WO1997001726A1 - Backlight system with multilayer optical film reflector - Google Patents

Backlight system with multilayer optical film reflector Download PDF

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Publication number
WO1997001726A1
WO1997001726A1 PCT/US1996/007596 US9607596W WO9701726A1 WO 1997001726 A1 WO1997001726 A1 WO 1997001726A1 US 9607596 W US9607596 W US 9607596W WO 9701726 A1 WO9701726 A1 WO 9701726A1
Authority
WO
WIPO (PCT)
Prior art keywords
light
backlight system
lamp cavity
normal
reflector
Prior art date
Application number
PCT/US1996/007596
Other languages
French (fr)
Inventor
David L. Wortman
Sanford Cobb, Jr.
Brian D. Cull
Michael F. Weber
Andrew J. Ouderkirk
Original Assignee
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining And Manufacturing Company filed Critical Minnesota Mining And Manufacturing Company
Priority to EP96920454A priority Critical patent/EP0832392B1/en
Priority to AU58750/96A priority patent/AU716525B2/en
Priority to DE69629471T priority patent/DE69629471T2/en
Priority to JP9504407A priority patent/JPH11508702A/en
Publication of WO1997001726A1 publication Critical patent/WO1997001726A1/en

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Classifications

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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/08Mirrors
    • G02B5/0816Multilayer mirrors, i.e. having two or more reflecting layers
    • G02B5/0825Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only
    • G02B5/0841Multilayer mirrors, i.e. having two or more reflecting layers the reflecting layers comprising dielectric materials only comprising organic materials, e.g. polymers
    • GPHYSICS
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    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • GPHYSICS
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    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
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    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/005Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
    • G02B6/0055Reflecting element, sheet or layer
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    • G02B6/0033Means for improving the coupling-out of light from the light guide
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    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0065Manufacturing aspects; Material aspects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2325/00Polymers of vinyl-aromatic compounds, e.g. polystyrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00Polyvinylhalogenides
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2333/00Polymers of unsaturated acids or derivatives thereof
    • B32B2333/04Polymers of esters
    • B32B2333/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2551/00Optical elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/0035Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
    • G02B6/004Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles
    • G02B6/0043Scattering dots or dot-like elements, e.g. microbeads, scattering particles, nanoparticles provided on the surface of the light guide
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/005Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
    • G02B6/0051Diffusing sheet or layer
    • GPHYSICS
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    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/005Means for improving the coupling-out of light from the light guide provided by one optical element, or plurality thereof, placed on the light output side of the light guide
    • G02B6/0053Prismatic sheet or layer; Brightness enhancement element, sheet or layer
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • G02B6/0058Means for improving the coupling-out of light from the light guide varying in density, size, shape or depth along the light guide
    • G02B6/0061Means for improving the coupling-out of light from the light guide varying in density, size, shape or depth along the light guide to provide homogeneous light output intensity
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • G02F1/133536Reflective polarizers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528Polarisers
    • G02F1/133545Dielectric stack polarisers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/1336Illuminating devices
    • G02F1/13362Illuminating devices providing polarized light, e.g. by converting a polarisation component into another one

