WO1995021203A1 - Dual donor catalyst system for the polymerization of olefins - Google Patents
Dual donor catalyst system for the polymerization of olefins Download PDFInfo
- Publication number
- WO1995021203A1 WO1995021203A1 PCT/US1995/001499 US9501499W WO9521203A1 WO 1995021203 A1 WO1995021203 A1 WO 1995021203A1 US 9501499 W US9501499 W US 9501499W WO 9521203 A1 WO9521203 A1 WO 9521203A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- donor
- dcpms
- teos
- catalyst
- catalyst system
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95910185A EP0743960B1 (en) | 1994-02-04 | 1995-02-06 | Dual donor catalyst system for the polymerization of olefins |
JP07520806A JP3095177B2 (en) | 1994-02-04 | 1995-02-06 | Dual donor catalyst system for olefin polymerization. |
DE69502480T DE69502480T2 (en) | 1994-02-04 | 1995-02-06 | TWO-DONOCATALYST SYSTEM FOR OLEFIN POLYMERIZATION |
NO963236A NO963236L (en) | 1994-02-04 | 1996-08-02 | Double donor catalyst system for polymerization of olefins |
MXPA/A/1996/003216A MXPA96003216A (en) | 1994-02-04 | 1996-08-02 | Dual donor catalyst system for olefi polymerization |
FI963081A FI963081A (en) | 1994-02-04 | 1996-08-05 | Catalyst system with two donors for polymerization of olefins |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US19221794A | 1994-02-04 | 1994-02-04 | |
US08/192,217 | 1994-02-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995021203A1 true WO1995021203A1 (en) | 1995-08-10 |
Family
ID=22708732
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1995/001499 WO1995021203A1 (en) | 1994-02-04 | 1995-02-06 | Dual donor catalyst system for the polymerization of olefins |
Country Status (11)
Country | Link |
---|---|
US (1) | US6111039A (en) |
EP (1) | EP0743960B1 (en) |
JP (1) | JP3095177B2 (en) |
CN (1) | CN1085219C (en) |
AT (1) | ATE166074T1 (en) |
CA (1) | CA2182717A1 (en) |
DE (1) | DE69502480T2 (en) |
ES (1) | ES2119401T3 (en) |
FI (1) | FI963081A (en) |
NO (1) | NO963236L (en) |
WO (1) | WO1995021203A1 (en) |
Cited By (18)
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---|---|---|---|---|
EP0704462A1 (en) * | 1994-04-11 | 1996-04-03 | Mitsui Petrochemical Industries, Ltd. | Process for producing propylene polymer composition, and propylene polymer composition |
EP0748820A1 (en) * | 1995-06-07 | 1996-12-18 | Sumitomo Chemical Company Limited | Alpha-olefin polymerization catalyst and process for producing alpha-olefin polymer |
WO1997043321A1 (en) * | 1996-05-15 | 1997-11-20 | Borealis A/S | Stereospecific catalyst system for olefin polymerization and multistaged polymerization processes using this catalyst system |
WO1999020663A2 (en) * | 1997-10-17 | 1999-04-29 | Exxon Chemical Patents Inc. | High impact, flexural moduli polymeric materials formed using sequential donors |
WO1999058585A1 (en) * | 1998-05-14 | 1999-11-18 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
US6087459A (en) * | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
US6111039A (en) * | 1994-02-04 | 2000-08-29 | Exxon Chemical Patents, Inc. | Dual donor catalyst system for the polymerization of olefin |
US6566294B2 (en) | 2000-12-21 | 2003-05-20 | Exxonmobil Chemical Patents Inc. | Multi-donor catalyst system for the polymerization of olefins |
US6686433B1 (en) | 1994-02-04 | 2004-02-03 | Exxonmobil Chemical Patents Inc. | Dual donor catalyst system for the polymerization of olefins |
WO2003106512A3 (en) * | 2002-06-14 | 2004-04-08 | Union Carbide Chem Plastic | Catalyst composition and polymerization process using mixtures of electron donors |
WO2005030815A1 (en) | 2003-09-23 | 2005-04-07 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
WO2005035596A1 (en) | 2003-09-23 | 2005-04-21 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
WO2005035594A1 (en) | 2003-09-23 | 2005-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process |
