US6537351B2 - Compact light weight condenser assembly - Google Patents

Compact light weight condenser assembly Download PDF

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Publication number
US6537351B2
US6537351B2 US09/866,994 US86699401A US6537351B2 US 6537351 B2 US6537351 B2 US 6537351B2 US 86699401 A US86699401 A US 86699401A US 6537351 B2 US6537351 B2 US 6537351B2
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US
United States
Prior art keywords
gas stream
foam body
lattice
foam
coolant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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US09/866,994
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US20020178920A1 (en
Inventor
Paul R. Margiott
Thomas J. Corrigan
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Audi AG
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UTC Fuel Cells LLC
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Publication date
Application filed by UTC Fuel Cells LLC filed Critical UTC Fuel Cells LLC
Priority to US09/866,994 priority Critical patent/US6537351B2/en
Assigned to INTERNATIONAL FUEL CELLS LLC reassignment INTERNATIONAL FUEL CELLS LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CORRIGAN, THOMAS J., MARGIOTT, PAUL R.
Priority to DE10296877T priority patent/DE10296877T5/en
Priority to JP2002593060A priority patent/JP3991101B2/en
Priority to PCT/US2002/014425 priority patent/WO2002096556A1/en
Publication of US20020178920A1 publication Critical patent/US20020178920A1/en
Application granted granted Critical
Publication of US6537351B2 publication Critical patent/US6537351B2/en
Assigned to UNITED TECHNOLOGIES CORPORATION reassignment UNITED TECHNOLOGIES CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: UTC POWER CORPORATION
Assigned to BALLARD POWER SYSTEMS INC. reassignment BALLARD POWER SYSTEMS INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: UNITED TECHNOLOGIES CORPORATION
Assigned to UTC FUEL CELLS, LLC reassignment UTC FUEL CELLS, LLC CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: INTERNATIONAL FUEL CELLS, LLC
Assigned to AUDI AG reassignment AUDI AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BALLARD POWER SYSTEMS INC.
Assigned to AUDI AG reassignment AUDI AG CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEE ADDRESS PREVIOUSLY RECORDED AT REEL: 035728 FRAME: 0905. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: BALLARD POWER SYSTEMS INC.
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04156Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying with product water removal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

A gas stream moisture condenser assembly for use in a fuel cell power plant includes a gas stream flow path which is formed from a monolithic open cell foam body. The foam body is preferably formed from a high temperature material such as stainless steel, nickel alloys and iron-aluminum alloys, or from a ceramic material. The foam body includes open cells or pores which are contained within a metal or ceramic lattice. Coolant tubes are in contact with the foam monolith so as to cool the lattice sufficiently to cause moisture in the gas stream to condense on a lattice surrounding the pores of the foam. The condensate migrates from the foam lattice into a reservoir. The condenser can be used to remove water from gas streams, such as a cathode exhaust stream or a mixed burner and cathode exhaust stream, of a fuel cell power plant.

