WO1997024484A1 - Covering for beds and similar items and method for its manufacture - Google Patents

Covering for beds and similar items and method for its manufacture Download PDF

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Publication number
WO1997024484A1
WO1997024484A1 PCT/BE1996/000135 BE9600135W WO9724484A1 WO 1997024484 A1 WO1997024484 A1 WO 1997024484A1 BE 9600135 W BE9600135 W BE 9600135W WO 9724484 A1 WO9724484 A1 WO 9724484A1
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WO
WIPO (PCT)
Prior art keywords
biocide
fibers
article according
covering
covering article
Prior art date
Application number
PCT/BE1996/000135
Other languages
French (fr)
Inventor
Peter Cornelis Siegfried Kluft
Original Assignee
Sogilo, Naamloze Vennootschap
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sogilo, Naamloze Vennootschap filed Critical Sogilo, Naamloze Vennootschap
Priority to AU13618/97A priority Critical patent/AU1361897A/en
Priority to NZ325161A priority patent/NZ325161A/en
Priority to JP9523920A priority patent/JPH11501246A/en
Priority to IL12160696A priority patent/IL121606A0/en
Priority to EP96943836A priority patent/EP0812372A1/en
Publication of WO1997024484A1 publication Critical patent/WO1997024484A1/en
Priority to NO973939A priority patent/NO973939D0/en

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Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G9/007Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows comprising deodorising, fragrance releasing, therapeutic or disinfecting substances
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47CCHAIRS; SOFAS; BEDS
    • A47C31/00Details or accessories for chairs, beds, or the like, not provided for in other groups of this subclass, e.g. upholstery fasteners, mattress protectors, stretching devices for mattress nets
    • A47C31/007Anti-mite, anti-allergen or anti-bacterial means
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G9/00Bed-covers; Counterpanes; Travelling rugs; Sleeping rugs; Sleeping bags; Pillows
    • A47G2009/001Anti-allergen; Anti-mite

Definitions

  • the present invention relates to a covering article for beds and the like, as well as to a method for making it.
  • the invention relates to a mattress protector; nevertheless, in general, it also relates to other covering articles for beds and the like such as quilts, cushions, filling materials for the latter, bedspreads, sheets, knitted bedspreads, etc. .
  • the above-mentioned covering articles for beds easily form homes in which organisms such as house dust mites and the like can settle.
  • House dust mites for example, feed on fungi and dander on human skin which, as we know, end up in bedding.
  • house dust mites of this type and of organisms of the same species causes, in many cases, allergic reactions. In the case of house dust mites, it is the droppings that cause allergic reactions. Therefore, one should exterminate the house dust mite to prevent allergies.
  • Fibers inter alia intended for bed covering articles, which are treated with a bactericide and / or a fungicide, as well as methods for the treatment during washing, are known in particular from GB-A-2.248 .774, document US-A-3,691,570, document US-A-4,525,409, document EP-A-0.113.254 and document FR-A-2.015.989 as well as according to the literature, more specifically according to the chapter “Antimicrobial protection” of "Textile progress", tome 22 (1992), n ° 2/3/4 and according to the article “Antimikrobielle Ausrustung von Textilien flir den- Spital Berlin" of "Textileveredlung ", volume 26 (October 1991), n ° 10.
  • the house dust mite is an arachnid, that is to say a being which is comparable neither to an insect, nor to a bacterium, nor to a fungus and that, for example products which are developed as insecticide, bactericide or fungicide have little or no effect in this case.
  • the subject of the invention is a covering article for beds and the like, by means of which the above-mentioned problem is avoided and eliminated.
  • the invention consists of a covering article for beds and the like which has the characteristic that it is provided with a house dust mothproof biocide fixed on the article.
  • the house dust moth biocide includes at least one miticide as an active ingredient.
  • a commercially available biocide A is used under the name "Amicide 90HP2".
  • a product based on a natural extract of chrysanthemum petals, more specifically based on pyrethinoid, will be used in accordance with the invention for the acaricide.
  • a further object of the invention is to provide a covering article for beds, in which the abovementioned miticide is applied permanently to the fibers of the covering article so that an active effect can be guaranteed for the life of the fiber, starting from the covering article.
  • the anti-mite biocide of house dust, more specifically the acaricide is fixed to the covering article by means of a binder.
  • the biocide is fixed to the covering article by means of a binder, the advantage is obtained that the biocide is only released very slowly and that a long-lasting effect is guaranteed. Likewise, the advantage is also obtained of being able to wash the covering article several times or even dozens of times without giving rise to the loss of the activity of the biocide.
  • a biocide which exhibits bactericidal, antifungal and acaricidal activity.
  • fungi we destroy these fungi so that we exclude a broth culture for mites of house dust.
  • bactericidal and acaricide action both at the larva stage and at the adult stage with regard to the house dust mite.
  • fungi release spores which in themselves also have a pronounced allergic effect and that by their elimination, it is possible to simultaneously suppress a second source of allergy.
  • use is preferably made of 4-chloro-3-methylphenol, 1Orophophenylphenol and glycol ether.
  • the above-mentioned binder can be of different types. In this case, one can use a product which is already used for other purposes or a product which is used exclusively for fixing the biocide.
  • a binder which consists of an acrylic-based product, more specifically based on perfluorinated acrylic compounds.
