WO1998016469A1 - Synthesis of large crystal zeolites - Google Patents
Synthesis of large crystal zeolites Download PDFInfo
- Publication number
- WO1998016469A1 WO1998016469A1 PCT/US1997/018948 US9718948W WO9816469A1 WO 1998016469 A1 WO1998016469 A1 WO 1998016469A1 US 9718948 W US9718948 W US 9718948W WO 9816469 A1 WO9816469 A1 WO 9816469A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- zeohte
- process recited
- temperature
- reaction mixture
- crystals
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C01B39/38—Type ZSM-5
- C01B39/40—Type ZSM-5 using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/29—MEL, e.g. ZSM-11
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97946269A EP0951444B9 (en) | 1996-10-17 | 1997-10-17 | Synthesis of large crystal zeolites |
CA002268767A CA2268767A1 (en) | 1996-10-17 | 1997-10-17 | Synthesis of large crystal zeolites |
JP51864598A JP4455679B2 (en) | 1996-10-17 | 1997-10-17 | Method for producing large crystal zeolite |
DE69705866T DE69705866T2 (en) | 1996-10-17 | 1997-10-17 | METHOD FOR PRODUCING LARGE ZEOLITE CRYSTALS |
BR9713485-6A BR9713485A (en) | 1996-10-17 | 1997-10-17 | Synthesis of large crystal zeolites |
AU51474/98A AU5147498A (en) | 1996-10-17 | 1997-10-17 | Synthesis of large crystal zeolites |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US2883096P | 1996-10-17 | 1996-10-17 | |
US60/028,830 | 1996-10-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998016469A1 true WO1998016469A1 (en) | 1998-04-23 |
Family
ID=21845695
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/018948 WO1998016469A1 (en) | 1996-10-17 | 1997-10-17 | Synthesis of large crystal zeolites |
Country Status (12)
Country | Link |
---|---|
US (1) | US5958366A (en) |
EP (1) | EP0951444B9 (en) |
JP (1) | JP4455679B2 (en) |
KR (1) | KR100484082B1 (en) |
CN (1) | CN1105680C (en) |
AU (1) | AU5147498A (en) |
BR (1) | BR9713485A (en) |
CA (1) | CA2268767A1 (en) |
DE (1) | DE69705866T2 (en) |
TW (1) | TW352379B (en) |
WO (1) | WO1998016469A1 (en) |
ZA (1) | ZA979264B (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000006494A1 (en) * | 1998-07-29 | 2000-02-10 | Exxon Chemical Patents, Inc. | Crystalline molecular sieves |
FR2785279A1 (en) * | 1998-11-02 | 2000-05-05 | Inst Francais Du Petrole | Synthesis of a zeolite of structural type EUO, useful for e.g. the preparation of isomerization catalysts for eight carbon aromatic hydrocarbons, with the aid of seeds of another zeolitic material |
NL1013892C2 (en) * | 1998-12-23 | 2000-06-26 | Inst Francais Du Petrole | Zeolite EUO, containing crystals and aggregates of crystals of certain grain sizes, and its use as a catalyst for the isomerization of C8 aromatics. |
FR2805255A1 (en) * | 2000-02-21 | 2001-08-24 | Inst Francais Du Petrole | ZEOLITHE MTT COMPRISING CRYSTALS AND CRYSTAL AGGREGATES OF SPECIFIC GRANULOMETRIES AND ITS USE AS A CATALYST FOR ISOMERIZATION OF LINEAR PARAFFINS |
US6388156B1 (en) | 1999-05-14 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2 |
US6459006B1 (en) | 1999-05-14 | 2002-10-01 | Exxonmobil Chemical Patents Inc. | Selective methylation to para-xylene using fuel syngas |
US6613708B1 (en) | 1999-06-07 | 2003-09-02 | Exxonmobil Chemical Patents Inc. | Catalyst selectivation |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6403855B1 (en) * | 1999-12-28 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Synthesis of crystalline silicoaluminophosphates and use in olefin production |
EP1138386A1 (en) * | 2000-03-29 | 2001-10-04 | Degussa AG | Process for the preparation of titanium silicalite shaped body |
JP4241068B2 (en) * | 2002-03-07 | 2009-03-18 | 昭和電工株式会社 | Method for producing MWW type zeolite material |
US6867341B1 (en) * | 2002-09-17 | 2005-03-15 | Uop Llc | Catalytic naphtha cracking catalyst and process |
US7125821B2 (en) | 2003-09-05 | 2006-10-24 | Exxonmobil Chemical Patents Inc. | Low metal content catalyst compositions and processes for making and using same |
US7442365B1 (en) * | 2004-06-14 | 2008-10-28 | Uop Llc | Process for preparing molecular sieve beads |
