WO1989002363A1

WO1989002363A1 - Impact absorbing composites and their production

Info

Publication number: WO1989002363A1
Application number: PCT/US1988/003249
Authority: WO
Inventors: Byron A. Donzis
Original assignee: Donzis Byron A
Priority date: 1987-09-21
Filing date: 1988-09-20
Publication date: 1989-03-23
Also published as: CA1336316C; AU2522088A

Abstract

An improved composite for absorbing and dispersing impacting forces is disclosed. The composite (10) includes a flexible plastic enclosure (12, 14) defining an internal cavity (15). The flexible enclosure is generally impermeable to air and capable of having its internal pressure changed. The composite further includes a foam core (11) filling the cavity and retained within the cavity and adhered on substantially all of its external surface to the internal surface of the cavity. The cavity can be pressurized by valve (16) for higher impact absorbance. Methods for fabricating the composites are disclosed, as well. These methods include forming the outer enclosure by applying a solution/suspension of the prepolymer of controlled solids content to the core and also can include the step of preheating the core prior to coating it.

Description

IMPACT ABSORBING COMPOSITES AND THEIR PRODUCTION

Description

Technical Field

This invention relates to improved impact absorbing compressible composites. These composites which are described in the above-noted parent application can be shaped into smooth compound curves and find application wherever high efficiency impact absorption is called for such as in athletic wear, in seating systems, in vehicle interior padding materials and the like. More particularly, the present invention relates to improvements in the production of these composites.

Background Art

There is a well-recognized need for high performance materials for spreading or absorbing impacts. In recent years, athletes, athletic equipment anufactur- ers and sports medicine professionals have recognized the need for improved impact absorbing materials in athletic equipment. These materials find application as heel pads and foot sole pads in shoes to absorb the shock of foot strike and as cushioning points under football or hockey pads such as shoulder pads, thigh pads, hip pads and the like to name but a few typical applications. Similar needs may be found in seating systems and in vehicle interiors, to name but a few representative fields in which impact absorption is a major interest. One common approach to impact absorption in the past has involved using felts or blocks of a soft padding material. Padding materials known heretofore include cot¬ ton padding, horsehair padding, foam rubber, foamed plastics, sponge rubber and the like. In these designs, the inherent resilience of the padding material is employed to absorb and disperse the applied impact. These designs have the disadvantage that they often "bottom out" or fully compress on severe impacts of the type regularly encountered during use such as in athletic equipment or in vehicle interiors and thus provide minimal protection. When made thicker to avoid this problem, they become cumbersome and can interfere with the design of the article being padded, and in the case of athletic equip-r ment can interfere with the wearer's freedom and perform- anc .

Impact absorbers have also been proposed which employ fluid-filled bladders such as cushioning air sacks These devices rely upon the compressibility of the enclosed fluid to provide the desired shock-absorbing. In some embodiments of these devices, the fluid is fully enclosed and can not escape. In others, the fluid is gradually and controllably forced out of the bladder dur¬ ing the impact with the rate of release being selected to prevent exhaustion of the fluid during the impact event. While effective as shock-absorbers, these devices can have the failing of ballooning or otherwise expanding in one region when another region is being compressed. This can lead to discomfort or at minimum give an unnatural or unstable feel to the user. In the case of footwear, this problem can lead to an unstable foot plant with increased opportunity for injury. Another issue with this, type of pad has related to problems in forming shapes based on compound curve and to retaining structural integrity with the above-described ballooning. Representative patents in the field of shock- absorbing or impact absorbing devices include United States Patent No. 4,513,449, SHOCK ABSORBING ATHLETIC EQUIPMENT; United States Patent No. 4,370,754, VARIABLE PRESSURE PAD; United States Patent No. 4,453,271, PROTEC- TIVE GARMENT; United States Patent No. 4,217,705, SELF- CONTAINED FLUID PRESSURE FOOT SUPPORT DEVICE, all issued to Donzis, United States Patent No. 4,446,634 for FOOTWEAR HAVING IMPROVED SHOCK ABSORPTION; United States Patent No. 4,397,104 for INFLATABLE SOLE-SHOE; United States Patent No. 2,863,230 for CUSHIONED SOLE AND HEEL FOR SHOES;

United States Patent No. 4,229,889 for PRESSURIZED POROUS MATERIAL CUSHION SHOE BASE; United States Patent No. 4,637,716 for METHOD FOR MAKING ELASTOMERIC SHOE SOLES; United States Patent No. 4,635,384 for FOOTWEAR SOLE; United States Patent No. 4,610,099 for SHOCK-ABSORBING

SHOE CONSTRUCTION; and United States Patent No. 4,571,853 for SHOE INSERT.

It is an object of the present invention to provide an improved impact absorbing composite. It is desired that this composite provide superior shock-absorb¬ ing performance and also be capable of being formed into complex compound curve shapes, be durable and hygienic.

