WO2002036513B1 - Low-e coating system including protective dlc - Google Patents

Low-e coating system including protective dlc

Info

Publication number
WO2002036513B1
WO2002036513B1 PCT/US2001/042792 US0142792W WO0236513B1 WO 2002036513 B1 WO2002036513 B1 WO 2002036513B1 US 0142792 W US0142792 W US 0142792W WO 0236513 B1 WO0236513 B1 WO 0236513B1
Authority
WO
WIPO (PCT)
Prior art keywords
coated article
layer
further characterized
inclusive layer
dlc inclusive
Prior art date
Application number
PCT/US2001/042792
Other languages
French (fr)
Other versions
WO2002036513A3 (en
WO2002036513A9 (en
WO2002036513A2 (en
Inventor
Vijayen S Veerasamy
Rudolph H Petrmichl
Scott V Thomsen
Original Assignee
Guardian Industries
Vijayen S Veerasamy
Rudolph H Petrmichl
Scott V Thomsen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guardian Industries, Vijayen S Veerasamy, Rudolph H Petrmichl, Scott V Thomsen filed Critical Guardian Industries
Priority to AU3238802A priority Critical patent/AU3238802A/en
Publication of WO2002036513A2 publication Critical patent/WO2002036513A2/en
Publication of WO2002036513A3 publication Critical patent/WO2002036513A3/en
Publication of WO2002036513B1 publication Critical patent/WO2002036513B1/en
Publication of WO2002036513A9 publication Critical patent/WO2002036513A9/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00—Methods preventing fouling
    • B08B17/02—Preventing deposition of fouling or of dust
    • B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B17/00—Methods preventing fouling
    • B08B17/02—Preventing deposition of fouling or of dust
    • B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
    • B08B17/065—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/1033—Laminated safety glass or glazing containing temporary protective coatings or layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00—Cleaning of vehicles
    • B60S1/02—Cleaning windscreens, windows or optical devices
    • B60S1/54—Cleaning windscreens, windows or optical devices using gas, e.g. hot air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00—Cleaning of vehicles
    • B60S1/02—Cleaning windscreens, windows or optical devices
    • B60S1/56—Cleaning windscreens, windows or optical devices specially adapted for cleaning other parts or devices than front windows or windscreens
    • B60S1/58—Cleaning windscreens, windows or optical devices specially adapted for cleaning other parts or devices than front windows or windscreens for rear windows
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
    • C03C17/3441—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising carbon, a carbide or oxycarbide
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
    • C03C17/3482—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising silicon, hydrogenated silicon or a silicide
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3621—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a fluoride
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3634—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing carbon, a carbide or oxycarbide
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3636—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing silicon, hydrogenated silicon or a silicide
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3655—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating containing at least one conducting layer
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0075—Cleaning of glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/26—Deposition of carbon only
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/20—Filters
    • G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/20—Materials for coating a single layer on glass
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    • C03C2217/282—Carbides, silicides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/75—Hydrophilic and oleophilic coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
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    • C03C2217/76—Hydrophobic and oleophobic coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/15—Deposition methods from the vapour phase
    • C03C2218/151—Deposition methods from the vapour phase by vacuum evaporation
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/30—Aspects of methods for coating glass not covered above
    • C03C2218/31—Pre-treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y10T428/24975—No layer or component greater than 5 mils thick
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A substrate is coated with a low-E coating system including at least one infrared (IR) reflective layer. A diamond-like carbon (DLC) inclusive protective coating system (e.g., including at least one highly tetrahedral amorphous carbon (ta-C) inclusive layer having sp3 carbon-carbon bonds) is provided on the substrate over at least the IR reflective layer in order to make the low-E coating system scratch resistant, abrasion resistant, and generally mechanically durable. The DLC inclusive protective coating system may be hydrophobic, hydrophillic, or neutral in different embodiments of the invention. Optionally, at least one fluoro-alkyl silane (FAS) compound inclusive layer may be provided on the substrate over at least one of the DLC inclusive layer(s) in hydrophobic embodiments in order to increase contact angle υ of the coated article.

Claims

AMENDED CLAIMS[received by the International Bureau on 28 May 2002 (28.05.2002); original claims 1-43 replaced by new claims 1-27 (6 pages)]
1. A coated article comprising a substrate (1) and a low-E coating system including at least one infrared (IR) reflecting layer (5) provided on said substrate, the coated article being characterized by: the low-E coating system comprising a protective substantially non- crystalline diamond-like carbon (DLC) inclusive layer (8, 9, and/or 10) provided in a position such that said IR reflecting layer (5) is located between said substrate (1) and said protective DLC inclusive layer, and wherein at least about 40% of carbon- carbon (C-C) bonds in said DLC inclusive layer are sp3 carbon-carbon bonds and wherein said DLC inclusive layer has an average density of at least about 2.4 gm/cm3.
2. The coated article of claim 1, further characterized in that said DLC inclusive layer includes highly tetrahedral amorphous carbon, and wherein the coated article has an initial contact angle θ of at least about 55 degrees.
3. The coated article of claim 1 , further characterized in that the DLC inclusive layer has a thickness of from 10 to 250 angstroms (A).
4. The coated article of claim 1 further characterized in that the DLC inclusive layer includes from about 5 to 35% hydrogen.
5. The coated article of claim 1 , further characterized in that said low-E coating system is provided in a manner so that the coated article has a normal emissivity of no greater than about 0.10, a hemispherical emissivity of no greater
47 than about 0.11, and a sheet resistance (Rj) of no greater than about 10.0 ohms/square.
6. The coated article of claim 5, further characterized in that said low-E coating system is provided in a manner so that the coated article has a normal emissivity of no greater than about 0.06, a hemispherical emissivity of no greater than about 0.07, and a sheet resistance of no greater than about 5.0 ohms/square.
7. The coated article of claim 5, further characterized in that the coated article has a visible transmittance of at least about 75%.
