WO2007055938A3 - Selective catalyst reduction of nitrogen oxides with hydrogen - Google Patents

Selective catalyst reduction of nitrogen oxides with hydrogen Download PDF

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Publication number
WO2007055938A3
WO2007055938A3 PCT/US2006/042151 US2006042151W WO2007055938A3 WO 2007055938 A3 WO2007055938 A3 WO 2007055938A3 US 2006042151 W US2006042151 W US 2006042151W WO 2007055938 A3 WO2007055938 A3 WO 2007055938A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
nitrogen oxides
selective catalyst
catalyst reduction
formula
Prior art date
Application number
PCT/US2006/042151
Other languages
French (fr)
Other versions
WO2007055938A2 (en
Inventor
Fabrizio C Rinaldi
Ralph T Yang
Gongshin Qi
Original Assignee
Tenneco Automotive Operating
Fabrizio C Rinaldi
Ralph T Yang
Gongshin Qi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tenneco Automotive Operating, Fabrizio C Rinaldi, Ralph T Yang, Gongshin Qi filed Critical Tenneco Automotive Operating
Priority to CN2006800415056A priority Critical patent/CN101506481B/en
Priority to KR1020087013450A priority patent/KR101395731B1/en
Priority to BRPI0618367-0A priority patent/BRPI0618367A2/en
Priority to JP2008540045A priority patent/JP4927862B2/en
Priority to DE112006003078T priority patent/DE112006003078T5/en
Publication of WO2007055938A2 publication Critical patent/WO2007055938A2/en
Priority to GB0808179A priority patent/GB2446324A/en
Publication of WO2007055938A3 publication Critical patent/WO2007055938A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/202—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/204—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/402—Dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/01—Engine exhaust gases
    • B01D2258/012—Diesel engines and lean burn gasoline engines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)

Abstract

A system and method for reducing nitrous oxides in diesel exhaust with hydrogen and carbon monoxide over a palladium based catalyst. The catalyst comprises a compound represented by the formula: X% Pd - Y% V2O5 / Z, where X is between about 0.1 to about 2.0, Y is between about 0.1 to about 7.0, and Z is an oxide support.
PCT/US2006/042151 2005-11-08 2006-10-26 Selective catalyst reduction of nitrogen oxides with hydrogen WO2007055938A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN2006800415056A CN101506481B (en) 2005-11-08 2006-10-26 Selective catalyst reduction of nitrogen oxides with hydrogen
KR1020087013450A KR101395731B1 (en) 2005-11-08 2006-10-26 Selective catalyst reduction of nitrogen oxides with hydrogen
BRPI0618367-0A BRPI0618367A2 (en) 2005-11-08 2006-10-26 catalytically selective reduction of nitrogen oxides with hydrogen
JP2008540045A JP4927862B2 (en) 2005-11-08 2006-10-26 Selective catalytic reduction of nitrogen oxides with hydrogen.
DE112006003078T DE112006003078T5 (en) 2005-11-08 2006-10-26 Selective catalytic reduction of nitrogen oxide with hydrogen
GB0808179A GB2446324A (en) 2005-11-08 2008-05-07 Selective catalyst reduction of nitrogen oxides with hydrogen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/269,124 US7712308B2 (en) 2005-11-08 2005-11-08 Selective catalyst reduction of nitrogen oxides with hydrogen
US11/269,124 2005-11-08

Publications (2)

Publication Number Publication Date
WO2007055938A2 WO2007055938A2 (en) 2007-05-18
WO2007055938A3 true WO2007055938A3 (en) 2009-05-07

Family

ID=38003934

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/042151 WO2007055938A2 (en) 2005-11-08 2006-10-26 Selective catalyst reduction of nitrogen oxides with hydrogen

Country Status (8)

Country Link
US (1) US7712308B2 (en)
JP (1) JP4927862B2 (en)
KR (1) KR101395731B1 (en)
CN (1) CN101506481B (en)
BR (1) BRPI0618367A2 (en)
DE (1) DE112006003078T5 (en)
GB (1) GB2446324A (en)
WO (1) WO2007055938A2 (en)

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DE102006012206A1 (en) * 2006-03-16 2007-09-20 Linde Ag Process for the removal of nitrogen oxides from flue gases from incinerators
US7820583B2 (en) * 2006-08-24 2010-10-26 Millennium Inorganic Chemicals, Inc. Nanocomposite particle and process of preparing the same
JP2010075787A (en) * 2008-09-24 2010-04-08 Mitsubishi Motors Corp Exhaust cleaning catalyst for use in internal combustion engine
GB2485530A (en) * 2010-11-11 2012-05-23 Johnson Matthey Plc Catalyst system
CN102008956B (en) * 2010-12-27 2012-10-24 国电科学技术研究院 Preparation method of low-temperature selective catalytic reduction (SCR) catalyst by removing NOx from flue gas
DE102011013271A1 (en) 2011-03-07 2012-09-13 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Process and plant for the reduction of nitrogen oxide emissions during steam reforming
CN102489294B (en) * 2011-12-22 2013-06-19 国电科学技术研究院 Low-temperature SCR catalyst prepared by extrusion molding, and preparation method thereof
KR101907147B1 (en) * 2012-03-28 2018-10-12 현대중공업 주식회사 Metallic filter for exhaust gas of marine
KR101318978B1 (en) * 2013-07-29 2013-10-17 대구대학교 산학협력단 A method of removing nitrous oxide in flue gases using low-temperature catalytic reduction
KR101798713B1 (en) 2015-07-15 2017-11-16 현대중공업 주식회사 SCR Catalyst for Nitrogen Oxide Removal and Manufacturing method thereof
DE102016107466A1 (en) 2016-04-22 2017-10-26 Keyou GmbH Catalyst, apparatus and method for selectively reducing NOx by means of hydrogen in exhaust gases containing NOx
CN106732699A (en) * 2016-12-26 2017-05-31 内蒙古华元科技有限公司 One kind is for coal steam-electric plant smoke denitration wide temperature range type Ti-base catalyst and preparation method thereof
KR20200054245A (en) * 2017-09-15 2020-05-19 할도르 토프쉐 에이/에스 Method for performing selective catalytic reduction of coke oven flue gas
DE102017124541A1 (en) 2017-10-20 2019-04-25 Argomotive Gmbh Apparatus for aftertreatment of exhaust gases of an internal combustion engine
DE102018127219A1 (en) 2018-10-31 2020-04-30 Keyou GmbH Catalyst for use in selective NOx reduction in NOx-containing exhaust gases, method for producing a catalyst, device for selective NOx reduction and method for selective NOx reduction
CN109589976B (en) * 2018-12-31 2021-08-17 天津大学 Catalyst for diesel engine based on oxide composite main catalyst and preparation method thereof

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Also Published As

Publication number Publication date
WO2007055938A2 (en) 2007-05-18
JP2009515095A (en) 2009-04-09
GB2446324A (en) 2008-08-06
KR101395731B1 (en) 2014-05-15
CN101506481B (en) 2011-07-27
JP4927862B2 (en) 2012-05-09
KR20080075145A (en) 2008-08-14
DE112006003078T5 (en) 2008-10-02
GB0808179D0 (en) 2008-06-11
US20070104633A1 (en) 2007-05-10
US7712308B2 (en) 2010-05-11
CN101506481A (en) 2009-08-12
BRPI0618367A2 (en) 2011-08-30

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