WO2004056449A3 - Process for removal of so2 from off-gases by reaction with h202 - Google Patents

Process for removal of so2 from off-gases by reaction with h202 Download PDF

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Publication number
WO2004056449A3
WO2004056449A3 PCT/EP2003/013699 EP0313699W WO2004056449A3 WO 2004056449 A3 WO2004056449 A3 WO 2004056449A3 EP 0313699 W EP0313699 W EP 0313699W WO 2004056449 A3 WO2004056449 A3 WO 2004056449A3
Authority
WO
WIPO (PCT)
Prior art keywords
gases
removal
reaction
gas
oxidised
Prior art date
Application number
PCT/EP2003/013699
Other languages
French (fr)
Other versions
WO2004056449A2 (en
Inventor
Peter Schoubye
Kurt Agerbaek Christensen
Morten Thellefsen Nielsen
Original Assignee
Haldor Topsoe As
Peter Schoubye
Kurt Agerbaek Christensen
Morten Thellefsen Nielsen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32668631&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2004056449(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Haldor Topsoe As, Peter Schoubye, Kurt Agerbaek Christensen, Morten Thellefsen Nielsen filed Critical Haldor Topsoe As
Priority to BRPI0317462-0A priority Critical patent/BR0317462B1/en
Priority to US10/539,604 priority patent/US7776299B2/en
Priority to AU2003288228A priority patent/AU2003288228B2/en
Priority to DE60319738T priority patent/DE60319738T2/en
Priority to CA2511311A priority patent/CA2511311C/en
Priority to EP03780121A priority patent/EP1578517B1/en
Priority to JP2004561212A priority patent/JP2006512190A/en
Publication of WO2004056449A2 publication Critical patent/WO2004056449A2/en
Publication of WO2004056449A3 publication Critical patent/WO2004056449A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/507—Sulfur oxides by treating the gases with other liquids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/20—Sulfur; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00—Intercepting solids
    • F23J2217/10—Intercepting solids by filters
    • F23J2217/102—Intercepting solids by filters electrostatic
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/40—Sorption with wet devices, e.g. scrubbers

Abstract

A process for removal of SO2 in off-gases having a temperature of 30-150°C and containing 0.001-1 vol% SO2 in which the SO2 is oxidised to H2 SO4 by spraying an aqueous solution of H2O2 into the off-gas upstream of an aerosol filter removing the produced sulphuric acid from the off-gas.
PCT/EP2003/013699 2002-12-21 2003-12-04 Process for removal of so2 from off-gases by reaction with h202 WO2004056449A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BRPI0317462-0A BR0317462B1 (en) 2002-12-21 2003-12-04 process for the removal of so2 in outlet gases by reaction with h2o2.
US10/539,604 US7776299B2 (en) 2002-12-21 2003-12-04 Process for removal of SO2 from off-gases by reaction with H2O2
AU2003288228A AU2003288228B2 (en) 2002-12-21 2003-12-04 Process for removal of SO2 from off-gases by reaction with H202
DE60319738T DE60319738T2 (en) 2002-12-21 2003-12-04 PROCESS FOR REMOVING SO2 FROM EXHAUST GASES BY MITH2O2 REACTION
CA2511311A CA2511311C (en) 2002-12-21 2003-12-04 Process for removal of so2 from off-gases by reaction with h2o2
EP03780121A EP1578517B1 (en) 2002-12-21 2003-12-04 Process for removal of so2 from off-gases by reaction with h202
JP2004561212A JP2006512190A (en) 2002-12-21 2003-12-04 Method for removing SO2 from off-gases by reaction with H2O2

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200201992 2002-12-21
DKPA200201992 2002-12-21

Publications (2)

Publication Number Publication Date
WO2004056449A2 WO2004056449A2 (en) 2004-07-08
WO2004056449A3 true WO2004056449A3 (en) 2004-09-30

Family

ID=32668631

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/013699 WO2004056449A2 (en) 2002-12-21 2003-12-04 Process for removal of so2 from off-gases by reaction with h202

