WO2011119386A3 - High voltage battery formation protocols and control of charging and discharging for desirable long term cyycling performance - Google Patents

High voltage battery formation protocols and control of charging and discharging for desirable long term cyycling performance Download PDF

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Publication number
WO2011119386A3
WO2011119386A3 PCT/US2011/028604 US2011028604W WO2011119386A3 WO 2011119386 A3 WO2011119386 A3 WO 2011119386A3 US 2011028604 W US2011028604 W US 2011028604W WO 2011119386 A3 WO2011119386 A3 WO 2011119386A3
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WO
WIPO (PCT)
Prior art keywords
battery
high voltage
charging
discharging
cycling
Prior art date
Application number
PCT/US2011/028604
Other languages
French (fr)
Other versions
WO2011119386A2 (en
Inventor
Shabab Amiruddin
Subramanian Venkatachalam
Herman Lopez
Sujeet Kumar
Original Assignee
Envia Systems, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Envia Systems, Inc. filed Critical Envia Systems, Inc.
Priority to CN201180020782XA priority Critical patent/CN102859778A/en
Priority to KR1020127027070A priority patent/KR20130060180A/en
Priority to JP2013501310A priority patent/JP2013524413A/en
Priority to EP11759922A priority patent/EP2553753A2/en
Publication of WO2011119386A2 publication Critical patent/WO2011119386A2/en
Publication of WO2011119386A3 publication Critical patent/WO2011119386A3/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0438—Processes of manufacture in general by electrochemical processing
    • H01M4/044—Activating, forming or electrochemical attack of the supporting material
    • H01M4/0445—Forming after manufacture of the electrode, e.g. first charge, cycling
    • H01M4/0447—Forming after manufacture of the electrode, e.g. first charge, cycling of complete cells or cells stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/0069—Charging or discharging for charge maintenance, battery initiation or rejuvenation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H01M10/446—Initial charging measures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Power Engineering (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Improved cycling of high voltage lithium ion batteries is accomplished through the use of a formation step that seems to form a more stable structure for subsequent cycling and through the improved management of the charge-discharge cycling. In particular, the formation charge for the battery can be performed at a lower voltage prior to full activation of the battery through a charge to the specified operational voltage of the battery. With respect to management of the charging and discharging of the battery, it has been discovered that for the lithium rich high voltage compositions of interest that a deeper discharge can preserve the cycling capacity at a greater number of cycles. Battery management can be designed to exploit the improved cycling capacity obtained with deeper discharges of the battery.
PCT/US2011/028604 2010-03-26 2011-03-16 High voltage battery formation protocols and control of charging and discharging for desirable long term cyycling performance WO2011119386A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201180020782XA CN102859778A (en) 2010-03-26 2011-03-16 High voltage battery formation protocols and control of charging and discharging for desirable long term cycling performance
KR1020127027070A KR20130060180A (en) 2010-03-26 2011-03-16 High voltage battery formation protocols and control of charging and discharging for desirable long term cycling performance
JP2013501310A JP2013524413A (en) 2010-03-26 2011-03-16 High voltage battery formation protocol and charge and discharge control for desirable long-term cycle performance
EP11759922A EP2553753A2 (en) 2010-03-26 2011-03-16 High voltage battery formation protocols and control of charging and discharging for desirable long term cyycling performance

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/732,520 US8765306B2 (en) 2010-03-26 2010-03-26 High voltage battery formation protocols and control of charging and discharging for desirable long term cycling performance
US12/732,520 2010-03-26

Publications (2)

Publication Number Publication Date
WO2011119386A2 WO2011119386A2 (en) 2011-09-29
WO2011119386A3 true WO2011119386A3 (en) 2012-04-05

Family

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Family Applications (1)

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PCT/US2011/028604 WO2011119386A2 (en) 2010-03-26 2011-03-16 High voltage battery formation protocols and control of charging and discharging for desirable long term cyycling performance

Country Status (7)

Country Link
US (1) US8765306B2 (en)
EP (1) EP2553753A2 (en)
JP (1) JP2013524413A (en)
KR (1) KR20130060180A (en)
CN (1) CN102859778A (en)
TW (1) TW201145651A (en)
WO (1) WO2011119386A2 (en)

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