US7449168B2 (en) | 2004-12-27 | 2008-11-11 | Saudi Basic Industries Corporation | Process for making a germanium-zeolite |
US8048402B2 (en) * | 2005-08-18 | 2011-11-01 | Exxonmobil Chemical Patents Inc. | Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins |
KR100919128B1 (en) * | 2007-12-27 | 2009-09-25 | 한국건설기술연구원 | The synthesis method of zeolite by calcination at high temperature and its product |
SG188173A1 (en) * | 2008-02-22 | 2013-03-28 | Exxonmobil Chem Patents Inc | Large crystal molecular sieves and their manufacture |
US8609925B2 (en) * | 2008-06-30 | 2013-12-17 | Uop Llc | Adsorbents with improved mass transfer properties and their use in the adsorptive separation of para-xylene |
US9623364B1 (en) * | 2008-12-15 | 2017-04-18 | University Of Puerto Rico | Removal of carbon dioxide from gas mixtures using ion-exchanged silicoaluminophosphates |
EP2440328B1 (en) | 2009-06-12 | 2016-08-17 | Albemarle Europe Sprl. | Sapo molecular sieve catalysts and their preparation and uses |
JP5615530B2 (en) * | 2009-11-20 | 2014-10-29 | ユニゼオ株式会社 | Method for producing MTW-type zeolite |
JP5351216B2 (en) * | 2010-07-01 | 2013-11-27 | 日本化学工業株式会社 | Method for producing zeolite |
US20120093715A1 (en) * | 2010-10-19 | 2012-04-19 | Uop Llc | Monolithic zeolite structures with and without hierarchical pore structures and methods for producing the same |
US20120157741A1 (en) * | 2010-12-17 | 2012-06-21 | Guang Cao | Synthesis of Silicoaluminophosphate Having Lev Framework-Type |
JP6338493B2 (en) * | 2014-09-18 | 2018-06-06 | 国立大学法人広島大学 | Method for producing MEI zeolite and MEI zeolite containing phosphorus |
CN111170333A (en) * | 2018-11-13 | 2020-05-19 | 中国科学院大连化学物理研究所 | Synthesis method of large-grain EU-1 molecular sieve |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB777233A (en) * | 1953-12-24 | 1957-06-19 | Union Carbide & Carbon Corp | Crystalline synthetic zeolites |
GB831076A (en) * | 1955-06-20 | 1960-03-23 | Union Carbide Corp | Improved process for manufacture of molecular sieve adsorbents |
EP0026963A1 (en) * | 1979-10-09 | 1981-04-15 | Mobil Oil Corporation | Method of producing large crystal zeolite ZSM-5 with controlled crystal size, and zeolite produced by this method |
JPS5926917A (en) * | 1982-08-06 | 1984-02-13 | Kao Corp | Preparation of crystalline aluminosilicate |
EP0156594A2 (en) * | 1984-03-23 | 1985-10-02 | Mobil Oil Corporation | A continuous process for manufacturing crystalline zeolites |
US4650656A (en) * | 1977-05-25 | 1987-03-17 | Mobil Oil Corporation | Large crystal ZSM-5 from template addition to the gel |
WO1993008124A1 (en) * | 1991-10-23 | 1993-04-29 | Exxon Chemical Patents Inc. | Process for preparing uniform mfi-type zeolite crystals |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3920798A (en) * | 1973-05-08 | 1975-11-18 | Union Carbide Corp | Zeolite y synthesis |
US4406822A (en) * | 1981-10-05 | 1983-09-27 | Ethyl Corporation | Method of making zeolites |
IT1152998B (en) * | 1982-07-01 | 1987-01-14 | Anic Spa | PROCEDURE FOR THE PREPARATION OF ALUMINUM-SILICATE POROUS CRYSTALS |
DE69318553T2 (en) * | 1992-06-05 | 1998-12-10 | Exxon Chemical Patents Inc | ZSM 22 ZEOLITH |
DE4323774A1 (en) * | 1993-07-15 | 1995-02-09 | Basf Ag | Hollow ball-like agglomerated pentasil zeolites |
US5714133A (en) * | 1994-06-13 | 1998-02-03 | Mobil Oil Corporation | Crystalline aluminosilicate zeolite syntheses |
-
1997
- 1997-10-16 ZA ZA979264A patent/ZA979264B/en unknown
- 1997-10-17 EP EP97946269A patent/EP0951444B9/en not_active Expired - Lifetime
- 1997-10-17 KR KR19997003345A patent/KR100484082B1/en not_active IP Right Cessation
- 1997-10-17 CA CA002268767A patent/CA2268767A1/en not_active Abandoned
- 1997-10-17 DE DE69705866T patent/DE69705866T2/en not_active Expired - Fee Related
- 1997-10-17 WO PCT/US1997/018948 patent/WO1998016469A1/en active IP Right Grant
- 1997-10-17 JP JP51864598A patent/JP4455679B2/en not_active Expired - Fee Related
- 1997-10-17 US US08/954,341 patent/US5958366A/en not_active Expired - Lifetime
- 1997-10-17 BR BR9713485-6A patent/BR9713485A/en not_active Application Discontinuation