  • a melamine-formaldehyde resin can also be added to the binder, so that the layer obtained more optimally meets the requirements imposed.
  • binder it is also possible to add to the binder, other secondary products such as, for example, products which promote resistance to washing and dry washing.
  • the biocide is fixed to the article by means of a binder dried using thermal drying, this thermal drying being able to be carried out both by heating and by lyophilization.
  • a covering article which is composed of a substrate and by a composite layer applied to the latter.
  • the use of a composite layer of this type in combination with the use of the biocide offers the advantage that a large contact surface is obtained on which the biocide can be fixed by means of the binder.
  • the biocide can be mixed with the material of which this coating layer is made so that the material of the coating layer acts as a binder.
  • a coating layer one can choose, in cases of this type, from among the materials listed below: a synthetic material waterproof; latex; a mixture of acrylic resins and polyurethane resins; a mixture of acrylic resins.
  • these fibers are preferably provided with the aforementioned biocide before making the article.
  • the biocide is optimally incorporated into the article.
  • the covering article is a knitted article, but it can also be a commercially available article, such as woven or tufted fabrics.
  • the invention especially demonstrates its usefulness in the case of a mattress protector and / or of what is called an interlayer skin which can be applied over the sheet and / or of an anti-decubitus skin. which is also designated by the expression anti-decubitus mattress pad and / or a bedspread. Indeed, it is most of the time in these articles and especially in interlayer skins of this type, as well as in anti-decubitus skins, that the population of house dust mites is the highest, at least when no specific measures are taken to control house dust mites.
  • the mattress protector is constituted in accordance with the invention, by a skin, of well-defined dimensions, of the aforementioned article formed by a substrate and by a composite layer.
  • a skin of well-defined dimensions, of the aforementioned article formed by a substrate and by a composite layer.
  • which is provided with '' a biocide as indicated above.
  • the invention can be implemented in combination with other kinds of mattress protectors, for example without a composite layer and / or having a base layer based on wool or cotton instead of a synthetic material.
  • the articles according to the invention apart from domestic use, have a complementary value when they are used in hospitals, in establishments for the elderly and in hotels thanks to the hygienic aspect. which is related to the invention.
  • the invention also relates to a method for making a covering article which consists in pretreating the fibers and fixing these fibers on a substrate so that these fibers form a composite layer, with the particularity that the fibers are also treated with during their pretreatment with a biocide, this biocide being fixed on the fibers by means of a binder.
  • the mixture of binder and biocide is sprayed onto the fibers during the carding of the latter.
  • the fibers treated with the biocide are kept, after treatment with the above-mentioned mixture, for a determined time in closed receptacles.
  • the biocide respectively the binder, has the possibility of optimally adhering to the fibers.
  • the back side of the substrate is provided with a biocide by mixing this biocide with a coating material and applying it jointly with the coating material on the back side and / or by applying the biocide to the substrate material before applying the coating layer, primer or coating.
  • a biocide by mixing this biocide with a coating material and applying it jointly with the coating material on the back side and / or by applying the biocide to the substrate material before applying the coating layer, primer or coating.
  • fibers 5 preferably synthetic fibers. These fibers 5 can be delivered in bales.
  • the fibers are successively subjected to different pretreatments.
  • they are represented by blocks 6, 7 and 8.
  • the fibers are dyed.
  • the fibers 5 are stretched for the first time and possibly mixed with fibers from other reserves. This is what is called "pickering".
  • the above steps can be replaced by a supply of fibrous rods, the fibrous rods being cut to obtain fibers of determined lengths.
  • the fibers 5 are subjected to an even better drawing by using carding.
  • the fibers 5 are treated during carding, preferably they are sprayed, with a mixture 9 of the binder with the biocide.
  • the biocide which is a house dust mothproof biocide, is dosed according to a ratio of 0.4 to 0.6% by weight of the total.
  • the treated fibers 4 and 5 are then temporarily stored in closed receptacles 10, for example in bags.
  • a continuous strip 11 is formed, formed by the substrate 2 and by the composite layer 3.
  • a knitting machine 12 is used for this purpose.
  • a substrate 2 is knitted from a fed material 13, for example synthetic knitting yarns and, systematically , the above fibers 5 are fixed therein by knitting them.
  • a primer is applied to the back side 14. This takes place for example by depositing, on the back side, a finishing agent 15 in an installation 16, for example using an automatic doctor blade mechanism, and then fixing this finishing agent 15 by drying in an oven 17.
  • a second addition of biocide is carried out during this step, more specifically by mixing it with the finishing agent 15, for example also in a ratio of 0.4 to 0.6% by weight, or by spraying the biocide onto the substrate, therefore, onto the fabric, before applying the sizing agent 15.
  • the article can still be subjected to various subsequent treatments such as polishing, combing and / or cutting the fibers 5 of the composite layer at the same height.
  • the skins 19 are obtained which either are directly intended to act as mattress protectors or can be subsequently fitted with additional accessories such as buckles. fixation and the like.