It is an additional object of this continuation- in-part application to provide and claim additional improved embodiments of this invention relating to the method for their production which fall within the general teachings of the parent .application. Disclosure of the Invention

An improved impact absorbing composite has now been found. This composite is capable of dispersing and absorbing impacting forces with high efficiency. The composite is characterized by a structure including a. flexible plastic wall (enclosure) defining an internal cavity. This flexible enclosure is made of a material that is generally impermeable to the gas such as air or a large molecule gas which it encloses and is capable of having its internal pressure changed. The internal cavity of the enclosure is filled with a foam core. This core is held in place by the cavity walls. Importantly, the core is intimately adhered (glued, bonded or the like) on substantially all of its external surfaces to the internal surface of the cavity. In preferred embodiments, the wall and the core are prestressed by one another. That is, the core presses out against the wall and the wall pushes in against the core. The intimate adherent contact between the foam core and the outer wall gives rise to an un- expected degree of product integrity and unexpectedly superior impact absorbing capabilities.

In some preferred embodiments, the composite has a valve or fitting communicating with the cavity so that the pressure within the cavity can be altered. Alternatively, the cavity can be pressurized by injecting fluid through the wall and sealing the injection orfice. This permits the composite to be adjusted to accommodate varying impacts. The invention can thus include in combination such a composite together with a device for pressurizing its cavity. In other preferred embodiments this fitting can be removable after pressurization has been completed or the pressurization can be effected by the use of diffusion pumping.

Also in preferred embodiments, the foam core is an open-celled foam or a reticulated foam so that the pressure within the core is uniform. Urethane polymers have been found to be excellent for forming the cavity and the foam and are preferred materials of construction.

In other aspects, the composites of the inven- tion can employ cores having a plurality of different foams arranged parallel or perpendicular to the impact direction. This permits differing densities and impact resistances to be present at different positions on the composite. The impact absorbers of this invention can be used in conjunction with other materials or layers includ¬ ing without limitation, cosmetic or hygienic overlayers, other shock-absorbing layers or the like.

In yet another aspect, this invention provides a variety of methods for fabricating these composites. All of these methods are characterized by creating an adherent bond between the foam core and the outer layer and by pressurizing the core to a value effective to provide ef¬ ficient impact absorption.

One such method involves shaping the wall surface to create a cavity, sizing and shaping the foam core so as to fully fill the cavity and preferably prestress the wall and core, adhering and enclosing the core within the cavity and adjusting the pressure within the cavity to a value effective to provide efficient impact absorption.

Another fabrication method involves shaping the wall surface to create a cavity, sizing and shaping the core so as to partially fill the cavity, placing the core within the cavity, forming an elastomeric foam and prefer- ably an open-celled or reticulated foam in situ within the cavity so as to fill the space between the preshaped foam and the cavity wall and to adhere the cavity wall to the core and preferably prestress the wall and core, and adjusting the pressure within the cavity to a value effec- tive to provide efficient impact absorption. Yet another fabrication method involves shaping the wall surface to create a cavity, forming a cavity- wall-adherent open-celled or reticulated foam core in situ within the cavity so as to fill the cavity and preferably prestress the wall and core, and adjusting the pressure within the cavity to a value effective to provide ef¬ ficient impact absorption.

A further fabrication method involves sizing and shaping the foam core, forming the outer wall in situ around and adherent to the foam core such as by shrinking a film a core-adherent material around the core or by ap¬ plying a layer of uncured wall material, such as a solu¬ tion of wall-forming polymer, around and adherent to the core and then curing the uncured wall material, thereby creating a cavity enclosing and preferably prestressing the core, and adjusting the pressure within the cavity to a value effective to provide efficient impact absorption. In a preferred embodiment of this process in which the wall is formed in situ around the core, the wall-forming polymer is employed as a viscous solution that is sprayed over the core with the number of coats of sprayed material being selected to yield an outer wall of appropriate thickness.

The present invention particularly involves two processing variants for forming the outer wall in situ. In one variant, the wall is formed by dipping a foam core in fluid uncured (prepolymer) wall material and thereafter curing the wall material. In this process it is essential that the wall forming phase be a very high solids content suspension. It has been found, that if this is done, unexpectedly, the core, especially in its preferred open cell form, does not adsorb (soak up) and become saturated with excess wall-forming material. Preferably the wall- forming material is from about 50 to about 85% solids, although at the high end of this reange the material may _ _

be too viscous to flow well. More preferably the wall- forming material is from about 50 to about 75% solids.

In the other variant for forming the outer wall in situ, it has been found that in cases where the wall- forming material is applied to the core, either by spraying or dipping, a better product results if the core is preheated to a temperature above ambient prior to application of the wall-forming material. This elevated temperature is preferably from about 80 F to about 250 F and more preferably from about 90 Fto about 150 F. This elevated temperature has the effect of minimizing adsorption of the liquid phase into the foam core.

