|Publication number||US4470884 A|
|Application number||US 06/291,116|
|Publication date||11 Sep 1984|
|Filing date||7 Aug 1981|
|Priority date||7 Aug 1981|
|Publication number||06291116, 291116, US 4470884 A, US 4470884A, US-A-4470884, US4470884 A, US4470884A|
|Original Assignee||National Ano-Wire, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (12), Referenced by (25), Classifications (12), Legal Events (7)|
|External Links: USPTO, USPTO Assignment, Espacenet|
1. Field of the Invention
This invention relates to wire anodizing, and, more particularly, to a high speed aluminum wire anodzing machine and process.
2. Description of the Prior Art
In recent years, there has been a rapid increase in the commercial use of anodized aluminum wire, strip stock and the like. This is especially true in the electrical equipment industry as a substitute for increasingly expensive copper wire. In addition, the dielectric properties of the anodizing have been found to be preferred over other types of dielectric wire coatings.
In the anodizing of aluminum wire and the like, a protective oxide film is formed on the metal by passing an electric current through a bath or eletrolyte in which the metal is suspended and through which it passes. Although the general process of anodizing is well known and in commercial use, current methods are slow and problematical. For example, one of the most common means of anodizing aluminum wire and the like is to pass the wire through a very long anodizing tank. In order to achieve sufficient retention time of the the wire in the tank to yield the desired anodized coating, the wire is run very slowly through the tank at a speed on the order of 20 feet per minute. Because of the very slow speed of this process, the cost of anodized wire produced by this type of process is unduly high.
Although attempts have been made to speed up the process of anodizing aluminum wire and the like, the results have been unsatisfactory. For example, the anodizing resulting from these attempts at increasing the speed of the process have included cracking and flaking of the anodizing, poor adherence, and incomplete coverage and eratic coating thicknesses.
Accordingly, there is a current need for a high speed means to anodize alumunum wire which will produce uniform anodized coating with complete wire coverage.
According to the present invention, there is provided a high speed aluminum wire anodizing machine and process which will produce uniform anodizing coatings with complete wire coverage with significant cost savings. Wire speeds of on the order of 1,000 feet per minute and higher are achievable with the unique machine and process of the present invention.
The process of the present invention includes anodizing alumunum wire and the like in a unique anodizing machine which includes a wire anodizing tank which has wire ingress and egress openings. An anode is provided proximal to the wire ingress opening, preferably in a contact cell which has an adjustable wire window to permit wire to continuously pass from the contact cell to wire accumulator drums in the anodizer tank.
At least two adjacent rotatable wire accumulator drums are provided in the tank with the axes of rotation of the drums in parallel alignment. Preferably, the accumulator drums are generally hollow and include end hubs on each end of the drums. Each drum has plurality of circumferential wire separators on the outer periphery of the sidewall of the drum and means for producing a flow of anodizing electrolyte into each drum through at least one of the end hubs and out of the sidewall of the drums past the wire separators. The preferred flow producing means includes at least one radial slot in at least one end hub in each of the drums with an external angled radial pumping vane adjacent to the slot. The sidewall of each drum comprises a plurality of spaced slanted support bars extending between the hubs perpendicular thereto.
FIG. 1 is a schematic flow diagram of a complete wire anodizing process utilizing the unique high speed wire anodizing machine of the present invention;
FIG. 2 is a side cross-sectional elevational view of the wire anodizing machine;
FIG. 3 is a cross-sectional elevational view of the anodizing machine taken along the line III--III of FIG. 2;
FIG. 4 is a cross-sectional view of a wire accumulator drum with a portion of the support bars shown;
FIG. 5 is a fragmentary cross-sectional view of the accumulator drum;
FIG. 6 is a fragmentary cross-sectional view of the accumulator drum showing the wire separators. and
FIG. 7 is end view of an accumulator drum sidewall support bar and a portion of the wire separators.
FIG. 1 is a schematic flow diagram of a complete wire anodizing process utilizing the unique high speed wire anodizing machine of the present invention. Although the process and machine will be described in terms of anodizing aluminum wire, it should be understood that the process and machine are also useful for other forms of aluminum such as strip stock and for electroplating other types of wires, strip stock and the like. Accordingly, the discussion in terms of anodizing aluminum wire is not to be construed as limiting the scope of the process and machine of the present invention.