Abstract

This covering for beds and similar items has the distinguishing feature of being equipped with an acaricidal biocide installed in the covering.

Description

Article de recouvrement pour des lits et analogues, et procédé pour sa confection. Covering article for beds and the like, and method for making same
La présente invention concerne un article de recouvrement pour des lits et analogues, ainsi qu'un procédé pour sa confection.The present invention relates to a covering article for beds and the like, as well as to a method for making it.
En premier lieu, l'invention concerne un protège-matelas; néanmoins, en général, elle concerne également d'autres articles de recouvrement pour des lits et analogues tels que des couettes, des coussins, des matières de remplissage pour ces derniers, des couvre-lits, des draps, des descentes de lit tricotées, etc.First, the invention relates to a mattress protector; nevertheless, in general, it also relates to other covering articles for beds and the like such as quilts, cushions, filling materials for the latter, bedspreads, sheets, knitted bedspreads, etc. .
Comme il est connu, les articles de recouvrement susmentionnés pour des lits forment facilement des foyers dans lesquels peuvent s'installer des organismes tels que des mites des poussières de maison et analogues.As is known, the above-mentioned covering articles for beds easily form homes in which organisms such as house dust mites and the like can settle.
Des mites des poussières de maison, par exemple, se nourrissent de champignons et de squames de peau humaine qui, comme on le sait, aboutissent dans la literie.House dust mites, for example, feed on fungi and dander on human skin which, as we know, end up in bedding.
La présence de mites des poussières de maison de ce type et d'organismes de même espèce provoque, dans de nombreux cas, des réactions allergiques. Dans le cas des mites des poussières de maison, ce sont les déjections qui provoquent des réactions allergiques. Par conséquent, on doit exterminer la mite des poussières de maison pour prévenir les allergies.The presence of house dust mites of this type and of organisms of the same species causes, in many cases, allergic reactions. In the case of house dust mites, it is the droppings that cause allergic reactions. Therefore, one should exterminate the house dust mite to prevent allergies.
Aussi bien la poussière formée par les déjections que les spores des champignons sont responsables d'allergies respiratoires et de crises d'asthme.Both the dust formed by the droppings and the spores of the fungi are responsible for respiratory allergies and asthma attacks.
Les solutions connues à l'heure actuelle pour lutter contre les mites des poussières de maison de ce type sont simples mais relativement critiquables. Elles consistent à procéder quotidiennement à une aération très minutieuse de la literie, éventuellement à la passer à l'aspirateur ou encore à la laver aussi souvent que possible.The solutions known at present for combating house dust mites of this type are simple but relatively open to criticism. They consist of daily very careful ventilation of the bedding, possibly vacuuming it or washing it as often as possible.
Des fibres, entre autres destinées à des articles de recouvrement de lit, qui sont traitées avec un bactéricide et/ou un fongicide, ainsi que des procédés pour le traitement lors du lavage, sont connus notamment d'après le document GB-A-2.248.774, le document US-A-3.691.570, le document US-A-4.525.409, le document EP-A-0.113.254 et le document FR-A-2.015.989 ainsi que d'après la littérature, plus spécifiquement d'après le chapitre "Antimicrobial protection" de "Textile progress", tome 22 (1992), n° 2/3/4 et d'après l'article "Antimikrobielle Ausrustung von Textilien flir den- Spitalbereich" de "Textileveredlung", tome 26 (octobre 1991), n° 10.Fibers, inter alia intended for bed covering articles, which are treated with a bactericide and / or a fungicide, as well as methods for the treatment during washing, are known in particular from GB-A-2.248 .774, document US-A-3,691,570, document US-A-4,525,409, document EP-A-0.113.254 and document FR-A-2.015.989 as well as according to the literature, more specifically according to the chapter "Antimicrobial protection" of "Textile progress", tome 22 (1992), n ° 2/3/4 and according to the article "Antimikrobielle Ausrustung von Textilien flir den- Spitalbereich" of "Textileveredlung ", volume 26 (October 1991), n ° 10.
Dans tous ces documents, on envisage principalement le monde médico-social. En l'occurrence on tente principalement de tuer les microbes, les bactéries et les champignons. Toutefois, on n'y offre aucune solution qui aurait pour cible de lutter contre les mites des poussières de maison, étant donné que ces dernières ne concernent pas au premier chef le monde médico-social. A cet égard, il convient de mentionner que la mite des poussières de maison est un arachnide, c'est-à-dire une être qui n'est comparable ni à un insecte, ni à une bactérie, ni à un champignon et que, par exemple des produits qui sont mis au point comme insecticide, comme bactéricide ou comme fongicide ont peu d'effet, voire aucun en l'occurrence.In all these documents, we mainly consider the medico-social world. In this case, we are mainly trying to kill microbes, bacteria and fungi. However, there is no solution offered which would target the fight against house dust mites, since these do not concern the first chief of the medico-social world. In this regard, it should be mentioned that the house dust mite is an arachnid, that is to say a being which is comparable neither to an insect, nor to a bacterium, nor to a fungus and that, for example products which are developed as insecticide, bactericide or fungicide have little or no effect in this case.
Toutes les techniques connues présentent également une fixation défectueuse qui est due avant tout à un manque de connaissance de la fixation elle-même.All the known techniques also exhibit a defective fixing which is due above all to a lack of knowledge of the fixing itself.
L'invention a pour objet un article de recouvrement pour des lits et analogues, grâce auquel on évite et on élimine le problème susmentionné.The subject of the invention is a covering article for beds and the like, by means of which the above-mentioned problem is avoided and eliminated.
A cet effet, l'invention consiste en un article de recouvrement pour des lits et analogues qui présente la caractéristique qu'il est muni d'un biocide antimites des poussières de maison fixé sur l'article.To this end, the invention consists of a covering article for beds and the like which has the characteristic that it is provided with a house dust mothproof biocide fixed on the article.
Le biocide antimites des poussières de maison comprend comme ingrédient actif au moins un acaricide.The house dust moth biocide includes at least one miticide as an active ingredient.
De préférence, on utilise un biocide A disponible dans le commerce sous la dénomination "Amicide 90HP2".Preferably, a commercially available biocide A is used under the name "Amicide 90HP2".
De préférence, on utilisera conformément à l'invention pour l'acaricide un produit à base d'un extrait naturel de pétales de chrysanthèmes, plus spécifiquement à base de pyréthinoïde.Preferably, a product based on a natural extract of chrysanthemum petals, more specifically based on pyrethinoid, will be used in accordance with the invention for the acaricide.