The present shock-absorbing composites can be employed in a wide range of applications. One excellent application is as heel pads and/or sole pads for shoes, especially sport shoes, where they serve to absorb foot strike impact with high efficiency.

The composites of this invention are character¬ ized by being easily formed in compound curve forms, by being very light weight and by being hygienic. They are further characterized by being adjustable in pressure, and thus in impact cushioning capacity. This permits them to serve in a wide range of applications with widely variable impacts.

Brief Description of the Drawings

The present invention will be described herein with reference being made to the accompanying drawings. Where practical in the drawings, a common reference numeral is used for the same part when it appears in more than one Figure. In the drawings:

Figure 1 is an exploded perspective view of the components of an impact absorber of this' invention;

Figure 2 is an cut away cross-sectional view of a shock-absorber of this invention; — o —

Figure 3 is a partially schematic cross sectional view of an impact absorbing heel pad not embodying this invention. This heel pad has a wall defin¬ ing a pressure-tight cavity but does not have a foam core adhered to and filling its inner surface. This figure illustrates the flaw in this design that an impact can be absorbed but at the same time ballooning occurs;

Figure 4 is similar to Figure 3 but illustrates that with the present invention ballooning is prevented; Figure 5 is a perspective view of an alternative foam core for use in this invention. This core has a plurality of differing compression strength foams arranged parallel to the impact force;

Figure 6 is a cut away cross-sectional view of another alternative embodiment of the impact absorber of this invention in which the wall material defining the cavity is further shaped to provide a supportive column;

Figure 7 is another cross sectional view of the absorber shown in Figure 6 taken along line 7-7'; Figure 8 is an exploded perspective view of the components of the absorber of Figures 6 and 7;

Figure 9 is a perspective view of an alternative embodiment of the impact absorber of this invention. This embodiment employs a core which has a plurality of differ- ing compression strength foams arranged perpendicular to the impact force;

Figure 10 is a phantom top view of a core configuration for use with closed cell foam materials;

Figure 11 is a cross sectional view of the core shown in Figure 10 taken along line 11-11';

Figure 12 is a phantom top view of another core configuration for use with closed cell foam materials;

Figure 13 is a cross sectional view of the core shown in Figure 12 taken along line 13-13'; Figure 14 is a cut away cross sectional view of a shoe containing a shock-absorber of the present inven¬ tion and additionally having a pump for pressurizing the core of the absorber; Figure 15 is a cross sectional view of an auto¬ motive dash board incorporating an impact absorber of this invention;

Figures 16 and 17 are two views of an additional representative application for the shock-absorbers of this invention as a foot pad;

Figure 18 is a perspective view of a shoulder pad under pad application for the shock-absorbers of this invention;

Figures 19 and 20 are graphs illustrating the effectiveness of the impact absorbers of this invention and their adaption to various body weights and to various impacts;

Figure 21 is a partially cross-sectional view of a shock-absorber of this invention employing an alternative pressurization modality and an alternative wall-forming technique; and

Figures 22A and 22B are partially cross- sectional views of two stages of pressurization of a shock-absorber of this invention employing a diffusional pressurization modality.

Modes for Carrying Out the Invention

Referring to Figures 1 and 2 in more detail, these figures illustrate an impact absorber 10. Impact absorber 10 includes a foam core 11 and top and bottom wall sections 12 and 14 which when joined define a cavity 15. A layer of adhesive 16 is present between essentially all of the inner surface of cavity 15 and the outer surface of foam core 11. This layer is shown on core 11 but could as well be on the inside surface of the wall or on both the core and the wall as desired. When wall sec¬ tions 12 and 14 are joined, the cavity which they define is pressure tight. It is possible to equip the impact absorber with a valve or fitting such as valve 16. Valve 16 is a "Halkey-Roberts" type urethane valve which is shown in Figure 1 in its pre-assembly form. After in¬ corporation, the top end of valve 16 is cut off flush with the surface of the shock-absorber as shown in Figure 2. Any equivalent form of valve, pressure control aperture or other means to increase the pressure within the cavity can be used, if desired. This valve allows the pressure in the interior (cavity 15) of the impact absorber to be adjusted, as desired, by adding or removing fluid from the cavity. The outer wall of the impact absorber is formed of flexible plastic. The materials used to form the wall can be selected from the film-forming flexible plastics. Virtually any plastic can be used so long as it is resist¬ ant to bacterial attack, flexible and shapable into the forms and configurations desired. Useful film-forming plastics include poly(urethane)s both of the poly(ether) and the poly(ester) form, poly(ester)s such as poly(ethylene terphthalate) , flexible poly(vinyl)s, elastomeric poly(olefin)s such as poly(isoprene) , poly(isobutylene) , and neoprene, low density poly(ethylene)s and the like.