EP1544218A1 (en) * | 2003-12-19 | 2005-06-22 | Borealis Technology Oy | Process for producing olefin polymers |
US7381779B2 (en) | 2003-09-23 | 2008-06-03 | Dow Global Technologies Inc | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
US7521512B2 (en) | 2003-06-24 | 2009-04-21 | Union Carbide Chemicals & Plastics Technology Llc | Catalyst composition and polymerization process using mixture of silane electron donors |
US7884164B2 (en) | 2007-01-30 | 2011-02-08 | Lg Chem, Ltd. | Catalyst system for olefin polymerization comprising trioxasilocane and method for olefin polymerization using the same |
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CN1137156C (en) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | Catalyst for olefine polymerization and its formula and application |
US6399707B1 (en) | 2000-09-29 | 2002-06-04 | Exxonmobil Chemical Patents Inc. | Impact copolymer and plastomer blend |
KR100421553B1 (en) * | 2000-12-27 | 2004-03-09 | 삼성아토피나주식회사 | A polymerization method of alpha-olefins |
EP1461368B1 (en) * | 2002-01-03 | 2006-08-16 | Innovene USA LLC | Gas phase olefin polymerizations using dual donor ziegler-natta catalyst systems |
US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
US7652092B2 (en) * | 2002-08-12 | 2010-01-26 | Exxonmobil Chemical Patents Inc. | Articles from plasticized thermoplastic polyolefin compositions |
US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
EP1530611B1 (en) * | 2002-08-12 | 2013-12-04 | ExxonMobil Chemical Patents Inc. | Plasticized polyolefin compositions |
US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
US7622523B2 (en) * | 2002-08-12 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
US7652094B2 (en) | 2002-08-12 | 2010-01-26 | Exxonmobil Chemical Patents Inc. | Plasticized polyolefin compositions |
US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
EP1670833A1 (en) * | 2003-09-23 | 2006-06-21 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition with mixed sca and propylene polymerization process |
US20050234172A1 (en) * | 2004-04-19 | 2005-10-20 | Fina Technology, Inc. | Random copolymer-impact copolymer blend |
US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
RU2008103837A (en) * | 2005-07-01 | 2009-08-10 | Базелль Полиолефин Италия С.Р.Л. (It) | PROPYLENE POLYMERS WITH A WIDE MOLECULAR MASS DISTRIBUTION |
JP5438966B2 (en) | 2005-07-15 | 2014-03-12 | エクソンモービル・ケミカル・パテンツ・インク | Elastomer composition |
US7977435B2 (en) * | 2006-07-12 | 2011-07-12 | Lin Chon-Yie | Propylene polymer compositions and processes for making the same |
RU2464282C2 (en) * | 2007-03-06 | 2012-10-20 | ИНЕОС ЮЭсЭй ЭлЭлСи | Olefin polymerisation method |
CN101125898A (en) | 2007-07-19 | 2008-02-20 | 中国科学院长春应用化学研究所 | Catalyst used for synthesizing polypropylene with wide molecular weight distribution |
EP2315789B1 (en) * | 2008-08-21 | 2015-09-02 | W.R. Grace & CO. - CONN. | Catalyst composition with mixed selectivity control agent and polymerisation method using it |
US7851554B2 (en) | 2008-10-27 | 2010-12-14 | Exxonmobil Chemical Patents Inc. | Propylene impact copolymers with balanced impact strength and stiffness |
CN101735351B (en) * | 2008-11-07 | 2011-10-05 | 中国石油天然气股份有限公司 | Method for preparing high-fluidity wide-distribution polypropylene and product thereof |
US9068030B2 (en) | 2010-01-22 | 2015-06-30 | China Petroleum & Chemical Corporation | Propylene homopolymer having high melt strength and preparation method thereof |
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JP5640402B2 (en) * | 2010-03-08 | 2014-12-17 | 住友化学株式会社 | α-Olefin polymerization catalyst |
EP2588504B1 (en) * | 2010-06-10 | 2015-02-18 | Ineos Technologies USA LLC | Controlling h2 distribution in a horizontal stirred bed reactor |
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US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
