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Color compositions

 Russell Chianelli et al
The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis condition...
Inventors: Russell Chianelli, Lori A. Polette
Assignees: Board of Regents, The University of Texas System
Primary Examiner: Anthony J. Green
Attorney: Fulbright & Jaworski

U.S. Classification
106/401; 106/487; 534/15; 548/457

View patent at USPTO

Citations

Patent NumberTitleIssue date
1058021(unknown)Apr 1913
2940928(unknown)Jun 1960
3950180Coloring composites13 Apr 1976
4246036Colored composite material of the asbestos-cement or similar type and its manufacture20 Jan 1981
4640862Coated, heat shrinkable expanded polystyrene3 Feb 1987
4868018Artifical marble19 Sep 1989
4874433Methods of preparing encapsulated pigments17 Oct 1989
5061290Rope dyeing process using halogen indigo derivative and dyed article thus obtained29 Oct 1991
5574081Waterborne clay-containing emulsion paints with improved application performance12 Nov 1996
5807540Nail varnish composition comprising a crosslinked polyester15 Sep 1998
5942285Extrusion coating compositions and method24 Aug 1999
5972049Clay-containing dispersing composition for carriers used in the disperse dyeing of hydrophobic textiles26 Oct 1999
5993920Incombustible artificial marble and a process for preparation thereof30 Nov 1999
6033466Pigment and pigment ink by applying the pigment7 Mar 2000
6162646Urine pH indicator system and associated methods19 Dec 2000
6197849Organophilic phyllosilicates6 Mar 2001
6200378Thiazine indigo pigments, solid solutions thereof and their preparation13 Mar 2001
6252024Fluorescent N-alkylated acrylamide copolymers and optical pH sensors26 Jun 2001
6294012High strength monoazo yellow pigment25 Sep 2001
6303385Fluorescent N-alkylated acrylamide copolymers and optical pH sensors16 Oct 2001
6323270Polybenzoxazine nanocomposites of clay and method for making same27 Nov 2001
6339084Process for the production of thiazine-indigo pigments15 Jan 2002
6346145Paints containing low sheen opacifying pigments obtained by flux calcination of kaolin clay12 Feb 2002
6402826Kaolin clay pigment for paper coating and method for producing same11 Jun 2002

Referenced by

Patent NumberTitleIssue date
7425235Color compositions and methods of manufacture16 Sep 2008
7429294Color compositions30 Sep 2008

Claims

What is claimed is:

1. A coating composition comprising:

a) a molecular derivative of indigo; and

b) a fibrous or layered clay.

2. The coating composition of claim 1, wherein said coating composition has a color/hue that is determined by the concentration of said molecular derivative of indigo and a pH of said coating composition.

3. The coating composition of claim 1, wherein said coating composition has a particle size that is between 0.01 μm and 20 μm.

4. The coating composition of claim 3, wherein the particle size of said coating composition is between 0.1 μm and 2 μm.

5. The coating composition of claim 1, wherein said fibrous clay is a palygorskite clay, a sepiolite clay, or a mixture of a palygorskite and a sepiolite clay.

6. The coating composition of claim 1, wherein said layered clay is a kaolinite, bentonite, nontronite, or mordenite clay.

7. The coating composition of claim 1, wherein said molecular derivative of indigo is dibromoindigo or thioindigo.

8. The coating composition of claim 1, wherein the coating composition is a powder or a liquid.

9. The coating composition of claim 1, wherein said coating composition is resistant to decomposition by light.

10. The coating composition of claim 1, wherein said coating composition is resistant to decomposition by acids, alkalis, and solvents.

11. A composition comprising:

wherein:

R1-R8 are individually H, CH3, CH2CH3, F, Cl, Br, I, CN, OH, SH, OCH3 or OCH2CH3;

R9-R11 are individually SiO3, SiOH or H2O;

Y is N, O, S, or Se;

X is O or S;
M(n+) is Al, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Pt, Pd or Zn; and n is 1, 2, 3 or 4.

12. A formulation comprising:

a) a molecular derivative of indigo;

b) a palygorskite clay, a sepiolite clay, or a mixture of a palygorskite and a sepiolite clay;

c) a polymer; and

d) an organic binding agent.

13. A formulation comprising:

a) a molecular derivative of indigo;

b) a palygorskite clay, a sepiolite clay, or a mixture of a palygorskite and a sepiolite clay; and

c) a gum arabic, a linseed oil, a copal, a polycarbonate, an egg tempura, or a turpentine.

14. A shapeable molding material comprising:

a) a molecular derivative of indigo;

b) a palygorskite clay, a sepiolite clay, or a mixture of a palygorskite and a sepiolite clay; and

c) a cement, a plastics or a polymer.

15. A shapeable tile material comprising:

a) a molecular derivative of indigo;

b) a palygorskite clay, a sepiolite clay, or a mixture of a palygorskite and a sepiolite clay; and

c) a cement, a plastic or a polymer.

16. A method of producing a coating composition comprising:

a) obtaining a molecular derivative of indigo;

b) combining said molecular derivative of indigo with a fibrous or layered clay to form a coating composition;

c) heating said coating composition; and

d) making a pH adjustment to the coating composition.

17. The method of claim 16, further comprising treating said coating composition with acid to remove impurities from the clay.

18. The method of claim 16, further comprising applying said coating composition to a surface.

19. The method of claim 16, further comprising blending said coating composition with a polymer or organic binder.

20. The method of claim 16, further comprising homogenizing said coating composition by blending, grinding, milling or stirring.

21. The method of claim 16, wherein said heating comprises heating at a temperature of between 100° C. and 300° C.

22. The method of claim 21, wherein the temperature is between 115° C. and 150° C.

23. The method of claim 16, wherein said heating lasts a maximum of four days.

24. The method of claim 16, wherein said coating composition contains water.

25. The method of claim 16, wherein said coating composition has a pH between 3 and 7.5.

26. The method of claim 16, wherein said coating composition contains said molecular derivative of indigo in the range of 0.01% to 20% by weight.

27. The method of claim 16, wherein said molecular derivative of indigo is in the range of 0.1% to 7% by weight.

28. The method of claim 16, wherein said coating composition contains a molecular derivative of indigo at about 6% by weight at neutral or acidic pH.

29. The method of claim 16, wherein said fibrous clay is a palygorskite clay, a sepiolite clay, or a mixture of a palygorskite and a sepiolite clay.

30. The method of claim 16, wherein said layered clay is a kaolinite, bentonite, nontronite, or mordenite clay.

31. The method of claim 16, wherein said coating composition has a particle size that is between 0.01 μm and 20 μm.

32. The method of claim 31, wherein the particle size of said coating composition is between 0.1 μm and 2 μm.

33. The method of claim 16, wherein said molecular derivative of indigo is thioindigo or dibromoindigo.

34. The method of claim 16, further comprising adding a binding agent to said coating composition.