As shown in FIG. 1, a spool of aluminum wire 10 is rotatably mounted on unwiding stand 11. Wire 10 passes over a conventional tensioning take-up roller 12 to maintain the proper tension on wire 10 as it is unwound from the spool.
Wire 10 is then passed through soap and caustic wash tank 20 in a conventional manner to strip oil and oxides from the surface of the wire. Preferably, a trisodium phosphate or equivalent soap is preferred. The caustic is preferably a mild solution of sodium hydroxide with a concentration of about 5% or less. Further, the wash tank solution should be maintained at elevated temperatures on the order of 180° F. Wire 10 is then passed over a second tensioning take-up roller 31 before entering anodizing machine 40, which will be explained in greater detail hereinafter.
Upon exiting anodizing tank 40, wire 10 passes over roller 70 into a cold water rise tank 71 with the temperature preferably at about 60° and 70° F. Wire 10 then passes over a third tensioning take-up roller 72 into hot rinse tank 73 where the temperature is maintained at about 180° F. Rinse tanks 71 and 73 function to remove all acid from the anodized wire, and the hot water in tank 73 facilitates quick drying of the wire. Wire 10 is then passed over roller 74, through hot air dryer 75 and around rollers 76 and 77 and, optionally, into a conventional sealant coating unit 78. Although any conventional sealant is suitable, preferably a zylene thinned silicone sealer is preferred to seal the pores and to prevent corrosion and staining of the anodized wire. Infrared heaters 79 are provided in unit 78 to dry the coating, and an exhaust fan 80 is provided to remove resulting fumes. The sealed anodized wire 10 is then passed over a series of rollers 81 and another tensioning take-up roller 82 before it is wound onto spool 83 as a finished product.
The unique anodizing machine 40 will now be described in greater detail. As shown in FIGS. 2 and 3, machine 40 includes anodizing tank 41 and a pair of adjacent rotatable wire accumulator drums 50. Tank 41 contains a conventional anodizing solution, which is typically an acid solution of an acid such as sulfuric, chromic or oxalic acid or the like. The preferred anodizing solution is about a 15 to 25% solution of sulfuric acid. The tank is filled with anodizing solution to solution level line 42 so that the accumulator drums 50 are submerged in solution.
The accumulator drums 50 are rotatably mounted in a conventional manner on axles 51 and are preferably motorized. When wire 10 is to follow the path shown in FIG. 2 between accumulator drums 50, both of drums 50 are rotatable in a counter-clockwise direction. However, to increase the retention time of wire 10 in tank 41, wire 10 can be made to traverse a figure eight pattern between drums 50 as shown in FIG. 1. In this case, the first drum is rotated in a clockwise direction and the second drum is rotated in a counter-clockwise direction.
The preferred accumulator drum 50 includes a pair of end hubs 52. The sidewalls of drum 50 are made of a plurality of spaced slanted support bars 56 attached to each of the hubs 52 and perpendicular thereto, the purpose of which will be explained below. A plurality of circumferential wire separators 53 are provided around support bars 56 as shown in FIG. 3. (Only a portion of the separators are shown in FIG. 3 to more clearly shown support bars 52).
In order to ensure uniform and complete coverage on wire 10, means are provided to produce a flow of anodizing electrolyte onto each of drums 50 through end hubs 52 and out of the space between support bars 56, passed wire separators 53. This is accomplished by providing a series of radial slots 54 on at least one of the end hubs 52 of each drum. External angled radial pumping vanes 55 are provided adjacent to each of slot 54. Thus, as drums 50 are rotated in the counter-clockwise direction, vanes 55 and slots 54 will act as an acid pump to draw acid into the interior of drums 50. Because of the spacing between support bars 56 and their configuration and mounting angle, as best shown in FIG. 4 and FIG. 7, the acid bath will be pumped out the sidewall of drums 50 and past wire separators 53. This pumping action serves two very important purposes. Not only does it ensure exposure of all surfaces of the wire to the anodizing fluid, it also acts to urge the wire away from touching wire separators 53 as best shown in FIG. 6. This greatly minimizes any contact between wire 10 and separators 53 or support bars 56 during anodizing to thereby avoid bare spots in the finished product.