In the embodiment shown in Figures 1 and 2, the outer wall is preshaped into the desired configuration and then the foam core is adhered to it. In another embodiment, the outer wall can be formed around the foam core. One way to accomplish this is to use a liquid polymer precure solution or suspension which is applied to the outer surface of the core and then cured. It has been found that this method has advantages when the solution or suspension is sprayed onto the foam. Since the foam employed herein is preferably of open-cell construction, it has been found that the use of spraying allows a coherent outer film to be achieved without soaking the foam with excess solution or suspension. Another way to accomplish this is to use plastic sheet stock and laminate it to the core or shrink it around the core. In any of these alternative modes of construction, it is essential that there be a strong adherent bond between the wall and essentially the entire outer surface of the core. Of the plastics useful in forming the films, preference is given to the flexible poly(urethane)s because of their ready availability. These materials are available from J.P. Stevens Company and Deerfield Urethane,Inc. , to name but two regular suppliers. Representative useful plastic films include the Deerfield "Dureflex" poly(urethane) films. These materials can be preformed, as in Figures 1 and 2 or they can be used as stock goods. When a liquid is used to apply the outer wall, it is typically a solution of a prepolymer or resole resin. Vinyl films can be used in this application. A typical vinyl film is the vinyl adhesive sealant produced by W.R. Grace and marketed by Eclectic Products as Eclectic 6000 adhesive sealant. These materials are solvented in halocarbons such as perchloroethylene and the like. A preferred liquid coating is based on the polyurethanes. Again, the nonrigid urethane polymers are preferred. The solutions known in the art for forming flexible urethane films are very suitable for this ap¬ plication. Typical urethane polymer solutions include the reaction product of a diisocyanate such as toluene diisocyanate or hexamethylene diisocyanate with a polyol such as a poly(ether polyol). These reaction products are commonly produced in a mixed solvent system such as a polar solvent (for example, 2-butoxyethanol, 2-ethoxyethyl acetate, 2-(2-butoxyethoxy)ethanol, or diacetone alcohol or the like) in combination with an aromatic solvent such as toluene, benzene, or hydrocarbon distillate fractions heavy in aromatics and having a boiling range in the range of from about 140 to 240 C. In preferred applications, the fluid film-forming material is sprayed onto the foam so as to minimize soak in and build up. In this case, it is preferable to use a relatively viscous, high solid content suspension/solution. Typical viscosities are lOOcps or greater such as us to about 1,000 cps. Typical solids contents are from about 25% to about 60%.

Materials outside of these ranges can be used but the above ranges are preferred.

In one preferred application, the liquid film forming material is applied to the foam by dipping. In this case it is preferable to use a high solid content suspension/solution. Preferably, the suspension/solution shall contain at least about 50% by weight solids and more preferably from abot 50 to about 75% by weight solids. Such solution/suspension has the advantage of not soaking into the foam core even when the foam core is open celled constructio .

This outer wall, when applied as a liquid can be dried (solvent removed) and cured by the application of heat and/or the application of a curing catalyst such as an amine. Other curing modalities such as photocuring can be employed as well, if appropriate. The liquid wall- forming compositions can contain plasticizers and builders and the like, if desired. The particular conditions used for forming the outer wall are conventional for processing polymers such as the urethanes which are preferred and are known to those of skill in the polymer arts.

In those applications where the outer wall is applied as a liquid, either by dipping or by spraying, it can be of advantage to preheat the foam core. This preheating raises the temperature of the foam core to above ambient, that is preferably above 80 and more preferably above 90° and up to the highest temperature at which the foam core remains thermally stable. Such high temperatues include 250°F or higher if possible. Preferred temperatures are from about 90-250 F and especially from about 100-150°F. This preheating of the core appears to assist the formation of a film when the liquid wall-forming material is applied. These elevated temperatures can be achieved by autoclaving the core prior to applying the outer material.

The outer wall, whether supplied as a preformed structure, a cured liquid overcoat or a shrunk or adhered layer of stock goods is commonly from about 1 to 200 mils in thickness with thicknesses in the range of from about 2 to 50 mils being preferred and excellent results being attained with thicknesses of from about 3 to about 35 mils.

The core of the impact absorber is a foam. This foam is preferably an open-celled foam, that is a foam in which the various cells are in communication with each other and with the outer surface of the foam. Similar properties are achieved with a reticulated foam, that is a foam which has been treated to break down membranes which separated various cells. Foam rubber, foamed latex, vinyl foams and the like can be used. The preferred foam material for use in the core is poly(urethane) foam. Representative foams include the "Ensolite" poly(urethane) foams sold by Uniroyal Plastics Co., Inc. and the flexible urethane foams sold by the E.R. Carpenter Company. Typical densities for the foam core range from between about 0.5 to about 15 pounds per cubic foot. Preferred foam densities are from about 2 to 10 pounds per cubic foot.

