US6613103B2 - Method for dyeing fabric comprising elastomeric fiber - Google Patents
Method for dyeing fabric comprising elastomeric fiber Download PDFInfo
- Publication number
- US6613103B2 US6613103B2 US09/735,558 US73555800A US6613103B2 US 6613103 B2 US6613103 B2 US 6613103B2 US 73555800 A US73555800 A US 73555800A US 6613103 B2 US6613103 B2 US 6613103B2
- Authority
- US
- United States
- Prior art keywords
- fabric
- bath
- dyeing
- minutes
- spandex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related, expires
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B9/00—Solvent-treatment of textile materials
- D06B9/02—Solvent-treatment of textile materials solvent-dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation
- D06B23/22—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration, distillation for heating
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/28—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics propelled by, or with the aid of, jets of the treating material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/26—Polyamides; Polyurethanes using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0036—Dyeing and sizing in one process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/926—Polyurethane fiber
Definitions
- This invention relates to a process for dyeing fabrics comprising elastomeric fiber and, more particularly, to such a process which results in dyed fabrics which are substantially free of a particular kind of undesirable nonuniformity, “fractures”.
- Fractures in elastomeric fiber-containing circular knit fabrics have not been eliminated without slitting, heat setting, and tacking the fabrics before dyeing, and a simpler method of eliminating fractures is still needed.
- the process of this invention for jet-dyeing a fabric comprising an elastomeric fiber comprise the steps of:
- elastomeric fiber is meant a staple fiber or continuous filament which, free of diluents, has a break elongation in excess of 100% independent of any crimp and which when stretched to twice its length, held for one minute, and then released, retracts to less than 1.5 times its original length within one minute of being released.
- Such fibers include spandex, polyetherester fiber, and elastoester, and can be covered with other, non-elastomeric fibers or can be bare (uncovered).
- spandex is a manufactured fiber in which the fiber-forming substance is a long chain synthetic polymer comprised of at least 85% by weight of a segmented polyurethane.
- fracture is meant a short (typically 3 cm or less), sharply defined mark that can appear in a fabric during jet-dyeing, possibly resulting from one or two elastomeric fibers becoming displaced from the plane of the fabric. Fractures are unique to fabrics comprising elastomeric fibers and are so named because, to the naked eye, they can look like cuts in the fabric. Fractures are aligned in the direction of the elastomeric fiber. For example, fractures can appear in the cross-direction in circular knits and either in the cross-direction or the machine-direction in warp knits and wovens, depending on the elastomeric fiber orientation.
- creases and crack marks result from folding of the fabric during wet processing, while fractures result either from a) highly localized drawing and permanent setting of one or two elastomeric fibers at a time after which the resulting longer fiber(s) must bulge out of the plane of the fabric for a short distance, or b) a highly localized inability to accommodate elastomeric fiber retractive forces generated elsewhere in the fabric during wet-finishing.
- “Rope marks” are dye-deficient areas in a fabric resulting from the inability of dye to penetrate the fabric in the vicinity of rope used to constrain the fabric during dyeing.
- “Not substantially heat-set” means that a fabric containing a spandex comprising polyurethaneurea has not been heated above about 320° F. (160° C.) under dry conditions or above about 250° F. (121° C.) with steam.
- a fabric containing a polyetherester fiber or a spandex comprising polyurethane it means the fabric has not been heated above about 280° F. (138° C.) under dry conditions or above about 220° F. (105° C.) with steam.
- an aqueous bath is prepared in a jet-dyeing machine by adding water and a textile dyebath lubricant.
- the bath is pre-heated to at least about 40° C., typically about 40-60° C. While creases and crack marks can be reduced or eliminated by adding lubricant to the bath after adding the fabric, doing so does not have the same beneficial effect on fractures, and it is a requirement of the inventive process that the water and lubricant be added to the dyeing machine before the fabric is added to the resulting bath. It is, however, immaterial whether the lubricant is added before or after the water is added, or before or after the bath is pre-heated.
- the lubricant can be used at a level of about 1.0-5.0 g/l, based on the water volume in the bath.
