WO2006126833A1 - Immersed hollow fiber membrane module - Google Patents

Immersed hollow fiber membrane module Download PDF

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Publication number
WO2006126833A1
WO2006126833A1 PCT/KR2006/001951 KR2006001951W WO2006126833A1 WO 2006126833 A1 WO2006126833 A1 WO 2006126833A1 KR 2006001951 W KR2006001951 W KR 2006001951W WO 2006126833 A1 WO2006126833 A1 WO 2006126833A1
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WIPO (PCT)
Prior art keywords
hollow fiber
fiber membrane
air
immersed
treated water
Prior art date
Application number
PCT/KR2006/001951
Other languages
French (fr)
Inventor
Sang Hoon Kim
Hang Duk Rho
Sung Su Bae
Tae Jeong Kim
Tae Duog Lee
Sung Du Leem
Original Assignee
Sk Chemicals Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sk Chemicals Co., Ltd. filed Critical Sk Chemicals Co., Ltd.
Publication of WO2006126833A1 publication Critical patent/WO2006126833A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/0233Manufacturing thereof forming the bundle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/022Encapsulating hollow fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/022Encapsulating hollow fibres
    • B01D63/0221Encapsulating hollow fibres using a mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/026Wafer type modules or flat-surface type modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/04Hollow fibre modules comprising multiple hollow fibre assemblies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/003Membrane bonding or sealing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08Prevention of membrane fouling or of concentration polarisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/02Specific tightening or locking mechanisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2315/00Details relating to the membrane module operation
    • B01D2315/06Submerged-type; Immersion type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/02Forward flushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/18Use of gases
    • B01D2321/185Aeration

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention relates to an immersed hollow fiber membrane module. More particularly, the present invention relates to an immersed hollow- fiber membrane module into which a guide for protecting and supporting the hollow fiber membrane and a new type of air diffuser to prevent entanglement and damage of the hollow fiber membrane and minimize fouling of the hollow fiber membrane.

Description

IMMERSED HOLLOW FIBER MEMBRANE MODULE
Technical Field
The present invention relates to an immersed hollow fiber membrane
module, particularly to an immersed hollow fiber membrane module into which a
guide for protecting and supporting the hollow fiber membrane and a new type of
air diffuser to prevent entanglement and damage of the hollow fiber membrane and
minimize fouling of the hollow fiber membrane.
Background Art
Since its first introduction for water purification and treatment of sewage
and wastewater in the 1960s, the use of a separation membrane has been increased
by leaps and bounds. Till now, the separation membrane has been mainly used for
advanced treatment, or treatment of primarily treated wastewater to further
improve the quality of water.
Although the conventional method provides relatively good quality of water,
it has disadvantages that there is required an additional facility for a separation
membrane process, thus increasing costs for installation, operation and maintenance.
To solve this problem, Kazuo Yamamoto et al. conducted the first successful experimentation of treating wastewater by immersing hollow fiber membrane
directly in the aeration tank based ("Direct Solid-Liquid Separation Using Hollow
Fiber Membrane in an Activated Sludge Aeration Tank") in 1989, and this resulted
in the rapid development in the membrane bioreactor (MBR) process.
The MBR process offers are considered very advantageous as set forth below.
First, the concentration (MLSS) of the activated sludge can be maintained at a
relatively higher level (8,000-15,000 ppm) than that of the conventional activated
sludge process, and thus sewage can be treated with less retention time, thereby
reducing the space required for sewage treatment. Second, stable sewage treatment
is possible even when the activated sludge does not sediment well, which may occur
in such bacterial process as the standard activated sludge process, because of organic
shock loading, bulking, foaming, etc.
However, the MBR process is prone to contamination of the separation
membrane, or membrane fouling.
Sewage treatment using separation membrane is mostly driven by pressure
difference. Membrane fouling resulting from the accumulation of activated sludge
or other membrane fouling materials on the surface or in the pores of the membrane
reduces effective membrane surface area and, thereby, reduces treatment capacity.
Many researchers have made extensive efforts to develop materials for separation membrane which are resistant to membrane fouling. Also, studies have
been also made on the method to induce a cross flow on the membrane surface.