Contrairement à la permitrine, cet extrait n'est pas soumis à un traitement de synthèse. Il reste donc sous la forme d'un produit naturel biodégradable. Un objet encore de l'invention consiste à offrir un article de recouvrement pour des lits, dans lequel on applique 1*acaricide précité à demeure sur les fibres de l'article de recouvrement de telle sorte que l'on peut garantir un effet actif pour la durée de vie de la fibre, partant de l'article de recouvrement. A cet effet, on fixe le biocide antimites des poussières de maison, plus spécifiquement l'acaricide, sur l'article de recouvrement au moyen d'un liant.Unlike permitrine, this extract is not subjected to a synthetic treatment. It therefore remains in the form of a biodegradable natural product. A further object of the invention is to provide a covering article for beds, in which the abovementioned miticide is applied permanently to the fibers of the covering article so that an active effect can be guaranteed for the life of the fiber, starting from the covering article. To this end, the anti-mite biocide of house dust, more specifically the acaricide, is fixed to the covering article by means of a binder.
Par le fait que le biocide est fixé sur l'article de recouvrement au moyen d'un liant, on obtient l'avantage que le biocide ne se libère que très lentement et que l'on garantit un effet à longue durée. De même, on obtient également l'avantage de pouvoir laver l'article de recouvrement à plusieurs reprises voire des dizaines de fois sans donner lieu à la perte de l'activité du biocide.By the fact that the biocide is fixed to the covering article by means of a binder, the advantage is obtained that the biocide is only released very slowly and that a long-lasting effect is guaranteed. Likewise, the advantage is also obtained of being able to wash the covering article several times or even dozens of times without giving rise to the loss of the activity of the biocide.
Dans la forme de réalisation de loin préférée, on fait usage d'un biocide qui manifeste une activité aussi bien de bactéricide, que antifongique et acaricide. Ainsi, on obtient la possibilité de lutter contre les mites des poussières de maison sur deux plans. D'une part, on s'oppose ainsi au développement des champignons, respectivement on détruit ces champignons si bien que l'on exclut un bouillon de culture pour les mites des poussières de maison. D'autre part, on lutte- également directement contre les mites des poussières de maison par l'action bactéricide et acaricide, aussi bien au stade de la larve qu'au stade de l'adulte en ce qui concerne la mite des poussières de maison. On remarquera que des champignons libèrent des spores qui ont en soi également un effet allergique prononcé et que par leur élimination, on parvient à supprimer simultanément une seconde source d'allergie. Pour l'effet bactéricide et fongicide, on fait usage de préférence du 4-chloro-3-méthylphénol, de 1Orthophényl- phénol et de l'éther de glycol.In the most preferred embodiment, use is made of a biocide which exhibits bactericidal, antifungal and acaricidal activity. Thus, we get the possibility of combating house dust mites on two levels. On the one hand, we oppose the development of fungi, respectively we destroy these fungi so that we exclude a broth culture for mites of house dust. On the other hand, we also fight directly against house dust mites by the bactericidal and acaricide action, both at the larva stage and at the adult stage with regard to the house dust mite. . It will be noted that fungi release spores which in themselves also have a pronounced allergic effect and that by their elimination, it is possible to simultaneously suppress a second source of allergy. For the bactericidal and fungicidal effect, use is preferably made of 4-chloro-3-methylphenol, 1Orophophenylphenol and glycol ether.
Le liant précité peut être de types différents. En l'occurrence, on peut employer un produit qui est déjà utilisé à d'autres fins ou encore un produit qui est utilisé exclusivement pour la fixation du biocide.The above-mentioned binder can be of different types. In this case, one can use a product which is already used for other purposes or a product which is used exclusively for fixing the biocide.
Dans ce dernier cas, on utilise de préférence un liant qui est constitué par un produit à base d'acrylique, plus spécifiquement à base de composés acryliques perfluorés.In the latter case, a binder is preferably used which consists of an acrylic-based product, more specifically based on perfluorinated acrylic compounds.
Conformément à une autre caractéristique de l'invention, on peut utiliser un liant qui est hydrofuge et oleophobe. Ce liant procure en même temps une protection contre les rayons UV et contre l'aspect mordant des produits de lessive.According to another characteristic of the invention, one can use a binder which is water repellent and oleophobic. At the same time, this binder provides protection against UV rays and the biting appearance of laundry products.
Conformément à l'invention, on peut également ajouter au liant, une résine de mélamine-formaldéhyde, de telle sorte que la couche obtenue répond de manière plus optimale aux exigences imposées.According to the invention, a melamine-formaldehyde resin can also be added to the binder, so that the layer obtained more optimally meets the requirements imposed.
On peut encore ajouter au liant, d'autres produits secondaires tels que par exemple des produits qui favorisent la résistance au lavage et au lavage à sec.It is also possible to add to the binder, other secondary products such as, for example, products which promote resistance to washing and dry washing.
De préférence, le biocide est fixé sur l'article au moyen d'un liant séché à l'aide d'un séchage par voie thermique, ce séchage par voie thermique pouvant être réalisé aussi bien par chauffage que par lyophilisation.Preferably, the biocide is fixed to the article by means of a binder dried using thermal drying, this thermal drying being able to be carried out both by heating and by lyophilization.
Conformément à une forme de réalisation préférée, on part d'un article de recouvrement qui est composé par un substrat et par une couche composite appliquée sur ce dernier. L'utilisation d'une couche composite de ce type en combinaison avec l'utilisation du biocide offre l'avantage que l'on obtient une grande surface de contact sur laquelle le biocide peut se fixer au moyen du liant.According to a preferred embodiment, one starts with a covering article which is composed of a substrate and by a composite layer applied to the latter. The use of a composite layer of this type in combination with the use of the biocide offers the advantage that a large contact surface is obtained on which the biocide can be fixed by means of the binder.
En l'occurrence, on crée également un double effet, c'est-à- dire, d'une part un premier effet s'exerçant sur la base de la matière où se trouve la mite des poussières de maison, et d'autre part également à la surface pour éviter que la mite des poussières de maison ne s'y fixe. Sur la base, on utilise de préférence une concentration supérieure à celle utilisée sur les fibres.In this case, we also create a double effect, that is to say, on the one hand a first effect exerted on the basis of the material where the mite of house dust is found, and on the other also leaves to the surface to prevent the house dust mite from becoming attached to it. On the base, a concentration higher than that used on the fibers is preferably used.
