US4963287A - Aqueous alkali metal halogenite compositions - Google Patents
Aqueous alkali metal halogenite compositions Download PDFInfo
- Publication number
- US4963287A US4963287A US07/267,650 US26765088A US4963287A US 4963287 A US4963287 A US 4963287A US 26765088 A US26765088 A US 26765088A US 4963287 A US4963287 A US 4963287A
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- US
- United States
- Prior art keywords
- composition
- perfume
- alkyl
- sulfonates
- anionic surfactant
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
TABLE 1 ______________________________________ SURFACTANTS TESTED Activity, Trade Name % Chemical Name ______________________________________ Anionic Surfactants: Sipon ES 27 Sodium lauryl ether sulfonate Bioterge AS-40 40 Sodium alpha olefin sulfonate Udet 92 Alkyl aryl sulfonate Sipon WD 30 Sodium lauryl sulfate Dowfax 3B2 45 Sodium n-decyldiphenyloxi- dedisulfonate Maprosyl 30 30 Sodium lauroyl sarcosinate Nonionic Surfactants: Triton N-101 100 Nonylphenoxypolyethoxy ethanol w/9.5 mols EO Surfonic J-4 100 Alkyl polyoxyalkylene ether Neodol 91-8 100 C9-C11 linear primary alcohol ethoxylate w/8 mol EO Igepal CO-630 100 Nonylphenoxy poly(ethyleneoxy) ethanol w/9 mol EO Clindrol 200CGN 100 Coconut oil diethanolamide ______________________________________
TABLE 2 ______________________________________ PERFUMES TESTED Perfume Type Manufacturer ______________________________________ Dragoco 0/710531 Fresh & Clean Dragoco, Inc. Florasynth S-1923 Floral Florasynth, Inc. BBA 860416 Green BBA Co., Inc. Florasynth T-4608 Fruity (Green Apple) Florasynth, Inc. BBA 871523 Citrus BBA Co., Inc. Dragoco 0/712227 Pine Dragoco, Inc. Lautier LA-79-1946 Powder Room Lautier ______________________________________
TABLE 3 ______________________________________ STORAGE TEST RESULTS ______________________________________ Part A: Anionic Surfactants Ex- am- ple Days to Form No. Surfactant Perfume Chlorine Dioxide 1 Sipon ES Dragoco 0/710531 >26 2 " Florasynth S-1923 5 3 " BBA 860416 18 4 " Florasynth T-4608 5 5 " BBA 871523 >26 6 " Dragoco 0/712227 >26 7 " Lautier LA-79-1946 >26 8 Bioterge Dragoco 0/710531 >26 AS-40 9 Bioterge Florasynth S-1923 >26 AS-40 10 Bioterge BBA 860416 >26 AS-40 11 Bioterge Florasynth T-4608 >26 AS-40 12 Bioterge BBA 871523 >26 AS-40 13 Bioterge Dragoco 0/712227 >26 AS-40 14 Bioterge Lautier LA-79-L946 >26 AS-40 15 Udet-950 Dragoco 0/710531 >26 16 " Florasynth S-1923 4 17 " BBA 860416 >26 18 " Florasynth T-4608 5 19 " BBA 871523 20 " Dragoco 0/712227 between 23 and 26 " Lautier LA-79-1946 >26 22 Sipon WD Dragoco 0/710531 >26 23 " Florasynth S-1923 5 24 " BBA 860416 >26 25 " Florasynth T-4608 18 26 " BBA 871523 >26 27 " Dragoco 0/712227 >26 28 " Lautier LA-79-1946 >26 29 Dowfax 3B2 Dragoco 0/619531 >26 30 " Florasynth S-1923 5 31 " BBA 860416 >26 32 " Florasynth T-4608 5 33 " BBA 871523 >26 34 " Dragoco 0/712227 >26 35 " Lautier LA-79-1946 between 23 and 26 36 Maprosyl 30 Dragoco 0/710531 >26 37 " Florasynth S-1923 between 9 and 11 38 " BBA 860416 >26 39 " Florasynth T-4608 14 40 " BBA 871523 >26 41 " Dragoco 0/712227 >26 42 " Lautier LA-79-1946 >26 Part B: Nonionic Surfactants Ex- am- ple Nonionic Days to Produce No. Surfactant Perfume Chlorine Dioxide 43 Triton N-101 Dragoco 0/710531 between 23 and 26 44 " Florasynth S-1923 4 45 " BBA 860416 between 23 and 26 46 " Florasynth T-4608 4 47 " BBA 871523 4 48 " Dragoco 0/712227 between 23 and 26 49 " Lautier LA-79-1946 >26 50 Surfonic J-4 Dragoco 0/710531 >26 51 " Florasynth S-1923 4 52 " BBA 860416 >26 53 " Florasynth T-4608 4 54 " BBA 871523 5 55 " Dragoco 0/712227 >26 56 " Lautier LA-79-1946 >26 57 Neodol 91-8 Dragoco 0/710531 18 58 " Florasynth S-1923 4 59 " BBA 860416 18 60 " Florasynth T-460B 4 61 " BBA 871523 5 62 " Dragoco 0/712227 between 23 and 26 63 " Lautier LA-79-1946 >26 64 Igepal CO-630 Dragoco 0/710531 >26 65 " Florasynth S-1923 4 66 " BBA 860416 >26 67 " Florasynth T-4608 4 68 " BBA 871523 5 69 " Dragoco 0/712227 >26 70 " Lautier LA-79-1946 >26 71 Clindrol 200CGN Dragoco 0/710531 >26 72 " Florasynth S-1923 between 9 and 11 73 " BBA 860416 >26 74 " Florasynth T-4608 19 75 " BBA 871523 5 76 " Dragoco 0/712227 >26 77 " Lautier LA-79-1946 >26 ______________________________________