It will be appreciated that because the foam core is adhered to the outer wall it is in effect a structural member. The adhered foam serves to prevent the ballooning of the device as previously described. This duty puts strain upon the foam of the core. If the foam separates under this strain it can result in a loss of integrity of the device. With this potential problem in mind, it is possible to reinforce the foam by including filaments or fibers or fabrics in it. Typical reinforce¬ ments can be inorganic materials such as fiberglass or carbon fiber; natural organic fibers such as silk, cotton, wool or the like or synthetic organic fibers such as urethane fibers, nylon filaments, nylon fabrics, aramid filaments and fabrics, and the like. This reinforcement can be laminated into the foam, incorporated into the foam or otherwise compounded into the foam as is known by those skilled in the art.

In the embodiment shown in Figures 1 and 2, the internal foam core is preshaped to fit tightly within the outer wall of the impact absorber.

This intimate fit may be accomplished in other ways as well. For one, the core can be foamed in place within the wall structure using injectable flexible foam forming materials known in the art. With the preferred urethane foams, a typical foaming mixture can include a polyether polyol, a diisocyanate such as toluene diisocyanate, water, and amine and organotin catalysts. This mixture generally contains polymeric fillers and flexibilizers (plasticizers) as well. The added water reacts with the isocyanates to produce an amine plus carbon dioxide gas which foams the liquid. Other foaming agents such as gases including carbon dioxide, nitrogen, air or the like as well as low boiling liquids, (commonly low-boiling fluorocarbons and the like) can also be added. By controlling the amount of foaming material added and the cure conditions, the core so formed can, if desired, prestress the outer wall as is preferred. The in situ cores can be closed-cell foams, open-celled foams or reticulated foams as desired.

In a hybrid form of construction, the foam core can be a composite of a preshaped foam body which does not completely fill the cavity created by the outer wall_^ and an added foam-in-place layer between the wall and the preshaped body. This form of fabrication has the advantage that the desired intimate fit is achieved with a minimum of preshaping and fitting while at the same time the preshaped core provides a measure of dimensional stabilty and integrity to the composite during fabrica¬ tion.

The third component of the impact absorbers of this invention is an adhesive for affixing the foam core to the wall. This adhesive is most conveniently an activated adhesive such as a light activated adhesive, UV activated adhesive or heat activated adhesive so as to permit the parts to be fitted together and then bonded. A typical heat-activated adhesive is the Royal Adhesive DC- 11324 material sold by Uniroyal. This adhesive is a two part poly(urethane)/isocyanate adhesive which has the added advantage of being water-based. When applied to the foam and/or wall it dries to a non-tacky surface which permits easy assembly. This material heat-activates at 300-325°F to form a tough adherent bond. Other useful adhesives can include epoxy adhesives, contact cement type poly(urethane) adhesives such as the Uniroyal "Silaprenes", the 3M "Scothgrip" adhesives and the isoprene contact cements. In general, one can employ as adhesive any material which will bond the foam to the outer wall with a strength which will not be exceeded by the forces of impact applied to the impact absorber or by the forces applied by the pressure applied to the impact absorber. In the fabrication methods in which a liquid solution of prepσlymer is applied to the core to create the outer layer or in which the core is foamed in place, it is often the case that the required intimate bond between the core and the outer wall is formed directly without the need for added adhesive.

The outer wall portions of the impact absorber are joined together such as by the use of adhesive or by heat sealing or the like to give a fluid impermeable wall to which the inner core is bonded. After the fusing together of the wall components, the impact absorber can be trimmed and, if desired, further shaped to conform to the environment of use.

The core of the present impact absorbers contain a fluid. Gases and in particular air are very suitable fluids. Liquids and gells could be used as well, if desired. One interesting class of fluids for use in inflating the present shock-absorbers are the gases denominated the "supergases" by Marion Rudy in his United States Patent No. 4,219,945 FOOTWEAR. These gases are large molecule gases such as the heavily substituted halocarbons, for example hexafluoroethane, perfluoropropane, perfluorobutane, perfluorohexane, perfluoroheptane, octafluorocyclobutane, hexafluoropropylene, tetrafluormethane, 1,2- dichlorotetrafluorethane, 1,1,2-trichloro-l,2,2- trifluorethane, bromotrifluoromethane and the like. These gases have the property of being preferentially retained within elastomeric membranes through which air, nitrogen, oxygen and other "smaller" molecules can diffuse. This leads to the interesting phenomenum that these smaller molecules of gas can, with the passage of time, diffuse into the cavity created by the polymeric wall and filled with the supergases and thus increase the observed pressure within the cavity. Turning to Figures 3 and 4, the advantages of the impact absorber of this invention are graphically il¬ lustrated. In each of these figures a shoe 30 is shown together with foot 31 impacting downward into a heel pad shown as 32 (in Figure 3 - not according to the invention) and as 10 (in Figure 4 - in accord with this invention). In the case of heel pad 32, the downward pressure of the heel causes the center of the pad 34 to be severely depressed while permitting the edges 35 and 36 to balloon up. This can be uncomfortable and unstable. With pad 10 the center 33 depresses somewhat but there is minimal bal¬ looning.