Dans le cas d'un article de recouvrement de ce type, on peut conformément à l'invention appliquer le biocide soit exclusivement sur les fibres de la couche composite, soit exclusivement sur le substrat ou encore l'appliquer aussi bien sur les fibres que sur le substrat.In the case of a covering article of this type, it is possible, in accordance with the invention, to apply the biocide either exclusively to the fibers of the composite layer, or exclusively to the substrate, or else to apply it both to the fibers and to the substrate.
Dans le cas où il s'agit d'un article de recouvrement sur lequel on a déjà prévu une couche d'enduction, comme par exmeple un apprêt, pour rendre par exemple cet article etanche à l'eau, on peut mélanger le biocide avec la matière dont est constituée cette couche d'enduction de telle sorte que la matière de la couche d'enduction fait office de liant.In the case of a covering article on which a coating layer has already been provided, such as a primer, to make this article waterproof, for example, the biocide can be mixed with the material of which this coating layer is made so that the material of the coating layer acts as a binder.
Comme couche d'enduction, on peut faire son choix, dans des cas de ce type, parmi des matières énumérées ci-après: une matière synthétique etanche à l'eau; du latex; un mélange de résines acryliques et résines de polyuréthanne; un mélange de résines acryliques.As a coating layer, one can choose, in cases of this type, from among the materials listed below: a synthetic material waterproof; latex; a mixture of acrylic resins and polyurethane resins; a mixture of acrylic resins.
Dans le cas où il s'agit d'un article de recouvrement qui est composé au moins en partie de fibres, comme c'est le cas par exemple, pour le composite précité, ces fibres sont munies de préférence du biocide précité avant la confection de l'article. Ainsi, on obtient le fait que le biocide est incorporé de manière optimale dans l'article.In the case of a covering article which is composed at least in part of fibers, as is the case for example, for the aforementioned composite, these fibers are preferably provided with the aforementioned biocide before making the article. Thus, one obtains the fact that the biocide is optimally incorporated into the article.
Conformément à une forme de réalisation préférée, l'article de recouvrement est un article tricoté, mais il peut également s'agir d'un article disponible dans le commerce, tel que des étoffes tissées ou tufetées.According to a preferred embodiment, the covering article is a knitted article, but it can also be a commercially available article, such as woven or tufted fabrics.
L'invention manifeste surtout son utilité dans le cas d'un protège-matelas et/ou de ce que l'on appelle une peau intercalaire que l'on peut appliquer par-dessus le drap et/ou d'une peau anti-escarres que l'on désigne également par l'expression alèse anti-décubitus et/ou d'un couvre-lit. En effet, c'est la plupart du temps dans ces articles et surtout dans des peaux intercalaires de ce type, ainsi que dans des peaux anti-escarres, que la population des mites des poussières de maison est la plus élevée, du moins lorsqu'aucune mesure spécifique n'est prise pour lutter contre les mites des poussières de maison.The invention especially demonstrates its usefulness in the case of a mattress protector and / or of what is called an interlayer skin which can be applied over the sheet and / or of an anti-decubitus skin. which is also designated by the expression anti-decubitus mattress pad and / or a bedspread. Indeed, it is most of the time in these articles and especially in interlayer skins of this type, as well as in anti-decubitus skins, that the population of house dust mites is the highest, at least when no specific measures are taken to control house dust mites.
Par conséquent, dans une forme de réalisation optimale, le protège-matelas est constitué conformément à l'invention, par une peau, de dimensions bien définies, de l'article précité formé par un substrat et par une couche composite .qui est munie d'un biocide comme indiqué ci-dessus. Toutefois, ceci n'exclut pas que l'invention puisse être mise en oeuvre en combinaison avec d'autres sortes de protège-matelas, par exemple sans couche composite et/ou possédant une couche de fond à base de laine ou de coton au lieu d'une matière synthétique.Consequently, in an optimal embodiment, the mattress protector is constituted in accordance with the invention, by a skin, of well-defined dimensions, of the aforementioned article formed by a substrate and by a composite layer. Which is provided with '' a biocide as indicated above. However, this does not exclude that the invention can be implemented in combination with other kinds of mattress protectors, for example without a composite layer and / or having a base layer based on wool or cotton instead of a synthetic material.
Dans le cas de coussins et de couettes, y compris des couettes en matière composite, il est préférable de réaliser, et la matière de remplissage, et la housse conformément à l'invention.In the case of cushions and quilts, including composite quilts, it is preferable to realize, and the filling material, and the cover according to the invention.
Il est à noter que les articles selon l'invention, en-dehors de l'utilisation domestique, ont une valeur complémentaires lorsqu'on les utilise dans des hôpitaux, dans des établissements pour personnes âgées et dans des hôtels grâce à l'aspect hygiénique qui est lié à l'invention.It should be noted that the articles according to the invention, apart from domestic use, have a complementary value when they are used in hospitals, in establishments for the elderly and in hotels thanks to the hygienic aspect. which is related to the invention.
Enfin, l'invention concerne également un procédé pour confectionner un article de recouvrement qui consiste à prétraiter les fibres et à fixer ces fibres sur un substrat de telle sorte que ces fibres forment une couche composite, avec cette particularité que les fibres sont également traitées au cours de leur prétraitement avec un biocide, ce biocide étant fixé sur les fibres au moyen d'un liant.Finally, the invention also relates to a method for making a covering article which consists in pretreating the fibers and fixing these fibers on a substrate so that these fibers form a composite layer, with the particularity that the fibers are also treated with during their pretreatment with a biocide, this biocide being fixed on the fibers by means of a binder.
Dans une forme de réalisation très pratique, on pulvérise le mélange du liant et du biocide sur les fibres au cours du cardage de ces dernières.In a very practical embodiment, the mixture of binder and biocide is sprayed onto the fibers during the carding of the latter.
Dans une forme de réalisation particulière, on conserve les fibres traitées avec le biocide, après le traitement avec le mélange précité, pendant un temps déterminé dans des réceptacles fermés. Ainsi, le biocide, respectivement le liant a la possibilité d'adhérer de manière optimale aux fibres.In a particular embodiment, the fibers treated with the biocide are kept, after treatment with the above-mentioned mixture, for a determined time in closed receptacles. Thus, the biocide, respectively the binder, has the possibility of optimally adhering to the fibers.