8. The coated article of claim 1, further characterized in that said DLC inclusive layer is deposited via an ion beam deposition process over the IR reflecting layer in a manner such that the IR reflecting layer is maintained at temperature(s) no greater than about 200 degrees C during the ion beam deposition process for depositing the DLC inclusive layer.
9. The coated article of claim 1, further characterized in that said low-E coating system further includes a first dielectric layer (2 and/or 3) disposed between said IR reflecting layer and said substrate, and a second dielectric layer (7) disposed between said IR reflecting layer and said DLC inclusive layer.
10. The coated article of claim 9, further characterized in that said first dielectric layer comprises Ti02 and said second dielectric layer comprises silicon nitride.
48
11. The coated article of claim 1 , further characterized in that said low-E coating system comprises, from said substrate outwardly, a layer system including:
a) a layer of transparent dielectric material (2);
b) a dielectric layer comprising silicon nitride (3);
c) a Ni inclusive layer (4);
d) said IR reflecting layer including Ag (5);
e) a Ni inclusive layer (6);
f) a dielectric layer comprising silicon nitride (7); and
g) said DLC inclusive layer (8).
12. The coated article of claim 11 , further characterized in that said low-E coating system comprises first and second DLC inclusive layers (9, 10) located outwardly of said IR reflecting layer.
13. The coated article of claim 12, further characterized in that each of said first and second DLC inclusive layers includes highly tetrahedral amorphous carbon.
14. The coated article of claim 1 , further characterized by a fluoro-alkyl silane (FAS) compound inclusive layer (11) located on said substrate such that said DLC inclusive layer is located between said FAS compound inclusive layer and said IR reflecting layer.
49
15. The coated article of claim 1 , further characterized in tha said DLC inclusive layer has an average hardness of at least about 10 GPa.
16. The coated article of claim 1 , further characterized in that said low-E coating system includes first and second DLC inclusive layers (9, 10), said first DLC inclusive layer including silicon (Si) and being provided between said second DLC inclusive layer and said substrate; and wherein said second DLC inclusive layer is deposited in a manner so that at least a portion of said second DLC inclusive layer has a greater hardness and higher density than said first DLC inclusive layer.
17. The coated article of claim 16, further characterized in that said low-E coating system further includes an FAS inclusive layer (11) provided on said second DLC inclusive layer, so that said second DLC inclusive layer is located between said first DLC inclusive layer and said FAS inclusive layer.
18. The coated article of claim 1 , further characterized in that said coated article has an initial contact angle of at least about 80 degrees.
19. The coated article of claim 18, further characterized in that said initial contact angle is at least about 100 degrees.
20. The coated article of claim 1 , further characterized in that said low-E coating system has a surface energy γc of less than or equal to about 20.2 mN/m.
50
21. The coated article of claim 20, further characterized in that said low-E coating system has a surface energy γc of less than or equal to about 19.5 mN/m.
22. The coated article of claim 1, further characterized by a fluoro-alkyl silane (FAS) compound inclusive layer (11) located on said substrate such that said DLC inclusive layer is located between said FAS compound inclusive layer and said IR reflecting layer; and wherein said FAS compound includes at least one of: CF3(CH2)2Si(OCH3)3; CF3(CF2)5(CH2)2Si(OCH2CH3)3; CF3(CH2)2SiCl3; CF3(CF2)5(CH2)2SiCl3; CF3(CF2)7(CH2)2Si(OCH3)3; CF3(CF2)5(CH2)2Si(OCH3)3; CF3(CF2)7(CH2)2SiCl3; CF3(CF2)7(CH2)2SiCH3Cl2; and CF3(CF2)7(CH2)2SiCH3(OCH3)2.
23. The coated article of claim 16, further characterized in that said first DLC inclusive layer comprises more silicon (Si) than said second DLC inclusive layer.
24. The coated article of claim 23, further characterized in that each of said first and second DLC inclusive layers include sp3 carbon-carbon bonds.
25. The coated article of claim 1, further characterized in that at least about 6 >00%% ooff ccaarrbboonn--carbon (C-C) bonds in said DLC inclusive layer are sp carbon-carbon bonds.
26. The coated article of claim 1, further characterized in that the coated article has a visible transmittance of at least about 70%.
27. The coated article of claim 1 , further characterized in that said low-E coating system is provided in a manner so as to have a sheet resistance (Rg) of no greater than about 10 ohms/square.