Researches on the separation membrane materials have been mainly focused
on modifying the membrane surface to have hydrophilic property using surfactants,
plasma, etc. Also, researches on physical solutions using air flow on the membrane
surface, especially by inducing a cross flow to sweep off the sludge cake
accumulated on the membrane surface or preventing the accumulation, have been
performed.
The conventional hollow fiber membrane modules for solving the membrane
fouling problem are as follows.
The hollow fiber membrane modules of Mitsubishi Rayon and Zenon are of
the type with the treated water collectors positioned at both ends. In these modules,
the water treated by the separation membrane is collected at the collectors and
transferred to the treatment tank by pumps.
In this type of modules, the movement of the hollow fiber membrane is
restricted because its both ends are fastened to the treated water collectors.
Consequently, despite the cross flow of treated water by air supply (supplied to the
hollow fiber membrane surface) or the physical shaking by air supply (vibration),
the sludge accumulated on the hollow fiber membrane is not removed easily. Especially, the hollow fiber membrane modules of the two companies have
two locations where decompression occurs first (i.e., the locations where the
pressure difference is largest) and strong sludge accumulation there cannot be
prevented.
The module of Zenon also has a problem that the activated sludge carried
upward by the air supplied at the bottom does not completely escape from the top
collector but is accumulated therein, resulting in an interrupted flow and
accumulation of sludge. In addition, because the air diffuser is equipped at the
bottom of the module, air is not directly transferred to the hollow fiber membrane
module, resulting in increased air loss. As a result, the energy required for
maintaining the air supply accounts for 30 to 70 % of total power consumption.
Such inefficient air supply triggers propagation of membrane fouling
(especially by sludge cake) to the region with larger pressure difference, or to the
less contaminated region. Consequently, the entire hollow fiber membrane is
contaminated, thereby reducing the cycle of maintenance cleaning and the durability
of the hollow fiber membrane.
The conventional hollow fiber membrane modules with the treated water
collector positioned at one end to solve the membrane fouling problem (the other
end is free end) are as follows. Although the use may be said to be different, a similar module with the
collector positioned at one end was disclosed in "Use of Sealed-End Hollow Fibers
for Bubbleless Membrane Aeration: Experimental Studies" by T. Ahmed et al. in
1992.
In addition, modules almost identical to that of the above paper are disclosed
in JP 11128692 by filed Toray and in JP 10202270 filed by Kuraray.
These modules are quite differently from the modules with the collectors
positioned at both ends in operation type, productivity and durability. As is often
found in the Toray's module, the sealed part at one end of the hollow fiber
membrane tends to be cut off during operation. Besides the durability problem,
membrane fouling is hardly reduced because of lack of air supply.
The most frequently occurring problem of the module with only one end of
the hollow fiber membrane fastened is that the hollow fiber membrane becomes
entangled as it falls or abnormal treated water flow happens because of a
non-uniform air flow. Physical stress is focused on the entangled region, resulting
in cutting off at the entangled part or at the interface with a binder.
The hollow fiber membrane (separation membrane) may not fall during the
operation of inside the aeration tank, but it may fall easily as the hollow fiber
membrane module is taken out of the aeration tank for maintenance or other purposes. And, the hollow fiber membrane may get entangled when the air
diffuser is inclined during the operation. In that case, there occurs water pressure
difference in the air diffuser. Less air is supplied at the region with higher water
pressure, while more air is supplied at the region with lower water pressure,
resulting in flow from the higher air supply region to the lower air supply region,
which makes the hollow fiber membrane entangled.
Also, if the hollow fiber membrane module is inclined, a regularly patterned
flow cannot be induced because the supplied air reaches different regions of the
module. The resultant abnormal flow causes counterflow in the module, thereby
resulting in entanglement of the hollow fiber membrane. Physical stress is focused
on the entangled region, resulting in cutting off at the entangled part or at the
interface with a binder.
Disclosure of the Invention
The present invention was come up with in order to solve the
afore-mentioned problems. An object of the present invention is to provide an
immersed hollow fiber membrane module in which a guide for protecting the
hollow fiber membrane is used to prevent tilting or entanglement of the hollow fiber
membrane and an air diffuser with new structure is provided at the guide, so that contamination of the hollow fiber membrane surface can be minimized with a small
amount of air.