Dans une forme de réalisation préférée du procédé, on munit le côté dorsal du substrat d'un biocide en mélangeant ce biocide avec une matière d'enduction et en l'appliquant conjointement avec la matière d'enduction sur le côté dorsal et/ou en appliquant le biocide sur la matière du substrat avant l'application de la couche d'enduction, de l'apprêt ou du revêtement. Dans le but de mieux faire ressortir les caractéristiques de l'invention, on décrit ci-après à titre d'exemple, sans aucun caractère limitatif, une forme de réalisation préférée d'un procédé de confection d'un article de recouvrement de l'invention en se référant à la figure unique annexée qui représente de manière schématique le procédé de fabrication.In a preferred embodiment of the method, the back side of the substrate is provided with a biocide by mixing this biocide with a coating material and applying it jointly with the coating material on the back side and / or by applying the biocide to the substrate material before applying the coating layer, primer or coating. In order to better highlight the characteristics of the invention, there is described below by way of example, without any limiting character, a preferred embodiment of a method of making an article of covering the invention with reference to the single appended figure which schematically represents the manufacturing process.
En l'occurrence, il s'agit d'un procédé de fabrication pour la confection de protège-matelas 1 qui sont composés d'un substrat 2 et d'une couche composite 3 fixée sur ce dernier.In this case, it is a manufacturing process for making mattress protectors 1 which are composed of a substrate 2 and a composite layer 3 fixed on the latter.
Pour la couche composite 3, on part d'une alimentation 4 en fibres 5, de préférence en fibres synthétiques. Ces fibres 5 peuvent être livrées en balles.For the composite layer 3, we start with a supply 4 of fibers 5, preferably synthetic fibers. These fibers 5 can be delivered in bales.
Les fibres sont soumises successivement à différents prétraitements. Dans le schéma logique de la figure, on les représente par les blocs 6, 7 et 8.The fibers are successively subjected to different pretreatments. In the logic diagram of the figure, they are represented by blocks 6, 7 and 8.
Dans la première étape représentée par le bloc 6, les fibres sont teintées.In the first step represented by block 6, the fibers are dyed.
Dans l'étape qui est représentée par le bloc 7, on étire une première fois les fibres 5 et on les mélange éventuellement avec des fibres provenant d'autres réserves. Il s'agit en l'occurrence de ce que-l'on appelle le "pickering".In the step which is represented by block 7, the fibers 5 are stretched for the first time and possibly mixed with fibers from other reserves. This is what is called "pickering".
En variante, on peut remplacer les étapes précitées par une alimentation de tiges fibreuses, les tiges fibreuses étant découpées pour obtenir des fibres de longueurs déterminées.Alternatively, the above steps can be replaced by a supply of fibrous rods, the fibrous rods being cut to obtain fibers of determined lengths.
Dans l'étape qui est représentée par le bloc 8, on soumet les fibres 5 à un meilleur étirage encore en utilisant un cardage. Conformément à l'invention, on traite les fibres 5 au cours du cardage, de préférence on les pulvérise, avec un mélange 9 du liant avec le biocide. Le biocide, qui est un biocide antimites des poussières de maison, est dosé conformément à un rapport de 0,4 à 0,6% en poids du total.In the step which is represented by block 8, the fibers 5 are subjected to an even better drawing by using carding. According to the invention, the fibers 5 are treated during carding, preferably they are sprayed, with a mixture 9 of the binder with the biocide. The biocide, which is a house dust mothproof biocide, is dosed according to a ratio of 0.4 to 0.6% by weight of the total.
Les fibres traitées 4 et 5 sont alors provisoirement stockées dans des réceptacles fermés 10, par exemple dans des sacs.The treated fibers 4 and 5 are then temporarily stored in closed receptacles 10, for example in bags.
Ensuite, on forme une bande continue 11 constituée par le substrat 2 et par la couche composite 3.Next, a continuous strip 11 is formed, formed by the substrate 2 and by the composite layer 3.
Dans l'exemple représenté, on utilise à cet effet une machine à tricoter 12. Dans cette machine à tricoter 12, on tricote un substrat 2 à partir d'un matière alimentée 13, par exemple des fils synthétiques à tricoter et, de manière systématique, on y fixe les fibres précitées 5 en les tricotant.In the example shown, a knitting machine 12 is used for this purpose. In this knitting machine 12, a substrate 2 is knitted from a fed material 13, for example synthetic knitting yarns and, systematically , the above fibers 5 are fixed therein by knitting them.
Ensuite, on applique un apprêt sur le côté dorsal 14. Ceci a lieu par exemple en déposant, sur le côté dorsal, un agent d'apprêtage 15 dans une installation 16, par exemple à l'aide d'un mécanisme automatique à racle, et en fixant ensuite cet agent d'apprêtage 15 par séchage dans un four 17.Then, a primer is applied to the back side 14. This takes place for example by depositing, on the back side, a finishing agent 15 in an installation 16, for example using an automatic doctor blade mechanism, and then fixing this finishing agent 15 by drying in an oven 17.
Conformément à l'invention, on procède au cours de cette étape à une seconde addition de biocide, plus spécifiquement en le mélangeant avec l'agent d'apprêtage 15, par exemple également dans un rapport de 0,4 à 0,6% en poids, ou bien en pulvérisant le biocide sur le substrat, par conséquent, sur l'étoffe, avant d'appliquer l'agent d'apprêtage 15. Dans un poste 18, l'article peut être encore soumis à différents traitements ultérieurs tels que le polissage, le peignage et/ou le découpage des fibres 5 de la couche composite à la même hauteur.In accordance with the invention, a second addition of biocide is carried out during this step, more specifically by mixing it with the finishing agent 15, for example also in a ratio of 0.4 to 0.6% by weight, or by spraying the biocide onto the substrate, therefore, onto the fabric, before applying the sizing agent 15. In a station 18, the article can still be subjected to various subsequent treatments such as polishing, combing and / or cutting the fibers 5 of the composite layer at the same height.
Après l'avoir coupé à la longueur et/ou à la largeur qui convient, on obtient les peaux 19 qui, soit sont directement destinées à faire office de protège-matelas, soit peuvent être munies ultérieurement d'accessoires supplémentaires tels que des boucles de fixation et analogues.After having cut it to the appropriate length and / or width, the skins 19 are obtained which either are directly intended to act as mattress protectors or can be subsequently fitted with additional accessories such as buckles. fixation and the like.
La présente invention n'est en aucune façon limitée à la forme de réalisation décrite à titre d'exemple et représentée dans la figure; article de recouvrement de ce type peut être mis en oeuvre dans différentes formes et dans différentes dimensions sans sortir du cadre de l'invention.The present invention is in no way limited to the embodiment described by way of example and shown in the figure; This type of covering article can be implemented in different shapes and in different dimensions without departing from the scope of the invention.
C'est ainsi que, par exemple dans le cas d'un oreiller muni d'un recouvrement en matière composite, on se borne à pulvériser les fibres. Thus, for example in the case of a pillow provided with a covering of composite material, it is limited to spraying the fibers.