Turning now to Figure 5, a variation of the core 11 is shown. This core (core 50) is fabricated from a plurality of foams of differing properties, for example density. As shown, the core includes a series of plugs 51A, 5IB, etc of firm density foam inserted into the body of core 11. This can result in a light weight core having the firmness of the plugs. This is merely a representative configuration and one could as well have one entire section of the core with one density foam and another section with another density. One could also vary the core based on other properties, such as the ability of a region of the foam to take a set or the like. The various core sections are adhered to the outer wall of the impact absorber as is shown in Figures 1 and 2. One could form a core of this type by placing preshaped pieces of one foam in the cavity and then foaming in place the other material, if desired. The plastic wall of the impact absorber can have structural properties and contribute to the rigidity and shock-absorbing properties of the device. Figures 6, 7 and 8 illustrate an embodiment 60 of the impact absorber which includes a depression or "column" 61 in its structure so as to provide additional wall surface and _. _Q

-18-

structure in that region of the absorber. In this embodiment as shown in Figure 8, the valve 16 is il¬ lustrated being laminated into the composite as the top 12 is joined to the bottom 14. Figure 9 illustrates other variations which may be employed without departing from the spirit of this invention. Figure 9 shows impact absorber 80. The foam core of absorber 80 is fabricated from several different foams including foam section 81, section 82, section 83 and section 84. These sections are all adhered to the wall 12/14. Valve 16 is again provided to permit the pressure of the core to be altered and controlled. The various core sections can be adhered to one another, if desired. If they are adhered to one another, it must be borne in mind that the glue layers or the like between the various sections can serve as barriers for the transport of fluid between the various sections. If such fluid com¬ munication is desired, gaps must be left in the glue lay¬ ers or glues which are fluid-permeable must be used. Absorber 80 includes several other features which can be incorporated into the present absorbers. An exterior pad 85 is provided. This can provide additional shock-absorbancy. A top layer 86 is also present. This can be a cosmetic over layer or can be provided as a replaceable hygienic layer.

In the absorbers shown in Figures 1, 6 and 9, the means for adjusting the pressure (valve 16) has been in communication with, the foam core itself and has relied upon the open-cell foam structure of the core to distribute the applied pressure throughout the core and thus provide a uniform level of support throughout the absorber. While this structure is very suitable, one can also employ closed-cell foams, if desired. Figures 10 and 11, and Figures 12 and 13 respectively illustrate two representative configurations for a closed-cell foam core. In the configuration shown in Figures 10 and 11, the core 87 contains an aperture 88 into which the pressure adjust¬ ing valve 16 can fit. This aperture 88 communicates with a network of channels 89 spaced throughout the core so as to transmit and distribute the pressure applied to aperture 88. In this embodiment, the network of channels is contained by and enclosed by the closed-cell foam core. This means that the core itself can contribute to the containment of the pressure applied to the channels. This offers the advantage that localized stress on the outer wall is avoided or minimized and possible failures due to rupture at localized stress points are minimized.

The configuration shown in Figures 12 and 13 is substantially the same as that shown in Figures 10 and 11 with the exception that aperture 97 communicates with a network of passages 98 which are not fully contained within the core. This configuration does not offer the localized stress relief of the configuration of Figures 10 and 11 but would be less expensive and simpler to produce. Turning to Figure 14 an additional embodiment of the impact absorber is shown as foot pad 90 housed within the sole portion of shoe 95. Foot pad 90 includes the foam core 11 and adherent outer wall 12/14 described herein. Pad 90 is equipped with a built in pump to alter the pressure within its core. This pump includes a one way check valve 16 which admits air into pump cavity 91. Pump cavity 91 is compressed and released to give a region of low pressure so that air can enter through valve 16. When the cavity 91 is depressed again, this forces the newly admitted air through passage 92 into the core 11, thus increasing its pressure. This process is repeated until the proper pressure is attained. Shoe 95 also includes a collar 93. This can be formed with the same structure as pad 90 with an internal core adhered to the walls. Such a collar would be very effective at absorbing __{2 Q}_

the shock which would occur as the wearer's foot comes up in the shoe and impacts it or would be effective as a protection to the wearer's ankle and achilles tendon region. Figure 15 illustrates that the present invention finds application in many areas beyond athletic equipment. It illustrates an automotive dashboard structure 101 hav¬ ing an impact pad 100 on its face as well as phantom steering wheel 102. Impact pad 101 includes core 11, wall 12/14 and valve 16. Such a pad can provide efficient dashboard impact protection for the occupants of the auto¬ mobile in the event of a crash.

Figures 16 and 17 illustrate in two views a ventilated footpad 110 for use in shoes. Pad 110 has a complex shape which requires numerous compound curves. In its application as a shoe footpad, pad 110 will be subjected to a wide variation in impacts depending upon the weight of the runner using it and the runner's light¬ ness of footstrike. It is of substantial advantage to adjust the pressure within the pad with valve 16 to accom¬ modate these variations.