52
PCT/US2001/042792 2000-10-30 2001-10-29 Low-e coating system including protective dlc WO2002036513A2 (en)

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US09/698,126 2000-10-30

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WO2002036513A9 WO2002036513A9 (en) 2003-05-01

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Families Citing this family (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5858477A (en) * 1996-12-10 1999-01-12 Akashic Memories Corporation Method for producing recording media having protective overcoats of highly tetrahedral amorphous carbon
US6335086B1 (en) 1999-05-03 2002-01-01 Guardian Industries Corporation Hydrophobic coating including DLC on substrate
US6461731B1 (en) * 1999-05-03 2002-10-08 Guardian Industries Corp. Solar management coating system including protective DLC
US6312808B1 (en) 1999-05-03 2001-11-06 Guardian Industries Corporation Hydrophobic coating with DLC & FAS on substrate
US6261693B1 (en) * 1999-05-03 2001-07-17 Guardian Industries Corporation Highly tetrahedral amorphous carbon coating on glass
US6303225B1 (en) 2000-05-24 2001-10-16 Guardian Industries Corporation Hydrophilic coating including DLC on substrate
US6514620B1 (en) * 1999-12-06 2003-02-04 Guardian Industries Corp. Matchable low-E I G units and laminates and methods of making same
US7267879B2 (en) * 2001-02-28 2007-09-11 Guardian Industries Corp. Coated article with silicon oxynitride adjacent glass
EP1394130A4 (en) * 2001-05-15 2007-07-11 Nippon Sheet Glass Co Ltd Heat insulating and shielding glass panel
US6605358B1 (en) 2001-09-13 2003-08-12 Guardian Industries Corp. Low-E matchable coated articles, and methods
WO2003038417A2 (en) * 2001-10-26 2003-05-08 Physical Electronics, Inc. System and method for depth profiling and characterization of thin films
US6610360B2 (en) * 2001-11-28 2003-08-26 Guardian Industries Corp. Buffing diamond-like carbon (DLC) to improve scratch resistance
US6770321B2 (en) * 2002-01-25 2004-08-03 Afg Industries, Inc. Method of making transparent articles utilizing protective layers for optical coatings
JP2003221257A (en) * 2002-01-31 2003-08-05 Nippon Sheet Glass Co Ltd Method for forming transparent thin film and transparent substrate equipped with the same
JP4153212B2 (en) * 2002-02-04 2008-09-24 富士通株式会社 Tetrahedral amorphous carbon film and method for producing the same
GB0202710D0 (en) * 2002-02-06 2002-03-20 Tyco Electronics Ltd Uk Fastener
US20030155065A1 (en) * 2002-02-13 2003-08-21 Thomsen Scott V. Method of making window unit
US6827977B2 (en) * 2002-03-07 2004-12-07 Guardian Industries Corp. Method of making window unit including diamond-like carbon (DLC) coating
US8555921B2 (en) 2002-12-18 2013-10-15 Vapor Technologies Inc. Faucet component with coating
US7866343B2 (en) 2002-12-18 2011-01-11 Masco Corporation Of Indiana Faucet
US8220489B2 (en) 2002-12-18 2012-07-17 Vapor Technologies Inc. Faucet with wear-resistant valve component
US7866342B2 (en) 2002-12-18 2011-01-11 Vapor Technologies, Inc. Valve component for faucet
US6891158B2 (en) * 2002-12-27 2005-05-10 Revera Incorporated Nondestructive characterization of thin films based on acquired spectrum
US6800852B2 (en) * 2002-12-27 2004-10-05 Revera Incorporated Nondestructive characterization of thin films using measured basis spectra
US20060257663A1 (en) * 2003-03-03 2006-11-16 Doll Gary L Wear resistant coatings to reduce ice adhesion on air foils
US20040191559A1 (en) * 2003-03-26 2004-09-30 Bustamante Anthony T. Method and apparatus for strengthening steel and cast iron parts
FR2858816B1 (en) 2003-08-13 2006-11-17 Saint Gobain TRANSPARENT SUBSTRATE HAVING ANTIREFLECTION COATING
US7150849B2 (en) * 2003-11-04 2006-12-19 Guardian Industries Corp. Heat treatable coated article with diamond-like carbon (DLC) and/or zirconium in coating
US7501148B2 (en) * 2003-11-04 2009-03-10 Guardian Industries Corp. Method of making heat treatable coated article with diamond-like carbon (DLC) and/or zirconium in coating
FR2859487B1 (en) * 2003-09-04 2006-12-15 Essilor Int METHOD FOR DEPOSITING AN AMORPHOUS LAYER CONTAINING MAJORITARILY FLUORINE AND CARBON AND DEVICE SUITABLE FOR ITS IMPLEMENTATION
US7129180B2 (en) * 2003-09-12 2006-10-31 Micron Technology, Inc. Masking structure having multiple layers including an amorphous carbon layer
US7132201B2 (en) * 2003-09-12 2006-11-07 Micron Technology, Inc. Transparent amorphous carbon structure in semiconductor devices
US7537801B2 (en) * 2003-11-04 2009-05-26 Guardian Industries Corp. Heat treatable coated article with diamond-like carbon (DLC) and/or zirconium in coating
US7507442B2 (en) * 2003-11-04 2009-03-24 Guardian Industries Corp. Heat treatable coated article with diamond-like carbon (DLC) and/or zirconium in coating
US7879202B2 (en) 2003-12-15 2011-02-01 Guardian Industries Corp. Scratch resistant coated glass article including carbide layer(s) resistant to fluoride-based etchant(s)
US7566481B2 (en) * 2003-12-15 2009-07-28 Guardian Industries Corp. Method of making scratch resistant coated glass article including layer(s) resistant to fluoride-based etchant(s)
US7445273B2 (en) * 2003-12-15 2008-11-04 Guardian Industries Corp. Scratch resistant coated glass article resistant fluoride-based etchant(s)
US7387816B2 (en) 2003-12-15 2008-06-17 Guardian Industries Corp. Scratch resistant coated glass article including layer(s) resistant to fluoride-based etchant(s), and method of making article using combustion CVD
US20050196632A1 (en) * 2003-12-18 2005-09-08 Afg Industries, Inc. Protective layer for optical coatings with enhanced corrosion and scratch resistance
US20050210921A1 (en) * 2004-03-29 2005-09-29 Guardian Industries Corp. Method of making coated glass article, and intermediate product used in same
US8524051B2 (en) 2004-05-18 2013-09-03 Centre Luxembourg de Recherches pour le Verre et al Ceramique S. A. (C.R.V.C.) Coated article with oxidation graded layer proximate IR reflecting layer(s) and corresponding method
CN1324332C (en) * 2004-06-14 2007-07-04 元太科技工业股份有限公司 Color light filter
US7311975B2 (en) * 2004-06-25 2007-12-25 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article having low-E coating with ion beam treated IR reflecting layer and corresponding method
US7229533B2 (en) * 2004-06-25 2007-06-12 Guardian Industries Corp. Method of making coated article having low-E coating with ion beam treated and/or formed IR reflecting layer