TABLE 4 ______________________________________ Surf. Conc. Example Nos. (Wt. % Group A Group B Group C Surfactant Active) ______________________________________ 78 87 97 Bioterge 2 79 88 98 Sipon WD 5 80 89 99 Flourad FC-129.sup.(1) 0.025 81 90 100 Triton X-100 5 82 91 101 Surfonic J-4 5 83 92 102 Flourad FC-171.sup.(2) 0.05 84 93 103 Igepal CO-630 5 85 94 104 Neodol 25-9.sup.(3) 5 86 95 105 BTC 2125M.sup.(4) 2.5 96 106 Dowfax 3B2 2.25 ______________________________________ .sup.(1) Anionic fluorocarbon surfactant manufactured by 3M Company; abou 50% active. .sup.(2) Nonionic fluorocarbon surfactant manufactured by 3M Company; 100 active. .sup.(3) C.sub.12 -C.sub.15 linear primary alcohol ethoxylate w/9 mol EO per molecule manufactured by Shell Chemical Company; 100% active. .sup.(4) Cationic surfactant mixture of dodecyl dimethyl ethylbenzyl and myristyl dimethyl benzyl ammonium chlorides manufactured by Onyx Chemical Co.; about 50% active.
TABLE 5 ______________________________________ Concentration, Wt. % Constituent 107 108 109 ______________________________________ Sodium chlorite 1.6 1.6 1.6 Alpha olefin sulfonate 6 6 6 Sodium borate 1 1 1 Sodium carbonate 1 1 0 Perfume per Examples 78-86 0.25 0.25 0.1 Dye 0.66 2 0.67 Water (By difference) ______________________________________
Claims (22)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/267,650 US4963287A (en) | 1987-05-26 | 1988-11-01 | Aqueous alkali metal halogenite compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5433887A | 1987-05-26 | 1987-05-26 | |
US07/267,650 US4963287A (en) | 1987-05-26 | 1988-11-01 | Aqueous alkali metal halogenite compositions |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US5433887A Continuation-In-Part | 1987-05-26 | 1987-05-26 |
Publications (1)
Publication Number | Publication Date |
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US4963287A true US4963287A (en) | 1990-10-16 |
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ID=26732912
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/267,650 Expired - Lifetime US4963287A (en) | 1987-05-26 | 1988-11-01 | Aqueous alkali metal halogenite compositions |
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US (1) | US4963287A (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5346089A (en) * | 1992-07-20 | 1994-09-13 | Brown Richard S | Produce packaging and methods of sealing same |
US6048836A (en) * | 1996-07-16 | 2000-04-11 | The Procter & Gamble Company | Use of a combination of surfactants, chelating agents and essential oils for effective disinfection |
US6189299B1 (en) | 1998-03-10 | 2001-02-20 | Fresh Express, Inc | Apparatus for cooling and packaging bulk fresh products |
US6196237B1 (en) | 1998-09-01 | 2001-03-06 | Fresh Express Corp. | Methods for washing cores of cored lettuce heads |
US6255267B1 (en) | 1996-03-04 | 2001-07-03 | Hpd Laboratories, Inc. | Manual toilet bowl cleaner |
US6358469B1 (en) | 1998-12-01 | 2002-03-19 | S. C. Johnson & Son, Inc. | Odor eliminating aqueous formulation |
US6379731B1 (en) | 2000-02-18 | 2002-04-30 | Fresh Express, Inc. | Methods for vacuum gas flush treatment of fresh produce |
US6435347B1 (en) | 2000-02-18 | 2002-08-20 | Fresh Express, Incorporated | Container for freshly harvested respiring, leafy produce |
US6467248B2 (en) | 2000-02-18 | 2002-10-22 | Fresh Express, Inc. | Method for processing freshly harvested leafy vegetables and subdivided, peeled fruit |
US6582682B2 (en) * | 2000-10-30 | 2003-06-24 | Noville, Inc. | Oral care compositions comprising stabilized chlorine dioxide |
US20030180247A1 (en) * | 2001-05-16 | 2003-09-25 | Alcide Corporation | Two-part disinfecting systems and compositions and methods relating thereto |
US6679276B1 (en) | 1999-04-20 | 2004-01-20 | Fresh Express, Inc. | Apparatus and methods for washing the cored areas of lettuce heads during harvest |