Description

TECHNICAL FIELD
This invention relates to a moist gas stream condenser assembly. More particularly, this invention relates to a condenser assembly which employs a gas stream flow path formed from a monolithic open cell foam component, the cells or pores of which form a high surface area flow path through which the moist gas stream passes. The open cell foam component includes a monolithic lattice which frames all of the cells in the foam and which serves as a heat transfer body. The foam component has a plurality of coolant passage tubes embedded inside of the foam which serve to cool the lattice and thus cause moisture in the gas stream to condense in the cells of the foam component.
BACKGROUND ART
U.S. Pat. No. 4,344,850, granted Aug. 17, 1982 describes a fuel cell power plant assembly which includes a condenser for removing Water from a cathode exhaust gas stream. The condenser receives the moist cathode exhaust gas stream and passes the exhaust gas stream over a coolant coil whereupon a portion of the moisture in the exhaust gas stream condenses out of the gas stream and settles into a water reservoir. The water thus collected is used to cool the fuel cell power plant active areas to prevent overheating of the fuel cell stack in the power plant and is also used to produce steam for a fuel gas steam reformer in the power plant. The coolant which is used in the condenser is air which is blown over the cathode exhaust stream. While the aforesaid condenser is servicable, it would be desirable to provide an increase in the cooled surface area on which the water will condense, and it would be desirable to be able to use other coolants in addition to air.
DISCLOSURE OF THE INVENTION
This invention relates to a condenser assembly which provides an increased surface area on which water can condense in the condenser, and which may be used with coolants other than air, although air may also be used as the coolant. The condenser may be used to condense water out of a moist gas stream in a fuel cell power plant, or may be used to condense water out of other types of moist gas streams. The condenser includes a very large surface area moist gas stream flow path which is cooled by a coolant fluid. The large surface area flow path is formed by a light weight monolithic open cell foam block, or a plurality of such foam blocks. The foam includes a plurality of interconnected open cells or pores which are contained in a lattice. The lattice is made from a highly efficient heat transfer material such as aluminum, stainless steel, aluminum-steel alloys, silicon carbide, nickel alloys, carbon, graphite, ceramics, or some similar suitable heat transfer material. The coolant is contained in tubes which are in direct contact with the foam monolith. To accomplish this, the tubes may be embedded in the foam monolith, or which may be sandwiched between adjacent foam monolith blocks. The coolant thus passes through the gas stream flow path and cools the lattice which forms a component of the gas stream flow path. Water will thus condense out of the moist gas stream onto the high surface area lattice in the gas stream flow path. The condensate can then fall by gravity or by other means into a reservoir adjacent to the condenser gas stream flow path. Coolants such as air, glycol, or the like can be utilized in the condenser assembly. When air is the coolant of choice, the coolant tubes may also be filled with the open cell foam in order to enhance heat transfer from the air stream to the coolant tubes.
It is therefore an object of this invention to provide an improved condenser assembly for condensing water or some other liquid out of a moist gas stream.
It is a further object of this invention to provide a condenser assembly of the character described which has an enhanced condensing surface area located in a gas flow path through which the moist gas stream is directed.
It is another object of this invention to provide a condenser assembly of the character described which includes a large surface area cooled open cell foam monolith through which the moist gas stream flows.
It is yet another object of this invention to provide a condenser assembly of the character described which includes one or more coolant fluid conduits which are in heat exchange contact with a lattice portion of the open cell foam monolith, the lattice portion forming a moisture condensing surface in the condenser.
BRIEF DESCRIPTION OF THE DRAWINGS
These and other objects and advantages of this invention will become readily apparent to one skilled in the art from the following detailed description of a preferred embodiment of the invention when taken in conjunction with the accompanying drawings in which:
FIG. 1 is a schematic view of a fuel cell power plant system which includes one embodiment of a condenser which is formed in accordance with this invention and which is used for condensing water out of a cathode exhaust gas stream; and
FIG. 2 is a perspective view on an open cell foam monolith of the type used in the condenser, and showing the manner in which the coolant fluid conduits can be arranged in heat exchange contact with a lattice component of the foam monolith.
SPECIFIC MODE FOR CARRYING OUT THE INVENTION
Referring now to the drawings, there is shown in FIG. 1 a schematic illustration of a fuel cell power plant denoted generally by the numeral 2, which includes a power section 4 having an electrolyte 6 sandwiched between an anode 8 and a cathode 10. A fuel source 12 is connected to a burner 14 which provides heat to a steam reformer 16 that converts a hydrocarbon fuel from a source 18 thereof to a hydrogen-rich gas which is fed into the anode side 8 of the power section 4 of the power plant 2. Air from a source 20 thereof is fed into the cathode side 10 of the power section 4 to provide oxygen for the reaction. The hydrogen and oxygen are converted to electrons and water in the power section 4. The product water from the reaction is vented from the power section, at least in part, in the cathode exhaust stream via line 22 which leads to a condenser assembly 24. The condenser assembly 24 contains a monolithic open cell foam body 26 through which the cathode exhaust gas stream flows. A plurality of coolant tubes 28 are disposed in heat exchange relationship with the foam body 26 and are operable to cool the foam body 26.
Referring to FIG. 2, details of the foam body 26 and coolant tubes 28 are disclosed. The foam body 26 includes a pervasive lattice 30 which defines a matrix of open cells 32. The cells 32 are open to each other in the X, Y and Z directions so as to form a very diffuse gas flow pattern for any gas flowing through the foam 26. The coolant tubes 28 are hollow tubes through which a coolant such as air, glycol, or the like flows. The foam 26 may be formed around the tubes 28, or the tubes 28 may be samdwiched between adjacent blocks of the foam. When air is the coolant, there can be open cell foam rods inserted inside the tubes 28 to aid in heat transfer between the air coolant and the wall of the tubes 28, as shown in coolant tube 28′.
The condenser operates as follows. The moist cathode exhaust gas flows through the open cells 32 of the foam body 26 and the coolant stream flows through the coolant tubes 28. The lattice 30 in the foam body 26 is cooled to a temperature below the condensing temperature of the moisture in the cathode exhaust gas stream and the moisture thus condenses out of the gas stream onto the lattice 30. The condensate then simply drips down under the influence of gravity into a reservoir 34 (see FIG. 1) in the condenser assembly 24. The recovered water from the reservoir 34 can then be used as a coolant for the power plant 2 or as a source of steam for the steam reformer 16, or both. Monolith foams of the type described above can be obtained from Porvair Advanced Material, Inc., Hendersonville, N.C.
It will be noted that the specific system shown in FIG. 1 utilizes the condenser assembly of this invention to condense water out of a moist cathode exhaust gas stream in a fuel cell power plant assembly. It will be readily appreciated that the condenser assembly of this invention could readily be used to condense water out of any moist gas stream, such as an anode exhaust, or a burner exhaust, which is directed through the open cell foam gas flow member of the condenser assembly.
Since many changes and variations of the disclosed embodiment of the invention may be made without departing from the inventive concept, it is not intended to limit the invention other than as required by the appended claims.