In order to attain the above goal, the present invention provides an
immersed hollow fiber membrane module comprising: a hollow fiber membrane
bundle, wherein the top end is sealed as a free end and the bottom end is open; a
bottom collector which comprises an upper block to which the bottom end of the
hollow fiber membrane bundle is fastened by a binder and a lower block at which
the treated water discharged from the hollow fiber membrane is collected; an air
diffuser which is formed on the upper block; an air supply pipe which is vertically
connected to the air diffuser; a treated water discharge pipe which is vertically
connected to the inside of the lower block; and a guide which encloses and protects
the entire hollow fiber membrane bundle wherein the bottom end of the guide is
engaged with the top surface of the upper block.
Preferably, the guide is squared and has a wastewater inlet which penetrates
the lower part of the guide from the front to the back.
The upper block of the bottom collector is squared and has a fastening means,
at which the hollow fiber membrane bundle is bound and fastened by a guider, on
the top; a united hole, through which the treated water discharge pipe passes, at one
end; and a united protrusion, by which the lower block is engaged, at the bottom. The lower block of the bottom collector is also squared and has an engaging
groove, in which the engaging protrusion is seated, on the top; a collection passage
for the treated water discharged from the open bottom end of the hollow fiber
membrane bundle, inside the engaging groove; and a united hole, through which
the treated water discharge pipe passes, at one end.
Preferably, the air diffuser comprises: an air inlet which is formed on one end
of the upper block (at the opposite side of the engagement hole), so that the bottom
end of the air supply pipe can be inserted; air supply lines which are connected with
the air inlet and are formed along the edge of the fastening means by which the
hollow fiber membrane bundle is fastened; and a plurality of air nozzles formed at
the air supply lines with equal spacing, with an angle of 45° to 65° to the hollow
fiber membrane, as injection holes.
Several of such immersed hollow fiber membrane modules are installed
inside a cassette of a SKID frame depending on the capacity of the aeration tank.
Preferably, on each end of the cassette are attached an air supply main pipe,
which is connected to the air supply pipe of each of the immersed hollow fiber
membrane modules, and a final discharge pipe, which is connected to each of the
treated water discharge pipe.
Hereinafter, the embodiments of the present invention will be described in detail with reference to accompanying drawings.
Fig. 1 and Fig. 2 are perspective views of the immersed hollow fiber
membrane module according to the present invention and Fig. 3 is a perspective
view illustrating the state in which several hollow fiber membrane modules are
installed inside a cassette.
The subject matter of the present invention is that a squared guide for
protecting the hollow fiber membrane bundle is used to prevent tilting,
entanglement and damage of the hollow fiber membrane and that a new type of air
diffuser is equipped at the bottom collector in order to minimize contamination of
the hollow fiber membrane surface with a small amount of air.
The immersed hollow fiber membrane module of the present invention
comprises a hollow fiber membrane (10), a bottom collector (12), a guide (14) for
protecting the hollow fiber membrane, an air diffuser, etc.
As seen in Fig. 1, the top end of the individual hollow fiber membrane (10) is
sealed as free end and the bottom end is in the form of open tube. The bottom end
of the hollow fiber membrane bundle is fastened to the bottom collector (12) by a
binder (16: adhesive).
In another embodiment, as seen in Fig. 2, the entire top end of the hollow
fiber membrane bundle (10) may be sealed by a sealant (adhesive). The squared guide (14) is fixed on the bottom collector (12). The hollow-
fiber membrane bundle (10) is accommodated inside the guide (14) to prevent the
hollow fiber membrane (10) from being tilted, entangled and damaged.
That is, when external force (e.g., flow of air or wastewater) is applied to the
hollow fiber membrane (10), the squared guide (14) prevents the hollow fiber
membrane (10) from being tilted, entangled and damaged by supporting the hollow
fiber membrane (10).
The guide (14) has a wastewater inlet (18) which penetrates the lower part of
the guide (14) from the front to the back.