Claims

REVENDICATIONS
1.- Article de recouvrement pour des lits et analogues, caractérisé en qu'il est muni d'un biocide antimites des poussières de maison, fixé sur l'article.1.- Covering article for beds and the like, characterized in that it is provided with a house dust mothproof biocide, fixed on the article.
2.- Article de recouvrement selon la revendication 1, caractérisé en ce que le biocide contient comme ingrédient actif au moins un acaricide.2. A covering article according to claim 1, characterized in that the biocide contains as active ingredient at least one acaricide.
3.- Article de recouvrement selon la revendication 1 ou 2, caractérisé en ce que l'ingrédient actif comprend au moins un extrait formé à partir de pétales de chrysanthèmes.3. A covering article according to claim 1 or 2, characterized in that the active ingredient comprises at least one extract formed from petals of chrysanthemums.
4.- Article de recouvrement selon la revendication 3, caractérisé en ce que l'ingrédient actif contient des pyréthinoïdes naturels.4. A covering article according to claim 3, characterized in that the active ingredient contains natural pyrethinoids.
5.- Article de recouvrement selon l'une quelconque des revendications précédentes, caractérisé en ce que le biocide comprend des ingrédients actifs qui présentent outre une activité acaricide, également une activité bactéricide et antifongique, respectivement fongicide.5. Cover article according to any one of the preceding claims, characterized in that the biocide comprises active ingredients which, in addition to acaricidal activity, also have bactericidal and antifungal activity, respectively fungicidal.
6.- Article de recouvrement selon la revendication 5, caractérisé en ce que le biocide comprend du 4-chloro-3- méthylphénol, de l'orthophénylphénol et de l'éther de glycol.6. A covering article according to claim 5, characterized in that the biocide comprises 4-chloro-3-methylphenol, orthophenylphenol and glycol ether.
7.- Article selon l'une quelconque des revendications précédentes, caractérisé en ce que le biocide est fixé sur l'article au moyen d'un liant.7.- Article according to any one of the preceding claims, characterized in that the biocide is fixed to the article by means of a binder.
8.- Article selon l'une quelconque des revendications précédentes, caractérisé en ce que le liant est constitué par un produit à base d'acrylique, plus spécifiquement à base de composés acryliques perfluorés.8.- Article according to any one of the preceding claims, characterized in that the binder is constituted with an acrylic-based product, more specifically based on perfluorinated acrylic compounds.
9.- Article de recouvrement selon les revendications 7 ou 8, caractérisé en ce que le biocide est fixé au moyen d'un liant séché à l'aide d'un processus de séchage par voie thermique, soit par chauffage, soit par lyophilisation.9. A covering article according to claims 7 or 8, characterized in that the biocide is fixed by means of a binder dried using a thermal drying process, either by heating or by lyophilization.
10.- Article de recouvrement selon quelconque des revendications précédentes, caractérisé en ce qu'il constitué par un substrat (2) et par une couche composite (3) .10.- covering article according to any one of the preceding claims, characterized in that it consists of a substrate (2) and a composite layer (3).
11.- Article de recouvrement selon la revendication 10, caractérisé en ce qu'on applique le biocide au moins sur les fibres (5) de la couche composite (3) .11. A covering article according to claim 10, characterized in that the biocide is applied at least to the fibers (5) of the composite layer (3).
12.- Article de recouvrement selon la revendication 10 ou 11, caractérisé en ce que le côté dorsal (14) est muni d'une couche d'enduction de telle sorte que le biocide est mélangé avec la matière, plus spécifiquement avec l'agent d'apprêtage (15) dont est constituée cette couche d'enduction, si bien que la matière de la couche d'enduction fait office de liant.12. A covering article according to claim 10 or 11, characterized in that the back side (14) is provided with a coating layer so that the biocide is mixed with the material, more specifically with the agent. primer (15) of which this coating layer is made, so that the material of the coating layer acts as a binder.
13.- Article de recouvrement selon la revendication 12, caractérisé en ce que la couche d'enduction est 'constituée par une matière choisie parmi la série ci-après: une couche de matière synthétique etanche à l'eau,; du latex; un mélange de résines acryliques et de résines de polyuréthanne; un mélange de résines acryliques.13. A covering article according to claim 12, characterized in that the coating layer is' constituted by a material chosen from the following series: a layer of waterproof synthetic material; latex; a mixture of acrylic resins and polyurethane resins; a mixture of acrylic resins.
14.- Article de recouvrement selon l'une quelconque des revendications 10 à 13, caractérisé en ce qu'on applique le biocide aussi bien sur le côté frontal, mais plus spécifiquement sur les fibres de la couche composite (3) , que sur le côté dorsal (14) .14. A covering article according to any one of claims 10 to 13, characterized in that the biocide is applied both on the front side, but more specifically on the fibers of the composite layer (3), than on the back side (14).
15.- Article de recouvrement selon l'une quelconque des revendications précédentes, qui est composé au moins partiellement de fibres, de fils ou analogues, caractérisé en qu'il comprend des fibres et/ou des fils qui ont été munis du biocide précité avant la confection de l'article.15.- covering article according to any one of the preceding claims, which is at least partially composed of fibers, threads or the like, characterized in that it comprises fibers and / or threads which have been provided with the aforementioned biocide before the making of the article.
16.- Article de recouvrement selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il s'agit d'un article tricoté ou tissé.16. Cover article according to any one of the preceding claims, characterized in that it is a knitted or woven article.
17.- Article de recouvrement selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il est constitué d'un protège-matelas (1) et/ou d'une peau intercalaire et/ou d'une peau anti-escarres et/ou d'un couvre-lit.17. Cover article according to any one of the preceding claims, characterized in that it consists of a mattress protector (1) and / or an interlayer skin and / or an anti-decubitus skin. and / or a bedspread.
18. Procédé pour la confection d'un article de recouvrement pour un lit, plus spécifiquement d'un protège-matelas (1), d'une peau anti-escarres, d'une peau intercalaire et/ou d'un couvre-lit selon l'une quelconque des revendications 10 à 17, consistant à soumettre les fibres (5) à un prétraitement et à fixer ces fibres (5) sur un substrat (2) de telle sorte que les fibres précitées (5) forment une couche composite (3), caractérisé en ce quJau cours de leur prétraitement, on traite également les fibres (5) avec un mélange (9) d'un biocide et d'un liant.18. Method for making a covering article for a bed, more specifically a mattress protector (1), an anti-decubitus skin, an interlayer skin and / or a bedspread according to any one of claims 10 to 17, consisting in subjecting the fibers (5) to a pretreatment and in fixing these fibers (5) on a substrate (2) so that the above-mentioned fibers (5) form a composite layer (3), characterized in that J during their pretreatment, the fibers (5) are also treated with a mixture (9) of a biocide and a binder.
19.- Procédé selon la revendication 18, caractérisé en ce qu'on soumet les fibres (5) au cours de leur prétraitement au moins à un cardage et en ce qu'on pulvérise le mélange (9) sur les fibres (5) au cours du cardage. 19.- Method according to claim 18, characterized in that the fibers (5) are subjected during their pretreatment at least to carding and in that the mixture (9) is sprayed on the fibers (5) to during carding.
20.- Procédé selon les revendications 18 ou 19, caractérisé en ce qu'on conserve les fibres (5) traitées avec un biocide, immédiatement après le traitement avec le mélange20.- Method according to claims 18 or 19, characterized in that the fibers (5) treated with a biocide are kept immediately after the treatment with the mixture
(9) précité, pendant un temps déterminé dans des réceptacles fermés (10) avant de les fixer sur le substrat (2) .(9) above, for a determined time in closed receptacles (10) before fixing them on the substrate (2).
21.- Procédé selon les revendications 18, 19 ou 20, caractérisé en ce qu'on munit le côté dorsal (14) du substrat (2), également d'un biocide et en ce que ceci a lieu en mélangeant le biocide avec une matière d'enduction plus spécifiquement avec un agent d'apprêtage (15), et ceci en l'appliquant sur le substrat (2), en même temps que la matière d'enduction (2), respectivement en la pulvérisant sur ce dernier avant d'appliquer la matière d'enduction. 21.- Method according to claims 18, 19 or 20, characterized in that the back side (14) of the substrate (2) is also provided with a biocide and in that this takes place by mixing the biocide with a coating material more specifically with a finishing agent (15), and this by applying it to the substrate (2), at the same time as the coating material (2), respectively by spraying it on the latter before to apply the coating material.
PCT/BE1996/000135 1995-12-28 1996-12-23 Covering for beds and similar items and method for its manufacture WO1997024484A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU13618/97A AU1361897A (en) 1995-12-28 1996-12-23 Covering for beds and similar items and method for its manufacture
NZ325161A NZ325161A (en) 1995-12-28 1996-12-23 Covering for beds and similar items with acaricidal biocide attached
JP9523920A JPH11501246A (en) 1995-12-28 1996-12-23 Articles for covers for beds and similar articles and methods of making same
IL12160696A IL121606A0 (en) 1995-12-28 1996-12-23 Covering article for beds and similar items and method for its manufacture
EP96943836A EP0812372A1 (en) 1995-12-28 1996-12-23 Covering for beds and similar items and method for its manufacture
NO973939A NO973939D0 (en) 1995-12-28 1997-08-27 Sengetöyartikkel