Definitions

  • the present invention relates to the field of backlight systems. More particularly, the present invention relates to improved backlight systems with multilayer optical film reflectors.
  • Liquid crystal (LC) displays are widely used for laptop computers, handheld calculators, digital watches, and similar devices in which information must be displayed to a viewer.
  • the displays incorporate a backlight to provide the light necessary to view the display when ambient light entering the display and reflected back out ofthe display is insufficient.
  • Backlight systems typically incorporate a light source and a light guide to direct light from the source and uniformly spread it over the display.
  • light guides have been provided of light transparent material which propagate light along their length through total internal reflection. The light is typically reflected off of the back surface of the light guide and towards the front surface at angles which allow it to exit the front surface of the light guide.
  • Various reflection mechanisms are used to distribute the light exiting the guide uniformly including reflective dots, channels, facets etc.
  • Backlight systems which use non-collimated light sources such as fluorescent lamps, etc. also typically incorporate at least two reflectors.
  • a lamp cavity mirror is typically used to reflect light exiting the light source in a direction away from the light guide back towards the guide.
  • This reflector can be specular or diffuse, although it is typically specular.
  • a second reflector is provided proximate the back surface of the light guide to reflect light escaping from the back surface of the light guide and redirect it towards the front surface of the light guide where it can be transmitted to the viewer.
  • These reflectors are typically constructed of a reflective white coating that also diffuse the reflected light over a Lambertian distribution.
  • a primary disadvantage with the conventional reflectors used in the lamp cavity and at the back surface of the light guide is, however, their relatively high absorptivities and high transmission of incident light.
  • Typical reflectors will absorb or transmit about 4 to about 15% of the light incident upon them.
  • the absorbed light is, of course, not available to the viewer, thereby degrading performance ofthe backlight.
  • the absorptive losses are, of course, increased with every reflection of light from the surface of conventional reflectors. With even the best conventional reflectors which absorb 4% of incident light, the intensity level of reflected light is about 81.5% after only five reflections.
  • Structured partially reflective films typically have excellent reflectivity over certain ranges of angles but high transmission over others.
  • Micro-replicated structured partially reflective films are available as Brightness Enhancement Film, available from Minnesota Mining and Manufacturing Company.
  • structured partially reflective films redirect and transmit light into a relatively narrow range of angles while reflecting the remainder of the light.
  • structured films transmit light and enhance brightness in backlight systems by recycling light which would otherwise exit a backlight outside a normal viewing angle.
  • the present invention includes a backlight system inco ⁇ orating a back reflector and/or a lamp cavity reflector constructed of a multilayer optical film.
  • Providing the multilayer optical film for lamp cavity mirrors and/or back reflectors in backlight systems according to the present invention provides a number of advantages.
  • One advantage is the low abso ⁇ tivity of the film.
  • the multilayer optical film according to the present invention can reflect over 99% of the light striking the surface ofthe film.
  • multilayer optical film is also highly efficient at reflecting light whether it is incident normal to the film surface or off-axis.
  • multilayer optical film reflectors Yet another advantage of backlight systems employing multilayer optical film reflectors is that the multilayer optical film is relatively low in weight as compared to many conventional reflectors.
  • Still another advantage of backlight systems employing multilayer optical film back reflectors is that because the film is relatively thin as compared to many conventional reflectors, the backlight systems can be thinner than a backlight system employing a convention back reflector.
  • an entire light guide can be constructed using multilayer optical film according to the present invention for both the front and back surfaces of the light guide, thereby eliminating the need for a separate light guide and further reducing the cost, weight and bulk of backlight systems.
  • Backlight systems according to the present invention can also inco ⁇ orate recycling technologies, such as structured films and/or reflective polarizers, without incurring the significant abso ⁇ tive losses associated with conventional reflectors.
  • FIGURES la and lb are diagrammatical views of the multilayer optical film ofthe present invention.
  • FIGURE 2 shows a two layer stack of films forming a single interface.
  • FIGURE 8 is a graphical representation illustrating the relationship between the number of reflections experienced by a ray of light (x-axis) as compared to the relative intensity of the light ray (y-axis) for reflective surfaces made of multilayer optical film and a standard reflector.
  • FIGURE 9 is a schematic cross-sectional view of one backlight system according to the present invention.
  • FIGURE 10 is a schematic cross-sectional view of an alternate backlight system according to the present invention.
  • FIGURE 11 is a schematic cross-sectional view of another alternate backlight system according to the present invention.
  • FIGURE 12 is a schematic cross-sectional view of another alternate backlight system according to the present invention.
  • FIGURE 13 shows a schematic cross-sectional view of another alternate backlight system according to the present invention.
  • FIGURE 14 shows a schematic cross-sectional view of another alternate backlight system according to the present invention.
  • Multilayer Optical Film The backlight systems described herein rely on the unique and advantageous properties of multilayer optical films. The advantages, characteristics and manufacturing of such films are most completely described in the above mentioned copending and commonly assigned U.S. Patent Application 08/402,041, filed March 10, 1995, titled OPTICAL FILM.
  • the multilayer optical film is useful, for example, as highly efficient mirrors and/or polarizers. A relatively brief description ofthe properties and characteristics ofthe multilayer optical film is presented below followed by a description of illustrative embodiments of backlight systems using the multilayer optical film according to the present invention.
  • Multilayer optical films as used in conjunction with the present invention exhibit relatively low abso ⁇ tion of incident light, as well as high reflectivity for off-axis as well as normal light rays. These properties generally hold whether the films are used for pure reflection or reflective polarization of light.
  • the unique properties and advantages of the multi-layer optical film provides an opportunity to design highly efficient backlight systems which exhibit low abso ⁇ tion losses when compared to known backlight systems.
  • Figures IA and IB includes a multilayer stack 10 having alternating layers of at least two materials 12 and 14. At least one of the materials has the property of stress induced birefringence, such that the index of refraction (n) of the material is affected by the stretching process.
  • Figure IA shows an exemplary multilayer stack before the stretching process in which both materials have the same index of refraction. Light ray 13 experiences no index of refraction change and passes through the stack.
  • Figure IB the same stack has been stretched, thus increasing the index of refraction of material 12. The difference in refractive index at each boundary between layers will cause part of ray 15 to be reflected.
  • the multilayer stack can thus be made useful as reflective polarizers or mirrors.
  • Multilayer optical films constructed according to the present invention exhibit a Brewster angle (the angle at which reflectance goes to zero for light incident at any of the layer interfaces) which is very large or is nonexistent.
  • known multilayer polymer films exhibit relatively small Brewster angles at layer interfaces, resulting in transmission of light and/or undesirable iridescence.
  • the multilayer optical films according to the present invention allow for the construction of mirrors and polarizers whose reflectivity for p polarized light decrease slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer stacks having high reflectivity for both s and p polarized light over a wide bandwidth, and over a wide range of angles can be achieved.
  • Figure 2 shows two layers of a multilayer stack, and indicates the three dimensional indices of refraction for each layer.
  • the indices of refraction for each layer are nix, nly, and nlz for layer 102, and n2x, n2y, and n2z for layer 104.
  • the relationships between the indices of refraction in each film layer to each other and to those of the other layers in the film stack determine the reflectance behavior of the multilayer stack at any angle of incidence, from any azimuthal direction.
  • the principles and design considerations described in U.S. patent application Serial Number 08/402,041 can be applied to create multilayer stacks having the desired optical effects for a wide variety of circumstances and applications.
  • the indices of refraction of the layers in the multilayer stack can be manipulated and tailored to produce the desired optical properties.
  • the multilayer stack 10 can include tens, hundreds or thousands of layers, and each layer can be made from any of a number of different materials.
  • the characteristics which determine the choice of materials for a particular stack depend upon the desired optical performance of the stack.
  • the stack can contain as many materials as there are layers in the stack. For ease of manufacture, preferred optical thin film stacks contain only a few different materials.
  • the boundaries between the materials, or chemically identical materials with different physical properties, can be abrupt or gradual. Except for some simple cases with analytical solutions, analysis of the latter type of stratified media with continuously varying index is usually treated as a much larger number of thinner uniform layers having abrupt boundaries but with only a small change in properties between adjacent layers.
  • the preferred multilayer stack is comprised of low/high index pairs of film layers, wherein each low/high index pair of layers has a combined optical thickness of 1/2 the center wavelength of the band it is designed to reflect. Stacks of such films are commonly referred to as quarterwave stacks. For multilayer optical films concerned with the visible and the near infrared wavelengths, a quarterwave stack design results in each of the layers in the multilayer stack having an average thickness of not more than 0.5 microns.
  • the desired average transmission for light of each polarization and plane of incidence generally depends upon the intended use of the reflective film.
  • One way to produce a multilayer mirror film is to biaxially stretch a multilayer stack which contains a birefringent material as the high index layer of the low/high index pair.
  • average transmission along each stretch direction at normal incidence over the visible spectrum is desirably less than 10% (reflectance greater than 90%), preferably less than 5% (reflectance greater than 95%), more preferably less than 2% (reflectance greater than 98%), and even more preferably less than 1% (reflectance greater than 99%).
  • the av rage transmission at 60 degrees from the normal from 400-700 nm is desirably less than 20% (reflectance greater than 80%), preferably less than 10% (reflectance greater than 90%), more preferably less than 5% (reflectance greater than 95%), and even more preferably less than 2% (reflectance greater than 98%), and even more preferably less than 1% (reflectance greater than 99%).
  • average transmission along one stretch direction may be desirably less than, for example, 50%, while the average transmission along the other stretch direction may be desirably less than, for example 20%, over a bandwidth of, for example, the visible spectrum (400-700 nm), or over the visible spectrum and into the near infrared (e.g, 400-850 nm).
  • Multilayer optical films can also be designed to opeiate as reflective polarizers.
  • One way to produce a multilayer reflective polarizer is to uniaxially stretch a multilayer stack which contains a birefringent material as the high index layer of the low/high index pair.
  • the resulting reflective polarizers have high reflectivity for light with its plane of polarization parallel to one axis (in the stretch direction) for a broad range of angles of incidence, and simultaneously have low reflectivity and high transmissivity for light with its plane of polarization parallel to the other axis (in the non-stretch direction) for a broad range of angles of incidence.
  • the desired polarizer behavior can be obtained.
  • the ideal reflecting polarizer has high reflectance along one axis (the so-called extinction axis) and zero reflectance along the other (the so-called transmission axis), at all angles of incidence.
  • the transmission axis of a polarizer it generally desirable to maximize transmission of light polarized in the direction ofthe transmission axis over the bandwidth of interest and also over the range of angles of interest.
  • the average transmission at normal incidence for a polarizer in the transmission axis across the visible spectrum is desirably at least 50%, preferably at least 70%, more preferably at least 85%, and even more preferably at least 90%.
  • the average transmission at 60 degrees from the normal (measured along the transmission axis for p-polarized light) for a polarizer from 400-700 nm is desirably at least 50%, preferably at least 70%, more preferably at least 80%, and even more preferably at least 90%.
  • the average transmission for a multilayer reflective polarizer at normal incidence for light polarized in the direction of the extinction axis across the visible spectrum is desirably at less than 50%, preferably less than 30%, more preferably less than 15%, and even more preferably less than 5%.
  • the average transmission at 60 degrees from the normal (measured along the transmission axis for p-polarized light) for a polarizer for light polarized in the direction of the extinction axis from 400-700 nm is desirably less than 50%, preferably less than 30%, more preferably less than 15%, and even more preferably less than 5%.
  • high reflectivity for p-polarized light with its plane of polarization parallel to the transmission axis at off-normal angles are preferred.
  • the average reflectivity for light polarized along the transmission axis should be more than 20% at an angle of at least 20 degrees from the normal.
  • reflective polarizing films and asymmetric reflective films are discussed separately herein, it should be understood that two or more of such films could be provided to reflect substantially all light incident on them (provided they are properly oriented with respect to each other to do so). This construction is typically desired when the multilayer optical film is used as a reflector in a backlight system according to the present invention.
  • the efficiency of the polarizer at off-normal angles may be reduced. If the reflectivity along the transmission axis is different for various wavelengths, color may be introduced into the transmitted light.
  • One way to measure the color is to determine the root mean square (RMS) value of the transmissivity at a selected angle or angles over the wavelength range of interest.
  • the % RMS color can be determined according to the equation:
  • the range ⁇ l to ⁇ 2 is the wavelength range, or bandwidth, of interest
  • T is the transmissivity along the transmission axis
  • T is the average transmissivity along the transmission axis in the wavelength range of interest.
  • the % RMS color should be less than 10%, preferably less than 8%, more preferably less than 3.5%, and even more preferably less than 2% at an angle of at least 30 degrees from the normal, preferably at least 45 degrees from the normal, and even more preferably at least 60 degrees from the normal.
  • a reflective polarizer combines the desired % RMS color along the transmission axis for the particular application with the desired amount of reflectivity along the extinction axis across the bandwidth of interest.
  • average transmission along the extinction axis at normal incidence is desirably less than 40%, more desirably less than 25%, preferably less than 15%, more preferably less than 5% and even more preferably less than 3%.
  • appropriate combinations may be achieved by selecting, as the first material, a crystalline or semi-crystalline material, preferably a polymer.
  • the second material may be crystalline, semi-crystalline, or amo ⁇ hous.
  • the second material may have a birefringence opposite of the first material. Or, the second material may have no birefringence, or less birefringence than the first material.
  • suitable materials include polyethylene naphthalate (PEN) and isomers thereof (e.g., 2,6-, 1,4-, 1,5-, 2,7-, and 2,3-PEN), polyalkylene terephthalates (e.g., polyethylene terephthalate, polybutylene terephthalate, and poly-l,4-cyclohexanedimethylene terephthalate), polyimides (e.g., polyacrylic imides), polyetherimides, atactic polystyrene, polycarbonates, polymethacrylates (e.g., polyisobutyl methacrylate, polypropylmethacrylate, polyethylmethacrylate, and polymethylmethacrylate), polyacrylates (e.g., polybutylacrylate and polymethylacrylate), syndiotactic polystyrene (sPS), syndiotactic poly-alpha-methyl styrene, syndiotactic polydichlorost
  • copolymers e.g., copolymers of PEN (e.g., copolymers of 2,6-, 1,4-, 1,5-, 2,7-, and/or 2,3-naphthalene dicarboxylic acid, or esters thereof, with (a) terephthalic acid, or esters thereof; (b) isophthalic acid, or esters thereof; (c) phthalic acid, or esters thereof; (d) alkane glycols; (e) cycloalkane glycols (e.g., cyclohexane dimethane diol); (f) alkane dicarboxylic acids; and/or (g) cycloalkane dicarboxylic acids (e.g., cyclohexane dicarboxylic acid)), copolymers of polyalkylene terephthalates (e.g., copolymers of terephthalic acid, or esters thereof, with (a) naphthalene
  • each individual layer may include blends of two or more of the above-described polymers or copolymers (e.g., blends of sPS and atactic polystyrene).
  • the coPEN described may also be a blend of pellets where at least one component is a polymer based on naphthalene dicarboxylic acid and other components are other polyesters or polycarbonates, such as a PET, a PEN or a co-PEN.
  • polarizers include PEN/co-PEN, polyethylene terephthalate (PET)/co-PEN, PEN/sPS, PET/sPS, PEN/Eastar, and PET/Eastar, where "co-PEN” refers to a copolymer or blend based upon naphthalene dicarboxylic acid (as described above) and Eastar is polycyclohexanedimethylene terephthalate commercially available from Eastman Chemical Co.
  • PET polyethylene terephthalate
  • co-PEN refers to a copolymer or blend based upon naphthalene dicarboxylic acid (as described above) and Eastar is polycyclohexanedimethylene terephthalate commercially available from Eastman Chemical Co.
  • Particularly preferred combinations of layers in the case of reflective films include PET/Ecdel, PEN/Ecdel, PEN/sPS, PEN/THV, PEN/co-PET, and PET/sPS, where "co-PET” refers to a copolymer or blend based upon terephthalic acid (as described above), Ecdel is a thermoplastic polyester commercially available from Eastman Chemical Co., and THV is a fluoropolymer commercially available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota.
  • the number of layers in the film is selected to achieve the desired optical properties using the minimum number of layers for reasons of film thickness, flexibility and economy.
  • the number of layers is preferably less than 10,000, more preferably less than 5,000, and even more preferably less than 2,000.
  • the ability to achieve the desired relationships among the various indices of refraction (and thus the optical properties of the multilayer film) is influenced by the processing conditions used to prepare the multilayer film.
  • the films are generally prepared by co-extruding the individual polymers to form a multilayer film and then orienting the film by stretching at a selected temperature, optionally followed by heat-setting at a selected temperature. Alternatively, the extrusion and orientation steps may be performed simultaneously.
  • the film is stretched substantially in one direction (uniaxial orientation), while in the case of reflective films the film is stretched substantially in two directions (biaxial orientation).
  • the film may be allowed to dimensionally relax in the cross-stretch direction from the natural reduction in cross-stretch (equal to the square root of the stretch ratio); it may simply be constrained to limit any substantial change in cross-stretch dimension; or it may be actively stretched in the cross-stretch dimension.
  • the film may be stretched in the machine direction, as with a length orienter, or in width using a tenter.
  • the pre-stretch temperature, stretch temperature, stretch rate, stretch ratio, heat set temperature, heat set time, heat set relaxation, and cross stretch relaxation are selected to yield a multilayer film having the desired refractive index relationship.
  • a relatively low stretch rate could be used if coupled with, e.g., a relatively low stretch temperature. It will be apparent to one of ordinary skill how to select the appropriate combination of these variables to achieve the desired multilayer film. In general, however, a stretch ratios in the range from 1:2 to 1: 10 (more preferably 1:3 to 1:7) in the stretch direction and from 1:0.2 to 1 :10 (more preferably from 1 :0.3 to 1:7) orthogonal to the stretch direction is preferred.
  • Suitable multilayer films may also be prepared using techniques such as spin coating (e.g., as described in Boese et al., J. Polym. Sci.: Part B, 30: 1321 (1992) for birefringent polyimides, and vacuum deposition (e.g., as described by Zang et. al., Appl. Phys. Letters, 59:823 (1991) for crystalline organic compounds; the latter technique is particularly useful for certain combinations of crystalline organic compounds and inorganic materials.
  • spin coating e.g., as described in Boese et al., J. Polym. Sci.: Part B, 30: 1321 (1992) for birefringent polyimides
  • vacuum deposition e.g., as described by Zang et. al., Appl. Phys. Letters, 59:823 (1991) for crystalline organic compounds; the latter technique is particularly useful for certain combinations of crystalline organic compounds and inorganic materials.
  • a coextruded film containing 449 layers was made by extruding the cast web in one operation and later orienting the film in a laboratory film-stretching apparatus.
  • a Polyethylene naphthalate (PEN) with an Intrinsic Viscosity of 0.53 dl/g (60 wt. % phenol/40 wt. % dichlorobenzene) was delivered by one extruder at a rate of 56 pounds per hour and THV 500 (a fluoropolymer available from Minnesota Mining and Manufacturing Company) was delivered by another extruder at a rate of 11 pounds per hour.
  • PEN was on the skin layers and 50% ofthe PEN was present in the two skin layers.
  • the feedblock method was used to generate 57 layers which was passed through three multipliers producing an extrudate of 449 layers.
  • the cast web was 20 mils thick and 12 inches wide.
  • the web was later biaxially oriented using a laboratory stretching device that uses a pantograph to grip a square section of film and simultaneously stretch it in both directions at a uniform rate.
  • a 7.46 cm square of web was loaded into the stretcher at about 100°C and heated to 140°C in 60 seconds. Stretching then commenced at 10%/sec (based on original dimensions) until the sample was stretched to about 3.5x3.5. Immediately after the stretching the sample was cooled by blowing room temperature air at it.
  • Figure 3 shows the transmission of this multilayer film.
  • Curve (a) shows the response at normal incidence, while curve (b) shows the response at 60 degrees for p-polarized light.
  • a coextruded film containing 601 layers was made on a sequential flat-film-making line via a coextrusion process.
  • Polyethylene Naphthalate (PEN) with an Intrinsic Viscosity of 0.57 dl/g 60 wt. % phenol/40 wt. % dichlorobenzene was delivered by extruder A at a rate of 114 pounds per hour with 64 pounds per hour going to the feedblock and the rest going to skin layers described below.
  • PMMA CP-82 from ICI of Americas
  • PEN was on the skin layers of the feedblock.
  • the feedblock method was used to generate 151 layers using the feedblock such as those described in U.S. Patent 3,801,429, after the feedblock two symmetric skin layers were coextruded using extruder C metering about 30 pounds per hour of the same type of PEN delivered by extruder A.