Figure 18 illustrates another embodiment of the present invention, an underpad 180 for use in conjunction with contact sports shoulder pads. Underpad 180 has a structure which includes numerous compound curves and a ' plurality of "Swiss-cheese" holes through its structure. The compound curve-forming ability and the plurality of holes permit the pad to conform to and bend over the wearer's shoulder with comfort and breathability. It is a special advantage that the present invention makes these complex curves possible and provides superior shock and impact absorption in such settings.

Figure 21 illustrates another embodiment of the present invention. It shows pad 210 in which the foam core 11 is surrounded by a wall 211 which has been formed around and in intimate adhesion to the core by applying a liquid polymer suspension to the outer surface of the core and then curing the polymer to produce the wall.

In one preferred embodiment, the outer surface is created by spraying several layers of a curable polymer suspension onto the open-cell foam of core 11. Typical polymer suspensions are the urethane suspensions such as the two part sprayable system marketed by Technical Urethanes, Inc, Clearbrook, Virginia as Techthane 9OSS. This representative material is a mixture of an aliphatic poly(ether urethane) and a curing agent. These two materials are mixed in about equal volume ratio and ap¬ plied typically with an airless sprayer at a viscosity of 100-200 cps. This suspension has a solids content of about 45-50% by weight which, when coupled with the viscosity just recited, gives rise to minimal soak-in into the open-cell foam. The material cures to a tightly adhered layer around the core at room temperature or can be quick-cured by the application of heat. Additional layers of the suspension can be applied to produce the desired strength and thickness of coating.

As noted above, the coating can be applied by dipping, as well, when the solids content of the suspen¬ sion is above about 50% by weight. This coating can be carried out with improved efficiency when the core is preheated and this preheat condition is maintained during the coating, or at least the initial stages of the coat¬ ing.

Under atmospheric conditions, this process will give rise to a shock-absorber having an atmospheric pres¬ sure within the core. This pressure can be increased by adding additional pressurization fluid to the core. This can be carried out using a valve as has been previously described or alternatively can be carried out as depicted in Figure 21 by injecting fluid such as a gas directly 9/02363 .„.

through the wall 211 by means of a needle 213. In the figure, this gas is supplied through line 212. Wall 211 can be self-sealing, or a sealant can be applied over the hole created by needle 213 so as to assure the retention of the pressure applied from line 212.

As previously noted, in some embodiments, the core or the shock-absorber can be pressurized using the process of diffusion pumping as disclosed in United States Patents Nos. 4,219,945 and 4,271,606, both of which il- lustrate typical materials for forming walls suitable for this process and are incorporated by reference. Figures 22A and 22B illustrate this process in schematic view. In these figures, Figure 22A illustrates a shock-absorber 220 having a spray- on outer wall 211 and a pressurizable open-celled foam core 11. Large molecule gas is present within the voids or cells of core 11. These large molecules are fancifully shown as 221, even though, of course they can not in fact be seen. These molecules are held and enclosed by wall 211 and can not escape as shown representationally by their bouncing off of the wall. Absorber 220 is at a low pressure mode as shown by its flat to concave section. Wall 211 is fabricated of a material which is permeable to small gas molecules and in particular nitrogen and oxygen molecules from air, shown as 222. These small molecules permeate the wall and cause the internal pressure of core 11 to increase. This effect is shown in Figure 2IB where the diffused "small" molecules have entered the core and caused it to press against the affixed wall 211 and expand the body. This pressurization by diffusion can lead to enhanced life for the shock-absorbers and to increased performance.

The effectiveness of the present invention can • be demonstrated by comparative tests^'. A series of impact tests were run on a standard state-of-the-art basketball shoe. The same tests were then performed on the same model shoe which had been modified by replacing a portion of its sole structure (the heel pad region) with an impact absorber of this invention. The impact absorber was fabricated from 35 mil flexible poly(urethane) . The core was about 1/2 inch thick open-cell poly(urethane) foam of 5 lbs per cubic foot density. The foam core slightly pre- stressed the outer wall by being somewhat oversized and was adhered to the walls using a heat activated water- based urethane adhesive. Tests were run with the core sealed at atmospheric pressure and with the core pres¬ surized to 5 and 10 psig. Figures 19 and 20 present the results of these tests. In each figure line A is the results observed with the prior art shoe. It can be seen that for a given application of energy to the shoe, i.e. a given impact, the shoe transmits a certain peak force and a certain acceleration, (in G's) to the wearer. Lines B show the results achieved when the atmospheric bladder is used. They show that the force and acceleration transmit¬ ted to the wearer is significantly reduced. Importantly, this reduction occurs over the entire range of applied energies. Thus the effectiveness of the present absorbers is substantially universal and will be observed with hard impacts such as may result with heavy athletes and also with lighter impacts such as may result with lighter weight athletes, etc.