US20050184273A1 (en) * | 2001-05-16 | 2005-08-25 | Ecolab Inc. | Acidified chlorite disinfectant compositions with olefin stabilizers |
US7278433B1 (en) | 2003-02-20 | 2007-10-09 | Dole Fresh Vegetables, Inc. | Washing a cored lettuce head |
US20080008621A1 (en) * | 2004-11-24 | 2008-01-10 | Maruishi Pharmaceutical Co., Ltd. (80%) | Hypochlorous Acid Based Sterilizing Composition |
WO2009021557A1 (en) * | 2007-08-16 | 2009-02-19 | Ecolab Inc. | Aqueous composition for inactivating sporulated and/or non-sporulated coccidian parasites |
EP2099296B1 (en) | 2006-12-04 | 2015-10-21 | S.K. Pharmaceuticals, Inc. | Synergistic antimicrobial preparations containing chlorite and hydrogen peroxide |
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US3271242A (en) * | 1963-03-29 | 1966-09-06 | Alexander R Reed Iii | Stable chlorine dioxide composition and method of making same |
US3386915A (en) * | 1964-03-18 | 1968-06-04 | Solvay | Process for the manufacturing of chlorine dioxide in solution and the use of the solution thus obtained |
US3537894A (en) * | 1968-10-08 | 1970-11-03 | Nalco Chemical Co | Method for cleaning oven walls |
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US3914185A (en) * | 1973-03-15 | 1975-10-21 | Colgate Palmolive Co | Method of preparing liquid detergent compositions |
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US4073888A (en) * | 1974-06-18 | 1978-02-14 | Pettibone Laboratories, Inc. | Chlorine dioxide and quaternary ammonium salts as sterilizing agents |
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USRE31779E (en) * | 1976-03-26 | 1984-12-25 | Alcide Corporation | Germ-killing composition and method |
US4499077A (en) * | 1981-02-03 | 1985-02-12 | Stockel Richard F | Anti-microbial compositions and associated methods for preparing the same and for the disinfecting of various objects |
US4511489A (en) * | 1983-06-01 | 1985-04-16 | The Drackett Company | Composition for cleaning and imparting antistatic properties to plastics surfaces |
EP0142883A2 (en) * | 1983-11-04 | 1985-05-29 | The Procter & Gamble Company | Hypochlorite bleach compositions containing optical brighteners |
EP0159923A2 (en) * | 1984-04-19 | 1985-10-30 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
US4587032A (en) * | 1984-11-06 | 1986-05-06 | Mobil Oil Corporation | Drain cleaner |
EP0204472A2 (en) * | 1985-05-28 | 1986-12-10 | The Procter & Gamble Company | Cleaning compositions |
JPS62109900A (en) * | 1985-11-07 | 1987-05-21 | 花王株式会社 | Aromatic liquid bleaching composition |
US4690772A (en) * | 1985-06-03 | 1987-09-01 | National Medical Care | Sterilant compositions |
US4692277A (en) * | 1985-12-20 | 1987-09-08 | The Procter & Gamble Company | Higher molecular weight diols for improved liquid cleaners |
US4790950A (en) * | 1988-03-07 | 1988-12-13 | The Drackett Company | Aqueous alkali metal halogenite compositions containing a colorant stabilized by NH4 OH |
US4861514A (en) * | 1988-06-08 | 1989-08-29 | The Drackett Company | Compositions containing chlorine dioxide and their preparation |
US4873013A (en) * | 1988-03-07 | 1989-10-10 | The Dracket Company | Aqueous alkali metal halogenite compositions containing a colorant stabilized by ammonium hydroxide |
US4880566A (en) * | 1985-12-23 | 1989-11-14 | Henkel Kommanditgesellschaft Auf Aktien | Silicate-and magnesium-free stabilizer mixtures |
-
1988
- 1988-11-01 US US07/267,650 patent/US4963287A/en not_active Expired - Lifetime
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US3123521A (en) * | 1964-03-03 | |||
US2145062A (en) * | 1930-04-17 | 1939-01-24 | Mathieson Alkali Works Inc | Bleaching of cellulosic materials |
US2071091A (en) * | 1936-07-13 | 1937-02-16 | Mathieson Alkali Works Inc | Chemical manufacture |
US2253368A (en) * | 1938-12-24 | 1941-08-19 | Mathieson Alkali Works Inc | Simultaneously scouring and bleaching with chlorite |
US2358866A (en) * | 1943-08-13 | 1944-09-26 | Mathieson Alkali Works Inc | Acid aqueous solutions of chlorites |