  • This extrudate passed through two multipliers producing an extrudate of about 601 layers.
  • U.S. Patent 3,565,985 describes similar coextrusion multipliers.
  • the extrudate passed through another device that coextruded skin layers at a total rate of 50 pounds per hour of PEN from extruder A.
  • the web was length oriented to a draw ratio of about 3.2 with the web temperature at about 280°F.
  • the film was subsequently preheated to about 310°F in about 38 seconds and drawn in the transverse direction to a draw ratio of about 4.5 at a rate of about 11% per second.
  • the film was then heat-set at 440°F with no relaxation allowed.
  • the finished film thickness was about 3 mil.
  • curve (a) the bandwidth at normal incidence is about 350 nm with an average in-band extinction of greater than 99%.
  • the amount of optical absorption is difficult to measure because of its low value, but is less than 1%.
  • At an incidence angle of 50° from the normal both s (curve (b)) and p-polarized (curve (c)) light showed similar extinctions, and the bands were shifted to shorter wavelengths as expected.
  • the red band-edge for s-polarized light is not shifted to the blue as much as for p-polarized light due to the expected larger bandwidth for s-polarized light, an due to the lower index seen by the p-polarized light in the PEN layers.
  • a coextruded film containing 481 layers was made by extruding the cast web in one operation and later orienting the film in a laboratory film-stretching apparatus.
  • the feedblock method was used with a 61 layer feedblock and three (2x) multipliers. Thick skin layers were added between the final multiplier and the die.
  • Polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.47 dl/g (60 wt. % phenol/40 wt. % dichlorobenzene) was delivered to the feedblock by one extruder at a rate of 25.0 pounds per hour.
  • Glycol modified polyethylene dimethyl cyclohexane terephthalate (PCTG 5445 from Eastman) was delivered by another extruder at a rate of 25.0 pounds per hour. Another stream of PEN from the above extruder was added as skin layers after the multipliers at a rate of 25.0 pounds per hour.
  • the cast web was 0.007 inches thick and 12 inches wide.
  • the web was layer uniaxially oriented using a laboratory stretching device that uses a pantograph to grip a section of film and stretch it in one direction at a uniform rate while it is allowed to freely relax in the other direction.
  • the sample of web loaded was about 5.40 cm wide (the unconstrained direction) and 7.45 cm long between the grippers of the pantograph.
  • the web was loaded into the stretcher at about 100°C and heated to 135°C for 45 seconds. Stretching was then commenced at 20%/second (based on original dimensions) until the sample was stretched to about 6:1 (based on gripper to gripper measurements). Immediately after stretching, the sample was cooled by blowing room temperature air at it. In the center, the sample was found to relax by a factor of 2.0.
  • Figure 5 shows the transmission of this multilayer film where curve a shows transmission of light polarized in the non-stretch direction at normal incidence, curve b shows transmission of p-polarized light polarized in the non-stretched direction at 60° incidence, and curve c shows the transmission of light polarized in the stretch direction at normal incidence.
  • Average transmission for curve a from 400-700nm is 89.7%
  • average transmission for curve b from 400-700nm is 96.9%
  • average transmission for curve c from 400-700nm is 4.0%.
  • % RMS color for curve a is 1.05%
  • %RMS color for curve b is 1.44%.
  • a coextruded film containing 601 layers was made on a sequential flat-film-making line via a coextrusion process.
  • a Polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.54 dl/g (60 wt % Phenol plus 40 wt % dichlorobenzene) was delivered by on extruder at a rate of 75 pounds per hour and the coPEN was delivered by another extruder at 65 pounds per hour.
  • the coPEN was a copolymer of 70 mole % 2,6 naphthalene dicarboxylate methyl ester, 15 % dimethyl isophthalate and 15% dimethyl terephthalate with ethjlene glycol.
  • the feedblock method was used to generate 151 layers.
  • the feedblock was designed to produce a stack of films having a thickness gradient from top to bottom, with a thickness ratio of 1.22 from the thinnest layers to the thickest layers.
  • the PEN skin layers were coextruded on the outside of the optical stack with a total thickness of 8% of the coextruded layers.
  • the optical stack was multiplied by two sequential multipliers. The nominal multiplication ratio of the multipliers were 1.2 and 1.27, respectively.
  • the film was subsequently preheated to 310°F in about 40 seconds and drawn in the transverse direction to a draw ratio of about 5.0 at a rate of 6% per second.
  • the finished film thickness was about 2 mils.
  • Figure 6 shows the transmission for this multilayer film.
  • Curve a shows transmission of light polarized in the non-stretch direction at normal incidence
  • curve b shows transmission of p-polarized light at 60° incidence
  • end curve c shows transmission of light polarized in the stretch direction at normal incidence.
  • curve c shows the very high reflectance of light polarized in the stretched direction in the visible range (400-700nm) shown by curve c. Reflectance is nearly 99% between 500 and 650nm.
  • PEN was on the outer layers and was extruded at 26 pounds per hour and the sPS at 23 pounds per hour.
  • the feedblock used produced 61 layers with each of the 61 being approximately the same thickness. After the feedblock three (2x) multipliers were used.
  • Equal thickness skin layers containing the same PEN fed to the feedblock were added after the final multiplier at a total rate of 22 pounds per hour.
  • the web was extruded through a 12" wide die to a thickness of about 0.01 1 inches (0.276 mm).
  • the extrusion temperature was 290°C.
  • This web was stored at ambient conditions for nine days and then uniaxially oriented on a tenter.
  • the film was preheated to about 320°F (160°C) in about 25 seconds and drawn in the transverse direction to a draw ratio of about 6:1 at a rate of about 28% per second. No relaxation was allowed in the stretched direction.
  • the finished film thickness was about 0.0018 inches (0.046 mm).
  • Figure 7A shows the optical performance of this PEN:sPS reflective polarizer containing 481 layers.
  • Curve a shows transmission of light polarized in the non-stretch direction at normal incidence
  • curve b shows transmission of p-polarized light at 60° incidence
  • curve c shows transmission of light polarized in the stretch direction at normal incidence.
  • Average transmission for curve a over 400-700 nm is 86.2%
  • the average transmission for curve t over 400-700 nm is 79.7%.
  • the film has an average transmission of 1.6% for curve c between 400 and 700 nm.
  • the % RMS color for curve a is 3.2%
  • the % RMS color for curve b is 18.2%.
  • a reflecting polarizer comprising 603 layers was made on a sequential flat-film making line via a coextrusion process.
  • a polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.47 dl g (in 60 wt% phenol plus 40 wt% dichlorobenzene) was delivered by an extruder at a rate of 83 pounds (38 kg) per hour and the CoPEN was delivered by another extruder at 75 pounds (34 kg) per hour.
  • the CoPEN was a copolymer of 70 mole %, 2,6 naphthalene dicarboxylate methyl ester, 15 mole % dimethyl terephthalate, and 15 mole % dimethyl isophthalate with ethylene glycol.
  • the feedblock method was used to generate 151 layers.
  • the feedblock was designed to produce a stack of films having a thickness gradient from top to bottom, with a thickness ratio of 1.22 from the thinnest layers to the thickest layers.
  • This optical stack was multiplied by two sequential multipliers.
  • the nominal multiplication ratio of the multipliers was 1.2 and 1.4, respectively.
  • skin layers were added composed of the same CoPEN described above, delivered by a third extruder at a total rate of 106 pounds (48 kg) per hour.
  • the film was subsequently preheated to 300°F (150°C) in about 30 seconds and drawn in the transverse direction to a draw ratio of approximately 6 at an initial rate of about 20% per second.
  • the finished film thickness was approximately 0.0035 inch (0.089 mm).
  • Figure 7B shows the optical performance of the polarizer of Example 6.
  • Curve a shows transmission of light polarized in the non-stretch direction at normal incidence
  • curve b shows transmission of p-polarized light in the nonstretch direciton at 50 degree angle of incidence
  • curve c shows transmission of light polarized in the stretch direction at normal incidence. Note the very high transmission of light polarized in the non-stretch direction. Average transmission for curve a over 400-700 nm is 87%. Also note the very high reflectance of light polarized in the stretched direction in the visible range (400-700nm) shown by curve c. The film has an average transmission of 2.5%) for curve c between 400 and 700 nm. The % RMS color for curve b is 5%.
  • Backlight systems according to the present invention use multilayer optical films to reflect light. Reflectors constructed of multilayer optical film are most advantageously located around the light source as well as along the back surface of the light guide, although in some instances they may be used in one or the other location alone.
  • Curve a shows the total reflectivity as a function of the number of reflections for a conventional reflector that has 96% reflectivity (i.e., about 4% ofthe light is absorbed at each reflection).
  • curve b shows the total reflectivity for a multilayer mirror film having a reflectivity of about 99.4%). Curve b clearly shows a much smaller decrease in reflectivity. The difference becomes especially pronounced after only 2-4 reflections.
  • the intensity of light is about 97% for light reflected from multilayer optical films according to the present invention, while the intensity drops to about 81.5% for light reflected from a conventional reflector which is only about 3.5% less efficient.
  • the number of reflections can be expected to increase as uniformity and/or aspect ratio (defined more completely below) increase in any given backlight system. Those increased reflections would cause a significant loss in efficiency for backlight systems using conventional reflectors which would not be experienced in backlight systems employing multilayer optical film reflectors according to the present invention.
  • the practical value of this characteristic is that the efficiency of the backlighting systems and any display employing one is greatly enhanced resulting in increased brightness and/or contrast as compared to systems employing conventional reflectors.
  • the number of acceptable reflections for a given light ray in backlight systems employing multilayer optical film reflectors according to the present invention can be significantly increased without substantially impairing the overall output of the backlight system as compared to backlight systems employing conventional reflectors.
  • the probability that a photon will not be lost is increased in backlight systems employing optical film reflectors.
  • FIGS. 9-12 will now be described.
  • the figures schematically depict various backlight systems manufactured according to the present invention, but are not intended to limit the scope of the present invention.
  • all of the figures depict light guides having essentially rectangular cross-sections.
  • the multilayer optical film reflectors can be used with any light guide including a lamp cavity reflector and/or a back reflector.
  • Other examples of light guides include wedge-shaped guides, channeled guides, pseudo-wedge guides, etc.
  • Figure 9 depicts, in a cross-sectional schematic view, an illustrative backlight system 110 which includes a light guide 112 and a light source 118.
  • Light source 118 may be any source which emits light, such as a fluorescent lamp, incandescent lamp, solid state source, electroluminescent (EL) light source or any other source of visible light.
  • EL electroluminescent
  • the embodiments described below typically include one such source, it will be understood that a backlight system according to the present invention could include two or more individual sources located at the same or different positions and combining to provide the required amount of light.
  • the light source 118 comprises a source emitting light having randomized polarization.
  • a reflective polarizer may be placed between the source and light guide such that light transmitted to the light guide 112 is substantially of one polarization orientation.
  • the reflective polarization can be accomplished using bulk optics or a multilayer reflective polarizer, both of which are described in copending and commonly-assigned U.S. patent application Serial No. 08/418,009, titled POLARIZED LIGHT SOURCES, filed on April 6, 1995.
  • the light guide 112 includes a front surface 114 and a back surface 116.
  • Components such as polarizers, diffusers, liquid crystal display panels, graphics films, prints and compensation/retarder films are typically placed above the front surface 1 14 of the light guide 112, are not depicted in Figure 9 (or any of the backlight systems depicted in any of the figures) but will be well known to those skilled in the art and will not be described herein.
  • a lamp cavity reflector 120 is depicted as partially surrounding the light source 118 and coupling the same to the light guide 1 12.
  • Conventional lamp cavity reflectors are constructed of a silvered film which exhibit reflectivities of about 96% for visible wavelengths, with the remaining light being substantially absorbed by the reflector.
  • a lamp reflector 120 constructed using multilayer optical film according to the present invention exhibits much higher reflectivities, typically about 98%) or greater which significantly reduces losses.
  • the presently described multilayer film has very high reflectivity, preferably at least 90%, more preferably 95%, and even more preferably at least 98%, at angles away from the normal (for example, greater than 45°). Since in many backligh'ing systems, such as those shown in Figures 9-12, the light enters from the side ofthe light guide, this is a distinct advantage.
  • the exterior surface of the reflector 120 can be coated with a metallic layer or an additional reflector can be provided (see reference number 224 in Figure 10 and the description below). This can increase infrared reflectance as well as reduce convective cooling ofthe lamp 118.
  • the lamp cavity reflector 120 will typically exhibit approximately a 20% or greater increase in brightness when a silvered optical film lamp reflector 120 is replaced by multilayer optical film according to the present invention, when all other variables are constant. This increase can be largely attributed to the extremely low abso ⁇ tivity and high reflectivity ofthe multilayer optical film.
  • the lamp cavity reflector 120 is preferably integrated with the back reflector 122, either by laminating or similarly attaching the two pieces together or by using one continuous sheet for both functions. As a result, there are essentially no losses associated with the interface between the two reflectors 120 and 122.
  • manufacturing ofthe backlight system 110 can be simplified by such a design.
  • the back reflector to the back of the light guide 112.
  • the mechanism used to extract light from the light guide 112 is not depicted in Figure 9 as any suitable mechanism could be used. Examples of extraction mechanisms include, but are not limited to: diffusing dots on the back surface 116 of light guide 112, channels in the back surface 116, the discontinuities associated with a pseudo-wedge light guide 112, and the increased reflected angles within a wedge-shaped light guide 112, and posts that adhere the reflector to the guide and provide light diffusion within the guide.
  • the back reflector 122 it may be advantageous to provide the back surface layer 122, i.e., the surface facing away from the light guide 112, with a thin metal or other reflective coating to decrease transmissive losses through the multilayer optical film reflector 122, thereby improving the reflectivity of the multilayer optical film 122.
  • the metallic or other reflective coating may suffer from some abso ⁇ tion losses, but the fraction of light transmitted through the film 122 will typically be less than 5% (more preferably less than about 1%) of the total light incident on the film 122.
  • backlight systems 110 inco ⁇ orating multilayer optical film for the back reflector 122 is in the flexibility for designing backlight systems which have relatively high aspect ratios.
  • Aspect ratio can be defined as the inverse of the thickness of the backlight system as opposed to its length or surface area (in the case of a planar surface over which light is to be distributed).
  • thickness ofthe light guide 112 is depicted as T while the length of the light guide is depicted as L. That ratio, L/T can be significantly higher in backlight systems 110 according to the present invention due to the relative thinness and flexibility ofthe multilayer optical films.
  • the aspect ratio can be higher because the number of reflections for any given light ray entering light guide 112 before it exits the backlight system 110 can be significantly higher without substantially degrading the overall light output of the backlight system 110 due to the low absorbance of the reflective surfaces provided by multilayer optical film back reflector 122.
  • the designer of a similar backlight system inco ⁇ orating conventional reflectors which absorb incident light must be concerned with the number of reflections experienced by the light before exiting the backlight and the resulting abso ⁇ tive losses.
  • FIG. 10 depicts, in a cross-sectional schematic view, an illustrative backlight system 210 which includes a light guide 212 and a light source 218.
  • the light guide 212 includes a front surface 214 and a back surface 216.
  • a lamp cavity reflector 220 is depicted as partially surrounding the light source 218 and coupling the same to the light guide 212.
  • the construction of backlight system 210 is similar to the construction of system 1 10 described above.
  • Differences include the addition of a separate lamp cavity reflector 224 disposed about the outer surface of the multilayer optical film lamp cavity reflector 220 to prevent transmissive losses in the event that a less efficient multilayer optical film is used. However, if a very efficient, e.g. at least 97% reflective, film is used, the reflector 224 may not be required.
  • An additional layer 226 is depicted as interposed between the back reflector 222 and the back surface 216 of the light guide 212. That additional layer preferably comprises a means of diffusing light directed towards back reflector 222. A means of diffusing light may be helpful in some backlight systems because typical multilayer optical films provided as mirrors exhibit specular reflection which may be undesirable on some applications.
  • the diffusing means 226 can be provided in many different forms as long as it diffuses the specular component of light reflected from the multilayer optical film back reflector 222. It is preferred, however, that the diffusing means absorb a minimum amount of incident light, thereby reducing its impact on the performance of the backlight system 210. It may also be preferred that the diffusing means 226 is polarization preserving (as shown below with respect to Figure 13) or polarization scrambling (as shown with respect to Figure 14).
  • diffusing light could include loading diffusing particles, such as barium sulfate, in a coextruded skin layer located on the multilayer optical film back reflector 222.
  • the diffusing particles could be included within one of the layers in the stack, preferably near the surface on which light is incident.
  • Diffusing layers could also be coated by extrusion coating on the multilayer optical film or they could be spread on the surface of the multilayer optical film using a suitable solvent.
  • Another diffusing means could comprise a commercially available diffusing film located between the multilayer optical film back reflector 222 and the back surface 216 of light guide 212.
  • a diffusing film is DFA-12, available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota.
  • a diffusing adhesive could be used to attach the multilayer optical film back reflector 222 to the back surface 216 ofthe light guide 212.
  • exemplary diffusing adhesives are described below.
  • One exemplary diffusing adhesive can be made by forming acrylic/styrene beads and dispersing the beads in a water based emulsion adhesive.
  • An adhesive containing 5% by weight ofthe microspheres was coated out on a PET liner film and was dried to form an 8.4 grain/4" x 6" adhesive layer.
  • Diffusing adhesive was coated to 4 mils wet at 17 feet per minute.
  • the drying oven was 30 feet in length. The drying temperature was 180° F.
  • the diffusing particles used in the system 210 should be as spherical as possible to preserve polarization.
  • the diffusing means also randomize polarization of the light to enhance that recycling process.
  • An alternative construction is to use the polarization preserving diffuser and a birefringent film or skin layer to depolarize the light
  • Figure l la depicts, in a cross-sectional schematic view, an alternate illustrative backlight system 310.
  • This backlight system illustrates the construction of a backlight system without a separate light guide as described in the above systems.
  • Light guides which are typically constructed of materials such as acrylic, add weight to the backlight system.
  • the mult Mayer optical films described above present the opportunity to construct a highly efficient backlight system 310 which does not require a separate light guide.
  • the backlight system 310 includes a front surface 314 and a back surface
  • the system 310 also preferably includes a diffusing means 326 to diffuse light directed towards the back reflector 316.
  • the diffusing means 326 should have varied amounts of diffusion across the back surface ofthe backlight to achieve uniform output.
  • the front surface 314 ofthe backlight system 310 can contain the extraction mechanism used to allow for the uniform transmission of light out of the front surface 314 ofthe backlight system 310.
  • One useful extraction mechanism is to construct the front surface 314 from the multilayer optical film and to provide perforations or voids in i.ie film 314 which allow light to exit the system 310.
  • Figure 1 lb which is a plan view of the front of backlight system 310, it may be preferred in certain applications for the number and/or area of voids 315 to increase as distance from the light source 318 increases.
  • Figuie 12 is a cross-sectional schematic view, another alternate illustrative backlight system 410 which includes a light guide 412 and a light source 418.
  • the light guide 412 includes a front surface 414 and a back surface 416.
  • a lamp cavity reflector 420 is depicted as partially surrounding the light source 418 and coupling the same to the light guide 412.
  • the construction of backlight system 410 is similar to the construction of systems 110 and 210 described above.
  • Light guide 412 is also depicted with diffusing extraction dots 417 located on its back surface 416, although any extraction mechanism could be used as described above.
  • the multilayer optical film back reflector 422 is provided with a structured surface facing the back surface of the light guide 412.
  • structured surface be designed to reflect light upward towards the front surface 414 of light guide 412 within a desired range of angles. This is particularly useful if the backlight system 410 will be used with a structured partially reflective film located in between the backlight and the viewer.
  • exemplary micro-replicated structured partially reflective films are available as Brightness Enhancement Film and Optical Lighting Film, both of which are available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota. Structured partially reflective films typically have excellent reflectivity over certain ranges of angles but high transmission over others.
  • back reflector 422 Because the range of angles within which light is reflected from the structured back reflector 422 can be somewhat controlled, the use of back reflector 422 with a structured surface and a structured film (not shown) located above the backlight system 410 can reduce the number of reflections needed before light can be refracted through the structured film, thereby further limiting any abso ⁇ tive losses in the system 410.
  • the reflective polarizer 419 is used to polarize light entering the guide 420, as shown in Figure 13, then the guide, the light extracting dots and the reflective multilayer mirror 420 are preferably polarization preserving.
  • the multilayer reflector 520 is preferably both diffuse scattering and polarization scrambling.