US7585396B2 (en) 2004-06-25 2009-09-08 Guardian Industries Corp. Coated article with ion treated overcoat layer and corresponding method
US7550067B2 (en) * 2004-06-25 2009-06-23 Guardian Industries Corp. Coated article with ion treated underlayer and corresponding method
US7563347B2 (en) * 2004-06-25 2009-07-21 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Method of forming coated article using sputtering target(s) and ion source(s) and corresponding apparatus
DE102004041235A1 (en) * 2004-08-26 2006-03-02 Ina-Schaeffler Kg Wear resistant coating and method of making same
US20060065350A1 (en) * 2004-09-27 2006-03-30 Guardian Industries Corp. Method of making heat treated coated glass article, and intermediate product used in same
US7455883B2 (en) * 2004-10-19 2008-11-25 Guardian Industries Corp. Hydrophilic DLC on substrate with flame pyrolysis treatment
US20060246218A1 (en) * 2005-04-29 2006-11-02 Guardian Industries Corp. Hydrophilic DLC on substrate with barrier discharge pyrolysis treatment
US7892662B2 (en) 2006-04-27 2011-02-22 Guardian Industries Corp. Window with anti-bacterial and/or anti-fungal feature and method of making same
US7846492B2 (en) * 2006-04-27 2010-12-07 Guardian Industries Corp. Photocatalytic window and method of making same
US7632543B2 (en) * 2006-12-05 2009-12-15 Guardian Industries Corp. Method of making IG window unit and forming silicon oxide based hydrophilic coating using chlorosilane vapor deposition
US8071166B2 (en) * 2007-01-29 2011-12-06 Guardian Industries Corp. Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film
US20120040160A1 (en) 2007-01-29 2012-02-16 Guardian Industries Corp. Method of making heat treated and ion-beam etched/milled coated article using diamond-like carbon (dlc) protective film
US7833574B2 (en) 2007-01-29 2010-11-16 Guardian Industries Corp. Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film
US7914857B2 (en) * 2007-01-29 2011-03-29 Guardian Industries Corp. Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film with oxygen content of protective film based on bending characteristics of coated article
US20120015196A1 (en) 2007-01-29 2012-01-19 Guardian Industries Corp. Method of making heat treated coated article using diamond-like carbon (dlc) coating and protective film on acid-etched surface
US8132426B2 (en) 2007-01-29 2012-03-13 Guardian Industries Corp. Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film
US8003167B2 (en) * 2007-01-29 2011-08-23 Guardian Industries Corp. Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film
US20120015195A1 (en) 2007-01-29 2012-01-19 Guardian Industries Corp. and C.R.V.C. Method of making heat treated and ion-beam etched/milled coated article using diamond-like carbon (dlc) coating and protective film
CN101663558B (en) 2007-04-05 2011-06-22 富士通半导体股份有限公司 Surface profile sensor and method for manufacturing the same
DE102007027271B4 (en) * 2007-06-11 2010-06-10 Gerhard Dipl.-Ing. Mangold Use of a surface material for architectural purposes
US20090044897A1 (en) * 2007-08-10 2009-02-19 Guardian Industries Corp. Method of making a heat-treated coated glass article using a polymer dispersion
US8114488B2 (en) * 2007-11-16 2012-02-14 Guardian Industries Corp. Window for preventing bird collisions
US20090258221A1 (en) * 2008-04-15 2009-10-15 Vtec Technologies, Llc Light-Reflective Articles and Methods for Making Same
US7864431B2 (en) * 2008-06-04 2011-01-04 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Windshield for use with head-up display and/or method of making the same
US8187671B2 (en) * 2008-07-28 2012-05-29 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Method of making heat treated coated article using diamond-like carbon (DLC) coating and protective film including removal of protective film via blasting
US8449704B2 (en) * 2008-07-31 2013-05-28 Guardian Industries Corp. Method of making a coated glass article, and intermediate product used in same
US8003164B2 (en) 2008-09-19 2011-08-23 Guardian Industries Corp. Method of making a scratch-and etch-resistant coated glass article
US20100155935A1 (en) * 2008-12-23 2010-06-24 Intel Corporation Protective coating for semiconductor substrates
US8304045B2 (en) 2010-02-26 2012-11-06 Guardian Industries Corp. Articles including anticondensation coatings and/or methods of making the same
EP2578726B1 (en) * 2010-05-31 2018-10-17 JTEKT Corporation Method for manufacturing a coated member
US9341748B2 (en) * 2011-12-28 2016-05-17 Guardian Industries Corp. Mirror for use in humid environments, and/or method of making the same
US9255029B2 (en) 2012-04-17 2016-02-09 Guardian Industries Corp. Method of making heat treated coated article using TCO and removable protective film
US9038419B2 (en) 2012-06-08 2015-05-26 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Method of making heat treated coated article using carbon based coating and protective film
CN102745907B (en) * 2012-08-10 2014-09-17 北京航空航天大学 Preparation method of low emissivity glass coated with inverse opal structure and a functional nano-film
TWI606986B (en) * 2012-10-03 2017-12-01 康寧公司 Physical vapor deposited layers for protection of glass surfaces
US10222921B2 (en) 2012-11-27 2019-03-05 Guardian Glass, LLC Transparent conductive coating for capacitive touch panel with silver having increased resistivity
US9434640B2 (en) 2012-12-04 2016-09-06 Guardian Industries Corp. Method of making heat treated coated article with carbon based coating and protective film
US9751800B2 (en) 2013-02-06 2017-09-05 Guardian Glass, LLC Heat treatable coated article with tungsten-doped zirconium based layer(s) in coating
US20140233106A1 (en) * 2013-02-21 2014-08-21 Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e.V. Object with reflection-reducing coating and method for the production thereof
FR3007024A1 (en) * 2013-06-14 2014-12-19 Essilor Int COATED ARTICLE WITH A SILICO-ORGANIC LAYER IMPROVING THE PERFORMANCE OF AN EXTERNAL COATING
FR3009302B1 (en) 2013-08-05 2018-01-12 Saint-Gobain Glass France SUBSTRATE CARRYING A FUNCTIONAL COATING AND A TEMPORARY PROTECTION LAYER
US9809712B2 (en) * 2013-11-26 2017-11-07 Baker Hughes, A Ge Company, Llc Hydrophobic and oleophobic coatings
US9534476B2 (en) 2013-11-26 2017-01-03 Baker Hughes Incorporated Scale-inhibiting coating
US9850570B2 (en) * 2015-07-06 2017-12-26 Intevac, Inc. Ion implantation for modification of thin film coatings on glass
MX2018015507A (en) * 2016-06-13 2019-06-06 Viavi Solutions Inc Protected item including a protective coating.