- the fabric and at least one dye are then added to the bath. After each of the steps of adding the lubricant and adding the fabric, it can be helpful to run the dyeing machine for 5-10 minutes, thoroughly to mix the water and lubricant and to wet the fabric, respectively. However, to minimize further the formation of fractures, it is preferred that the fabric spend less than about 45 minutes in the bath (during fabric wetting and dye addition) before beginning to heat the bath to the dyeing temperature, which heating can take place over a period of less than about 100 minutes. After dyeing is complete, the bath can be cooled. It is preferred that the dyebath be heated rapidly, for example at an average rate of at least about 1° C./minute, and cooled rapidly, for example also at an average rate of at least about 1° C./minute, for maximum avoidance of fractures.
- Both tank-type and horizontal (low profile) machines can be used, as can any desired liquor ratio (for example 7:1 to 25:1 weight ratio of dyebath to fabric).
- Optional pre-process preparations can include relaxing the fabric to avoid structural distortion and uneven dyeing, for example by steaming or pre-scouring.
- Optional post-dyeing operations can include reduction clearing, soaping, wet or dry heat setting, and the like.
- the process of the invention can be carried out with a Samil horizontal (low profile) jet dyeing machine with single jersey circular knits (e.g., 10 wt % Lycra® spandex) and rib knits (e.g., 4 wt % Lycra® spandex) in which the companion fiber can be polyester, nylon, acetate, or rayon, utilizing a lubricant such as 1.5 g/l Lubrigen® BA, resulting in fracture-free fabrics. Due to the elimination of pre-heat-setting, the total dye cycle time can be reduced from 6 hours to 4 hours. Also, dye uptake can be more level than in conventional processes.
- fibers that can be used in the fabric to be dyed by the present process include cotton, rayon, acetate, and fibers prepared from polycaproamide, poly(hexamethylene adipamide), poly(ethylene terephthalate), poly(trimethylene terephthalate), and the like.
- Such additional fibers can be companion fibers to the spandex, for example as a covering for the spandex, or they can be knit or woven into the fabric along with, or separately from, the spandex.
- Fabrics that can be used in the present process include circular knits, warp knits, flat weft knits, and wovens.
- circular knits especially, a dramatic reduction in the number of steps is possible as a result of eliminating the need for heat-setting the fabric before dyeing.
- Conventionally, such knits have been slit open, pre-heat-set, tacked back into a cylindrical shape, dyed, de-tacked, dried, and post-heat-set.
- circular knits free of fractures can be prepared in just four steps: dyeing, slitting open, drying, and post-heating.
- Lubricants that can be used in the process of the invention include those typically used in the dyeing of textiles, including metal salts of fatty acid sulfates and sulfonated fatty acid esters, fatty amides, fatty acid ethoxylates, polyacrylates, poly(acrylamide-co-acrylic acid)s, polysiloxanes, and paraffins, as described in American Dyestuff Reporter, September 1994, pp. 68 ff. Use of unsaturated fatty acids, however, was observed to generate fuming during heat setting and to create oil spots, and such lubricants can degrade spandex. Such lubricants are therefore not preferred.
- the dyes used in the present process can include disperse, cationic, acid, and metallized dyes, and, especially with cotton, fiber-reactive dyes and direct dyes.
- Typical dyeing times at the dyeing temperature can be those conventionally used, for example about 25-45 minutes at 100-125° C.; such conditions can be readily adjusted by one skilled in the dyeing art to suit the selected fibers and dyes.
- a fabric was knit on a 28 needles/inch (11 needles/cm) circular knitting machine from 78 dtex Lycra® Type 169B spandex (a registered trademark of E. I. du Pont de Nemours and Company) plated into every course with a 30 singles (180 denier, 200 decitex) textured staple poly(ethylene terephthalate) yarn.
- the fabric was 11 wt % spandex and 89 wt % polyester.
- a Scholl Bleachstar (tank type) jet-dyeing machine was used at a nozzle pressure of 14 psi (97 kPa), a nozzle diameter of 80 mm, and a fabric speed of 2.5 minutes per fabric revolution.
- Water and 2.0 g/l Persoftal® ACL (a lubricant from Bayer) (concentration based on water volume) were added to the machine.
- the resulting dyebath was heated to 40° C., and the machine was run for 5 minutes.
- the knit fabric was added; the dyebath/fabric (liquor) weight ratio was 10:1.
- the machine was run for 10 minutes, after which 1.5 g/l (based on water) of Sandacid VS (a pH control agent from Sandoz) was added.