Claims (4)

What is claimed is:
1. A condenser assembly for condensing water out of a moist gas stream, said assembly comprising:
a) a monolithic open cell foam body which forms a gas flow path for the moist gas stream, said foam body including a thermally conductive lattice which defines a matrix of open cells throughout the foam body;
b) one or more coolant conduits in contact with said foam body such that each of said coolant conduits including an outer wall which contacts said thermally conductive lattice;
c) means for directing the moist gas stream into said open cells in said foam body; and
d) means for directing a coolant fluid into said coolant conduits whereby said themally conductive lattice is cooled thereby causing said themally conductive lattice to cool so as to condense water out of the moist gas stream.
2. The condenser assembly of claim 1 wherein said coolant conduits include an internal open cell foam lattice which contacts said outer wall and through which the coolant fluid flows.
3. A method for condensing water out of a moist gas stream, said method comprising the steps of:
a) passing the moist gas stream through a monolithic open cell foam body, said foam body including a thermally conductive lattice which defines a matrix of open cells throughout the foam body through which cells the moist gas stream flows; and
b) passing a coolant fluid through one or more coolant conduits which are in contact with said foam body such that each of said coolant conduits including an outer wall which contacts said thermally conductive lattice whereby said thermally conductive lattice is cooled sufficiently to condense water out of the moist gas stream and into said open cells.
4. The method of claim 3 wherein said coolant conduits include internal open cell foam components which contact the outer walls of said coolant conduits and are operative to enhance thermal transfer from said coolant fluid to said outer walls of said coolant conduits.
US09/866,994 2001-05-29 2001-05-29 Compact light weight condenser assembly Expired - Fee Related US6537351B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US09/866,994 US6537351B2 (en) 2001-05-29 2001-05-29 Compact light weight condenser assembly
DE10296877T DE10296877T5 (en) 2001-05-29 2002-05-07 Compact, lightweight capacitor arrangement
JP2002593060A JP3991101B2 (en) 2001-05-29 2002-05-07 Compact and lightweight condenser assembly
PCT/US2002/014425 WO2002096556A1 (en) 2001-05-29 2002-05-07 Compact light weight condenser assembly

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/866,994 US6537351B2 (en) 2001-05-29 2001-05-29 Compact light weight condenser assembly

Publications (2)

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US20020178920A1 US20020178920A1 (en) 2002-12-05
US6537351B2 true US6537351B2 (en) 2003-03-25

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US09/866,994 Expired - Fee Related US6537351B2 (en) 2001-05-29 2001-05-29 Compact light weight condenser assembly

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US (1) US6537351B2 (en)
JP (1) JP3991101B2 (en)
DE (1) DE10296877T5 (en)
WO (1) WO2002096556A1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030175201A1 (en) * 2000-01-24 2003-09-18 Klett James W. Humidifier for fuel cell using high conductivity carbon foam
US20100043289A1 (en) * 2008-08-20 2010-02-25 England Diane M Fuel cell reformer
US20130146250A1 (en) * 2011-12-08 2013-06-13 Lockheed Martin Corporation System and method for desalination of water using a graphite foam material
WO2015089191A1 (en) * 2013-12-10 2015-06-18 Eco Squared Solutions, Inc. System and apparatus for atmospheric water generation using alternate cold sources
US9464847B2 (en) 2011-02-04 2016-10-11 Lockheed Martin Corporation Shell-and-tube heat exchangers with foam heat transfer units
US9513059B2 (en) 2011-02-04 2016-12-06 Lockheed Martin Corporation Radial-flow heat exchanger with foam heat exchange fins
US9951997B2 (en) 2011-02-04 2018-04-24 Lockheed Martin Corporation Staged graphite foam heat exchangers

