner surface within and outside the field of view;
wherein the inner surface is positioned adjacent to the internal cavity when said shutter is within the field of view.
15. The thermal radiation thermometer of claim 14, wherein the shutter is movable between a closed position that closes the internal cavity of the thermal shield to the thermal radiation emanated by the object and an open position that opens the internal cavity of the thermal shield to the thermal radiation emanated by the object.
16. The thermal radiation thermometer of claim 14, wherein the inner surface of the shutter is substantially reflective within a spectral range of 4 to 15 µm.
17. The thermal radiation thermometer of claim 1, further comprising:
a thermal insulator positioned adjacent to the outer surface.
a thermal insulator positioned adjacent to the outer surface.
18. The thermal radiation thermometer of claim 1, wherein a surface of the internal cavity of the thermal shield is substantially non-reflective within a spectral range of 4 to 15 µm.
19. The thermal radiation thermometer of claim 1, further comprising:
a protective window fixed in the housing, the protective window configured for receiving the thermal radiation emanated by the object and transmitting the thermal radiation to the optical device.
a protective window fixed in the housing, the protective window configured for receiving the thermal radiation emanated by the object and transmitting the thermal radiation to the optical device.
20. A method of remotely measuring a surface temperature of an object by a thermal radiation thermometer comprising a thermal radiation sensor, the method comprising the steps of:
providing the thermal radiation sensor with a thermal shield that is thermally coupled to the thermal radiation sensor, the thermal shield including an interior surface within a field of view of the thermal radiation sensor and being configured to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of a housing of the thermal radiation thermometer;
heating the thermal radiation sensor to a temperature that is substantially within a range of anticipated surface temperatures of the object;
receiving thermal radiation emanated from the object onto the thermal radiation sensor;
determining a thermal flux (I) of the thermal radiation emanated from the object according to an output signal of the thermal radiation sensor;
calculating the surface temperature of the object as a function of the thermal flux and the sensor temperature; and displaying the calculated temperature of the object on a display of the thermal radiation thermometer.
providing the thermal radiation sensor with a thermal shield that is thermally coupled to the thermal radiation sensor, the thermal shield including an interior surface within a field of view of the thermal radiation sensor and being configured to substantially shield the thermal radiation sensor from stray thermal radiation emanating from interior surfaces of a housing of the thermal radiation thermometer;
heating the thermal radiation sensor to a temperature that is substantially within a range of anticipated surface temperatures of the object;
receiving thermal radiation emanated from the object onto the thermal radiation sensor;
determining a thermal flux (I) of the thermal radiation emanated from the object according to an output signal of the thermal radiation sensor;
calculating the surface temperature of the object as a function of the thermal flux and the sensor temperature; and displaying the calculated temperature of the object on a display of the thermal radiation thermometer.
21. The method of remotely measuring a surface temperature according to claim 20, further comprising the step of heating or cooling the thermal radiation sensor to reach a sensor temperature that is substantially within a range of anticipated surface temperatures of the object.
22. The thermal radiation thermometer of claim 1 wherein an inner surface of the thermal shield is coated with a heat absorbing coating.
23. The method of claim 20 wherein an inner surface of the thermal shield is coated with a heat absorbing coating.
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PCT/US2009/061842 WO2010048505A1 (en) | 2008-10-23 | 2009-10-23 | Non-contact medical thermometer with stray radiation shielding |
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- 2009-10-23 JP JP2011533369A patent/JP2012507007A/en active Pending
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2015
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WO2010048505A1 (en) | 2010-04-29 |
MX2011004364A (en) | 2011-07-20 |
US8834019B2 (en) | 2014-09-16 |
CN102265125A (en) | 2011-11-30 |
EP2347233A1 (en) | 2011-07-27 |
JP2012507007A (en) | 2012-03-22 |
CA2762188A1 (en) | 2010-04-29 |
CN102265125B (en) | 2015-09-30 |
US20110228811A1 (en) | 2011-09-22 |
KR101622427B1 (en) | 2016-05-31 |
JP6389444B2 (en) | 2018-09-12 |
JP2015166743A (en) | 2015-09-24 |
KR20110089405A (en) | 2011-08-08 |
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