Although a conventional anode and cathode arrangement may be utilized, it is preferred that a contact cell 60 be provided at wire ingress opening 61 to tank 41. Contact cell 60 is a fluid chamber which contains anodes 62 and an adjustable wire egress window 63. Any conventional adjustable window means can be employed for window 63 such as a sliding door, camera type shutter mechanism or the like. It has been found that if window opening 63 is adjusted to the point where bubbles appear on the wire surface, the optimum anodizing will take place. Optionally, the window can be also adjustable lengthwise to alter the distance between the anodes and the drums to optimize anodizing.
The preferred cathode means includes a center cathode 65, a series of cathode plates 66 surrounding both of drums 50, or both. Cathode plates 66 are suspended by insulated wood frame insulating members 76 in tank 41. It is especially important that cathode plates 66 be located above and below drums 60 adjacent the sidewalls of the drums. In the case of using the figure eight wire pattern shown in FIG. 1, the cathode 65 between drums 50 is eliminated.
Finally, a wire egress opening 67 is provided which leads to the rinse stage 70 of the anodizing process. In addition, a series of rollers 68 can be provided to guide wire 10 in its revolutions about drums 50.
While a variety of sizes of tanks and drums may be utilized, depending upon the particular size wire being anodized and the solutions used, it has been found that speeds in excess of 1,000 feet per minute of anodizing of the wire can be accomplished with a tank which is only about three feet deep, four feet long and four feet wide, with about one foot diameter accumulator drums approximately two feet long. For aluminum wire of approximately a 0.125 inch diameter, a retention time of about three to five minutes is required for optimum anodizing. Accordingly, with the above-described accumulator drums and tank size, the wire should be wrapped approximately 170 to 180 revolutions on each drum when running at a speed of approximately 1000 feet per minute. When larger drums are used, it may be required to use internal radial support members, such as member 58 shown partially in FIG. 5.
In terms of the electrical requirements, it has been found that between about 18 and 40 volts of DC current, with an amperage of approximately 60 to 75 amps per square foot of aluminum wire in the tank, is optimum.
While the preferred embodiments of the present invention have been described and illustrated, it will be obvious so those skilled in the art that various modifications and changes can be made without departing from the spirit of the present invention. As indicated, while the above disclosure has related to aluminum wire, aluminum strip stock and the like can also be processed according to the present invention. In addition, materials other than aluminum can be electroplated using the principles of the process and unique machine of the present invention. Accordingly, the scope of the present invention is deemed to be limited only by the appended claims when construed in terms of the equivalence discussed herein.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US1058047 *||4 Sep 1909||8 Apr 1913||Gibbs Company||Apparatus and process for making wire electrolytically.|
|US1120191 *||4 Apr 1912||8 Dec 1914||Gibbs Company||Apparatus for electrolytic production of wire.|
|US1804486 *||18 Aug 1928||12 May 1931||Wright Parvin||Apparatus for treating wires|
|US3046214 *||8 Sep 1958||24 Jul 1962||Chain Anodizers Inc||Apparatus for continuously electrolytically treating flexible articles|
|US3113094 *||23 Nov 1959||3 Dec 1963||Gen Electric||Electrodeposition cell|
|US3359190 *||4 Feb 1964||19 Dec 1967||Aluminium Lab Ltd||One-side anodizing of aluminum sheet|
|US3432407 *||1 May 1967||11 Mar 1969||Ricci Anthony J||Method of anodizing aluminum wire|
|US3629077 *||10 Jun 1970||21 Dec 1971||Sylvania Electric Prod||Process for plating of stripes on longitudinal electrically conductive material|