US10611678B2 (en) 2016-11-04 2020-04-07 Guardian Glass, LLC Heat treatable coated article with carbon-doped zirconium based layer(s) in coating
US10738375B2 (en) 2016-11-15 2020-08-11 HPVico AB Hard thin films
CN106495504A (en) * 2016-12-23 2017-03-15 重庆物华天宝镀膜科技有限公司 It is not likely to produce the Low emissivity list silver coating glass of cut
US10782741B2 (en) 2017-03-09 2020-09-22 Apple Inc. Abrasion-resistant surface finishes on metal enclosures
US10472274B2 (en) 2017-07-17 2019-11-12 Guardian Europe S.A.R.L. Coated article having ceramic paint modified surface(s), and/or associated methods
WO2019035030A1 (en) 2017-08-16 2019-02-21 Guardian Glass, LLC Transparent conductive coating for capacitive touch panel with additional functional film(s)
WO2019035031A1 (en) 2017-08-16 2019-02-21 Guardian Glass, LLC Transparent conductive coating for capacitive touch panel
CN107365089A (en) * 2017-09-08 2017-11-21 蚌埠玻璃工业设计研究院 A kind of low radiation coated glass
US10611679B2 (en) 2017-10-26 2020-04-07 Guardian Glass, LLC Coated article including noble metal and polymeric hydrogenated diamond like carbon composite material having antibacterial and photocatalytic properties, and/or methods of making the same
US20190127272A1 (en) 2017-10-26 2019-05-02 Guardian Glass, LLC Coated article including noble metal and polymeric hydrogenated diamond like carbon composite material having antibacterial and photocatalytic properties, and/or methods of making the same
WO2019126330A1 (en) 2017-12-21 2019-06-27 Guardian Glass, LLC Transparent conductive coating for capacitive touch panel with silver having increased resistivity
WO2019126338A1 (en) 2017-12-21 2019-06-27 Guardian Glass, LLC Transparent conductive coating for capacitive touch panel with silver having adjusted resistance
JP2021510438A (en) 2018-01-11 2021-04-22 ガーディアン・グラス・エルエルシーＧｕａｒｄｉａｎ Ｇｌａｓｓ， Ｌｌｃ Transparent conductive coating for capacitive touch panels and its manufacturing method
US11460393B2 (en) * 2019-06-27 2022-10-04 The Insulating Glass Certification Council System and method for accelerated weathering testing of insulating glass units
CN111045127B (en) * 2019-12-25 2022-04-15 富泰华精密电子（郑州）有限公司 Perspective covering piece and preparation method thereof
CN113549887B (en) * 2021-07-26 2022-11-01 吉林大学 Infrared reflection composite coating and preparation method and application thereof

Family Cites Families (136)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3959577A (en) 1974-06-10 1976-05-25 Westinghouse Electric Corporation Hermetic seals for insulating-casing structures
US4060660A (en) 1976-01-15 1977-11-29 Rca Corporation Deposition of transparent amorphous carbon films
US4263350A (en) 1979-12-31 1981-04-21 Ppg Industries, Inc. Silane release surfaces on glass
USRE32272E (en) 1980-05-29 1986-10-28 Sumitomo Chemical Company, Limited Non-fogging coating composition and a shaped article coated therewith
EP0049032B1 (en) 1980-08-21 1986-09-17 National Research Development Corporation Coating insulating materials by glow discharge
US4504519A (en) 1981-10-21 1985-03-12 Rca Corporation Diamond-like film and process for producing same
US4495263A (en) 1983-06-30 1985-01-22 Eastman Kodak Company Electrophotographic elements containing polyamide interlayers
DE3421739A1 (en) * 1984-06-12 1985-12-12 Battelle-Institut E.V., 6000 Frankfurt METHOD FOR PRODUCING DIAMOND-LIKE CARBON LAYERS
US4877677A (en) 1985-02-19 1989-10-31 Matsushita Electric Industrial Co., Ltd. Wear-protected device
FR2592874B1 (en) 1986-01-14 1990-08-03 Centre Nat Rech Scient PROCESS FOR DIPPING A GLASS OR VITREOUS OBJECT AND OBJECT THUS DIPPED
US4666802A (en) 1986-07-16 1987-05-19 Eastman Kodak Company Photoconductive elements sensitive to infrared radiation having a bromoindium phthalocyanine pigment
US5514885A (en) 1986-10-09 1996-05-07 Myrick; James J. SOI methods and apparatus
US4777090A (en) 1986-11-03 1988-10-11 Ovonic Synthetic Materials Company Coated article and method of manufacturing the article
US4806220A (en) 1986-12-29 1989-02-21 Ppg Industries, Inc. Method of making low emissivity film for high temperature processing
US5028759A (en) 1988-04-01 1991-07-02 Ppg Industries, Inc. Low emissivity film for a heated windshield
US5000831A (en) 1987-03-09 1991-03-19 Minolta Camera Kabushiki Kaisha Method of production of amorphous hydrogenated carbon layer
US4816291A (en) 1987-08-19 1989-03-28 The Regents Of The University Of California Process for making diamond, doped diamond, diamond-cubic boron nitride composite films
NL8800607A (en) 1988-03-11 1989-10-02 Pelt & Hooykaas Laser mirrors - has substrate and diamond-like layers of material with alternating higher and lower refractive index
US4935303A (en) 1987-10-15 1990-06-19 Canon Kabushiki Kaisha Novel diamond-like carbon film and process for the production thereof
JPH01227161A (en) 1988-03-07 1989-09-11 Minolta Camera Co Ltd Photosensitive body and production thereof