- the machine was closed, and pre-mixed dyes were added from an addition tank.
- the dyes and their concentration were 1.175% Foron Brilliant Yellow S6GL (C.I. Disperse Yellow 231), 0.915% Foron Rubine RD-GFL 200, and 2.925% Foron Navy RD RLS-300 (all from Clariant).
- the choice of these dye concentrations was based on experience with conventional dyeing processes.
- the dyebath was heated at a rate of 1.5° C./minute. When the temperature reached about 95° C., the bath pH was checked and determined to be 5-6. After the bath reached 120° C., the machine was run for 30 minutes, then cooled at 1.5° C./minute to 80° C.
- a reduction clearing step sodium hydroxide and thiourea dioxide (each at 2.0 g/l of bath volume) were added, and the pH was checked to ensure that it was above 10.
- the machine was run for 20 minutes, and while the bath was being cooled, the fabric was rinsed with overflow at 70° C. and again at 60° C.
- the dyed fabric was dried at 160° C. with a Santex drier, slit, and dry heat-set on a tenter frame at 88° C. for 30 seconds. The resulting black fabric exhibited no fractures.
- Example 1 was repeated except that the amounts of dye were decreased to 0.47% Foron Brilliant Yellow S6GL (C.I. Disperse Yellow 231), 0.37% Foron Rubine RD-GFL 200, and 1.71% Foron Navy RD RLS-300, and the 120° C. dyeing step was run for 45 minutes instead of 30 minutes. Even at this reduced dye level (40-60% of the amount typically used on a fabric of this composition and construction), the color of the dyed fabric was a satisfactory black, indicating much higher dye yield and consequently much more efficient use of the dyes than with a conventional dyeing process.
- Foron Brilliant Yellow S6GL C.I. Disperse Yellow 231
- Foron Rubine RD-GFL 200 0.37%
- Foron Navy RD RLS-300 1.71%
- the 120° C. dyeing step was run for 45 minutes instead of 30 minutes. Even at this reduced dye level (40-60% of the amount typically used on a fabric of this composition and construction), the color of the dyed fabric was a satisfactory black, indicating
- Comparable fabrics which had not been pre-heat set, dyed by a conventional process, for example placed into a jet dyebath before the lubricant and run for 60 minutes at no more than about 30° C., heated at an average rate of 0.6° C./minute over a period of 140 minutes to dyeing temperature, followed by cooling at 0.5° C./minute, exhibited an unacceptable number of fractures.
Abstract
Description
Claims (7)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/735,558 US6613103B2 (en) | 2000-12-13 | 2000-12-13 | Method for dyeing fabric comprising elastomeric fiber |
EP01988226A EP1341954A2 (en) | 2000-12-13 | 2001-11-15 | Method for dyeing fabric comprising elastomeric fiber |
JP2002550155A JP2004515666A (en) | 2000-12-13 | 2001-11-15 | Method for dyeing woven fabrics comprising elastic fibers |
CNA01820354XA CN1479820A (en) | 2000-12-13 | 2001-11-15 | Method for dyeing fabric comprising elastomeric fiber |
PCT/US2001/045418 WO2002048448A2 (en) | 2000-12-13 | 2001-11-15 | Method for dyeing fabric comprising elastomeric fiber |
KR10-2003-7007833A KR20030060115A (en) | 2000-12-13 | 2001-11-15 | Method for Dyeing Fabric Comprising Elastomeric Fiber |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/735,558 US6613103B2 (en) | 2000-12-13 | 2000-12-13 | Method for dyeing fabric comprising elastomeric fiber |
Publications (2)
Publication Number | Publication Date |
---|---|
US20020069467A1 US20020069467A1 (en) | 2002-06-13 |
US6613103B2 true US6613103B2 (en) | 2003-09-02 |
Family
ID=24956279
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/735,558 Expired - Fee Related US6613103B2 (en) | 2000-12-13 | 2000-12-13 | Method for dyeing fabric comprising elastomeric fiber |