|US3676322 *||6 Jan 1970||11 Jul 1972||Furukawa Electric Co Ltd||Apparatus and method for continuous production of electrolytically treated wires|
|US3827951 *||22 May 1972||6 Aug 1974||Mallory & Co Inc P R||Continuous forming of anodes for capacitors|
|US3919069 *||15 Aug 1972||11 Nov 1975||Karl Neumayer Gmbh Fa||Means for plating stranded cables|
|US3959090 *||28 Jul 1975||25 May 1976||Swiss Aluminium Ltd.||Continuous electrolyte coloring of a pre-anodised aluminum foil or strip|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6261437 *||4 Nov 1997||17 Jul 2001||Asea Brown Boveri Ab||Anode, process for anodizing, anodized wire and electric device comprising such anodized wire|
|US6279850||4 Nov 1997||28 Aug 2001||Abb Ab||Cable forerunner|
|US6357688||2 Feb 1998||19 Mar 2002||Abb Ab||Coiling device|
|US6369470||4 Nov 1997||9 Apr 2002||Abb Ab||Axial cooling of a rotor|
|US6376775||27 May 1997||23 Apr 2002||Abb Ab||Conductor for high-voltage windings and a rotating electric machine comprising a winding including the conductor|
|US6396187||4 Nov 1997||28 May 2002||Asea Brown Boveri Ab||Laminated magnetic core for electric machines|
|US6417456||27 May 1997||9 Jul 2002||Abb Ab||Insulated conductor for high-voltage windings and a method of manufacturing the same|
|US6439497||2 Feb 1998||27 Aug 2002||Abb Ab||Method and device for mounting a winding|
|US6465979||2 Feb 1998||15 Oct 2002||Abb Ab||Series compensation of electric alternating current machines|
|US6525265||30 Nov 1998||25 Feb 2003||Asea Brown Boveri Ab||High voltage power cable termination|
|US6525504||23 Feb 2000||25 Feb 2003||Abb Ab||Method and device for controlling the magnetic flux in a rotating high voltage electric alternating current machine|
|US6577487||27 May 1997||10 Jun 2003||Asea Brown Boveri Ab||Reduction of harmonics in AC machines|
|US6646363||2 Feb 1998||11 Nov 2003||Abb Ab||Rotating electric machine with coil supports|
|US6801421||29 Sep 1998||5 Oct 2004||Abb Ab||Switchable flux control for high power static electromagnetic devices|
|US6822363||27 May 1997||23 Nov 2004||Abb Ab||Electromagnetic device|
|US6825585||2 Feb 1998||30 Nov 2004||Abb Ab||End plate|
|US6828701||2 Feb 1998||7 Dec 2004||Asea Brown Boveri Ab||Synchronous machine with power and voltage control|
|US6831388||27 May 1997||14 Dec 2004||Abb Ab||Synchronous compensator plant|
|US7052740||26 Sep 2002||30 May 2006||Apollo Plating, Inc.||Frame assembly and method for coating a strand of workpieces|
|US8512872||16 Nov 2010||20 Aug 2013||Dupalectpa-CHN, LLC||Sealed anodic coatings|
|US8609254||19 May 2010||17 Dec 2013||Sanford Process Corporation||Microcrystalline anodic coatings and related methods therefor|
|US20040069642 *||26 Sep 2002||15 Apr 2004||Mcnulty Todd||Frame assembly and method for coating a strand of workpieces|
|US20060204668 *||9 May 2006||14 Sep 2006||Apollo Plating, Inc.||Frame assembly and method for coating a strand of workpieces|
|WO1991014024A1 *||13 Mar 1991||19 Sep 1991||Norsk Hydro As||Method and device for surface treatment of elongated, metallic articles|
|WO1998021385A1 *||4 Nov 1997||22 May 1998||Asea Brown Boveri||Anode, process for anodizing, anodized wire and electric device comprising such anodized wire|
|U.S. Classification||205/139, 204/206, 205/147, 174/DIG.33|
|International Classification||C25D7/06, C25D11/04|
|Cooperative Classification||Y10S174/33, C25D11/04, C25D7/0607, C25D11/005|
|European Classification||C25D7/06B, C25D11/04|
|29 Jun 1984||AS||Assignment|
Owner name: NATIONAL ANO-WIRE, INC. MUSKEGON, MI A CORP. OF MI
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:CARR, DANIEL;REEL/FRAME:004275/0430
Effective date: 19840629
|30 Apr 1985||CC||Certificate of correction|
|14 Mar 1988||FPAY||Fee payment|
Year of fee payment: 4
|14 Apr 1992||REMI||Maintenance fee reminder mailed|
|13 Sep 1992||LAPS||Lapse for failure to pay maintenance fees|
|17 Nov 1992||FP||Expired due to failure to pay maintenance fee|
Effective date: 19920913
|24 Nov 1992||FP||Expired due to failure to pay maintenance fee|
Effective date: 19920913