US4898789A (en) 1988-04-04 1990-02-06 Ppg Industries, Inc. Low emissivity film for automotive heat load reduction
US5902505A (en) 1988-04-04 1999-05-11 Ppg Industries, Inc. Heat load reduction windshield
US5098737A (en) 1988-04-18 1992-03-24 Board Of Regents The University Of Texas System Amorphic diamond material produced by laser plasma deposition
DE3821614A1 (en) 1988-06-27 1989-12-28 Licentia Gmbh Covering layer of amorphous carbon on a substrate, process for producing the covering layer and use of the covering layer
US5242560A (en) 1989-03-09 1993-09-07 Guardian Industries Corp. Heat treatable sputter-coated glass
US5188887A (en) 1989-03-09 1993-02-23 Guardian Industries Corp. Heat treatable sputter-coated glass
GB9018608D0 (en) 1989-08-30 2013-11-13 Texas Instruments Inc Durable wideband anti-reflection coating for infrared windows
US5143963A (en) 1989-12-06 1992-09-01 Res Development Corp. Thermoplastic polymers with dispersed fluorocarbon additives
US5688864A (en) 1990-04-03 1997-11-18 Ppg Industries, Inc. Autophobic water repellent surface treatment
US5328768A (en) 1990-04-03 1994-07-12 Ppg Industries, Inc. Durable water repellant glass surface
US5419969A (en) 1990-07-05 1995-05-30 Asahi Glass Company Ltd. Low emissivity film
CA2022039A1 (en) 1990-07-26 1992-01-27 Julio O. Gun Composition for producing a monomolecular film on the surfaces of various materials
US5240886A (en) 1990-07-30 1993-08-31 Ppg Industries, Inc. Ultraviolet absorbing, green tinted glass
US5455081A (en) 1990-09-25 1995-10-03 Nippon Steel Corporation Process for coating diamond-like carbon film and coated thin strip
US5527596A (en) 1990-09-27 1996-06-18 Diamonex, Incorporated Abrasion wear resistant coated substrate product
US5135808A (en) 1990-09-27 1992-08-04 Diamonex, Incorporated Abrasion wear resistant coated substrate product
US5637353A (en) 1990-09-27 1997-06-10 Monsanto Company Abrasion wear resistant coated substrate product
US5268217A (en) 1990-09-27 1993-12-07 Diamonex, Incorporated Abrasion wear resistant coated substrate product
US5190807A (en) 1990-10-18 1993-03-02 Diamonex, Incorporated Abrasion wear resistant polymeric substrate product
EP0492545B1 (en) 1990-12-25 1998-03-25 Matsushita Electric Industrial Co., Ltd. Transparent substrate with monomolecular film thereon and method of manufacturing the same
DE69232591T2 (en) 1991-01-23 2002-08-22 Matsushita Electric Ind Co Ltd Water and oil repellent adsorbed film
JP2929779B2 (en) 1991-02-15 1999-08-03 トヨタ自動車株式会社 Water-repellent glass with carbon coating
US5352493A (en) 1991-05-03 1994-10-04 Veniamin Dorfman Method for forming diamond-like nanocomposite or doped-diamond-like nanocomposite films
US5718976A (en) 1991-05-03 1998-02-17 Advanced Refractory Technologies, Inc. Erosion resistant diamond-like nanocomposite coatings for optical components
JPH0597478A (en) 1991-10-04 1993-04-20 Nippon Sheet Glass Co Ltd Water repellent glass article and its production
US5229194A (en) 1991-12-09 1993-07-20 Guardian Industries Corp. Heat treatable sputter-coated glass systems
BR9204887A (en) 1991-12-23 1993-06-29 Comision Nac Energ Atom PROCESS FOR FORMING A SOLID SUBSTRATE ON A PROPERTY FILM SIMILAR TO THE DIAMOND, THE SOLID BODIES SO COATED AND THE COVERED FILM SO OBTAINED
JPH05170486A (en) 1991-12-25 1993-07-09 Central Glass Co Ltd Water repellent for glass surface and water-repellent glass
US5543371A (en) 1992-03-31 1996-08-06 Sumitomo Electric Industries, Ltd. Slide member and method of manufacturing the same
US5344718A (en) 1992-04-30 1994-09-06 Guardian Industries Corp. High performance, durable, low-E glass
US5214008A (en) 1992-04-17 1993-05-25 Guardian Industries Corp. High visible, low UV and low IR transmittance green glass composition
JP2815057B2 (en) 1992-06-08 1998-10-27 キヤノン株式会社 Mold for molding optical element, method for producing the same, optical element and lens
US5425983A (en) 1992-08-10 1995-06-20 Santa Barbara Research Center Infrared window protected by multilayer antireflective coating
JP2906006B2 (en) 1992-10-15 1999-06-14 東京エレクトロン株式会社 Processing method and apparatus
US5435900A (en) 1992-11-04 1995-07-25 Gorokhovsky; Vladimir I. Apparatus for application of coatings in vacuum
US5449531A (en) 1992-11-09 1995-09-12 North Carolina State University Method of fabricating oriented diamond films on nondiamond substrates and related structures
GB9224697D0 (en) * 1992-11-25 1993-01-13 Amaratunga Gehan A J Doping of highly tetrahedral diamond-like amorphous carbon
US6001431A (en) 1992-12-28 1999-12-14 Semiconductor Energy Laboratory Co., Ltd. Process for fabricating a magnetic recording medium
US5470661A (en) 1993-01-07 1995-11-28 International Business Machines Corporation Diamond-like carbon films from a hydrocarbon helium plasma
US5474816A (en) 1993-04-16 1995-12-12 The Regents Of The University Of California Fabrication of amorphous diamond films
US5688585A (en) 1993-08-05 1997-11-18 Guardian Industries Corp. Matchable, heat treatable, durable, IR-reflecting sputter-coated glasses and method of making same