Country Status (13)

Country Link
US (1) US7776299B2 (en)
EP (1) EP1578517B1 (en)
JP (1) JP2006512190A (en)
KR (1) KR20050084454A (en)
CN (1) CN100354028C (en)
AT (1) ATE388751T1 (en)
AU (1) AU2003288228B2 (en)
BR (1) BR0317462B1 (en)
CA (1) CA2511311C (en)
DE (1) DE60319738T2 (en)
ES (1) ES2300632T3 (en)
RU (1) RU2346731C2 (en)
WO (1) WO2004056449A2 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7404938B2 (en) * 2004-05-11 2008-07-29 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Emission control system
DE102005041794A1 (en) * 2005-09-02 2007-03-08 Basf Ag Method and apparatus for removing sulfur dioxide from a dry gas stream
CN100393393C (en) * 2006-03-30 2008-06-11 国电科技环保集团有限公司 Arrangement for sprinkling and pre-washing flue gas in entrance of flue gas-desulfurizing absorption tower
CN100463847C (en) * 2006-06-23 2009-02-25 李开春 Method for preparing vitriol from flue gas
DE102007020141A1 (en) * 2007-04-26 2008-10-30 Bayer Materialscience Ag Recycle gas scrubber for the removal of SOx and sulfuric acid aerosols from chlorine-containing process gases
DE102007039926B4 (en) * 2007-08-23 2012-03-22 Götaverken Miljö AB Method and device for exhaust gas purification
KR101039715B1 (en) * 2009-01-23 2011-06-13 엘에스니꼬동제련 주식회사 Method of Treating a By-product Gas from Copper Smelting
KR101341967B1 (en) * 2012-06-22 2013-12-16 한국에너지기술연구원 Method for producing hydrogen and sulfuric acid from sulfur dioxide using electrochemical process
US8877152B2 (en) * 2013-02-27 2014-11-04 Alstom Technology Ltd Oxidation system and method for cleaning waste combustion flue gas
CN103657375B (en) * 2014-01-07 2015-07-08 上海科洋科技股份有限公司 Method and system for removing trace SO2 in tail gas by gas phase oxidation
CA3025381C (en) 2016-05-24 2022-11-15 Haldor Topsoe A/S A method for the removal of oxygen from an industrial gas
AU2018222356B2 (en) 2017-02-16 2023-09-28 Haldor Topsøe A/S A method for the removal of oxygen from an industrial gas feed
EP3592449A1 (en) * 2017-03-08 2020-01-15 Shell Internationale Research Maatschappij B.V. Process for removing so2 from gas with so2 content that is temporarily very high
CN107970911B (en) * 2017-12-01 2020-10-13 南京云高新型材料有限公司 Environment-friendly energy-saving high-conversion-rate rare earth catalyst and preparation method thereof
CN110407181A (en) * 2019-08-19 2019-11-05 广东新生环保科技股份有限公司 A kind of tail gas sulphur dioxide relieving haperacidity recovery system
US11071947B2 (en) 2019-10-30 2021-07-27 W. L. Gore & Associates, Inc. Catalytic efficiency of flue gas filtration
US10940471B1 (en) 2019-10-30 2021-03-09 W. L. Gore & Associates, Inc. Catalytic efficiency of flue gas filtration

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3733393A (en) * 1970-09-30 1973-05-15 Air Liquide Purification of combustion products before discharge into the atmosphere
US3953578A (en) * 1972-02-04 1976-04-27 Oxysynthese Method for purification of industrial flue gases
DE4036899A1 (en) * 1990-11-20 1992-05-21 Degussa Sulphuric acid prodn. by oxidn. of sulphur di:oxide mixt. - using hydrogen peroxide for desulphurisation of gases arising from sulphite-treated grape juice
DE4424367A1 (en) * 1994-07-11 1996-01-18 Siemens Ag Process and appts. to purify flue gas

