WO2005095310A3 - The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes - Google Patents

The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes Download PDF

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Publication number
WO2005095310A3
WO2005095310A3 PCT/US2005/009272 US2005009272W WO2005095310A3 WO 2005095310 A3 WO2005095310 A3 WO 2005095310A3 US 2005009272 W US2005009272 W US 2005009272W WO 2005095310 A3 WO2005095310 A3 WO 2005095310A3
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WO
WIPO (PCT)
Prior art keywords
zirconium
alkanes
reaction
ethoxylates
olefins
Prior art date
Application number
PCT/US2005/009272
Other languages
French (fr)
Other versions
WO2005095310A2 (en
Inventor
Ronald Anthony Hoffpauir
Lizbeth Olivia-Cisnero Trevino
Original Assignee
Shell Oil Co
Ronald Anthony Hoffpauir
Lizbeth Olivia-Cisnero Trevino
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Co, Ronald Anthony Hoffpauir, Lizbeth Olivia-Cisnero Trevino filed Critical Shell Oil Co
Publication of WO2005095310A2 publication Critical patent/WO2005095310A2/en
Publication of WO2005095310A3 publication Critical patent/WO2005095310A3/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/12—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids
    • C07C29/124—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids of halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/16—Preparation of ethers by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/22—Synthesis of the oxirane ring by oxidation of saturated compounds with air or molecular oxygen

Abstract

This invention relates to a process for the production of olefins, alcohols, ethers, ethoxylates, glycols, and olefin oxides from alkanes in a halogen, preferably bromine or chlorine, system, wherein there are halogenation (reaction of halogen with the alkanes), oxidation (reaction of alkyl halide with a metal oxide), optional neutralization (reaction of hydrogen halide and metal oxide), and regeneration (reaction of metal halide with air, oxygen, or other oxygen gas containing mixtures) reactions which take place in the process and wherein at least one of the reactions wherein water and halogen and/or hydrogen halide are present is carried out in reactors made from metallurgy including zirconium and/or zirconium-based alloys that contain varying amounts of alloying elements such as tin, niobium, chromium, iron, oxygen, and nickel. Preferably, this same metallurgy is used in the fabrication of separation and purification equipment for the process.
PCT/US2005/009272 2004-03-23 2005-03-21 The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes WO2005095310A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55547604P 2004-03-23 2004-03-23
US60/555,476 2004-03-23

Publications (2)

Publication Number Publication Date
WO2005095310A2 WO2005095310A2 (en) 2005-10-13
WO2005095310A3 true WO2005095310A3 (en) 2005-12-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/009272 WO2005095310A2 (en) 2004-03-23 2005-03-21 The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes

Country Status (2)

Country Link
US (1) US20050215837A1 (en)
WO (1) WO2005095310A2 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
RU2366642C2 (en) 2003-07-15 2009-09-10 Джи Ар Ти, Инк. Hydrocarbons synthesis
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
CA2641348C (en) 2006-02-03 2014-12-23 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
KR101335397B1 (en) 2006-02-03 2013-12-02 지알티, 인코포레이티드 Separation of light gases from halogens
JP2010528054A (en) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド Zone reactor incorporating reversible hydrogen halide capture and release
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
KR101740419B1 (en) 2008-07-18 2017-05-26 지알티, 인코포레이티드 Continuous process for converting natural gas to liquid hydrocarbons
US7812201B2 (en) 2008-10-01 2010-10-12 Targa Resources, Inc. Process and catalyst for converting alkanes
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2014577A (en) * 1978-02-20 1979-08-30 Mitsubishi Gas Chemical Co Process and apparatus for producing terephthalic acid with high purity
US4219666A (en) * 1978-08-07 1980-08-26 Basf Aktiengesellschaft Preparation of carboxylic acid esters of vicinal glycols
JPS58118541A (en) * 1982-01-06 1983-07-14 Mitsubishi Gas Chem Co Inc Preparation of aromatic polycarboxylic acid
US6403840B1 (en) * 2001-06-20 2002-06-11 Grt, Inc. Process for synthesizing olefin oxides
US20020198416A1 (en) * 2001-06-20 2002-12-26 Zhou Xiao Ping Integrated process for synthesizing alcohols, ethers, and olefins from alkanes

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172915A (en) * 1965-03-09 Preparation of oxygenated methane derivatives
NL293359A (en) * 1962-06-02
US3705926A (en) * 1970-02-20 1972-12-12 Paul Rumpf Manufacture of long chain alpha-olefines from mixtures of heavy paraffins
GB1538747A (en) * 1975-07-17 1979-01-24 Shell Int Research Detergent compositions
GB1542320A (en) * 1976-10-26 1979-03-14 Labofina Sa Process for the preparation of aromatic dicarboxylic acids
US4330676A (en) * 1977-07-04 1982-05-18 Imperial Chemical Industries Limited Oxidation process
US4474678A (en) * 1982-03-29 1984-10-02 Shell Oil Company Alkanol ethoxylate-containing detergent compositions
US5034158A (en) * 1989-10-24 1991-07-23 Shell Oil Company Monionic surfactant based powdered laundry detergent formulation containing an alkenyl or alkyl carboxysulfonate component
US5075041A (en) * 1990-06-28 1991-12-24 Shell Oil Company Process for the preparation of secondary alcohol sulfate-containing surfactant compositions
GB9210832D0 (en) * 1992-05-21 1992-07-08 Ici Plc Bromine catalysed oxidation process
US5243098A (en) * 1992-11-04 1993-09-07 Energia Andina Ltd. Conversion of methane to methanol
US5389277A (en) * 1993-09-30 1995-02-14 Shell Oil Company Secondary alkyl sulfate-containing powdered laundry detergent compositions
US5849960A (en) * 1996-11-26 1998-12-15 Shell Oil Company Highly branched primary alcohol compositions, and biodegradable detergents made therefrom
US6525230B2 (en) * 2001-04-18 2003-02-25 Grt, Inc. Zone reactor
US6452058B1 (en) * 2001-05-21 2002-09-17 Dow Global Technologies Inc. Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto
US20030078456A1 (en) * 2001-06-20 2003-04-24 Aysen Yilmaz Integrated process for synthesizing alcohols, ethers, aldehydes, and olefins from alkanes
US6465699B1 (en) * 2001-06-20 2002-10-15 Gri, Inc. Integrated process for synthesizing alcohols, ethers, and olefins from alkanes

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2014577A (en) * 1978-02-20 1979-08-30 Mitsubishi Gas Chemical Co Process and apparatus for producing terephthalic acid with high purity
US4219666A (en) * 1978-08-07 1980-08-26 Basf Aktiengesellschaft Preparation of carboxylic acid esters of vicinal glycols
JPS58118541A (en) * 1982-01-06 1983-07-14 Mitsubishi Gas Chem Co Inc Preparation of aromatic polycarboxylic acid
US6403840B1 (en) * 2001-06-20 2002-06-11 Grt, Inc. Process for synthesizing olefin oxides
US20020198416A1 (en) * 2001-06-20 2002-12-26 Zhou Xiao Ping Integrated process for synthesizing alcohols, ethers, and olefins from alkanes

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 198411, Derwent World Patents Index; Class E14, AN 1984-064812, XP002348462 *
YAU, T.-L.; BIRD, K.W.: "Manage corrosion with Zirconium", CHEMICAL ENGINEERING PROGRESS, 1995, pages 42 - 46, XP001207388 *

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US20050215837A1 (en) 2005-09-29
WO2005095310A2 (en) 2005-10-13

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