Abstract

The present invention includes a backlight system incorporating a back reflector and/or a lamp cavity reflector constructed of a multilayer optical film.

Description

BACKLIGHT SYSTEM WITH MULTILAYER OPTICAL FILM REFLECTOR
Technical Field The present invention relates to the field of backlight systems. More particularly, the present invention relates to improved backlight systems with multilayer optical film reflectors.
Background ofthe Invention Liquid crystal (LC) displays are widely used for laptop computers, handheld calculators, digital watches, and similar devices in which information must be displayed to a viewer. In many applications, the displays incorporate a backlight to provide the light necessary to view the display when ambient light entering the display and reflected back out ofthe display is insufficient. Backlight systems typically incorporate a light source and a light guide to direct light from the source and uniformly spread it over the display. Traditionally, light guides have been provided of light transparent material which propagate light along their length through total internal reflection. The light is typically reflected off of the back surface of the light guide and towards the front surface at angles which allow it to exit the front surface of the light guide. Various reflection mechanisms are used to distribute the light exiting the guide uniformly including reflective dots, channels, facets etc.
Backlight systems which use non-collimated light sources such as fluorescent lamps, etc. also typically incorporate at least two reflectors. A lamp cavity mirror is typically used to reflect light exiting the light source in a direction away from the light guide back towards the guide. This reflector can be specular or diffuse, although it is typically specular.
A second reflector is provided proximate the back surface of the light guide to reflect light escaping from the back surface of the light guide and redirect it towards the front surface of the light guide where it can be transmitted to the viewer. These reflectors are typically constructed of a reflective white coating that also diffuse the reflected light over a Lambertian distribution.
A primary disadvantage with the conventional reflectors used in the lamp cavity and at the back surface of the light guide is, however, their relatively high absorptivities and high transmission of incident light. Typical reflectors will absorb or transmit about 4 to about 15% of the light incident upon them. The absorbed light is, of course, not available to the viewer, thereby degrading performance ofthe backlight. The absorptive losses are, of course, increased with every reflection of light from the surface of conventional reflectors. With even the best conventional reflectors which absorb 4% of incident light, the intensity level of reflected light is about 81.5% after only five reflections.
These absorptive losses are also substantially increased when the backlight is used in combination with various light recycling films such as a structured partially reflective film. One micro-replicated structured partially reflective film is available as OPTICAL LIGHTING FILM from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota.
Structured partially reflective films typically have excellent reflectivity over certain ranges of angles but high transmission over others. Micro-replicated structured partially reflective films are available as Brightness Enhancement Film, available from Minnesota Mining and Manufacturing Company. In general, structured partially reflective films redirect and transmit light into a relatively narrow range of angles while reflecting the remainder of the light. As a result, structured films transmit light and enhance brightness in backlight systems by recycling light which would otherwise exit a backlight outside a normal viewing angle.
Although recycling light in that manner is generally desired, it is a disadvantage when combined with conventional reflectors because a portion of the light which is reflected back into the light guide is absorbed or transmitted by the conventional back reflectors. Those increased absoφtion losses reduce the luminance or brightness attainable by this combination ofthe backlight system.
Summary ofthe Invention The present invention includes a backlight system incoφorating a back reflector and/or a lamp cavity reflector constructed of a multilayer optical film.
Providing the multilayer optical film for lamp cavity mirrors and/or back reflectors in backlight systems according to the present invention provides a number of advantages. One advantage is the low absoφtivity of the film. The multilayer optical film according to the present invention can reflect over 99% of the light striking the surface ofthe film.
Another advantage is that the multilayer optical film is also highly efficient at reflecting light whether it is incident normal to the film surface or off-axis.
Yet another advantage of backlight systems employing multilayer optical film reflectors is that the multilayer optical film is relatively low in weight as compared to many conventional reflectors.
Still another advantage of backlight systems employing multilayer optical film back reflectors is that because the film is relatively thin as compared to many conventional reflectors, the backlight systems can be thinner than a backlight system employing a convention back reflector.
Still a further advantage is that an entire light guide can be constructed using multilayer optical film according to the present invention for both the front and back surfaces of the light guide, thereby eliminating the need for a separate light guide and further reducing the cost, weight and bulk of backlight systems. Backlight systems according to the present invention can also incoφorate recycling technologies, such as structured films and/or reflective polarizers, without incurring the significant absoφtive losses associated with conventional reflectors.
Another advantage is that the multilayer optical film is nonconductive, and cannot inductively couple with the lamp. These and other features and advantages of backlight assemblies according to the present invention will become apparent on reading the detailed description below together with reference to the drawings.
Brief Description ofthe Drawings
FIGURES la and lb are diagrammatical views of the multilayer optical film ofthe present invention.
FIGURE 2 shows a two layer stack of films forming a single interface. FIGURES 3-6, 7 A and 7B depict the optical performance of multilayer mirrors given in Examples 1-5.
FIGURE 8 is a graphical representation illustrating the relationship between the number of reflections experienced by a ray of light (x-axis) as compared to the relative intensity of the light ray (y-axis) for reflective surfaces made of multilayer optical film and a standard reflector. FIGURE 9 is a schematic cross-sectional view of one backlight system according to the present invention.
FIGURE 10 is a schematic cross-sectional view of an alternate backlight system according to the present invention.
FIGURE 11 is a schematic cross-sectional view of another alternate backlight system according to the present invention.
FIGURE 12 is a schematic cross-sectional view of another alternate backlight system according to the present invention.
FIGURE 13 shows a schematic cross-sectional view of another alternate backlight system according to the present invention. FIGURE 14 shows a schematic cross-sectional view of another alternate backlight system according to the present invention.
Detailed Description ofthe Invention I. Multilayer Optical Film The backlight systems described herein rely on the unique and advantageous properties of multilayer optical films. The advantages, characteristics and manufacturing of such films are most completely described in the above mentioned copending and commonly assigned U.S. Patent Application 08/402,041, filed March 10, 1995, titled OPTICAL FILM. The multilayer optical film is useful, for example, as highly efficient mirrors and/or polarizers. A relatively brief description ofthe properties and characteristics ofthe multilayer optical film is presented below followed by a description of illustrative embodiments of backlight systems using the multilayer optical film according to the present invention.
Multilayer optical films as used in conjunction with the present invention exhibit relatively low absoφtion of incident light, as well as high reflectivity for off-axis as well as normal light rays. These properties generally hold whether the films are used for pure reflection or reflective polarization of light. The unique properties and advantages of the multi-layer optical film provides an opportunity to design highly efficient backlight systems which exhibit low absoφtion losses when compared to known backlight systems. An exemplary multilayer optical film ofthe present invention as illustrated in
Figures IA and IB includes a multilayer stack 10 having alternating layers of at least two materials 12 and 14. At least one of the materials has the property of stress induced birefringence, such that the index of refraction (n) of the material is affected by the stretching process. Figure IA shows an exemplary multilayer stack before the stretching process in which both materials have the same index of refraction. Light ray 13 experiences no index of refraction change and passes through the stack. In Figure IB, the same stack has been stretched, thus increasing the index of refraction of material 12. The difference in refractive index at each boundary between layers will cause part of ray 15 to be reflected. By stretching the multilayer stack over a range of uniaxial to biaxial orientation, a film is created with a range of reflectivities for differently oriented plane-polarized incident light. The multilayer stack can thus be made useful as reflective polarizers or mirrors.
Multilayer optical films constructed according to the present invention exhibit a Brewster angle (the angle at which reflectance goes to zero for light incident at any of the layer interfaces) which is very large or is nonexistent. In contrast, known multilayer polymer films exhibit relatively small Brewster angles at layer interfaces, resulting in transmission of light and/or undesirable iridescence. The multilayer optical films according to the present invention, however, allow for the construction of mirrors and polarizers whose reflectivity for p polarized light decrease slowly with angle of incidence, are independent of angle of incidence, or increase with angle of incidence away from the normal. As a result, multilayer stacks having high reflectivity for both s and p polarized light over a wide bandwidth, and over a wide range of angles can be achieved.
Figure 2 shows two layers of a multilayer stack, and indicates the three dimensional indices of refraction for each layer. The indices of refraction for each layer are nix, nly, and nlz for layer 102, and n2x, n2y, and n2z for layer 104. The relationships between the indices of refraction in each film layer to each other and to those of the other layers in the film stack determine the reflectance behavior of the multilayer stack at any angle of incidence, from any azimuthal direction. The principles and design considerations described in U.S. patent application Serial Number 08/402,041 can be applied to create multilayer stacks having the desired optical effects for a wide variety of circumstances and applications. The indices of refraction of the layers in the multilayer stack can be manipulated and tailored to produce the desired optical properties.
Referring again to Figure IB, the multilayer stack 10 can include tens, hundreds or thousands of layers, and each layer can be made from any of a number of different materials. The characteristics which determine the choice of materials for a particular stack depend upon the desired optical performance of the stack. The stack can contain as many materials as there are layers in the stack. For ease of manufacture, preferred optical thin film stacks contain only a few different materials.
The boundaries between the materials, or chemically identical materials with different physical properties, can be abrupt or gradual. Except for some simple cases with analytical solutions, analysis of the latter type of stratified media with continuously varying index is usually treated as a much larger number of thinner uniform layers having abrupt boundaries but with only a small change in properties between adjacent layers. The preferred multilayer stack is comprised of low/high index pairs of film layers, wherein each low/high index pair of layers has a combined optical thickness of 1/2 the center wavelength of the band it is designed to reflect. Stacks of such films are commonly referred to as quarterwave stacks. For multilayer optical films concerned with the visible and the near infrared wavelengths, a quarterwave stack design results in each of the layers in the multilayer stack having an average thickness of not more than 0.5 microns.
In those applications where reflective films (e.g. mirrors are desired, the desired average transmission for light of each polarization and plane of incidence generally depends upon the intended use of the reflective film. One way to produce a multilayer mirror film is to biaxially stretch a multilayer stack which contains a birefringent material as the high index layer of the low/high index pair. For a high efficiency reflective film, average transmission along each stretch direction at normal incidence over the visible spectrum (400-700nm) is desirably less than 10% (reflectance greater than 90%), preferably less than 5% (reflectance greater than 95%), more preferably less than 2% (reflectance greater than 98%), and even more preferably less than 1% (reflectance greater than 99%). The av rage transmission at 60 degrees from the normal from 400-700 nm is desirably less than 20% (reflectance greater than 80%), preferably less than 10% (reflectance greater than 90%), more preferably less than 5% (reflectance greater than 95%), and even more preferably less than 2% (reflectance greater than 98%), and even more preferably less than 1% (reflectance greater than 99%).
In addition, asymmetric reflective films may be desirable for certain applications. In that case, average transmission along one stretch direction may be desirably less than, for example, 50%, while the average transmission along the other stretch direction may be desirably less than, for example 20%, over a bandwidth of, for example, the visible spectrum (400-700 nm), or over the visible spectrum and into the near infrared (e.g, 400-850 nm).
Multilayer optical films can also be designed to opeiate as reflective polarizers. One way to produce a multilayer reflective polarizer is to uniaxially stretch a multilayer stack which contains a birefringent material as the high index layer of the low/high index pair. The resulting reflective polarizers have high reflectivity for light with its plane of polarization parallel to one axis (in the stretch direction) for a broad range of angles of incidence, and simultaneously have low reflectivity and high transmissivity for light with its plane of polarization parallel to the other axis (in the non-stretch direction) for a broad range of angles of incidence. By controlling the three indices of refraction of each film, nx, ny and nz, the desired polarizer behavior can be obtained.
For many applications, the ideal reflecting polarizer has high reflectance along one axis (the so-called extinction axis) and zero reflectance along the other (the so-called transmission axis), at all angles of incidence. For the transmission axis of a polarizer, it generally desirable to maximize transmission of light polarized in the direction ofthe transmission axis over the bandwidth of interest and also over the range of angles of interest.
The average transmission at normal incidence for a polarizer in the transmission axis across the visible spectrum (400-700 nm for a bandwidth of 300 nm) is desirably at least 50%, preferably at least 70%, more preferably at least 85%, and even more preferably at least 90%. The average transmission at 60 degrees from the normal (measured along the transmission axis for p-polarized light) for a polarizer from 400-700 nm is desirably at least 50%, preferably at least 70%, more preferably at least 80%, and even more preferably at least 90%.
The average transmission for a multilayer reflective polarizer at normal incidence for light polarized in the direction of the extinction axis across the visible spectrum (400-700 nm for a bandwidth of 300 nm) is desirably at less than 50%, preferably less than 30%, more preferably less than 15%, and even more preferably less than 5%. The average transmission at 60 degrees from the normal (measured along the transmission axis for p-polarized light) for a polarizer for light polarized in the direction of the extinction axis from 400-700 nm is desirably less than 50%, preferably less than 30%, more preferably less than 15%, and even more preferably less than 5%. For certain applications, high reflectivity for p-polarized light with its plane of polarization parallel to the transmission axis at off-normal angles are preferred. The average reflectivity for light polarized along the transmission axis should be more than 20% at an angle of at least 20 degrees from the normal.
In addition, although reflective polarizing films and asymmetric reflective films are discussed separately herein, it should be understood that two or more of such films could be provided to reflect substantially all light incident on them (provided they are properly oriented with respect to each other to do so). This construction is typically desired when the multilayer optical film is used as a reflector in a backlight system according to the present invention.
If some reflectivity occurs along the transmission axis, the efficiency of the polarizer at off-normal angles may be reduced. If the reflectivity along the transmission axis is different for various wavelengths, color may be introduced into the transmitted light. One way to measure the color is to determine the root mean square (RMS) value of the transmissivity at a selected angle or angles over the wavelength range of interest. The % RMS color, can be determined according to the equation:
Figure imgf000011_0001
where the range λl to λ2 is the wavelength range, or bandwidth, of interest, T is the transmissivity along the transmission axis, and T is the average transmissivity along the transmission axis in the wavelength range of interest. For applications where a low color polarizer is desirable, the % RMS color should be less than 10%, preferably less than 8%, more preferably less than 3.5%, and even more preferably less than 2% at an angle of at least 30 degrees from the normal, preferably at least 45 degrees from the normal, and even more preferably at least 60 degrees from the normal.
Preferably, a reflective polarizer combines the desired % RMS color along the transmission axis for the particular application with the desired amount of reflectivity along the extinction axis across the bandwidth of interest. For polarizers having a bandwidth in the visible range (400-700 nm, or a bandwidth of 300 nm), average transmission along the extinction axis at normal incidence is desirably less than 40%, more desirably less than 25%, preferably less than 15%, more preferably less than 5% and even more preferably less than 3%.
Materials Selection and Processing
With the design considerations described in the above mentioned U.S. Patent Application Serial Number 08/402,041, one of ordinary skill will readily appreciate that a wide variety of materials can be used to form multilayer reflective films or polarizers according to the invention when processed under conditions selected to yield the desired refractive index relationships. The desired refractive index relationships can be achieved in a variety of ways, including stretching during or after film formation (e.g., in the case of organic polymers), extruding (e.g., in the case of liquid crystalline materials), or coating. In addition, it is preferred that the two materials have similar rheological properties (e.g., melt viscosities) such that they can be co-extruded.
In general, appropriate combinations may be achieved by selecting, as the first material, a crystalline or semi-crystalline material, preferably a polymer. The second material, in turn, may be crystalline, semi-crystalline, or amoφhous. The second material may have a birefringence opposite of the first material. Or, the second material may have no birefringence, or less birefringence than the first material.
Specific examples of suitable materials include polyethylene naphthalate (PEN) and isomers thereof (e.g., 2,6-, 1,4-, 1,5-, 2,7-, and 2,3-PEN), polyalkylene terephthalates (e.g., polyethylene terephthalate, polybutylene terephthalate, and poly-l,4-cyclohexanedimethylene terephthalate), polyimides (e.g., polyacrylic imides), polyetherimides, atactic polystyrene, polycarbonates, polymethacrylates (e.g., polyisobutyl methacrylate, polypropylmethacrylate, polyethylmethacrylate, and polymethylmethacrylate), polyacrylates (e.g., polybutylacrylate and polymethylacrylate), syndiotactic polystyrene (sPS), syndiotactic poly-alpha-methyl styrene, syndiotactic polydichlorostyrene, copolymers and blends of any of these polystyrenes, cellulose derivatives (e.g., ethyl cellulose, cellulose acetate, cellulose propionate, cellulose acetate butyrate, and cellulose nitrate), polyalkylene polymers (e.g., polyethylene, polypropylene, polybutylene, polyisobutylene, and poly(4-methyl)pentene), fluorinated polymers (e.g., perfluoroalkoxy resins, polytetrafluoroethylene, fluorinated ethylene-propylene copolymers, polyvinylidene fluoride, and polychlorotrifluoroethylene), chlorinated polymers (e.g., polyvinylidene chloride and polyvinylchloride), polysulfones, polyethersulfones, polyacrylonitrile, polyamides, silicone resins, epoxy resins, polyvinylacetate, polyether-amides, ionomeric resins, elastomers (e.g., polybutadiene, polyisoprene, and neoprene), and polyurethanes. Also suitable are copolymers, e.g., copolymers of PEN (e.g., copolymers of 2,6-, 1,4-, 1,5-, 2,7-, and/or 2,3-naphthalene dicarboxylic acid, or esters thereof, with (a) terephthalic acid, or esters thereof; (b) isophthalic acid, or esters thereof; (c) phthalic acid, or esters thereof; (d) alkane glycols; (e) cycloalkane glycols (e.g., cyclohexane dimethane diol); (f) alkane dicarboxylic acids; and/or (g) cycloalkane dicarboxylic acids (e.g., cyclohexane dicarboxylic acid)), copolymers of polyalkylene terephthalates (e.g., copolymers of terephthalic acid, or esters thereof, with (a) naphthalene dicarboxylic acid, or esters thereof; (b) isophthalic acid, or esters thereof; (c) phthalic acid, or esters thereof; (d) alkane glycols; (e) cycloalkane glycols (e.g., cyclohexane dimethane diol); (f) alkane dicarboxylic acids; and/or (g) cycloalkane dicarboxylic acids (e.g., cyclohexane dicarboxylic acid)), and styrene copolymers (e.g., styrene-butadiene copolymers and styrene-acrylonitrile copolymers), 4,4'-bibenzoic acid and ethylene glycol. In addition, each individual layer may include blends of two or more of the above-described polymers or copolymers (e.g., blends of sPS and atactic polystyrene). The coPEN described may also be a blend of pellets where at least one component is a polymer based on naphthalene dicarboxylic acid and other components are other polyesters or polycarbonates, such as a PET, a PEN or a co-PEN.
Particularly preferred combinations of layers in the case of polarizers include PEN/co-PEN, polyethylene terephthalate (PET)/co-PEN, PEN/sPS, PET/sPS, PEN/Eastar, and PET/Eastar, where "co-PEN" refers to a copolymer or blend based upon naphthalene dicarboxylic acid (as described above) and Eastar is polycyclohexanedimethylene terephthalate commercially available from Eastman Chemical Co.
Particularly preferred combinations of layers in the case of reflective films include PET/Ecdel, PEN/Ecdel, PEN/sPS, PEN/THV, PEN/co-PET, and PET/sPS, where "co-PET" refers to a copolymer or blend based upon terephthalic acid (as described above), Ecdel is a thermoplastic polyester commercially available from Eastman Chemical Co., and THV is a fluoropolymer commercially available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota. The number of layers in the film is selected to achieve the desired optical properties using the minimum number of layers for reasons of film thickness, flexibility and economy. In the case of both polarizers and reflective films, the number of layers is preferably less than 10,000, more preferably less than 5,000, and even more preferably less than 2,000. As discussed above, the ability to achieve the desired relationships among the various indices of refraction (and thus the optical properties of the multilayer film) is influenced by the processing conditions used to prepare the multilayer film. In the case of organic polymers which can be oriented by stretching, the films are generally prepared by co-extruding the individual polymers to form a multilayer film and then orienting the film by stretching at a selected temperature, optionally followed by heat-setting at a selected temperature. Alternatively, the extrusion and orientation steps may be performed simultaneously. In the case of polarizers, the film is stretched substantially in one direction (uniaxial orientation), while in the case of reflective films the film is stretched substantially in two directions (biaxial orientation).
The film may be allowed to dimensionally relax in the cross-stretch direction from the natural reduction in cross-stretch (equal to the square root of the stretch ratio); it may simply be constrained to limit any substantial change in cross-stretch dimension; or it may be actively stretched in the cross-stretch dimension. The film may be stretched in the machine direction, as with a length orienter, or in width using a tenter. The pre-stretch temperature, stretch temperature, stretch rate, stretch ratio, heat set temperature, heat set time, heat set relaxation, and cross stretch relaxation are selected to yield a multilayer film having the desired refractive index relationship. These variables are inter-dependent; thus, for example, a relatively low stretch rate could be used if coupled with, e.g., a relatively low stretch temperature. It will be apparent to one of ordinary skill how to select the appropriate combination of these variables to achieve the desired multilayer film. In general, however, a stretch ratios in the range from 1:2 to 1: 10 (more preferably 1:3 to 1:7) in the stretch direction and from 1:0.2 to 1 :10 (more preferably from 1 :0.3 to 1:7) orthogonal to the stretch direction is preferred.
Suitable multilayer films may also be prepared using techniques such as spin coating (e.g., as described in Boese et al., J. Polym. Sci.: Part B, 30: 1321 (1992) for birefringent polyimides, and vacuum deposition (e.g., as described by Zang et. al., Appl. Phys. Letters, 59:823 (1991) for crystalline organic compounds; the latter technique is particularly useful for certain combinations of crystalline organic compounds and inorganic materials.
Exemplary multilayer reflective mirror films and multilayer reflective polarizers will now be described in the following examples.
EXAMPLE 1 (PEN:THV 500. 449. Mirror)
A coextruded film containing 449 layers was made by extruding the cast web in one operation and later orienting the film in a laboratory film-stretching apparatus. A Polyethylene naphthalate (PEN) with an Intrinsic Viscosity of 0.53 dl/g (60 wt. % phenol/40 wt. % dichlorobenzene) was delivered by one extruder at a rate of 56 pounds per hour and THV 500 (a fluoropolymer available from Minnesota Mining and Manufacturing Company) was delivered by another extruder at a rate of 11 pounds per hour. The PEN was on the skin layers and 50% ofthe PEN was present in the two skin layers. The feedblock method was used to generate 57 layers which was passed through three multipliers producing an extrudate of 449 layers. The cast web was 20 mils thick and 12 inches wide. The web was later biaxially oriented using a laboratory stretching device that uses a pantograph to grip a square section of film and simultaneously stretch it in both directions at a uniform rate. A 7.46 cm square of web was loaded into the stretcher at about 100°C and heated to 140°C in 60 seconds. Stretching then commenced at 10%/sec (based on original dimensions) until the sample was stretched to about 3.5x3.5. Immediately after the stretching the sample was cooled by blowing room temperature air at it.
Figure 3 shows the transmission of this multilayer film. Curve (a) shows the response at normal incidence, while curve (b) shows the response at 60 degrees for p-polarized light.
EXAMPLE 2 fPEN:PMMA. 601. Mirror
A coextruded film containing 601 layers was made on a sequential flat-film-making line via a coextrusion process. Polyethylene Naphthalate (PEN) with an Intrinsic Viscosity of 0.57 dl/g (60 wt. % phenol/40 wt. % dichlorobenzene) was delivered by extruder A at a rate of 114 pounds per hour with 64 pounds per hour going to the feedblock and the rest going to skin layers described below. PMMA (CP-82 from ICI of Americas) was delivered by extruder B at a rate of 61 pounds per hour with all of it going to the feedblock. PEN was on the skin layers of the feedblock. The feedblock method was used to generate 151 layers using the feedblock such as those described in U.S. Patent 3,801,429, after the feedblock two symmetric skin layers were coextruded using extruder C metering about 30 pounds per hour of the same type of PEN delivered by extruder A. This extrudate passed through two multipliers producing an extrudate of about 601 layers. U.S. Patent 3,565,985 describes similar coextrusion multipliers. The extrudate passed through another device that coextruded skin layers at a total rate of 50 pounds per hour of PEN from extruder A. The web was length oriented to a draw ratio of about 3.2 with the web temperature at about 280°F. The film was subsequently preheated to about 310°F in about 38 seconds and drawn in the transverse direction to a draw ratio of about 4.5 at a rate of about 11% per second. The film was then heat-set at 440°F with no relaxation allowed. The finished film thickness was about 3 mil. As seen in Figure 4, curve (a), the bandwidth at normal incidence is about 350 nm with an average in-band extinction of greater than 99%. The amount of optical absorption is difficult to measure because of its low value, but is less than 1%. At an incidence angle of 50° from the normal both s (curve (b)) and p-polarized (curve (c)) light showed similar extinctions, and the bands were shifted to shorter wavelengths as expected. The red band-edge for s-polarized light is not shifted to the blue as much as for p-polarized light due to the expected larger bandwidth for s-polarized light, an due to the lower index seen by the p-polarized light in the PEN layers.