Country Status (6)
Country | Link |
---|---|
US (1) | US6613103B2 (en) |
EP (1) | EP1341954A2 (en) |
JP (1) | JP2004515666A (en) |
KR (1) | KR20030060115A (en) |
CN (1) | CN1479820A (en) |
WO (1) | WO2002048448A2 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050132509A1 (en) * | 2003-06-02 | 2005-06-23 | Cheng-Yuan Chuang | Dyed 2GT polyester-spandex circular-knit fabrics and method of making same |
US20060260074A1 (en) * | 2002-12-27 | 2006-11-23 | Sara Lee Corporation | Composition for dyeing of cellulosic fabric |
US20070199164A1 (en) * | 2002-12-27 | 2007-08-30 | Hbi Branded Apparel Enterprises, Llc. | Composition for dyeing of cellulosic fabric |
US7931699B2 (en) | 2002-12-27 | 2011-04-26 | Hbi Branded Apparel Enterprises, Llc | Compositions for spray dyeing cellulosic fabrics |
US20110203057A1 (en) * | 2008-10-13 | 2011-08-25 | Hietpas Geoffrey D | Fabric including polyurethane elastic yarn |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005079726A1 (en) | 2004-02-23 | 2005-09-01 | Fisher & Paykel Healthcare Limited | Breathing assistance apparatus |
EP3936180B1 (en) | 2004-04-02 | 2023-11-29 | Fisher & Paykel Healthcare Limited | Breathing assistance apparatus |
US20070000066A1 (en) * | 2005-06-29 | 2007-01-04 | Invista North America S.A R.I. | Dyed 2GT polyester-spandex circular-knit fabrics and method of making same |
CA2998247A1 (en) | 2006-07-14 | 2008-01-17 | Fisher & Paykel Healthcare Limited | Breathing assistance apparatus with support member |
US10792451B2 (en) | 2008-05-12 | 2020-10-06 | Fisher & Paykel Healthcare Limited | Patient interface and aspects thereof |
US11660413B2 (en) | 2008-07-18 | 2023-05-30 | Fisher & Paykel Healthcare Limited | Breathing assistance apparatus |
US9901700B2 (en) | 2008-10-10 | 2018-02-27 | Fisher & Paykel Healthcare Limited | Nasal pillows for a patient interface |
CN105816949B (en) * | 2009-05-12 | 2020-07-28 | 费雪派克医疗保健有限公司 | Patient interface and aspects thereof |
WO2012047121A1 (en) | 2010-10-08 | 2012-04-12 | Fisher & Paykel Healthcare Limited | Breathing assistance apparatus |
SG10201700946YA (en) | 2012-08-08 | 2017-03-30 | Fisher & Paykel Healthcare Ltd | Headgear for patient interface |
US10876253B2 (en) * | 2016-02-18 | 2020-12-29 | Dyecoo Textile Systems B.V. | Method of dyeing a substrate comprising elastomeric fibre and non-elastomeric fibre, and a dyed subtrate comprising these fibres |
CN108118472B (en) * | 2017-12-13 | 2020-05-12 | 互太(番禺)纺织印染有限公司 | Dyeing device and method for polyester fabric and application of dyeing device |
CN108547099A (en) * | 2018-07-04 | 2018-09-18 | 张家港市凯利雅特种纺织纱线有限公司 | A kind of anti-fracture spandex dyeing apparatus |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3653798A (en) | 1967-01-07 | 1972-04-04 | Geigy Ag J R | Process for the dyeings of blends of spandex fibers and polyamide fibers |
US5230709A (en) * | 1990-11-15 | 1993-07-27 | E. I. Du Pont De Nemours And Company | Polyamide dyeing process utilizing controlled anionic dye addition |
US5399616A (en) | 1991-03-25 | 1995-03-21 | Ciba-Geigy Corporation | Lubricant-containing aqueous preparations of copolymers |
US5648010A (en) * | 1995-06-19 | 1997-07-15 | Henkel Corporation | Lubricant for air entanglement replacement |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH644732GA3 (en) * | 1976-11-17 | 1984-08-31 | Wet treatment of textile material using polyurethane as lubricant |
-
2000
- 2000-12-13 US US09/735,558 patent/US6613103B2/en not_active Expired - Fee Related
-
2001
- 2001-11-15 KR KR10-2003-7007833A patent/KR20030060115A/en not_active Application Discontinuation