The construction of a bottom collector having an air diffuser is as follows.
Fig. 4 and Fig. 5 show perspective views of the collector of the immersed
hollow fiber membrane module in accordance with the present invention showing
the separated state. And, Fig. 6 is a perspective view showing the assembled state.
The bottom collector (12) comprises an upper block (20), to which the bottom
end of a hollow fiber membrane bundle (10) is fastened by a binder (16), and a lower
block (22), at which the treated water discharged from the bottom end of the hollow
fiber membrane (10) is collected.
The upper block (20) of the bottom collector (12) is a squared block and has a
fastening means (24), at which the hollow fiber membrane bundle (10) is bound and fastened by the binder (16), on the top, an engagement hole (28), through which a
treated water discharge pipe (30) passes, at one end, and an engaging protrusion (32),
by which the lower block (22) is engaged, at the bottom.
The fastening means (24) has a stair-shaped leak bump (58) at the inner
circumference for preventing leakage caused by contraction of the binder (16).
After the bottom end of the hollow fiber membrane bundle (10) is bonded
and fastened to the fastening means (24) of the upper block (20) by molding with an
adhesive, the bottom end of the hollow fiber membrane bundle (10) protruding out
of the fastening means (24) is cut off along with the binder. As a result, the bottom
end of the hollow fiber membrane bundle (10) is aligned parallel to the engaging
protrusion (32) and becomes opened.
The upper block (20) is also equipped with an air diffuser. An air inlet (34)
is formed on one end of the upper block (20) [at the opposite side of the engagement
hole (28)]. A pair of air supply lines (36) are formed along the edge of the fastening
means (24) by which the hollow fiber membrane bundle (10) is fastened. And a
plurality of air nozzles are formed at the air supply lines with equal spacing,
resulting in an air supply passage.
The air nozzles (38) are formed with an angle of from 45° to 65° with
reference to the hollow fiber membrane bundle (10), as injection holes. The air inlet (34) of the upper block (20) is engaged with the bottom end of an
air supply pipe (40) and the engagement hole (28) at the opposite side is engaged
with the bottom end of a treated water discharge pipe (30). The air supply pipe (40)
and the treated water discharge pipe (30) are set upright and stretch to the top end
of the guide (14), as accommodated in the guide (14).
The lower block (22) of the bottom collector (12) is squared and matches the
bottom of the upper block (20). The lower block (22) has an engaging groove (42),
in which an engaging protrusion (32) formed at the bottom of the upper block (20) is
seated, on the top; a collection passage (44) for the treated water discharged from the
open bottom end of the hollow fiber membrane bundle (10), inside the engaging
groove (42); and an insertion hole (46), through which the treated water discharge
pipe (30) passes, at one end.
The upper block (20) and the lower block (22) are assembled as follows. The
engaging protrusion (32) of the upper block (20) is inserted into the engaging groove
(42) of the lower block (22) and bolts (48) are inserted into a plurality of bolt holes
formed along the edge of the upper block (20) and the lower block (22). The bottom
end of the hollow fiber membrane bundle (10) is cut off, so that it is aligned parallel
to the engaging protrusion (32) and becomes open and connected to the treated
water collection passage (44) of the lower block (22). A rubber seal (50) is equipped on top of the lower block (22) at which it
engages with the upper block (20), i.e., along the outer circumference of the
engaging groove (42), in order to prevent the treated water collected at the collection
passage (44) of the lower block (22) from being leaked.
Several of such immersed hollow fiber membrane modules are installed
inside a cassette (52), or a framework, depending on the capacity of the aeration tank,
as seen in Fig. 3.
On each end of the cassette (52) are attached an air supply main pipe (54),
which is connected to the air supply pipe (40) of each of the immersed hollow fiber
membrane modules, and a final discharge pipe (56), which is connected to each of
the treated water discharge pipe (30).
Of course, the air supply main pipe (54) is connected to an air supply means
(not shown) and the final discharge pipe (56) is connected to a container for
collecting or post-treating the treated water.
The immersed hollow fiber membrane module of the present invention is
operated as follows.