EXAMPLE 3 (PEN:PCTG. 449. Polarizer)
A coextruded film containing 481 layers was made by extruding the cast web in one operation and later orienting the film in a laboratory film-stretching apparatus. The feedblock method was used with a 61 layer feedblock and three (2x) multipliers. Thick skin layers were added between the final multiplier and the die. Polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.47 dl/g (60 wt. % phenol/40 wt. % dichlorobenzene) was delivered to the feedblock by one extruder at a rate of 25.0 pounds per hour. Glycol modified polyethylene dimethyl cyclohexane terephthalate (PCTG 5445 from Eastman) was delivered by another extruder at a rate of 25.0 pounds per hour. Another stream of PEN from the above extruder was added as skin layers after the multipliers at a rate of 25.0 pounds per hour. The cast web was 0.007 inches thick and 12 inches wide. The web was layer uniaxially oriented using a laboratory stretching device that uses a pantograph to grip a section of film and stretch it in one direction at a uniform rate while it is allowed to freely relax in the other direction. The sample of web loaded was about 5.40 cm wide (the unconstrained direction) and 7.45 cm long between the grippers of the pantograph. The web was loaded into the stretcher at about 100°C and heated to 135°C for 45 seconds. Stretching was then commenced at 20%/second (based on original dimensions) until the sample was stretched to about 6:1 (based on gripper to gripper measurements). Immediately after stretching, the sample was cooled by blowing room temperature air at it. In the center, the sample was found to relax by a factor of 2.0.
Figure 5 shows the transmission of this multilayer film where curve a shows transmission of light polarized in the non-stretch direction at normal incidence, curve b shows transmission of p-polarized light polarized in the non-stretched direction at 60° incidence, and curve c shows the transmission of light polarized in the stretch direction at normal incidence. Average transmission for curve a from 400-700nm is 89.7%, average transmission for curve b from 400-700nm is 96.9%, and average transmission for curve c from 400-700nm is 4.0%. % RMS color for curve a is 1.05%, and %RMS color for curve b is 1.44%.
EXAMPLE 4 (PEN:CoPEN. 601. Polarizer)
A coextruded film containing 601 layers was made on a sequential flat-film-making line via a coextrusion process. A Polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.54 dl/g (60 wt % Phenol plus 40 wt % dichlorobenzene) was delivered by on extruder at a rate of 75 pounds per hour and the coPEN was delivered by another extruder at 65 pounds per hour. The coPEN was a copolymer of 70 mole % 2,6 naphthalene dicarboxylate methyl ester, 15 % dimethyl isophthalate and 15% dimethyl terephthalate with ethjlene glycol. The feedblock method was used to generate 151 layers. The feedblock was designed to produce a stack of films having a thickness gradient from top to bottom, with a thickness ratio of 1.22 from the thinnest layers to the thickest layers. The PEN skin layers were coextruded on the outside of the optical stack with a total thickness of 8% of the coextruded layers. The optical stack was multiplied by two sequential multipliers. The nominal multiplication ratio of the multipliers were 1.2 and 1.27, respectively. The film was subsequently preheated to 310°F in about 40 seconds and drawn in the transverse direction to a draw ratio of about 5.0 at a rate of 6% per second. The finished film thickness was about 2 mils.
Figure 6 shows the transmission for this multilayer film. Curve a shows transmission of light polarized in the non-stretch direction at normal incidence, curve b shows transmission of p-polarized light at 60° incidence, end curve c shows transmission of light polarized in the stretch direction at normal incidence. Note the very high transmission of p-polarized light in the non-stretch direction at both normal and 60° incidence (80-100%). Also note the very high reflectance of light polarized in the stretched direction in the visible range (400-700nm) shown by curve c. Reflectance is nearly 99% between 500 and 650nm.
EXAMPLE 5 CPEN:sPS. 481. Polarizer)
A 481 layer multilayer film was made from a polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.56 dl/g measured in 60 wt. % phenol and 40 wt % dichlorobenzene purchased from Eastman Chemicals and a syndiotactic polystyrene (sPS) homopolymer (weight average molecular weight = 200,000 Daltons, sampled from Dow Corporation). The PEN was on the outer layers and was extruded at 26 pounds per hour and the sPS at 23 pounds per hour. The feedblock used produced 61 layers with each of the 61 being approximately the same thickness. After the feedblock three (2x) multipliers were used. Equal thickness skin layers containing the same PEN fed to the feedblock were added after the final multiplier at a total rate of 22 pounds per hour. The web was extruded through a 12" wide die to a thickness of about 0.01 1 inches (0.276 mm). The extrusion temperature was 290°C. This web was stored at ambient conditions for nine days and then uniaxially oriented on a tenter. The film was preheated to about 320°F (160°C) in about 25 seconds and drawn in the transverse direction to a draw ratio of about 6:1 at a rate of about 28% per second. No relaxation was allowed in the stretched direction. The finished film thickness was about 0.0018 inches (0.046 mm). Figure 7A shows the optical performance of this PEN:sPS reflective polarizer containing 481 layers. Curve a shows transmission of light polarized in the non-stretch direction at normal incidence, curve b shows transmission of p-polarized light at 60° incidence, and curve c shows transmission of light polarized in the stretch direction at normal incidence. Note the very high transmission of p-polarized lir' t at both normal and 60° incidence. Average transmission for curve a over 400-700 nm is 86.2%, the average transmission for curve t over 400-700 nm is 79.7%. Also note the very high reflectance of light polarized in the stretched direction in the visible range (400-700nm) shown by curve c. The film has an average transmission of 1.6% for curve c between 400 and 700 nm. The % RMS color for curve a is 3.2%, while the % RMS color for curve b is 18.2%.
EXAMPLE 6 (PEN oPEN. 603. Polarizer)
A reflecting polarizer comprising 603 layers was made on a sequential flat-film making line via a coextrusion process. A polyethylene naphthalate (PEN) with an intrinsic viscosity of 0.47 dl g (in 60 wt% phenol plus 40 wt% dichlorobenzene) was delivered by an extruder at a rate of 83 pounds (38 kg) per hour and the CoPEN was delivered by another extruder at 75 pounds (34 kg) per hour. The CoPEN was a copolymer of 70 mole %, 2,6 naphthalene dicarboxylate methyl ester, 15 mole % dimethyl terephthalate, and 15 mole % dimethyl isophthalate with ethylene glycol. The feedblock method was used to generate 151 layers. The feedblock was designed to produce a stack of films having a thickness gradient from top to bottom, with a thickness ratio of 1.22 from the thinnest layers to the thickest layers. This optical stack was multiplied by two sequential multipliers. The nominal multiplication ratio of the multipliers was 1.2 and 1.4, respectively. Between the final multiplier and the die, skin layers were added composed of the same CoPEN described above, delivered by a third extruder at a total rate of 106 pounds (48 kg) per hour. The film was subsequently preheated to 300°F (150°C) in about 30 seconds and drawn in the transverse direction to a draw ratio of approximately 6 at an initial rate of about 20% per second. The finished film thickness was approximately 0.0035 inch (0.089 mm). Figure 7B shows the optical performance of the polarizer of Example 6.
Curve a shows transmission of light polarized in the non-stretch direction at normal incidence, curve b shows transmission of p-polarized light in the nonstretch direciton at 50 degree angle of incidence, and curve c shows transmission of light polarized in the stretch direction at normal incidence. Note the very high transmission of light polarized in the non-stretch direction. Average transmission for curve a over 400-700 nm is 87%. Also note the very high reflectance of light polarized in the stretched direction in the visible range (400-700nm) shown by curve c. The film has an average transmission of 2.5%) for curve c between 400 and 700 nm. The % RMS color for curve b is 5%.
II. Backlight Systems Using Multilayer Optical Films
Backlight systems according to the present invention use multilayer optical films to reflect light. Reflectors constructed of multilayer optical film are most advantageously located around the light source as well as along the back surface of the light guide, although in some instances they may be used in one or the other location alone.
The advantages of using multilayer optical film for reflectors in backlight systems are graphically illustrated in Figure 8. Curve a shows the total reflectivity as a function of the number of reflections for a conventional reflector that has 96% reflectivity (i.e., about 4% ofthe light is absorbed at each reflection). As shown by curve a, the intensity of light which has been reflected from a conventional reflector decreases significantly after a relatively low number of reflections. In contrast, curve b shows the total reflectivity for a multilayer mirror film having a reflectivity of about 99.4%). Curve b clearly shows a much smaller decrease in reflectivity. The difference becomes especially pronounced after only 2-4 reflections. For example, after five reflections, the intensity of light is about 97% for light reflected from multilayer optical films according to the present invention, while the intensity drops to about 81.5% for light reflected from a conventional reflector which is only about 3.5% less efficient. Although it is difficult to determine the average number of reflections experienced by light in a backlight system, the number of reflections can be expected to increase as uniformity and/or aspect ratio (defined more completely below) increase in any given backlight system. Those increased reflections would cause a significant loss in efficiency for backlight systems using conventional reflectors which would not be experienced in backlight systems employing multilayer optical film reflectors according to the present invention. The practical value of this characteristic is that the efficiency of the backlighting systems and any display employing one is greatly enhanced resulting in increased brightness and/or contrast as compared to systems employing conventional reflectors. Put another way, the number of acceptable reflections for a given light ray in backlight systems employing multilayer optical film reflectors according to the present invention can be significantly increased without substantially impairing the overall output of the backlight system as compared to backlight systems employing conventional reflectors. Put another way, the probability that a photon will not be lost is increased in backlight systems employing optical film reflectors.
Figures 9-12 will now be described. The figures schematically depict various backlight systems manufactured according to the present invention, but are not intended to limit the scope of the present invention. For example, all of the figures depict light guides having essentially rectangular cross-sections. It will be understood, however, that the multilayer optical film reflectors can be used with any light guide including a lamp cavity reflector and/or a back reflector. Other examples of light guides include wedge-shaped guides, channeled guides, pseudo-wedge guides, etc.
Figure 9 depicts, in a cross-sectional schematic view, an illustrative backlight system 110 which includes a light guide 112 and a light source 118. Light source 118 may be any source which emits light, such as a fluorescent lamp, incandescent lamp, solid state source, electroluminescent (EL) light source or any other source of visible light. Although the embodiments described below typically include one such source, it will be understood that a backlight system according to the present invention could include two or more individual sources located at the same or different positions and combining to provide the required amount of light.
In the preferred embodiments, the light source 118 comprises a source emitting light having randomized polarization. A reflective polarizer may be placed between the source and light guide such that light transmitted to the light guide 112 is substantially of one polarization orientation. The reflective polarization can be accomplished using bulk optics or a multilayer reflective polarizer, both of which are described in copending and commonly-assigned U.S. patent application Serial No. 08/418,009, titled POLARIZED LIGHT SOURCES, filed on April 6, 1995.
The light guide 112 includes a front surface 114 and a back surface 116. Components such as polarizers, diffusers, liquid crystal display panels, graphics films, prints and compensation/retarder films are typically placed above the front surface 1 14 of the light guide 112, are not depicted in Figure 9 (or any of the backlight systems depicted in any of the figures) but will be well known to those skilled in the art and will not be described herein.
A lamp cavity reflector 120 is depicted as partially surrounding the light source 118 and coupling the same to the light guide 1 12. Conventional lamp cavity reflectors are constructed of a silvered film which exhibit reflectivities of about 96% for visible wavelengths, with the remaining light being substantially absorbed by the reflector. A lamp reflector 120 constructed using multilayer optical film according to the present invention, however, exhibits much higher reflectivities, typically about 98%) or greater which significantly reduces losses. In addition, the presently described multilayer film has very high reflectivity, preferably at least 90%, more preferably 95%, and even more preferably at least 98%, at angles away from the normal (for example, greater than 45°). Since in many backligh'ing systems, such as those shown in Figures 9-12, the light enters from the side ofthe light guide, this is a distinct advantage.
It may be desirable to provide for increased lamp operating temperatures in which case the exterior surface of the reflector 120 can be coated with a metallic layer or an additional reflector can be provided (see reference number 224 in Figure 10 and the description below). This can increase infrared reflectance as well as reduce convective cooling ofthe lamp 118.
Backlight systems incoφorating multilayer optical film as the lamp cavity reflector 120 will typically exhibit approximately a 20% or greater increase in brightness when a silvered optical film lamp reflector 120 is replaced by multilayer optical film according to the present invention, when all other variables are constant. This increase can be largely attributed to the extremely low absoφtivity and high reflectivity ofthe multilayer optical film. In the backlight system 110, the lamp cavity reflector 120 is preferably integrated with the back reflector 122, either by laminating or similarly attaching the two pieces together or by using one continuous sheet for both functions. As a result, there are essentially no losses associated with the interface between the two reflectors 120 and 122. In addition, manufacturing ofthe backlight system 110 can be simplified by such a design. In addition, it maybe preferred in certain applications to laminate or otherwise similarly attach the back reflector to the back of the light guide 112. This eliminates the air gap between components, thus reducing surface reflections and increasing overall efficiency ofthe system. The mechanism used to extract light from the light guide 112 is not depicted in Figure 9 as any suitable mechanism could be used. Examples of extraction mechanisms include, but are not limited to: diffusing dots on the back surface 116 of light guide 112, channels in the back surface 116, the discontinuities associated with a pseudo-wedge light guide 112, and the increased reflected angles within a wedge-shaped light guide 112, and posts that adhere the reflector to the guide and provide light diffusion within the guide.
In the instance where a less efficient multilayer reflective film is used as the back reflector 122, it may be advantageous to provide the back surface layer 122, i.e., the surface facing away from the light guide 112, with a thin metal or other reflective coating to decrease transmissive losses through the multilayer optical film reflector 122, thereby improving the reflectivity of the multilayer optical film 122. It will of course, be understood that the metallic or other reflective coating may suffer from some absoφtion losses, but the fraction of light transmitted through the film 122 will typically be less than 5% (more preferably less than about 1%) of the total light incident on the film 122.
Another advantage of backlight systems 110 incoφorating multilayer optical film for the back reflector 122 is in the flexibility for designing backlight systems which have relatively high aspect ratios. Aspect ratio can be defined as the inverse of the thickness of the backlight system as opposed to its length or surface area (in the case of a planar surface over which light is to be distributed). In Figure 9, thickness ofthe light guide 112 is depicted as T while the length of the light guide is depicted as L. That ratio, L/T can be significantly higher in backlight systems 110 according to the present invention due to the relative thinness and flexibility ofthe multilayer optical films. The aspect ratio can be higher because the number of reflections for any given light ray entering light guide 112 before it exits the backlight system 110 can be significantly higher without substantially degrading the overall light output of the backlight system 110 due to the low absorbance of the reflective surfaces provided by multilayer optical film back reflector 122. In contrast, the designer of a similar backlight system incoφorating conventional reflectors which absorb incident light must be concerned with the number of reflections experienced by the light before exiting the backlight and the resulting absoφtive losses.
Although both the lamp cavity reflector 120 and back reflector 122 of backlight system 110 are described as being constructed of multilayer optical film according to the present invention, it will be understood that only one of the reflectors 120 or 122 may be constructed of multilayer optical film while the other is constructed of conventional reflective materials. However, such a construction may not be preferred for certain applications due the absoφtion losses which would be experienced. Figure 10 depicts, in a cross-sectional schematic view, an illustrative backlight system 210 which includes a light guide 212 and a light source 218. The light guide 212 includes a front surface 214 and a back surface 216. A lamp cavity reflector 220 is depicted as partially surrounding the light source 218 and coupling the same to the light guide 212. In most respects, the construction of backlight system 210 is similar to the construction of system 1 10 described above.
Differences include the addition of a separate lamp cavity reflector 224 disposed about the outer surface of the multilayer optical film lamp cavity reflector 220 to prevent transmissive losses in the event that a less efficient multilayer optical film is used. However, if a very efficient, e.g. at least 97% reflective, film is used, the reflector 224 may not be required. An additional layer 226 is depicted as interposed between the back reflector 222 and the back surface 216 of the light guide 212. That additional layer preferably comprises a means of diffusing light directed towards back reflector 222. A means of diffusing light may be helpful in some backlight systems because typical multilayer optical films provided as mirrors exhibit specular reflection which may be undesirable on some applications.
The diffusing means 226 can be provided in many different forms as long as it diffuses the specular component of light reflected from the multilayer optical film back reflector 222. It is preferred, however, that the diffusing means absorb a minimum amount of incident light, thereby reducing its impact on the performance of the backlight system 210. It may also be preferred that the diffusing means 226 is polarization preserving (as shown below with respect to Figure 13) or polarization scrambling (as shown with respect to Figure 14).
Other means of diffusing light could include loading diffusing particles, such as barium sulfate, in a coextruded skin layer located on the multilayer optical film back reflector 222. Alternately, the diffusing particles could be included within one of the layers in the stack, preferably near the surface on which light is incident. Diffusing layers could also be coated by extrusion coating on the multilayer optical film or they could be spread on the surface of the multilayer optical film using a suitable solvent.
Another diffusing means could comprise a commercially available diffusing film located between the multilayer optical film back reflector 222 and the back surface 216 of light guide 212. One example of a diffusing film is DFA-12, available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota.
In another variation, a diffusing adhesive could be used to attach the multilayer optical film back reflector 222 to the back surface 216 ofthe light guide 212. Exemplary diffusing adhesives are described below.
One exemplary diffusing adhesive can be made by forming acrylic/styrene beads and dispersing the beads in a water based emulsion adhesive. An adhesive containing 5% by weight ofthe microspheres, was coated out on a PET liner film and was dried to form an 8.4 grain/4" x 6" adhesive layer. Diffusing adhesive was coated to 4 mils wet at 17 feet per minute. The drying oven was 30 feet in length. The drying temperature was 180° F.
Preparation of Styrene Particles
3 grams of poly(vinyl alcohol) and 9 grams of standapol-A (ammonium lauryl sulfate - Hercules) was dissolved in 480 grams of water. 2 grams of Lucidol™-75 (75% benzoyl peroxide - Elf Atochem) was dissolved in 120g of styrene. The above two mixtures were blended and emulsified in a Gaulin homogenizer until the droplet size was approximately 2 microns. The emulsion was charged to a 1 liter reactor, heated to 80°C, degassed with argon and allowed to react for 12 hours.
Preparation of Pressure-Sensitve Adhesive Microparticles by Suspension Polymerization Method
1 gram of sodium dodecyl benzene sulfonate was dissolved in 360 grams of deionized water. 2.4 grams of poly( ethylene oxide)i6 acrylate (PEO), 4.8 grams of acrylic acid and 1.05 grams of Lucidol™75 (75% benzoyl peroxide from Elf Atochem) were dissolved in 232.8 grams of iso-octyl acrylate (IOA). The above mixture was emulsified in a Gaulin homogenizer such that the droplet size was 1 micron or less. This emulsion was then charged to 1 liter reactor, stirred at 400 RPM and heated to 65°C for 4 hours. The 97/2/1 IOA/AA/PEO resulting particles had a size of approximately 2 microns as viewed with an optical microscope and had an index of refraction of 1.47.
Light-Diffusing Adhesive Preparation
440 grams of the above Pressure Sensitive Adhesive Suspension was blended with 58 grams of the above poly(styrene) suspension, 1.5 grams of Triton GR-5M (Rohm & Haas) and 1.8 grams Polyphobe 104 (Union Carbide). The mixture was neutralized with ammonium hydroxide to a pH of 8.3. The diffuser adhesive solution was coated onto a PET release liner at 4 mils wet and dried at 65°C for lO minutes.
If it is desired to preserve the polarization of the light exiting from the backlight system 210, e.g., where a liquid crystal display is being illuminated and the light source 218 emits polarized light, the diffusing particles used in the system 210 should be as spherical as possible to preserve polarization.
Conversely, if the backlight system 210 is being used in conjunction with a multilayer or other type of reflective polarizing film (not shown) iocated above the front surface 214 to recycle light having the "wrong" polarization it is desirable that the diffusing means also randomize polarization of the light to enhance that recycling process. An alternative construction is to use the polarization preserving diffuser and a birefringent film or skin layer to depolarize the light
Figure l la depicts, in a cross-sectional schematic view, an alternate illustrative backlight system 310. This backlight system illustrates the construction of a backlight system without a separate light guide as described in the above systems. Light guides, which are typically constructed of materials such as acrylic, add weight to the backlight system. As described below, the mult Mayer optical films described above present the opportunity to construct a highly efficient backlight system 310 which does not require a separate light guide. The backlight system 310 includes a front surface 314 and a back surface
316 as well as a light source 318 and a lamp cavity mirror 320 The system 310 also preferably includes a diffusing means 326 to diffuse light directed towards the back reflector 316. The diffusing means 326 should have varied amounts of diffusion across the back surface ofthe backlight to achieve uniform output. The front surface 314 ofthe backlight system 310 can contain the extraction mechanism used to allow for the uniform transmission of light out of the front surface 314 ofthe backlight system 310.
One useful extraction mechanism is to construct the front surface 314 from the multilayer optical film and to provide perforations or voids in i.ie film 314 which allow light to exit the system 310. As shown in Figure 1 lb, which is a plan view of the front of backlight system 310, it may be preferred in certain applications for the number and/or area of voids 315 to increase as distance from the light source 318 increases. In a system such as that depicted in Figures l la and l ib, it may be desirable to place a diffusing layer above the front surface 314 to obscure the voids 315. If such a diffusing layer is provided, the diffusing layer 326 depicted as lying between front surface 314 and back reflector 316 may be unnecessary.
Figuie 12 is a cross-sectional schematic view, another alternate illustrative backlight system 410 which includes a light guide 412 and a light source 418. The light guide 412 includes a front surface 414 and a back surface 416. A lamp cavity reflector 420 is depicted as partially surrounding the light source 418 and coupling the same to the light guide 412. In most respects, the construction of backlight system 410 is similar to the construction of systems 110 and 210 described above. Light guide 412 is also depicted with diffusing extraction dots 417 located on its back surface 416, although any extraction mechanism could be used as described above. One of the primary differences is that the multilayer optical film back reflector 422 is provided with a structured surface facing the back surface of the light guide 412. It is preferred that structured surface be designed to reflect light upward towards the front surface 414 of light guide 412 within a desired range of angles. This is particularly useful if the backlight system 410 will be used with a structured partially reflective film located in between the backlight and the viewer. Exemplary micro-replicated structured partially reflective films are available as Brightness Enhancement Film and Optical Lighting Film, both of which are available from Minnesota Mining and Manufacturing Company, St. Paul, Minnesota. Structured partially reflective films typically have excellent reflectivity over certain ranges of angles but high transmission over others. Because the range of angles within which light is reflected from the structured back reflector 422 can be somewhat controlled, the use of back reflector 422 with a structured surface and a structured film (not shown) located above the backlight system 410 can reduce the number of reflections needed before light can be refracted through the structured film, thereby further limiting any absoφtive losses in the system 410. Another alternative to providing the structured surface directly in the back reflector 422, would be to inteφose a layer of structured film between the back reflector and the back surface ofthe light guide.
When the reflective polarizer 419 is used to polarize light entering the guide 420, as shown in Figure 13, then the guide, the light extracting dots and the reflective multilayer mirror 420 are preferably polarization preserving.
In light recycling backlights such as that shown in Figure 14, where reflective polarizers 523, brightness enhancement film 525 or combination thereof are placed on top of the light guide, the multilayer reflector 520 is preferably both diffuse scattering and polarization scrambling.
The present invention has been described above with respect to illustrative examples to which modifications may be made without departing from the scope of the invention as defined by the appended claims.