US5376455A (en) 1993-10-05 1994-12-27 Guardian Industries Corp. Heat-treatment convertible coated glass and method of converting same
US5415297A (en) 1993-10-26 1995-05-16 Lynk, Inc. Storage rack for optical disc storage cases
US5674625A (en) 1993-11-10 1997-10-07 Central Glass Company, Limited Multilayered water-repellent film and method of forming same on glass substrate
US5616179A (en) 1993-12-21 1997-04-01 Commonwealth Scientific Corporation Process for deposition of diamondlike, electrically conductive and electron-emissive carbon-based films
US5731046A (en) 1994-01-18 1998-03-24 Qqc, Inc. Fabrication of diamond and diamond-like carbon coatings
US5846649A (en) 1994-03-03 1998-12-08 Monsanto Company Highly durable and abrasion-resistant dielectric coatings for lenses
US5508368A (en) 1994-03-03 1996-04-16 Diamonex, Incorporated Ion beam process for deposition of highly abrasion-resistant coatings
US5888593A (en) 1994-03-03 1999-03-30 Monsanto Company Ion beam process for deposition of highly wear-resistant optical coatings
EP0755460B1 (en) 1994-04-06 1999-01-27 The Regents Of The University Of California Process to produce diamond films
US5571569A (en) 1994-04-14 1996-11-05 Kabushiki Kaisha Toyoda Jidoshokki Seisakusho Thin-film forming method
US5507987A (en) 1994-04-28 1996-04-16 Saint Gobain/Norton Industrial Ceramics Corp. Method of making a free-standing diamond film with reduced bowing
JP3498363B2 (en) 1994-06-13 2004-02-16 住友電気工業株式会社 Diamond synthesis method
US5518780A (en) 1994-06-16 1996-05-21 Ford Motor Company Method of making hard, transparent amorphous hydrogenated boron nitride films
US5614574A (en) 1994-07-12 1997-03-25 Lyondell Petrochemical Company Wettable polyolefin fiber compositions and method
US5559367A (en) 1994-07-12 1996-09-24 International Business Machines Corporation Diamond-like carbon for use in VLSI and ULSI interconnect systems
FR2722493B1 (en) 1994-07-13 1996-09-06 Saint Gobain Vitrage MULTI-LAYERED HYDROPHOBIC GLAZING
US5527559A (en) 1994-07-18 1996-06-18 Saint Gobain/Norton Industrial Ceramics Corp. Method of depositing a diamond film on a graphite substrate
DE4428234C1 (en) 1994-08-10 1995-08-31 Jenaer Glaswerk Gmbh Coloured boro-silicate glass useful e.g. as filter or solar absorber
JP2788412B2 (en) 1994-08-11 1998-08-20 麒麟麦酒株式会社 Apparatus and method for producing carbon film-coated plastic container
US5873921A (en) 1994-09-09 1999-02-23 Hoya Precisions Inc. Process for manufacturing glass optical elements
FR2726579A1 (en) 1994-11-07 1996-05-10 Neuville Stephane PROCESS FOR DEPOSITING A PROTECTIVE COATING OF THE PSEUDO CARBON DIAMOND AMORPHOUS TYPE
FR2727107B1 (en) 1994-11-21 1996-12-27 Saint Gobain Vitrage GLAZING PROVIDED WITH AT LEAST ONE THIN FILM AND PROCESS FOR OBTAINING SAME
US5514476A (en) 1994-12-15 1996-05-07 Guardian Industries Corp. Low-E glass coating system and insulating glass units made therefrom
US5557462A (en) 1995-01-17 1996-09-17 Guardian Industries Corp. Dual silver layer Low-E glass coating system and insulating glass units made therefrom
US5538151A (en) 1995-01-20 1996-07-23 International Business Machines Corp. Recovery of an anodically bonded glass device from a susstrate by use of a metal interlayer
TW366367B (en) 1995-01-26 1999-08-11 Ibm Sputter deposition of hydrogenated amorphous carbon film
EP0723944A1 (en) 1995-01-26 1996-07-31 Optical Coating Laboratory, Inc. Wear resistant windows
US5624718A (en) 1995-03-03 1997-04-29 Southwest Research Institue Diamond-like carbon based electrocatalytic coating for fuel cell electrodes
EP0743375B1 (en) 1995-03-31 2000-07-12 CeramOptec GmbH Method of producing diamond-like-carbon coatings
US5635258A (en) 1995-04-03 1997-06-03 National Science Council Method of forming a boron-doped diamond film by chemical vapor deposition
US5762715A (en) 1995-06-07 1998-06-09 Saint-Gobain/Norton Industrial Ceramics Corporation Segmented substrate for improved ARC-JET diamond deposition
US5763064A (en) 1995-06-26 1998-06-09 Asahi Glass Company Ltd. Laminate
LU88653A1 (en) 1995-09-06 1996-10-04 Glaverbel Soda-lime dark light gray glass
US5653812A (en) 1995-09-26 1997-08-05 Monsanto Company Method and apparatus for deposition of diamond-like carbon coatings on drills
DE19536708C1 (en) 1995-09-30 1996-10-31 Jenaer Glaswerk Gmbh Boro-silicate glass contg. zirconium and lithium oxide(s)
US5795648A (en) 1995-10-03 1998-08-18 Advanced Refractory Technologies, Inc. Method for preserving precision edges using diamond-like nanocomposite film coatings
US5776103A (en) 1995-10-11 1998-07-07 Science Incorporated Fluid delivery device with bolus injection site
US5776846A (en) 1996-03-01 1998-07-07 Nippon Sheet Glass Co., Ltd. Ultraviolet- and infrared-absorbing glass
MX9605168A (en) 1995-11-02 1997-08-30 Guardian Industries Neutral, high performance, durable low-e glass coating system, insulating glass units made therefrom, and methods of making same.