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US10647795B2 (en) | 2014-02-07 | 2020-05-12 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US9428598B2 (en) | 2014-02-07 | 2016-08-30 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
CN108174605B (en) * | 2015-08-07 | 2021-03-26 | Sabic环球技术有限责任公司 | Process for the polymerization of olefins |
US10696756B2 (en) | 2015-08-07 | 2020-06-30 | Sabic Global Technologies B.V. | Process for the polymerization of olefins |
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KR20210004977A (en) * | 2018-04-20 | 2021-01-13 | 도호 티타늄 가부시키가이샤 | Olefin polymer and method for producing olefin polymer |
CN114426596A (en) * | 2020-10-15 | 2022-05-03 | 中国石油化工股份有限公司 | Catalyst for olefin polymerization, application thereof, olefin polymerization method and polymer |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0349772A2 (en) * | 1988-06-09 | 1990-01-10 | Hoechst Aktiengesellschaft | Process for preparing a polypropylene |
EP0385765A2 (en) * | 1989-03-02 | 1990-09-05 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins and catalyst for polymerizing olefins |
EP0601496A1 (en) * | 1992-12-04 | 1994-06-15 | Mitsui Petrochemical Industries, Ltd. | Process for the preparation of olefin polymer |
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-
1995
- 1995-02-06 EP EP95910185A patent/EP0743960B1/en not_active Expired - Lifetime
- 1995-02-06 CN CN95191937A patent/CN1085219C/en not_active Expired - Lifetime
- 1995-02-06 AT AT95910185T patent/ATE166074T1/en not_active IP Right Cessation
- 1995-02-06 DE DE69502480T patent/DE69502480T2/en not_active Expired - Fee Related
- 1995-02-06 WO PCT/US1995/001499 patent/WO1995021203A1/en active IP Right Grant
- 1995-02-06 ES ES95910185T patent/ES2119401T3/en not_active Expired - Lifetime
- 1995-02-06 CA CA002182717A patent/CA2182717A1/en not_active Abandoned
- 1995-02-06 JP JP07520806A patent/JP3095177B2/en not_active Expired - Fee Related
-
1996
- 1996-08-02 NO NO963236A patent/NO963236L/en unknown
- 1996-08-05 FI FI963081A patent/FI963081A/en unknown
- 1996-12-19 US US08/770,618 patent/US6111039A/en not_active Expired - Lifetime
Patent Citations (3)
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EP0349772A2 (en) * | 1988-06-09 | 1990-01-10 | Hoechst Aktiengesellschaft | Process for preparing a polypropylene |
EP0385765A2 (en) * | 1989-03-02 | 1990-09-05 | Mitsui Petrochemical Industries, Ltd. | Process for polymerizing olefins and catalyst for polymerizing olefins |
EP0601496A1 (en) * | 1992-12-04 | 1994-06-15 | Mitsui Petrochemical Industries, Ltd. | Process for the preparation of olefin polymer |
Cited By (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6111039A (en) * | 1994-02-04 | 2000-08-29 | Exxon Chemical Patents, Inc. | Dual donor catalyst system for the polymerization of olefin |
US6686433B1 (en) | 1994-02-04 | 2004-02-03 | Exxonmobil Chemical Patents Inc. | Dual donor catalyst system for the polymerization of olefins |
EP0704462A4 (en) * | 1994-04-11 | 1996-08-07 | Mitsui Petrochemical Ind | Process for producing propylene polymer composition, and propylene polymer composition |
US5854354A (en) * | 1994-04-11 | 1998-12-29 | Mitsui Petrochemical Industries, Ltd. | Process for preparing propylene polymer composition and propylene polymer composition |
EP0704462A1 (en) * | 1994-04-11 | 1996-04-03 | Mitsui Petrochemical Industries, Ltd. | Process for producing propylene polymer composition, and propylene polymer composition |
EP0748820A1 (en) * | 1995-06-07 | 1996-12-18 | Sumitomo Chemical Company Limited | Alpha-olefin polymerization catalyst and process for producing alpha-olefin polymer |
US6133189A (en) * | 1995-06-07 | 2000-10-17 | Sumitomo Chemical Company, Limited | α-olefin polymerization catalyst and process for producing α-olefin polymer |
WO1997043321A1 (en) * | 1996-05-15 | 1997-11-20 | Borealis A/S | Stereospecific catalyst system for olefin polymerization and multistaged polymerization processes using this catalyst system |