Claims

Claims
1. A backlight system comprising: a) a light guide defining a back surface; b) a light source optically connected to the light guide, the light source emitting light into the light guide; and c) a back reflector proximate the back surface of the light guide, the back reflector comprising a multilayer optical film which reflects at least about 80% of normal light and at least about 80% of light incident at an angle of 60 degrees from normal.
2. A backlight system according to claim 1, wherein the back reflector reflects at least about 90% of normally incident light.
3. A backlight system according to claim 1, wherein the back reflector reflects at least about 95% of normally incident light.
4. A backlight system according to claim 1, wherein the back reflector reflects at least about 98% of normally incident light.
5. A backlight system according to claim 1, wherein the back reflector reflects at least about 99% of normally incident light.
6. A backlight system according to claim 1, wherein the back reflector reflects at least about 90% ofthe light incident at an angle of 60 degrees from normal.
7. A backlight system according to claim 1, wherein the back reflector reflects at least about 95% ofthe light incident at an angle of 60 degrees from normal.
8. A backlight system according to claim 1, wherein the back reflector reflects at least about 98% ofthe light incident at an angle of 60 degrees from normal.
9. A backlight system according to claim 1, wherein the back reflector reflects at least about 99% ofthe light incident at an angle of 60 degrees from normal.
10. A backlight system according to claim 1, further comprising diffusing means for diffusing light reflected from the back reflector towards the back surface of the light guide.
11. A backlight system according to claim 10, wherein the diffusing means comprises diffusing particles within at least one layer ofthe multilayer optical film.
12. A backlight system according to claim 10, wherein the diffusing means comprises diffusing particles located on a surface ofthe multilayer optical film.
13. A backlight system according to claim 10, wherein the diffusing means comprises a diffusing film located between the back reflector and the back surface ofthe light guide.
14. A backlight system according to claim 1, wherein the back surface of the light guide is formed by the back reflector.
15. A backlight system according to claim 1, further comprising a lamp cavity reflector located about at least a portion of the light source, the lamp cavity reflector directing light from light source generally towards an edge of the light guide, the lamp cavity reflector further comprising a multilayer optical film which reflects at least about 80% of normal light and at least about 80% of light incident at an angle of 60 degrees from normal.
16. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 90% of normally incident light.
17. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 95% of normally incident light.
18. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 98%) of normally incident light.
19. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 99% of normally incident light.
20. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 90% of the light incident at an angle of 60 degrees from normal.
21. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 95% of the light incident at an angle of 60 degrees from normal.
22. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 98% of the light incident at an angle of 60 degrees from normal.
23. A backlight system according to claim 15, wherein the lamp cavity reflector reflects at least about 99% of the light incident at an angle of 60 degrees from normal.
24. A backlight system comprising: a) a light guide defining a back surface; b) a light source optically connected to the light guide, the light source emitting light into the light guide; c) a back reflector proximate the back surface of the light guide, the back reflector comprising a multilayer optical film which reflects at least about 90% of normal light and at least about 80% of light incident at an angle of 60 degrees from normal; and d) a lamp cavity reflector located about at least a portion of the light source, the lamp cavity reflector directing light from light source generally towards an edge of the light guide, the lamp cavity reflector further comprising the multilayer optical film.
25. A backlight system according to claim 24, further comprising diffusing means for diffusing light reflected from the back reflector towards the back surface ofthe light guide.
26. A backlight system according to claim 1, wherein the multilayer optical film further comprises:
(a) a first layer comprising an oriented birefringent polymer, the first layer having an average thickness of not more than about 0.5 microns; and
(b) a second layer of a selected second polymer, each second layer having an average thickness of not more than 0.5 microns.
27. A backlight system according to claim 26, wherein the first layer of the multilayer optical film comprises a crystalline naphthalene dicarboxylic acid polyester.
28. A backlight system according to claim 26, wherein the multilayer optical film comprises a plurality of the first and second layers, wherein one of the second layers is located between each adjacent pair of first layers.
29. A backlight system according to claim 28, wherein the first and second layers ofthe multilayer optical film are adhered to each other.
30. A backlight system according to claim 26, wherein the multilayer optical film comprises at least fifty of e . !ι ofthe first and second layers.
31. A backlight system according to claim 26, wherein the oriented birefringent polymer has been stretched in at least two in-plane directions.
32. A backlight system according to claim 26, wherein the oriented birefringent polymer is more birefringent than the second polymer, and further wherein the refractive index of one polymer is higher than the other polymer.
33. A backlight system according to claim 32, wherein the higher index of refraction is at least 0.05 higher.
34. A backlight system according to claim 32, wherein the higher index of refraction is at least 0.10 higher.
35. A backlight system according to claim 32, wherein the higher index of refraction is at least 0.20 higher.
36. A backlight system according to claim 27, wherein the naphthalene dicarboxylic acid polyester is a poly(ethylene naphthalate).
37. A backlight system according to claim 27, wherein the naphthalene dicarboxylic acid polyester is a copolyester comprising naphthalate units and terephthalate units.
38. A backlight system according to claim 27, wherein the second polymer is a polyester.
39. A backlight system according to claim 38, wherein the second polymer comprises naphthalene units.
40. A backlight system according to claim 38, wherein the second polymer is a copolyester comprising naphthalate units and terephthalate units.
41. A backlight system according to claim 27, wherein the second polymer is a polystyrene.
42. A backlight system according to claim 27, wherein the second polymer is a fluoropolymer.
43. A backlight system according to claim 27, wherein the second polymer is a polyacrylate, polymethacrylate, or polyolefin.
44. A backlight system comprising: a) a light guide defining a back surface; b) a light source optically connected to the light guide, the light source emitting light into the light guide; c) a back reflector proximate the back surface of the light guide, the back reflector comprising a multilayer optical film which reflects at least about 90% of normal light and at least about 80% of light incident at an angle of 60 degrees from normal, the multilayer optical film further comprising:
(1) a first layer comprising a biaxially oriented birefringent polymer, the first layer having an average thickness of not more than about 0.5 microns; and
(2) a second layer of a selected second polymer, each second layer having an average thickness of not more than 0.5 microns; ar.d d) a lamp cavity reflector located about at least a portion of the light source, the lamp cavity reflector directing light from light source generally towards an edge of the light guide, the lamp cavity reflector further comprising the multilayer optical film.
45. A backlight system comprising: a) a light guide defining a back surface; b) a light source optically connected to the light guide, the light source emitting light into the light guide; and c) a lamp cavity reflector located about at least a portion of the light source, the lamp cavity reflector directing light from light source generally towards an edge ofthe light guide, the lamp cavity reflector further comprising a multilayer optical film which reflects at least about 80% of normal light and at least about 80% of light incident at an angle of 60 degrees from normal.
46. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 90% of normally incident light.
47. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 95% of normally incident light.
48. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 98% of normally incident light.
49. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 99% of normally incident light.
50. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 90% of the light incident at an angle of 60 degrees from normal.
51. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 95% of the light incident at an angle of 60 degrees from normal.
52. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 98% of the light incident at an angle of 60 degrees from normal.
53. A backlight system according to claim 45, wherein the lamp cavity reflector reflects at least about 99% of the light incident at an angle of 60 degrees from normal.
PCT/US1996/007596 1995-06-26 1996-05-24 Backlight system with multilayer optical film reflector WO1997001726A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP96920454A EP0832392B1 (en) 1995-06-26 1996-05-24 Backlight system with multilayer optical film reflector
AU58750/96A AU716525B2 (en) 1995-06-26 1996-05-24 Backlight system with multilayer optical film reflector
DE69629471T DE69629471T2 (en) 1995-06-26 1996-05-24 BACKLIGHTING DEVICE WITH MULTILAYER FILM REFLECTOR
JP9504407A JPH11508702A (en) 1995-06-26 1996-05-24 Backlight system with multilayer optical film reflector