First, a cassette (52) in which several immersed hollow fiber membrane
modules are installed is immersed in an aeration tank (not shown) containing
wastewater. Then, the wastewater in the aeration tank flows toward the hollow fiber
membrane bundle (10) through the inlet (18) of the guide (14). At the same time,
the wastewater is passed through the hollow fiber membrane (10) by external
pressure, while being filtered.
The hollow fiber membrane (10) may be, for example, a tube having an outer
diameter ranging from 0.2 to 4.2 mm and an inner diameter ranging from 0.05 to 4.1
mm made of polysulfone, sulfonated polysulfone, polyethersulfone, polyvinylidene
fluoride, etc. It has numerous micropore size that are hardly discernible with eyes.
That is, the wastewater is filtered while it passes from the outside to the
inside of the hollow fiber membrane (10).
The filtered treated water flows down inside the hollow fiber membrane (10)
and is collected at the treated water collection passage (44) of the lower block (22) of
the bottom collector (12).
Subsequently, the treated water collected at the treated water collection
passage (44) of the lower block (22) is discharged through the treated water
discharge pipe (30) inserted in the insertion hole (46) of the lower block (22), as seen
in Fig. 9. Then, the treated water flows into the facility for post-treatment or
collection through a final discharge pipe (56), which is formed from the combination
of the treated water discharge pipe (30) of each hollow fiber membrane module. As the wastewater is filtered, the surface of the hollow fiber membrane is
contaminated by impurities (dirt, cake, clog), particularly by sludge cake. The air
diffuser removes the impurities to prevent membrane fouling.
Removal of impurities by the air diffuser may be carried out as follows.
Air may be sprayed on the surface of the hollow fiber membrane (10) to
detach sludge cake or other impurities. Especially, by inducing cross flow of
wastewater with the sprayed air, accumulation of sludge cake on the membrane
surface can be prevented.
First, air is supplied to the air supply pipe (40) of each hollow fiber
membrane module through the air supply main pipe (54) equipped on one end of
the cassette (14) (see Fig. 7).
Subsequently, the air is supplied to the pair of air supply lines (36) through
the air inlet (34) of the upper block (20). Finally, it is sprayed through the air
nozzles (38: injection holes formed at an angle of about 45° to 65° to the hollow
fiber membrane) formed on the air supply lines (36) with equal spacing (see Fig. 8).
Since air is sprayed uniformly at the front and back of the bottom end of the
hollow fiber membrane bundle (10), impurities can be removed easily with a small
amount of air.
As a result, bubbles formed in the wastewater by the air sprayed through the air nozzles (38) offer the effect of scrubbing and vibration as they rise, thereby
removing sludge cake or other impurities accumulated on the surface of the hollow
fiber membrane (10).
As seen in Fig. 10, the wastewater is filtered in the horizontal direction
[perpendicular to the hollow fiber membrane (10)], while the air and the bubbles rise
upward.
More particularly, the filtering direction of the wastewater and the rising
direction of the bubbles are perpendicular to each other and, thus, induce cross flow.
The cross flow removes impurities as they are accumulated on the surface of the
hollow fiber membrane (10) and, thus, minimizes membrane fouling.
In conventional methods, an abnormal flow of wastewater or a non-uniform
flow of air causes falling or entanglement of the hollow fiber membrane, thereby
resulting in the cutting off of the hollow fiber membrane. In contrast, the present
invention is free from such problem because the hollow fiber membrane bundle (10)
is installed in the squared guide (14).
That is, even when physical stress caused by abnormal flow is accumulated
on the hollow fiber membrane (10), the squared guide (14) supports the hollow fiber
membrane (10) and prevents it from falling or being entangled. Brief Description of the Drawings
Fig. 1 is a perspective view of the immersed hollow fiber membrane module
according to the present invention.
Fig. 2 is a perspective view of the immersed hollow fiber membrane module
according to another embodiment of the present invention.
Fig. 3 is a perspective view illustrating the state in which several of the
hollow fiber membrane modules shown in Fig. 1 are installed inside a cassette.
Fig. 4 and Fig. 5 are perspective views of the collector of the immersed
hollow fiber membrane module in accordance with the present invention showing
the separated state.