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DE436899C (en) 1926-11-09 August Henze Freischaeler for beet harvesters
US3503704A (en) 1966-10-03 1970-03-31 Alvin M Marks Method and apparatus for suppressing fumes with charged aerosols
US3760061A (en) * 1971-03-02 1973-09-18 Du Pont High-strength acid containing h2o2 to scrub so2
CA1069273A (en) 1974-05-23 1980-01-08 Fmc Corporation Purification of sulfur-containing waste gases with hydrogen peroxide
JPS53135878A (en) 1977-04-30 1978-11-27 Ishikawajima Harima Heavy Ind Co Ltd Wet denitrating or wet denitrating and desulurizing method
DE3237699A1 (en) 1982-10-12 1984-04-12 Toschi Produktions-Gesellschaft mbH, 2800 Bremen METHOD FOR SEPARATING AIR POLLUTANTS FROM EXHAUST GAS, IN PARTICULAR FROM FLUE GAS, BY CONDENSATION
CA1159773A (en) * 1981-09-30 1984-01-03 George Drzewiecki Wet electrostatic precipitator having removable nested hexagonal collector plates and magnetic aligning and rapping means
JPS60153923A (en) 1984-01-25 1985-08-13 Hitachi Zosen Corp Recovery of available component in high temperature gas
US4678481A (en) * 1986-09-02 1987-07-07 Nalco Chemical Company H2 O2 as a conditioning agent for electrostatic precipitators
DK168702B1 (en) * 1988-06-02 1994-05-24 Topsoe Haldor As Process for preparing sulfuric acid and apparatus for use in the practice of the process
US5017350A (en) * 1989-06-02 1991-05-21 Union Carbide Canada Limited Gas scrubbing process
CN2133353Y (en) * 1992-09-17 1993-05-19 王明环 Smoke sweetening duster for coal boiler
JPH06142440A (en) 1992-11-13 1994-05-24 Nippon Steel Corp Oxidation treatment of gas containing harmful gas and device for the same
US5595713A (en) 1994-09-08 1997-01-21 The Babcock & Wilcox Company Hydrogen peroxide for flue gas desulfurization
CN1173386A (en) * 1996-08-12 1998-02-18 中国科学院生态环境中心 Flue gas desulphurization process
US20040062697A1 (en) * 2002-10-01 2004-04-01 Airborne Pollution Control Inc. Flue gas purification method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3733393A (en) * 1970-09-30 1973-05-15 Air Liquide Purification of combustion products before discharge into the atmosphere
US3953578A (en) * 1972-02-04 1976-04-27 Oxysynthese Method for purification of industrial flue gases
DE4036899A1 (en) * 1990-11-20 1992-05-21 Degussa Sulphuric acid prodn. by oxidn. of sulphur di:oxide mixt. - using hydrogen peroxide for desulphurisation of gases arising from sulphite-treated grape juice
DE4424367A1 (en) * 1994-07-11 1996-01-18 Siemens Ag Process and appts. to purify flue gas

Also Published As

Publication number Publication date
EP1578517B1 (en) 2008-03-12
AU2003288228A1 (en) 2004-07-14
RU2346731C2 (en) 2009-02-20
AU2003288228B2 (en) 2009-08-06
RU2005123041A (en) 2006-01-27
DE60319738T2 (en) 2009-04-02
BR0317462A (en) 2005-11-16
BR0317462B1 (en) 2013-02-05
US7776299B2 (en) 2010-08-17
ATE388751T1 (en) 2008-03-15
CN1729039A (en) 2006-02-01
CA2511311C (en) 2011-09-20
ES2300632T3 (en) 2008-06-16
DE60319738D1 (en) 2008-04-24
JP2006512190A (en) 2006-04-13
CA2511311A1 (en) 2004-07-08
US20060057047A1 (en) 2006-03-16
KR20050084454A (en) 2005-08-26
WO2004056449A2 (en) 2004-07-08
EP1578517A2 (en) 2005-09-28
CN100354028C (en) 2007-12-12

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