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Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999036257A1 (en) * 1998-01-13 1999-07-22 Minnesota Mining And Manufacturing Company Clear to colored security film
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US5986731A (en) * 1997-08-07 1999-11-16 Seiko Epson Corporation Liquid crystal display device and electronic device using same
US6008871A (en) * 1997-01-20 1999-12-28 Seiko Epson Corporation Transflective liquid crystal display device having a reflective polarizer
WO2000029212A1 (en) * 1998-11-16 2000-05-25 Engelhard Corporation Multi-layer iridescent films
EP1022129A2 (en) * 1999-01-22 2000-07-26 Elf Atochem S.A. Light diffusing composites
US6118504A (en) * 1996-08-23 2000-09-12 Seiko Epson Corporation Display device and electronic apparatus comprising the same
US6124905A (en) * 1997-09-18 2000-09-26 Seiko Epson Corporation Display device employing a reflective polarizer and a reflective diffuser between a light source and the display device
US6141068A (en) * 1997-06-13 2000-10-31 Seiko Epson Corporation Display devices, electronic apparatus using the same, and polarized light separator
US6147934A (en) * 1997-06-09 2000-11-14 Seiko Epson Corporation Display device and electronic watch
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US6184955B1 (en) 1997-01-17 2001-02-06 Seiko Epson Corporation Liquid crystal device and electronic apparatus using it
US6201770B1 (en) 1997-07-09 2001-03-13 Seiko Epson Corporation Electronic timepiece
WO2001026891A1 (en) * 1999-10-12 2001-04-19 3M Innovative Properties Company Optical bodies made with a birefringent polymer
US6233029B1 (en) 1996-08-23 2001-05-15 Seiko Epson Corporation Display device and electronic apparatus using the same having a reflective polarizer between LCD and optical element which emits light responsive to light from polarizer
US6246455B1 (en) 1996-09-17 2001-06-12 Seiko Epson Corporation Display device with liquid crystal between reflective polarizers, and a light source illuminating between the polazers
WO2001053745A1 (en) * 2000-01-19 2001-07-26 Omlidon Technologies Llc Polarizing device
US6285422B1 (en) 1996-09-17 2001-09-04 Seiko Epson Corporation Transflective liquid crystal device with bright reflective display
US6300989B1 (en) 1997-06-13 2001-10-09 Seiko Epson Corporation Display device using polarized light separating means and electronic apparatus using the same
US6328447B1 (en) 1997-12-03 2001-12-11 Seiko Epson Corporation Projection device
US6447135B1 (en) 1999-10-08 2002-09-10 3M Innovative Properties Company Lightguide having a directly secured reflector and method of making the same
US6507380B1 (en) 1997-07-25 2003-01-14 Seiko Epson Corporation Display device and electronic apparatus using the same
US6529250B1 (en) 1997-05-22 2003-03-04 Seiko Epson Corporation Projector
WO2003042290A1 (en) * 2001-11-16 2003-05-22 Röhm GmbH & Co. KG Light conducting body and method for the production thereof
US6610356B2 (en) 1998-01-13 2003-08-26 3M Innovative Properties Company Dichroic polarizing film and optical polarizer containing the film
US6641900B2 (en) 1998-01-13 2003-11-04 3M Innovative Properties Company Modified copolyesters and improved multilayer reflective films
US6798468B1 (en) 1997-09-18 2004-09-28 Seiko Epson Corporation Display device with a light-reflective polarizer and electronic apparatus employing the same
WO2006038417A1 (en) * 2004-10-01 2006-04-13 Nitto Denko Corporation Polarized interference recycling backlight module and liquid crystal display incorporating the same
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EP1059484B2 (en) 1999-05-25 2014-05-14 Siteco Beleuchtungstechnik GmbH Luminaire with wide beam light intensity distribution
US8848132B2 (en) 2008-02-07 2014-09-30 3M Innovative Properties Company Hollow backlight with structured films
US8926159B2 (en) 2007-05-20 2015-01-06 3M Innovative Properties Company Thin hollow backlights with beneficial design characteristics
US9028108B2 (en) 2007-05-20 2015-05-12 3M Innovative Properties Company Collimating light injectors for edge-lit backlights
US9091408B2 (en) 2007-05-20 2015-07-28 3M Innovative Properties Company Recycling backlights with semi-specular components
US9541698B2 (en) 2008-02-22 2017-01-10 3M Innovative Properties Company Backlights having selected output light flux distributions and display systems using same
US9588270B2 (en) 1998-01-13 2017-03-07 3M Innovative Properties Company Post-formable multilayer optical films and methods of forming

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6926952B1 (en) * 1998-01-13 2005-08-09 3M Innovative Properties Company Anti-reflective polymer constructions and method for producing same
US6952310B1 (en) * 1999-05-12 2005-10-04 Nitto Denko Corporation Light pipe and polarized-light source
JP3555863B2 (en) * 2000-07-06 2004-08-18 Nec液晶テクノロジー株式会社 Reflector, method of manufacturing the same, and liquid crystal display device using the same
CN1318901C (en) * 2002-11-27 2007-05-30 鸿富锦精密工业(深圳)有限公司<Del/> LCD device
JP4216577B2 (en) * 2002-12-20 2009-01-28 シチズン電子株式会社 Light guide plate
EP1576052B1 (en) * 2002-12-27 2007-02-14 Kolon Industries, Inc. Light diffusion resin composition
TWI225878B (en) * 2002-12-27 2005-01-01 Kolon Inc Light diffusion resin composition
JP2006522445A (en) * 2003-04-07 2006-09-28 コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ lighting equipment
US20050030729A1 (en) * 2003-08-07 2005-02-10 Tia-Cheng Yu Surface emitting device
US7303322B2 (en) * 2003-12-23 2007-12-04 3M Innovative Properties Company Multiple lightguide backlight
US7223005B2 (en) * 2003-12-23 2007-05-29 Lamb David J Hybrid lightguide backlight
US7733443B2 (en) 2004-03-09 2010-06-08 Nitto Denko Corporation LCD comprising backlight and reflective polarizer on front panel
US7456915B2 (en) * 2004-03-26 2008-11-25 Nitto Denko Corporation Liquid crystal display panel with broadband interference polarizers
TW200532290A (en) * 2004-03-30 2005-10-01 Optimax Tech Corp Manufacturing method of optical thin film
US8033706B1 (en) * 2004-09-09 2011-10-11 Fusion Optix, Inc. Lightguide comprising a low refractive index region
GB0427607D0 (en) * 2004-12-16 2005-01-19 Microsharp Corp Ltd Structured optical film
US7474286B2 (en) * 2005-04-01 2009-01-06 Spudnik, Inc. Laser displays using UV-excitable phosphors emitting visible colored light
US7791561B2 (en) 2005-04-01 2010-09-07 Prysm, Inc. Display systems having screens with optical fluorescent materials
US7733310B2 (en) * 2005-04-01 2010-06-08 Prysm, Inc. Display screens having optical fluorescent materials
US20060221022A1 (en) * 2005-04-01 2006-10-05 Roger Hajjar Laser vector scanner systems with display screens having optical fluorescent materials
US8000005B2 (en) 2006-03-31 2011-08-16 Prysm, Inc. Multilayered fluorescent screens for scanning beam display systems
US7994702B2 (en) 2005-04-27 2011-08-09 Prysm, Inc. Scanning beams displays based on light-emitting screens having phosphors
US8089425B2 (en) * 2006-03-03 2012-01-03 Prysm, Inc. Optical designs for scanning beam display systems using fluorescent screens
US7220036B2 (en) * 2005-05-20 2007-05-22 3M Innovative Properties Company Thin direct-lit backlight for LCD display
US7591094B2 (en) * 2005-05-31 2009-09-22 The University Of British Columbia Perforated multi-layer optical film luminaire
US7537374B2 (en) * 2005-08-27 2009-05-26 3M Innovative Properties Company Edge-lit backlight having light recycling cavity with concave transflector
WO2007027759A2 (en) * 2005-09-02 2007-03-08 Colorlink, Inc. Polarization beam splitter and combiner
US7884816B2 (en) * 2006-02-15 2011-02-08 Prysm, Inc. Correcting pyramidal error of polygon scanner in scanning beam display systems
US8451195B2 (en) * 2006-02-15 2013-05-28 Prysm, Inc. Servo-assisted scanning beam display systems using fluorescent screens
US20080037127A1 (en) * 2006-03-31 2008-02-14 3M Innovative Properties Company Wide angle mirror system
CN101416077B (en) * 2006-03-31 2011-08-24 东洋纺织株式会社 Light diffusion film
US7660509B2 (en) 2006-05-24 2010-02-09 3M Innovative Properties Company Backlight asymmetric light input wedge
US7317182B2 (en) * 2006-05-24 2008-01-08 3M Innovative Properties Company Backlight wedge with encapsulated light source
US7740387B2 (en) * 2006-05-24 2010-06-22 3M Innovative Properties Company Backlight wedge with side mounted light source
KR101201782B1 (en) * 2006-08-25 2012-11-15 삼성디스플레이 주식회사 Light emitting device and display apparatus using the same
US20080068295A1 (en) * 2006-09-19 2008-03-20 Hajjar Roger A Compensation for Spatial Variation in Displayed Image in Scanning Beam Display Systems Using Light-Emitting Screens
TW200815787A (en) * 2006-09-20 2008-04-01 Ind Tech Res Inst Polarization light source
TW200827872A (en) * 2006-10-26 2008-07-01 Koninkl Philips Electronics Nv Illumination system and display device
KR100809849B1 (en) * 2006-11-10 2008-03-04 엘지.필립스 엘시디 주식회사 Optical film and method for fabricating the same, liquid crystal display device having the same
US8013506B2 (en) * 2006-12-12 2011-09-06 Prysm, Inc. Organic compounds for adjusting phosphor chromaticity
GB2460802B (en) 2007-03-20 2012-09-05 Prysm Inc Delivering and displaying advertisment or other application data to display systems
US8169454B1 (en) 2007-04-06 2012-05-01 Prysm, Inc. Patterning a surface using pre-objective and post-objective raster scanning systems
US7697183B2 (en) * 2007-04-06 2010-04-13 Prysm, Inc. Post-objective scanning beam systems
WO2008144673A2 (en) 2007-05-17 2008-11-27 Spudnik, Inc. Multilayered screens with light-emitting stripes for scanning beam display systems
JP2010528432A (en) * 2007-05-20 2010-08-19 スリーエム イノベイティブ プロパティズ カンパニー White light backlight using color LED light source efficiently and similar products
EP2162770B1 (en) 2007-06-14 2012-08-08 Avery Dennison Corporation Illuminated graphical and information display
US8556430B2 (en) 2007-06-27 2013-10-15 Prysm, Inc. Servo feedback control based on designated scanning servo beam in scanning beam display systems with light-emitting screens
US7878657B2 (en) * 2007-06-27 2011-02-01 Prysm, Inc. Servo feedback control based on invisible scanning servo beam in scanning beam display systems with light-emitting screens
JP2009128647A (en) * 2007-11-26 2009-06-11 Hitachi Displays Ltd Liquid crystal display device
EP2297607B1 (en) * 2008-06-04 2014-04-23 3M Innovative Properties Company Hollow backlight with tilted light source
US7869112B2 (en) * 2008-07-25 2011-01-11 Prysm, Inc. Beam scanning based on two-dimensional polygon scanner for display and other applications
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KR20110080170A (en) 2008-10-27 2011-07-12 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Semispecular hollow backlight with gradient extraction
US20100142222A1 (en) * 2008-12-04 2010-06-10 World Properties, Inc. Light guide with refractive layer
US8152349B2 (en) * 2009-01-15 2012-04-10 Microsoft Corporation End reflector for a flat panel lens
SG174534A1 (en) * 2009-03-25 2011-10-28 Pixalux Innovations Pty Ltd Illumination panel
US10243510B2 (en) 2009-03-25 2019-03-26 Pixalux Innovations Pty Ltd Illumination panel
US9341887B2 (en) 2009-09-11 2016-05-17 Dolby Laboratories Licensing Corporation Displays with a backlight incorporating reflecting layer
US8804067B2 (en) * 2011-05-02 2014-08-12 Au Optronics Corporation Display device
TW201305487A (en) * 2011-07-13 2013-02-01 Rambus Inc Lighting assembly with controlled configurable light redirection
TWI596385B (en) * 2012-02-13 2017-08-21 東麗股份有限公司 Reflective film
US8809811B2 (en) 2012-09-13 2014-08-19 Prysm, Inc. Reduction of intensity ringing in fluorescent displays
US20140268879A1 (en) * 2013-03-14 2014-09-18 Panasonic Corporation Transparent waveguide diffuser for lighting and methods of manufacturing transparent waveguide diffuser
KR102459467B1 (en) * 2015-07-17 2022-10-27 삼성디스플레이 주식회사 Display device
WO2018160866A1 (en) 2017-03-02 2018-09-07 3M Innovative Properties Company Dynamic reflected color film with low optical caliper sensitivity
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CN110389468A (en) * 2018-04-17 2019-10-29 宸盛光电有限公司 Backlight module and its display device
CN112041735B (en) * 2018-05-02 2023-09-01 3M创新有限公司 multilayer reflector

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0167721A1 (en) * 1984-07-02 1986-01-15 Mitsubishi Rayon Co., Ltd. Light diffuser
EP0490279A2 (en) * 1990-12-08 1992-06-17 Minnesota Mining And Manufacturing Company Light box
EP0500089A1 (en) * 1991-02-21 1992-08-26 Tosoh Corporation Back lighting device
EP0504910A2 (en) * 1991-03-22 1992-09-23 Tosoh Corporation Backlighting device
EP0506116A2 (en) * 1991-03-29 1992-09-30 Nissha Printing Co., Ltd. Surface light source device
WO1994010589A1 (en) * 1992-10-29 1994-05-11 The Dow Chemical Company Formable reflective multilayer body
WO1995017692A1 (en) * 1993-12-21 1995-06-29 Minnesota Mining And Manufacturing Company Reflective polarizer with brightness enhancement
WO1995017691A1 (en) * 1993-12-21 1995-06-29 Minnesota Mining And Manufacturing Company Optical polarizer
WO1995017303A1 (en) * 1993-12-21 1995-06-29 Minnesota Mining And Manufacturing Company Multilayered optical film
WO1996019347A2 (en) * 1994-12-20 1996-06-27 Minnesota Mining And Manufacturing Company Multilayered optical film