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100708693B1 (en) * 2005-06-24 2007-04-18 삼성에스디아이 주식회사 Direct liquid feed fuel cell stack
KR100700547B1 (en) * 2005-08-23 2007-03-28 엘지전자 주식회사 Fuel cell system
CN101331081A (en) * 2005-12-16 2008-12-24 国际壳牌研究有限公司 Process for cooling down a hot flue gas stream
KR100784017B1 (en) 2006-11-20 2007-12-07 삼성에스디아이 주식회사 Non-reactive fuel recycling device and fuel cell system possessing it
WO2013138249A2 (en) * 2012-03-12 2013-09-19 Nuvera Fuel Cells, Inc. Cooling system and method for use with a fuel cell

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US5105430A (en) * 1991-04-09 1992-04-14 The United States Of America As Represented By The United States Department Of Energy Thin planar package for cooling an array of edge-emitting laser diodes
US5105429A (en) * 1990-07-06 1992-04-14 The United States Of America As Represented By The Department Of Energy Modular package for cooling a laser diode array
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US5131233A (en) * 1991-03-08 1992-07-21 Cray Computer Corporation Gas-liquid forced turbulence cooling
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US5453641A (en) * 1992-12-16 1995-09-26 Sdl, Inc. Waste heat removal system
US6140266A (en) 1999-02-18 2000-10-31 International Fuel Cells, Co., Llc Compact and light weight catalyst bed for use in a fuel cell power plant and method for forming the same

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Publication number Priority date Publication date Assignee Title
US5126829A (en) * 1988-09-26 1992-06-30 Hitachi, Ltd. Cooling apparatus for electronic device
US5179500A (en) * 1990-02-27 1993-01-12 Grumman Aerospace Corporation Vapor chamber cooled electronic circuit card
US5105429A (en) * 1990-07-06 1992-04-14 The United States Of America As Represented By The Department Of Energy Modular package for cooling a laser diode array
US5131233A (en) * 1991-03-08 1992-07-21 Cray Computer Corporation Gas-liquid forced turbulence cooling
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US6140266A (en) 1999-02-18 2000-10-31 International Fuel Cells, Co., Llc Compact and light weight catalyst bed for use in a fuel cell power plant and method for forming the same

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030175201A1 (en) * 2000-01-24 2003-09-18 Klett James W. Humidifier for fuel cell using high conductivity carbon foam
US7147214B2 (en) * 2000-01-24 2006-12-12 Ut-Battelle, Llc Humidifier for fuel cell using high conductivity carbon foam
US20100043289A1 (en) * 2008-08-20 2010-02-25 England Diane M Fuel cell reformer
US7976787B2 (en) 2008-08-20 2011-07-12 Delphi Technologies, Inc. Fuel cell reformer
US9464847B2 (en) 2011-02-04 2016-10-11 Lockheed Martin Corporation Shell-and-tube heat exchangers with foam heat transfer units
US9513059B2 (en) 2011-02-04 2016-12-06 Lockheed Martin Corporation Radial-flow heat exchanger with foam heat exchange fins
US9951997B2 (en) 2011-02-04 2018-04-24 Lockheed Martin Corporation Staged graphite foam heat exchangers
US20130146250A1 (en) * 2011-12-08 2013-06-13 Lockheed Martin Corporation System and method for desalination of water using a graphite foam material
WO2015089191A1 (en) * 2013-12-10 2015-06-18 Eco Squared Solutions, Inc. System and apparatus for atmospheric water generation using alternate cold sources
US10350512B2 (en) 2013-12-10 2019-07-16 Eco Squared Solutions, Inc. System and apparatus for atmospheric water generation using alternate cold sources

Also Published As

Publication number Publication date
DE10296877T5 (en) 2004-10-14
US20020178920A1 (en) 2002-12-05
WO2002096556A1 (en) 2002-12-05
JP2005509122A (en) 2005-04-07
JP3991101B2 (en) 2007-10-17

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