- 2001-11-15 CN CNA01820354XA patent/CN1479820A/en active Pending
- 2001-11-15 EP EP01988226A patent/EP1341954A2/en not_active Withdrawn
- 2001-11-15 WO PCT/US2001/045418 patent/WO2002048448A2/en not_active Application Discontinuation
- 2001-11-15 JP JP2002550155A patent/JP2004515666A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3653798A (en) | 1967-01-07 | 1972-04-04 | Geigy Ag J R | Process for the dyeings of blends of spandex fibers and polyamide fibers |
US5230709A (en) * | 1990-11-15 | 1993-07-27 | E. I. Du Pont De Nemours And Company | Polyamide dyeing process utilizing controlled anionic dye addition |
US5399616A (en) | 1991-03-25 | 1995-03-21 | Ciba-Geigy Corporation | Lubricant-containing aqueous preparations of copolymers |
US5648010A (en) * | 1995-06-19 | 1997-07-15 | Henkel Corporation | Lubricant for air entanglement replacement |
Non-Patent Citations (4)
Title |
---|
Houser, N., Wet Processing of Cotton/Spandex Fabric, AATCC Symposium, Elastic Fibers, Nov. 2-3, 1998, pp. 192-201. |
Lloyd Barringer, Jr., Selected Chemistries of Dyebath Lubriants, American Dyestuff Reporter, pp. 68-74 and 102, Sep. 1994. |
Martin White, Developments in Jet Dyeing, 1998, Rev. Prog. Coloration, pp. 80-94, vol. 28. |
N. E. Houser, Wet Processing of Cotton/Spandex Fabrics, 1998, AATCC Symposium, Elastrics, pp. 192-201, Nov. 2-3, 1998. |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060260074A1 (en) * | 2002-12-27 | 2006-11-23 | Sara Lee Corporation | Composition for dyeing of cellulosic fabric |
US20070199164A1 (en) * | 2002-12-27 | 2007-08-30 | Hbi Branded Apparel Enterprises, Llc. | Composition for dyeing of cellulosic fabric |
US7931701B2 (en) | 2002-12-27 | 2011-04-26 | Hbi Branded Apparel Enterprises, Llc | Composition for dyeing of cellulosic fabric |
US7931700B2 (en) | 2002-12-27 | 2011-04-26 | Hbi Branded Apparel Enterprises, Llc | Composition for dyeing of cellulosic fabric |
US7931699B2 (en) | 2002-12-27 | 2011-04-26 | Hbi Branded Apparel Enterprises, Llc | Compositions for spray dyeing cellulosic fabrics |
US20110179589A1 (en) * | 2002-12-27 | 2011-07-28 | May Ruth E | Compositions for spray dyeing of cellulosic fabrics |
US20110179588A1 (en) * | 2002-12-27 | 2011-07-28 | May Ruth E | Composition for dyeing of cellulosic fabric |
US8568492B2 (en) | 2002-12-27 | 2013-10-29 | Hbi Branded Apparel Enterprises, Llc | Composition for dyeing of cellulosic fabric |
US8597374B2 (en) | 2002-12-27 | 2013-12-03 | Hbi Branded Apparel Enterprises, Llc | Compositions for spray dyeing of cellulosic fabrics |
US20050132509A1 (en) * | 2003-06-02 | 2005-06-23 | Cheng-Yuan Chuang | Dyed 2GT polyester-spandex circular-knit fabrics and method of making same |
US20110203057A1 (en) * | 2008-10-13 | 2011-08-25 | Hietpas Geoffrey D | Fabric including polyurethane elastic yarn |
Also Published As
Publication number | Publication date |
---|---|
CN1479820A (en) | 2004-03-03 |
EP1341954A2 (en) | 2003-09-10 |
JP2004515666A (en) | 2004-05-27 |
WO2002048448A3 (en) | 2002-08-22 |
US20020069467A1 (en) | 2002-06-13 |
WO2002048448A2 (en) | 2002-06-20 |
KR20030060115A (en) | 2003-07-12 |
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Owner name: E. I. DU PONT DE NEMOURS AND COMPANY, DELAWARE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:IMMEDIATO, ROBERT F.;LUONGO, RONALD R.;REEL/FRAME:011935/0734;SIGNING DATES FROM 20010228 TO 20010301 |
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Owner name: INVISTA NORTH AMERICA S.A.R.L., DELAWARE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:E. I. DU PONT DE NEMOURS AND COMPANY;REEL/FRAME:015286/0708 Effective date: 20040430 |
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