Family Cites Families (112)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US364612A (en) * 1887-06-07 Broiler
US3124639A (en) 1964-03-10 figure
US1610423A (en) 1921-01-22 1926-12-14 Aloysius J Cawley Daylight-projecting system
US2492809A (en) 1938-11-16 1949-12-27 Alvin M Marks Unitary multiply polarizer
US3213753A (en) 1962-01-24 1965-10-26 Polaroid Corp Multilayer lenticular light polarizing device
US3528723A (en) 1967-08-30 1970-09-15 Polaroid Corp Light polarizing device
US3759647A (en) 1969-04-10 1973-09-18 Turner Alfrey Us Apparatus for the preparation of multilayer plastic articles
US3801429A (en) 1969-06-06 1974-04-02 Dow Chemical Co Multilayer plastic articles
US3647612A (en) 1969-06-06 1972-03-07 Dow Chemical Co Multilayer plastic articles
US3610729A (en) 1969-06-18 1971-10-05 Polaroid Corp Multilayered light polarizer
US3860036A (en) 1970-11-02 1975-01-14 Dow Chemical Co Variable geometry feed block for multilayer extrusion
US3711176A (en) 1971-01-14 1973-01-16 Dow Chemical Co Highly reflective thermoplastic bodies for infrared, visible or ultraviolet light
BE789478A (en) 1971-10-01 1973-03-29 Dow Chemical Co METHOD AND DEVICE FOR EXTRUDING PLASTICS IN MULTI-LAYER SHEETS
US4025688A (en) 1974-08-01 1977-05-24 Polaroid Corporation Polarizer lamination
US4094947A (en) 1976-09-03 1978-06-13 The Dow Chemical Company Multilayer coextrusion process for producing selective reflectivity
DE2915847C2 (en) 1978-09-29 1986-01-16 Nitto Electric Industrial Co., Ltd., Ibaraki, Osaka Electro-optically activated display
US4310584A (en) 1979-12-26 1982-01-12 The Mearl Corporation Multilayer light-reflecting film
US4315258A (en) 1980-02-15 1982-02-09 The United States Of America As Represented By The Secretary Of The Navy Transmissive and reflective liquid crystal display
DE3129162C2 (en) 1980-07-31 1983-10-20 Nitto Electric Industrial Co., Ltd., Ibaraki, Osaka Polarizing film
US4525413A (en) 1981-03-02 1985-06-25 Polaroid Corporation Optical device including birefringent polymer
US4521588A (en) 1981-03-02 1985-06-04 Polaroid Corporation Optical device including birefringent polyhydrazide polymer
US4446305A (en) 1981-03-02 1984-05-01 Polaroid Corporation Optical device including birefringent polymer
US4520189A (en) 1981-03-02 1985-05-28 Polaroid Corporation Optical device including birefringent aromatic amino carboxylic acid polymer
US4456336A (en) 1981-10-06 1984-06-26 Minnesota Mining And Manufacturing Company High brightness internal reflector for liquid crystal displays and its method of fabrication
US4540623A (en) 1983-10-14 1985-09-10 The Dow Chemical Company Coextruded multi-layered articles
US4678285A (en) 1984-01-13 1987-07-07 Ricoh Company, Ltd. Liquid crystal color display device
JPS6155684A (en) 1984-08-27 1986-03-20 三菱レイヨン株式会社 Light diffuser
US4714983A (en) 1985-06-10 1987-12-22 Motorola, Inc. Uniform emission backlight
JPS62195601A (en) 1985-09-20 1987-08-28 Nissho Giken Kk Optical direction converter
US4720426A (en) 1986-06-30 1988-01-19 General Electric Company Reflective coating for solid-state scintillator bar
GB2196100B (en) 1986-10-01 1990-07-04 Mitsubishi Rayon Co Light diffusing device
US5255029A (en) 1987-04-30 1993-10-19 Nview Corporation Liquid crystal display for projection systems
US4984855A (en) 1987-11-10 1991-01-15 Anritsu Corporation Ultra-black film and method of manufacturing the same
US4798448A (en) 1988-02-16 1989-01-17 General Electric Company High efficiency illumination system for display devices
US5211878A (en) 1988-03-10 1993-05-18 Merck Patent Gesellschaft Mit Beschrankter Haftung Difluorobenzonitrile derivatives
US4952023A (en) 1988-03-18 1990-08-28 Minnesota Mining And Manufacturing Company Internally illuminated retroreflective sign
JP2862571B2 (en) 1988-07-28 1999-03-03 株式会社東芝 Transmissive liquid crystal display
US4917465A (en) 1989-03-28 1990-04-17 In Focus Systems, Inc. Color display system
US4937134A (en) 1989-04-17 1990-06-26 The Dow Chemical Company Elastomeric optical interference films
US5122905A (en) 1989-06-20 1992-06-16 The Dow Chemical Company Relective polymeric body
US5486949A (en) 1989-06-20 1996-01-23 The Dow Chemical Company Birefringent interference polarizer
US5235443A (en) 1989-07-10 1993-08-10 Hoffmann-La Roche Inc. Polarizer device
US5089318A (en) 1989-10-31 1992-02-18 The Mearl Corporation Iridescent film with thermoplastic elastomeric components
US5319478A (en) 1989-11-01 1994-06-07 Hoffmann-La Roche Inc. Light control systems with a circular polarizer and a twisted nematic liquid crystal having a minimum path difference of λ/2
US5149578A (en) 1989-12-26 1992-09-22 The Dow Chemical Company Multilayer film for tamper indication by use of optical interference reflection
US5202074A (en) 1989-12-26 1993-04-13 The Dow Chemical Company Method for producing injection molded multilayer articles
US5278694A (en) 1990-01-11 1994-01-11 The Dow Chemical Company Optically dissimilar composition for polymeric reflective bodies
US5095210A (en) 1990-04-06 1992-03-10 The Dow Chemical Company Multilayer film indicator for determining the integrity or authenticity of an item and process for using same
NL9000808A (en) 1990-04-06 1991-11-01 Koninkl Philips Electronics Nv LIQUID CRYSTALLINE MATERIAL AND IMAGE DISPLAY CELL CONTAINING THIS MATERIAL.
US5157526A (en) 1990-07-06 1992-10-20 Hitachi, Ltd. Unabsorbing type polarizer, method for manufacturing the same, polarized light source using the same, and apparatus for liquid crystal display using the same
US5103337A (en) 1990-07-24 1992-04-07 The Dow Chemical Company Infrared reflective optical interference film
US5126880A (en) 1990-12-18 1992-06-30 The Dow Chemical Company Polymeric reflective bodies with multiple layer types
US5094793A (en) 1990-12-21 1992-03-10 The Dow Chemical Company Methods and apparatus for generating interfacial surfaces
US5094788A (en) 1990-12-21 1992-03-10 The Dow Chemical Company Interfacial surface generator
US5217794A (en) 1991-01-22 1993-06-08 The Dow Chemical Company Lamellar polymeric body
DE69220870T2 (en) 1991-08-22 1998-02-05 Tosoh Corp Rear lighting device
US5408387A (en) 1991-11-30 1995-04-18 Meitaku System Co., Ltd. Edge light panel and its production
EP0627991A1 (en) 1992-02-25 1994-12-14 The Dow Chemical Company All-polymeric ultraviolet reflecting film
US5234729A (en) 1992-02-27 1993-08-10 The Dow Chemical Company Multilayer polymeric reflective bodies for decorative and security applications
US5528720A (en) 1992-03-23 1996-06-18 Minnesota Mining And Manufacturing Co. Tapered multilayer luminaire devices
US5303322A (en) 1992-03-23 1994-04-12 Nioptics Corporation Tapered multilayer luminaire devices
US5294657A (en) 1992-05-15 1994-03-15 Melendy Peter S Adhesive composition with decorative glitter
US5422756A (en) 1992-05-18 1995-06-06 Minnesota Mining And Manufacturing Company Backlighting system using a retroreflecting polarizer
US5233465A (en) 1992-05-27 1993-08-03 The Dow Chemical Company Visibly transparent infrared reflecting film with color masking
DE4326521B4 (en) 1992-08-10 2005-12-22 Bridgestone Corp. Light scattering material and method for its production
JPH0695112A (en) 1992-09-16 1994-04-08 Hitachi Ltd Prism plate and information display device formed by using this plate
US5269995A (en) 1992-10-02 1993-12-14 The Dow Chemical Company Coextrusion of multilayer articles using protective boundary layers and apparatus therefor
US5339198A (en) 1992-10-16 1994-08-16 The Dow Chemical Company All-polymeric cold mirror
US5333072A (en) 1992-12-31 1994-07-26 Minnesota Mining And Manufacturing Company Reflective liquid crystal display overhead projection system using a reflective linear polarizer and a fresnel lens
US5325218A (en) 1992-12-31 1994-06-28 Minnesota Mining And Manufacturing Company Cholesteric polarizer for liquid crystal display and overhead projector
DE69409977T2 (en) 1993-01-11 1998-10-22 Koninkl Philips Electronics Nv Lighting system and such a comprehensive display device
TW289095B (en) 1993-01-11 1996-10-21
US5598280A (en) * 1993-03-23 1997-01-28 Dai Nippon Printing Co., Ltd. Film lens and a surface light source using the same
US5360659A (en) 1993-05-24 1994-11-01 The Dow Chemical Company Two component infrared reflecting film
US5389324A (en) 1993-06-07 1995-02-14 The Dow Chemical Company Layer thickness gradient control in multilayer polymeric bodies
US5486935A (en) 1993-06-29 1996-01-23 Kaiser Aerospace And Electronics Corporation High efficiency chiral nematic liquid crystal rear polarizer for liquid crystal displays having a notch polarization bandwidth of 100 nm to 250 nm
US5381309A (en) 1993-09-30 1995-01-10 Honeywell Inc. Backlit display with enhanced viewing properties
US6025897A (en) * 1993-12-21 2000-02-15 3M Innovative Properties Co. Display with reflective polarizer and randomizing cavity
US5424119A (en) 1994-02-04 1995-06-13 Flex Products, Inc. Polymeric sheet having oriented multilayer interference thin film flakes therein, product using the same and method
US5629055A (en) 1994-02-14 1997-05-13 Pulp And Paper Research Institute Of Canada Solidified liquid crystals of cellulose with optically variable properties
US5481445A (en) 1994-02-15 1996-01-02 Lexalite International Corp. Transflection reflector having controlled reflected and transmitted light distribution
US6101032A (en) * 1994-04-06 2000-08-08 3M Innovative Properties Company Light fixture having a multilayer polymeric film
US5451449A (en) 1994-05-11 1995-09-19 The Mearl Corporation Colored iridescent film
JP4034365B2 (en) 1995-03-09 2008-01-16 大日本印刷株式会社 Ultrafine particle-containing antireflection film, polarizing plate and liquid crystal display device
US5751388A (en) 1995-04-07 1998-05-12 Honeywell Inc. High efficiency polarized display
US6088067A (en) * 1995-06-26 2000-07-11 3M Innovative Properties Company Liquid crystal display projection system using multilayer optical film polarizers
EP0855043B1 (en) 1995-06-26 2003-02-05 Minnesota Mining And Manufacturing Company Diffusely reflecting multilayer polarizers and mirrors
US5686979A (en) 1995-06-26 1997-11-11 Minnesota Mining And Manufacturing Company Optical panel capable of switching between reflective and transmissive states
US6080467A (en) * 1995-06-26 2000-06-27 3M Innovative Properties Company High efficiency optical devices
US5699188A (en) * 1995-06-26 1997-12-16 Minnesota Mining And Manufacturing Co. Metal-coated multilayer mirror
KR100468560B1 (en) * 1995-06-26 2005-08-04 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 Multilayer polymer film with additional coatings or layers
US5767935A (en) 1995-08-31 1998-06-16 Sumitomo Chemical Company, Limited Light control sheet and liquid crystal display device comprising the same
US5867316A (en) 1996-02-29 1999-02-02 Minnesota Mining And Manufacturing Company Multilayer film having a continuous and disperse phase
US5783120A (en) 1996-02-29 1998-07-21 Minnesota Mining And Manufacturing Company Method for making an optical film
US5825543A (en) * 1996-02-29 1998-10-20 Minnesota Mining And Manufacturing Company Diffusely reflecting polarizing element including a first birefringent phase and a second phase
US5661839A (en) * 1996-03-22 1997-08-26 The University Of British Columbia Light guide employing multilayer optical film
US5808794A (en) 1996-07-31 1998-09-15 Weber; Michael F. Reflective polarizers having extended red band edge for controlled off axis color
US5940149A (en) 1997-12-11 1999-08-17 Minnesota Mining And Manufacturing Company Planar polarizer for LCD projectors
US6049419A (en) * 1998-01-13 2000-04-11 3M Innovative Properties Co Multilayer infrared reflecting optical body
US6179948B1 (en) * 1998-01-13 2001-01-30 3M Innovative Properties Company Optical film and process for manufacture thereof
US6012820A (en) * 1998-01-13 2000-01-11 3M Innovative Properties Compnay Lighted hand-holdable novelty article
US6082876A (en) * 1998-01-13 2000-07-04 3M Innovative Properties Company Hand-holdable toy light tube with color changing film
US6207260B1 (en) * 1998-01-13 2001-03-27 3M Innovative Properties Company Multicomponent optical body
US6111697A (en) * 1998-01-13 2000-08-29 3M Innovative Properties Company Optical device with a dichroic polarizer and a multilayer optical film
US6045894A (en) * 1998-01-13 2000-04-04 3M Innovative Properties Company Clear to colored security film
JP4274696B2 (en) * 1998-01-13 2009-06-10 スリーエム カンパニー Modified copolyester and improved multilayer reflective film
US6053795A (en) * 1998-01-13 2000-04-25 3M Innovative Properties Company Toy having image mode and changed image mode
US6531230B1 (en) * 1998-01-13 2003-03-11 3M Innovative Properties Company Color shifting film
US6569515B2 (en) * 1998-01-13 2003-05-27 3M Innovative Properties Company Multilayered polymer films with recyclable or recycled layers
US6096247A (en) * 1998-07-31 2000-08-01 3M Innovative Properties Company Embossed optical polymer films
US6256146B1 (en) * 1998-07-31 2001-07-03 3M Innovative Properties Post-forming continuous/disperse phase optical bodies
US6208466B1 (en) * 1998-11-25 2001-03-27 3M Innovative Properties Company Multilayer reflector with selective transmission

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0167721A1 (en) * 1984-07-02 1986-01-15 Mitsubishi Rayon Co., Ltd. Light diffuser
EP0490279A2 (en) * 1990-12-08 1992-06-17 Minnesota Mining And Manufacturing Company Light box
EP0500089A1 (en) * 1991-02-21 1992-08-26 Tosoh Corporation Back lighting device
EP0504910A2 (en) * 1991-03-22 1992-09-23 Tosoh Corporation Backlighting device
EP0506116A2 (en) * 1991-03-29 1992-09-30 Nissha Printing Co., Ltd. Surface light source device
WO1994010589A1 (en) * 1992-10-29 1994-05-11 The Dow Chemical Company Formable reflective multilayer body
WO1995017692A1 (en) * 1993-12-21 1995-06-29 Minnesota Mining And Manufacturing Company Reflective polarizer with brightness enhancement
WO1995017691A1 (en) * 1993-12-21 1995-06-29 Minnesota Mining And Manufacturing Company Optical polarizer
WO1995017303A1 (en) * 1993-12-21 1995-06-29 Minnesota Mining And Manufacturing Company Multilayered optical film
WO1996019347A2 (en) * 1994-12-20 1996-06-27 Minnesota Mining And Manufacturing Company Multilayered optical film

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* Cited by examiner, † Cited by third party
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US6531230B1 (en) 1998-01-13 2003-03-11 3M Innovative Properties Company Color shifting film
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US6905220B2 (en) 2005-06-14
DE69629471D1 (en) 2003-09-18
AU716525B2 (en) 2000-02-24
EP0832392A1 (en) 1998-04-01
EP0832392B1 (en) 2003-08-13
AU5875096A (en) 1997-01-30
US20020141194A1 (en) 2002-10-03
DE69629471T2 (en) 2004-06-09

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