- 1997-10-17 CN CN97199907A patent/CN1105680C/en not_active Expired - Fee Related
- 1997-10-17 AU AU51474/98A patent/AU5147498A/en not_active Abandoned
-
1998
- 1998-02-16 TW TW86115413A patent/TW352379B/en active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB777233A (en) * | 1953-12-24 | 1957-06-19 | Union Carbide & Carbon Corp | Crystalline synthetic zeolites |
GB831076A (en) * | 1955-06-20 | 1960-03-23 | Union Carbide Corp | Improved process for manufacture of molecular sieve adsorbents |
US4650656A (en) * | 1977-05-25 | 1987-03-17 | Mobil Oil Corporation | Large crystal ZSM-5 from template addition to the gel |
EP0026963A1 (en) * | 1979-10-09 | 1981-04-15 | Mobil Oil Corporation | Method of producing large crystal zeolite ZSM-5 with controlled crystal size, and zeolite produced by this method |
JPS5926917A (en) * | 1982-08-06 | 1984-02-13 | Kao Corp | Preparation of crystalline aluminosilicate |
EP0156594A2 (en) * | 1984-03-23 | 1985-10-02 | Mobil Oil Corporation | A continuous process for manufacturing crystalline zeolites |
WO1993008124A1 (en) * | 1991-10-23 | 1993-04-29 | Exxon Chemical Patents Inc. | Process for preparing uniform mfi-type zeolite crystals |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 008, no. 114 (C - 225) 26 May 1984 (1984-05-26) * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000006494A1 (en) * | 1998-07-29 | 2000-02-10 | Exxon Chemical Patents, Inc. | Crystalline molecular sieves |
US7264789B1 (en) | 1998-07-29 | 2007-09-04 | Exxonmobil Chemical Patents Inc. | Crystalline molecular sieves |
FR2785279A1 (en) * | 1998-11-02 | 2000-05-05 | Inst Francais Du Petrole | Synthesis of a zeolite of structural type EUO, useful for e.g. the preparation of isomerization catalysts for eight carbon aromatic hydrocarbons, with the aid of seeds of another zeolitic material |
NL1013892C2 (en) * | 1998-12-23 | 2000-06-26 | Inst Francais Du Petrole | Zeolite EUO, containing crystals and aggregates of crystals of certain grain sizes, and its use as a catalyst for the isomerization of C8 aromatics. |
US6514479B1 (en) | 1998-12-23 | 2003-02-04 | Institut Francais Du Petrole | EUO zeolite comprising crystals and aggregates of crystals with specific granulometrys and its use as a catalyst in the isomerisation of C8 aromatic compounds |
US6388156B1 (en) | 1999-05-14 | 2002-05-14 | Exxonmobil Chemical Patents Inc. | Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2 |
US6459006B1 (en) | 1999-05-14 | 2002-10-01 | Exxonmobil Chemical Patents Inc. | Selective methylation to para-xylene using fuel syngas |
US6613708B1 (en) | 1999-06-07 | 2003-09-02 | Exxonmobil Chemical Patents Inc. | Catalyst selectivation |
FR2805255A1 (en) * | 2000-02-21 | 2001-08-24 | Inst Francais Du Petrole | ZEOLITHE MTT COMPRISING CRYSTALS AND CRYSTAL AGGREGATES OF SPECIFIC GRANULOMETRIES AND ITS USE AS A CATALYST FOR ISOMERIZATION OF LINEAR PARAFFINS |
EP1129993A1 (en) * | 2000-02-21 | 2001-09-05 | Institut Francais Du Petrole | Zeolite with MTT-structure containing crystals and crystal aggregates with specific particle size distributions, and its use as isomerization catalyst for linear paraffins |
US6692723B2 (en) | 2000-02-21 | 2004-02-17 | Institut Francais Du Petrole | MTT zeolite comprising crystals and crystal aggregates with specific granulometries, and its use as a catalyst for isomerizing straight chain paraffins |
Also Published As
Publication number | Publication date |
---|---|
EP0951444B1 (en) | 2001-07-25 |
EP0951444A1 (en) | 1999-10-27 |
JP2001506215A (en) | 2001-05-15 |
JP4455679B2 (en) | 2010-04-21 |
EP0951444B9 (en) | 2001-12-05 |
AU5147498A (en) | 1998-05-11 |
CA2268767A1 (en) | 1998-04-23 |
TW352379B (en) | 1999-02-11 |
CN1105680C (en) | 2003-04-16 |
DE69705866D1 (en) | 2001-08-30 |
KR100484082B1 (en) | 2005-04-20 |
CN1237947A (en) | 1999-12-08 |
US5958366A (en) | 1999-09-28 |
ZA979264B (en) | 1998-12-29 |
BR9713485A (en) | 2000-10-31 |
KR20000049241A (en) | 2000-07-25 |
DE69705866T2 (en) | 2002-04-11 |
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