Fig. 6 is a perspective view of the collector of the immersed hollow fiber
membrane module in accordance with the present invention showing the assembled
state.
Fig. 7 is a cross-sectional view of Fig. 6 along the line A-A.
Fig. 8 is a cross-sectional view of Fig. 6 along the line B-B.
Fig. 9 is a cross-sectional view of Fig. 6 along the line C-C.
Fig. 10 is a schematic diagram for illustrating the process by which the cross
flow of wastewater is induced by the action of the air diffuser of the immersed
hollow fiber membrane module in accordance with the present invention. Fig. 11 is a graph showing the membrane resistance of the immersed hollow
fiber membrane module with or without a guide.
Best Mode for Carrying Out the Invention
Practical and preferred embodiments of the present invention are illustrated
as shown in the following examples. However, it will be appreciated that those
skilled in the art may, in consideration of this disclosure, make modifications or
improvements within the spirit and scope of the present invention.
As can be seen in the result of Experimental Examples 1 and 2 below, the
immersed hollow fiber membrane module of the present invention experienced little
damage of the hollow fiber membrane and used 1/3 of air compared with the
conventional methods. Thus, 30 to 70 % of energy saving can be attained with
regard to operation and maintenance.
Experimental Example 1
An experiment was performed to compare air consumption by the immersed
hollow fiber membrane module in accordance with present invention and the
conventional hollow fiber membrane module.
At an activated-sludge concentration (MLSS: mixed liquor suspended solids) of 8,000, the modules of the present invention, M company and Z company were
operated at a fixed flux (throughput) of 25 LMH (L/m2/hr). The surface area of
each hollow fiber membrane was 1 m2.
Operation scheme is as follows: constant-flow operation using inverter;
normal washing for 14 minutes and reverse washing for 1 minute. The optimum
air amount was determined by varying air flow until there was no change in
pressure and flow rate.
As seen in Table 1 below, the amount of air required to prevent membrane
fouling was 0.08 Nm3/min-module for the present invention, about 1/3 that of the
conventional methods.
Table 1
Figure imgf000021_0001
Experimental Example 2
Maintenance cost of the immersed hollow fiber membrane module of the
present invention was compared with those of M company and Z company at an
MBR sewage works.
Power consumption by the hollow fiber membrane module for air supply accounted for 30 % or more of the total power consumption, which means that air
supply takes up quite a large portion of the management cost.
As seen in Table 2 below, the present invention reduced about 40 % of
management cost.
Table 2
Maintenance cost per ton (unit: won/m3)
Figure imgf000022_0001
Experimental Example 3
Membrane fouling of the immersed hollow fiber membrane module of the
present invention was measured with or without the squared guide. The result is
shown in Fig. 11.
As seen in Fig. 11, the membrane resistance differed as much as double
depending on the presence of the guide. When there was no guide, membrane
fouling was accelerated because of air loss, thereby increasing the membrane
resistance. To conclude, the guide used in the immersed hollow fiber membrane module
of the present invention prevents tilting and entanglement of the hollow fiber
membrane while minimizing air loss. As a result, the membrane resistance
constant of the hollow fiber membrane remains at a level almost same as that of the
initial one and thus membrane fouling can be minimized.
Industrial Applicability
As apparent from the foregoing description, the immersed hollow fiber
membrane module in accordance with the present invention offers the following
advantageous effects.
1) With the air supplied from the air diffuser inside the bottom collector,
impurities (dirt, cake, clog) can be easily removed from the hollow fiber membrane.
Therefore, the problems of entanglement and cutting off of the hollow fiber
membrane and membrane fouling can be resolved.
2) The air supplied from the air diffuser induces cross flow inside the guide,
which prevents the air from leaking outward while offering quick flow inside the
guide. Therefore, accumulation of impurities on the surface of the hollow fiber
membrane can be prevented effectively.
3) Although the tope end of the hollow fiber membrane is sealed as free end, the protective and supporting action of the guide prevents the hollow fiber
membrane from tilting or being entangled.
4) Several of the squared hollow fiber membrane modules of the present
invention can be installed to cope with large capacity. The small spacing between
each module saves installation space as compared with the conventional immersed
modules.