US5770321A (en) 1995-11-02 1998-06-23 Guardian Industries Corp. Neutral, high visible, durable low-e glass coating system and insulating glass units made therefrom
KR0152251B1 (en) 1995-11-02 1998-10-15 장진 Process for preparation of diamond. like carbon tft-lcd
JP3058066B2 (en) 1995-11-06 2000-07-04 富士電機株式会社 Magnetic recording medium and method of manufacturing the same
US5620745A (en) 1995-12-19 1997-04-15 Saint Gobain/Norton Industrial Ceramics Corp. Method for coating a substrate with diamond film
US5776612A (en) 1996-02-21 1998-07-07 Exotic Materials Inc. Window that transmits light energy and selectively absorbs microwave energy
US5776553A (en) 1996-02-23 1998-07-07 Saint Gobain/Norton Industrial Ceramics Corp. Method for depositing diamond films by dielectric barrier discharge
CA2173676A1 (en) 1996-03-18 1997-09-19 Gregory Bak-Boychuk Diamond film deposition
US5830812A (en) 1996-04-01 1998-11-03 Ppg Industries, Inc. Infrared and ultraviolet radiation absorbing green glass composition
FR2746811B1 (en) 1996-04-02 1998-04-30 Saint Gobain Vitrage COMPOSITION FOR A NON-MOISTABLE COATING, PROCESS FOR TREATING GLAZE USING THE COMPOSITION AND PRODUCTS OBTAINED
US5876753A (en) 1996-04-16 1999-03-02 Board Of Regents, The University Of Texas System Molecular tailoring of surfaces
US5965629A (en) 1996-04-19 1999-10-12 Korea Institute Of Science And Technology Process for modifying surfaces of materials, and materials having surfaces modified thereby
US5900342A (en) 1996-04-26 1999-05-04 Eastman Kodak Company Photoconductive element having an outermost layer of a fluorinated diamond-like carbon and method of making the same
JPH1045425A (en) 1996-05-28 1998-02-17 Nippon Sheet Glass Co Ltd Ultraviolet-ray and infrared-ray absorbing glass
US5858477A (en) 1996-12-10 1999-01-12 Akashic Memories Corporation Method for producing recording media having protective overcoats of highly tetrahedral amorphous carbon
US5792254A (en) 1996-06-12 1998-08-11 Saint-Gobain/Norton Industrial Ceramics Corp. Production of diamond film
US5693928A (en) 1996-06-27 1997-12-02 International Business Machines Corporation Method for producing a diffusion barrier and polymeric article having a diffusion barrier
US5824374A (en) 1996-07-22 1998-10-20 Optical Coating Laboratory, Inc. In-situ laser patterning of thin film layers during sequential depositing
JPH10101368A (en) 1996-10-01 1998-04-21 Nippon Sheet Glass Co Ltd Ultraviolet ray and infrared ray absorbing glass
DE19643550A1 (en) 1996-10-24 1998-05-14 Leybold Systems Gmbh Light-transparent, heat radiation reflecting layer system
US5776845A (en) 1996-12-09 1998-07-07 Ford Motor Company High transmittance green glass with improved UV absorption
US5879775A (en) 1996-12-12 1999-03-09 Eastman Kodak Compnay Protective inorganic and DLC coatings for plastic media such as plastic cards
AU5802698A (en) * 1996-12-19 1998-07-15 Energy Conversion Devices Inc. Selective solar radiation control coatings for windows and plastic films characterized by an absence of silver
US5858551A (en) 1997-01-31 1999-01-12 Seydel Research, Inc. Water dispersible/redispersible hydrophobic polyester resins and their application in coatings
US5880552A (en) 1997-05-27 1999-03-09 The United States Of America As Represented By The Secretary Of The Navy Diamond or diamond like carbon coated chemical sensors and a method of making same
US5851940A (en) 1997-07-11 1998-12-22 Ford Motor Company Blue glass with improved UV and IR absorption
US6046758A (en) 1998-03-10 2000-04-04 Diamonex, Incorporated Highly wear-resistant thermal print heads with silicon-doped diamond-like carbon protective coatings
US6002208A (en) 1998-07-02 1999-12-14 Advanced Ion Technology, Inc. Universal cold-cathode type ion source with closed-loop electron drifting and adjustable ion-emitting slit
US6572935B1 (en) * 1999-03-13 2003-06-03 The Regents Of The University Of California Optically transparent, scratch-resistant, diamond-like carbon coatings
US6277480B1 (en) 1999-05-03 2001-08-21 Guardian Industries Corporation Coated article including a DLC inclusive layer(s) and a layer(s) deposited using siloxane gas, and corresponding method
US6284377B1 (en) 1999-05-03 2001-09-04 Guardian Industries Corporation Hydrophobic coating including DLC on substrate
US6303225B1 (en) 2000-05-24 2001-10-16 Guardian Industries Corporation Hydrophilic coating including DLC on substrate
US6338901B1 (en) * 1999-05-03 2002-01-15 Guardian Industries Corporation Hydrophobic coating including DLC on substrate
US6312808B1 (en) 1999-05-03 2001-11-06 Guardian Industries Corporation Hydrophobic coating with DLC & FAS on substrate
US6261693B1 (en) * 1999-05-03 2001-07-17 Guardian Industries Corporation Highly tetrahedral amorphous carbon coating on glass
US6280834B1 (en) 1999-05-03 2001-08-28 Guardian Industries Corporation Hydrophobic coating including DLC and/or FAS on substrate
US6335086B1 (en) 1999-05-03 2002-01-01 Guardian Industries Corporation Hydrophobic coating including DLC on substrate

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US20020192371A1 (en) 2002-12-19
US6663753B2 (en) 2003-12-16
AU3238802A (en) 2002-05-15

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