US6057407A (en) * | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
WO1999020663A3 (en) * | 1997-10-17 | 1999-09-02 | Exxon Chemical Patents Inc | High impact, flexural moduli polymeric materials formed using sequential donors |
WO1999020663A2 (en) * | 1997-10-17 | 1999-04-29 | Exxon Chemical Patents Inc. | High impact, flexural moduli polymeric materials formed using sequential donors |
US6087459A (en) * | 1998-05-14 | 2000-07-11 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
WO1999058585A1 (en) * | 1998-05-14 | 1999-11-18 | Exxon Chemical Patents Inc. | Polymeric materials formed using blends of electron donors |
US6566294B2 (en) | 2000-12-21 | 2003-05-20 | Exxonmobil Chemical Patents Inc. | Multi-donor catalyst system for the polymerization of olefins |
WO2003106512A3 (en) * | 2002-06-14 | 2004-04-08 | Union Carbide Chem Plastic | Catalyst composition and polymerization process using mixtures of electron donors |
US7141635B2 (en) | 2002-06-14 | 2006-11-28 | Union Carbide Chemicals And Plastics Tech | Catalyst composition and polymerization process using mixtures of selectivity control agents |
US7521512B2 (en) | 2003-06-24 | 2009-04-21 | Union Carbide Chemicals & Plastics Technology Llc | Catalyst composition and polymerization process using mixture of silane electron donors |
US7678868B2 (en) | 2003-09-23 | 2010-03-16 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
US7491670B2 (en) | 2003-09-23 | 2009-02-17 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
US7781363B2 (en) | 2003-09-23 | 2010-08-24 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
WO2005035594A1 (en) | 2003-09-23 | 2005-04-21 | Union Carbide Chemicals & Plastics Technology Corporation | Self-extiguishing catalyst compostion with monocarboxylic acid ester internal donor and propylene polymerization process |
US7381779B2 (en) | 2003-09-23 | 2008-06-03 | Dow Global Technologies Inc | Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process |
US7393806B2 (en) | 2003-09-23 | 2008-07-01 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
US7420021B2 (en) | 2003-09-23 | 2008-09-02 | Union Carbide Chemicals & Plastics Technology Llc | Self-extinguishing catalyst composition with monocarboxylic acid ester internal door and propylene polymerization process |
US7687426B2 (en) | 2003-09-23 | 2010-03-30 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
WO2005035596A1 (en) | 2003-09-23 | 2005-04-21 | Dow Global Technologies Inc. | Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process |
WO2005030815A1 (en) | 2003-09-23 | 2005-04-07 | Dow Global Technologies Inc. | Self limiting catalyst composition and propylene polymerization process |
US7531607B2 (en) | 2003-12-19 | 2009-05-12 | Borealis Technology Oy | Process for producing olefin polymers |
EP1544218A1 (en) * | 2003-12-19 | 2005-06-22 | Borealis Technology Oy | Process for producing olefin polymers |
WO2005058984A1 (en) * | 2003-12-19 | 2005-06-30 | Borealis Technology Oy | Process for producing olefin polymers |
US7884164B2 (en) | 2007-01-30 | 2011-02-08 | Lg Chem, Ltd. | Catalyst system for olefin polymerization comprising trioxasilocane and method for olefin polymerization using the same |
Also Published As
Publication number | Publication date |
---|---|
ES2119401T3 (en) | 1998-10-01 |
CN1156999A (en) | 1997-08-13 |
JP3095177B2 (en) | 2000-10-03 |
FI963081A (en) | 1996-10-03 |
DE69502480D1 (en) | 1998-06-18 |
NO963236L (en) | 1996-09-25 |
DE69502480T2 (en) | 1998-12-10 |
MX9603216A (en) | 1997-07-31 |
JPH09508657A (en) | 1997-09-02 |
NO963236D0 (en) | 1996-08-02 |
CN1085219C (en) | 2002-05-22 |
ATE166074T1 (en) | 1998-05-15 |
FI963081A0 (en) | 1996-08-05 |
EP0743960A1 (en) | 1996-11-27 |
CA2182717A1 (en) | 1995-08-10 |
EP0743960B1 (en) | 1998-05-13 |
US6111039A (en) | 2000-08-29 |
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