5) Damage of membrane can be checked during operation. That is, damage
of the hollow fiber membrane can be checked from air pressure difference and visual
inspection.
6) The immersed hollow fiber membrane module of the present invention
can reduce air consumption to about 1/3, compared with the conventional
immersed hollow fiber membrane modules, and saves operation and maintenance
cost by 30 to 70 %.
Those skilled in the art will appreciate that the concepts and specific
embodiments disclosed in the foregoing description may be readily utilized as a
basis for modifying or designing other embodiments for carrying out the same
purposes of the present invention. Those skilled in the art will also appreciate that
such equivalent embodiments do not depart from the spirit and scope of the present
invention as set forth in the appended claims.

Claims

Claims
1. An immersed hollow fiber membrane module comprising:
(a) a hollow fiber membrane bundle, wherein the top end is sealed as a free
end and the bottom end is open;
(b) a bottom collector which comprises an upper block to which the bottom
end of the hollow fiber membrane bundle is fastened by a binder and a lower block
at which the treated water discharged from the hollow fiber membrane is collected;
(c) an air diffuser which is formed on the upper block;
(d) an air supply pipe which is vertically connected to the air diffuser;
(e) a treated water discharge pipe which is vertically connected to the inside
of the lower block; and
(f) a guide which encloses and protects the entire hollow fiber membrane
bundle wherein the bottom end of guide is engaged with the top surface of the
upper block.
2. The immersed hollow fiber membrane module as set forth in Claim 1,
wherein the guide is squared and has a wastewater inlet which penetrates the lower
part of the guide from the front to the back.
3. The immersed hollow fiber membrane module as set forth in Claim 1,
wherein the upper block of the bottom collector is squared and has (a) a fastening
means, at which the hollow fiber membrane bundle is bound and fastened by a
binder, on the top; (b) an engagement hole, through which the treated water
discharge pipe passes, at one end; and (c) an engaging protrusion, by which the
lower block is engaged, at the bottom.
4. The immersed hollow fiber membrane module as set forth in Claim 1,
wherein the lower block of the bottom collector is also squared and has (a) an
engaging groove, in which the engaging protrusion is seated, on the top; (b) a
collection passage for the treated water discharged from the open bottom end of the
hollow fiber membrane bundle, inside the engaging groove; and (c) an insertion hole,
through which the treated water discharge pipe passes, at one end.
5. The immersed hollow fiber membrane module as set forth in Claim 1,
wherein the air diffuser comprises:
(a) an air inlet which is formed on one end of the upper block (at the opposite
side of the engagement hole), so that the bottom end of the air supply pipe can be
inserted; (b) air supply lines which are connected with the air inlet and are formed
along the edge of the fastening means by which the hollow fiber membrane bundle
is fastened; and
(c) a plurality of air nozzles formed at the air supply lines with equal spacing,
with an angle of 45° to 65° to the hollow fiber membrane, as injection holes.
6. The immersed hollow fiber membrane module as set forth in any of
Claims 1 to 5, which is installed inside a cassette of a frame, depending on the
capacity of the aeration tank, along with other such immersed hollow fiber
membrane modules.
7. The immersed hollow fiber membrane module as set forth in Claims 6,
wherein on each end of the cassette are attached an air supply main pipe, which is
connected to the air supply pipe of each of the immersed hollow fiber membrane
modules, and a final discharge pipe, which is connected to each of the treated water
discharge pipe.
PCT/KR2006/001951 2005-05-25 2006-05-24 Immersed hollow fiber membrane module WO2006126833A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020050043943A KR101214439B1 (en) 2005-05-25 2005-05-25 Immersed hollow fiber membrane module
KR10-2005-0043943 2005-05-25

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WO2006126833A1 true WO2006126833A1 (en) 2006-11-30

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WO (1) WO2006126833A1 (en)

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US10543461B2 (en) 2013-12-23 2020-01-28 Econity Co., Ltd. Cartridge-type hollow fiber membrane module comprising submerged hollow fiber membrane unit module with free end and submerged apparatus for water treatment comprising air diffuser apparatus capable of intermittent/continuous aeration and its aeration method
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