US2477631A (en) * | 1945-02-21 | 1949-08-02 | Ecusta Paper Corp | Catalytic bleaching with chlorites |
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US2711363A (en) * | 1949-12-27 | 1955-06-21 | Hoechst Ag | Bleaching and disinfecting agents |
US2900219A (en) * | 1954-09-09 | 1959-08-18 | Hoechst Ag | Bleaching process by means of chlorites |
US3065040A (en) * | 1957-09-24 | 1962-11-20 | Hoechst Ag | Textile bleaching process using chlorite bleaching baths |
US2988514A (en) * | 1958-06-11 | 1961-06-13 | Olin Mathieson | Bleaching composition and method |
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US3591515A (en) * | 1968-04-16 | 1971-07-06 | Int Dioxide Inc | Pulverulent chlorine dioxide compositions |
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US3547573A (en) * | 1968-11-29 | 1970-12-15 | Air Liquide | Process for the bleaching of textiles |
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US3790343A (en) * | 1971-12-10 | 1974-02-05 | S Ikeda | Method for bleaching fibrous materials and compositions therefor |
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US3914185A (en) * | 1973-03-15 | 1975-10-21 | Colgate Palmolive Co | Method of preparing liquid detergent compositions |
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US4073888A (en) * | 1974-06-18 | 1978-02-14 | Pettibone Laboratories, Inc. | Chlorine dioxide and quaternary ammonium salts as sterilizing agents |
US4084747A (en) * | 1976-03-26 | 1978-04-18 | Howard Alliger | Germ killing composition and method |
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EP0159923A2 (en) * | 1984-04-19 | 1985-10-30 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
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EP0204472A2 (en) * | 1985-05-28 | 1986-12-10 | The Procter & Gamble Company | Cleaning compositions |
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JPS62109900A (en) * | 1985-11-07 | 1987-05-21 | 花王株式会社 | Aromatic liquid bleaching composition |
US4692277A (en) * | 1985-12-20 | 1987-09-08 | The Procter & Gamble Company | Higher molecular weight diols for improved liquid cleaners |
US4880566A (en) * | 1985-12-23 | 1989-11-14 | Henkel Kommanditgesellschaft Auf Aktien | Silicate-and magnesium-free stabilizer mixtures |
US4790950A (en) * | 1988-03-07 | 1988-12-13 | The Drackett Company | Aqueous alkali metal halogenite compositions containing a colorant stabilized by NH4 OH |
US4873013A (en) * | 1988-03-07 | 1989-10-10 | The Dracket Company | Aqueous alkali metal halogenite compositions containing a colorant stabilized by ammonium hydroxide |
US4861514A (en) * | 1988-06-08 | 1989-08-29 | The Drackett Company | Compositions containing chlorine dioxide and their preparation |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5346089A (en) * | 1992-07-20 | 1994-09-13 | Brown Richard S | Produce packaging and methods of sealing same |
US6255267B1 (en) | 1996-03-04 | 2001-07-03 | Hpd Laboratories, Inc. | Manual toilet bowl cleaner |
US6048836A (en) * | 1996-07-16 | 2000-04-11 | The Procter & Gamble Company | Use of a combination of surfactants, chelating agents and essential oils for effective disinfection |
US6189299B1 (en) | 1998-03-10 | 2001-02-20 | Fresh Express, Inc | Apparatus for cooling and packaging bulk fresh products |
US6196237B1 (en) | 1998-09-01 | 2001-03-06 | Fresh Express Corp. | Methods for washing cores of cored lettuce heads |
US6276375B1 (en) | 1998-09-01 | 2001-08-21 | Fresh Express, Inc. | Apparatus and methods for washing cores of cored lettuce heads |
US6358469B1 (en) | 1998-12-01 | 2002-03-19 | S. C. Johnson & Son, Inc. | Odor eliminating aqueous formulation |
US6679276B1 (en) | 1999-04-20 | 2004-01-20 | Fresh Express, Inc. | Apparatus and methods for washing the cored areas of lettuce heads during harvest |
US6379731B1 (en) | 2000-02-18 | 2002-04-30 | Fresh Express, Inc. | Methods for vacuum gas flush treatment of fresh produce |
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