Lines C show that even better shock-absorbancy is achieved when a positive pressure is applied to the bladders. Similar results were obtained with the 5 and 10 pound pressures which suggest that in practical terms these pressures may be quite adequate. On the basis of these tests, it is believed that pressures in the range of 0 to about 20 psig are preferred.

The present invention has been described herein in detail with respect to a number of preferred embodiments and configurations. It will be appreciated, however, that modifications and changes to various aspects of these embodiments may be made while still coming with in the spirit and scope of this invention which is as^■ defined by the following claims.

Claims

Clai s

1. A shock-absorbing composite for absorbing and dispersing impacting forces comprising a flexible plastic enclosure defining an internal cavity therein, said flexible enclosure being capable of having its internal pressure changed, and a foam core filling said cavity and retained within said cavity and adhered on substantially all of its external surface to the internal surface of the cavity.

2. The shock-absorbing composite of claim 1 wherein the foam core comprises foam selected from the class consisting of reticulated foams and open celled foams.

3. The shock-absorbing composite of claim 2 ^"wherein the foam core comprises open celled foam.

4. The shock-absorbing composite of claim 2 wherein the flexible enclosure comprises a preshaped, preformed enclosure.

5. The shock-absorbing composite of claim 2 wherein the flexible plastic enclosure comprises a layer of cured polymer applied by spraying a suspension of precured polymer onto the surface of the foam core and curing.

6. The shock absorbing composite of claim 2 wherein the flexible enclosure comprises a layer of cured polymer applied by dipping the outer surface of said core into a suspension of prepolymer having a solids content of at least about 50% by weight, thereby forming a layer of said suspension on said core and curing the layer of prepolymer suspension to yield a flexible plastic layer.

7. The shock-absorbing composite of claim 2 additionally comprising means for pressurizing the internal cavity.

8. The shock-absorbing composite of claim 7 wherein the means for pressurizing the cavity comprise a wall portion which can be sealably punctured by an inflation needle.

9. The shock absorbing composite of claim 2 wherein the foam core comprises a plurality of horizontally stacked sections varying in compression strength.

10. The shock absorbing composite of claim 3 wherein the foam comprises urethane foam and wherein the flexible plastic enclosure comprises urethane.

11. The shock absorbing composite of claim 2 wherein the flexible plastic enclosure is shaped to form one or more supportive passages through the foam.

12. The shock absorbing composite of claim 1 wherein the foam core comprises closed celled foam and the foam core additionally comprises an aperture for changing the pressure within said cavity said aperture being in pressure communication with a network of open-ended passages through the body of said core. _ _

13. A shock-absorbing heel pad for shoes for protecting the wearer from foot strike forces impacting the wearer's heel comprising a flexible plastic enclosure defining an internal cavity therein and adopted to fit into the heel region of a shoe midsole, said flexible enclosure being generally impermeable to air and capable of having its internal pressure changed, and a foam core filling said cavity and retained within said cavity and adhered on substantially all of its external surface to the internal surface of the cavity.

14. The shock absorbing heel pad of claim 13 wherein the foam core comprises open celled foam.

15. The shock absorbing heel pad of claim 13 additionally comprising means for pressurizing the internal cavity.

16. A method for producing a shock absorbing composite for absorbing and dispersing impacting forces comprising forming a flexible plastic enclosure defining an internal cavity therein, said flexible enclosure being generally impermeable to air and capable of having its internal pressure changed, placing within said enclosure a foam core filling said cavity and retained within said cavity and adhered on substantially all of its external surface to the internal surface of the enclosure, and pressurizing the core to a value effective to provide ef¬ ficient impact absorption. ,_fi.

17. The method of claim 16 wherein the foam core is adhered to the enclosure with a heat activated adhesive.

18. A method for producing a shock-absorbing composite for absorbing and dispersing impacting forces comprising forming a flexible foam core shaped and sized as required for said shock-absorbing composite, applying to the outer surface of said core a flexible plastic layer thereby forming a flexible enclosure sur¬ rounding and adhered on all sides to said core, said flex¬ ible enclosure being capable of having its internal pressure changed, and pressurizing the core to a value effective to provide ef¬ ficient impact absorption.

19. A method for producing a shock-absorbing composite for absorbing and dispersing impacting forces comprising forming a flexible foam core shaped and sized as required for said shock-absorbing composite, applying to the outer surface of said core a layer of prepolymer solution/suspension, curing the layer of prepolymer solution/suspension to yield a flexible plastic layer thereby forming a flexible enclosure surrounding and adhered on all sides to said core, said flexible enclosure being capable of having its internal pressure changed.

20. The method of claim 19 wherein said applying is carried out by dipping and wherein the solution/suspension is a suspension having a solids content of at least about 50% by weight.

21. The method of claim 20 wherein the core is open celled foam and wherein the core is preheated to a temperature of from about 90 to 250 F prior to said applying,