Applications Claiming Priority (2)

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BE9501073A BE1009900A5 (en) 1995-12-28 1995-12-28 Cover article for beds and the like, and method for manufacturing same.
BE9501073 1995-12-28

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JP (1) JPH11501246A (en)
AU (1) AU1361897A (en)
BE (1) BE1009900A5 (en)
CZ (1) CZ269797A3 (en)
DE (1) DE29622338U1 (en)
ES (1) ES2113328B1 (en)
FR (1) FR2742977B3 (en)
IL (1) IL121606A0 (en)
NL (1) NL1004907C2 (en)
NO (1) NO973939D0 (en)
NZ (1) NZ325161A (en)
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WO1999021421A1 (en) * 1997-10-23 1999-05-06 Akzo Nobel Uk Limited Methods of controlling house dust mites and bedmites
AU755332B2 (en) * 1997-10-23 2002-12-12 Acordis Uk Limited Methods of controlling house dust mites and bedmites
EP1183947A3 (en) * 1997-10-24 2002-04-17 Protec Health International Limited Covering impregnated with insecticide
EP1183947A2 (en) * 1997-10-24 2002-03-06 Protec Health International Limited Covering impregnated with insecticide
US6440438B2 (en) 1997-10-24 2002-08-27 Protec Health International Limited Covering impregnated with insecticide
WO1999021420A1 (en) * 1997-10-24 1999-05-06 Protec Health International Limited Covering impregnated with insecticide
GB2339692A (en) * 1998-07-17 2000-02-09 Magiseal Corp Dust mite control
GB2339692B (en) * 1998-07-17 2000-06-28 Magiseal Corp Fabric, carpet and upholstery protectant with biocide and acaricide
WO2000003593A1 (en) * 1998-07-17 2000-01-27 Magiseal Corporation Fabric, carpet and upholstery protectant with biocide and acaricide
US6379686B1 (en) 1998-07-17 2002-04-30 Magiseal Corporation Fabric, carpet and upholstery protectant with biocide and acaricide
DE202012004456U1 (en) 2012-04-11 2012-07-04 Gerd Gundersheimer Apparatus for destroying mites, insects, micro-organisms, allergens and fungi in upholstered articles and in filled bedding
DE102012007245B3 (en) * 2012-04-11 2013-10-02 Gerd Gundersheimer Method for removing mites from bed materials e.g. pillow, involves collecting settled mites by sucking and air supply line, and providing to sucking and blowing unit
DE202012004898U1 (en) 2012-05-16 2012-07-03 Gerd Gundersheimer Light window device for bedding and upholstery
CN115474797A (en) * 2022-08-31 2022-12-16 慕思健康睡眠股份有限公司 Sterilization method based on intelligent mattress and related product
CN115474797B (en) * 2022-08-31 2024-02-27 慕思健康睡眠股份有限公司 Sterilization method based on intelligent mattress and related products

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DE29622338U1 (en) 1997-03-13
NL1004907C2 (en) 1999-01-19
JPH11501246A (en) 1999-02-02
ES2113328A1 (en) 1998-04-16
BE1009900A5 (en) 1997-10-07
NZ325161A (en) 1998-12-23
NO973939L (en) 1997-08-27
NO973939D0 (en) 1997-08-27
ES2113328B1 (en) 1999-02-01
IL121606A0 (en) 1998-02-08
AU1361897A (en) 1997-07-28
CZ269797A3 (en) 1998-02-18
FR2742977B3 (en) 1997-12-05
FR2742977A3 (en) 1997-07-04
EP0812372A1 (en) 1997-12-17

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