US3344457A - Paintbrushes - Google Patents

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Publication number
US3344457A
US3344457A US567431A US56743166A US3344457A US 3344457 A US3344457 A US 3344457A US 567431 A US567431 A US 567431A US 56743166 A US56743166 A US 56743166A US 3344457 A US3344457 A US 3344457A
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Prior art keywords
bristles
cross
section
paint
paintbrush
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Expired - Lifetime
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US567431A
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Grobert Jacques
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Rhodiaceta SA
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Rhodiaceta SA
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0238Bristles with non-round cross-section
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/20Brushes for applying products to surfaces in general
    • A46B2200/202Applicator paint brush

Description

Oct. 3, 1967 J- G ROBERT PAINTBRUSHES Filed July 25, 1966 I nvenlor ZZWWMW Attorneys United States Patent 3,344,457 PAINTBRUSIES Jacques Grobert, Lyon, France, assignor to Societe Rhodiaceta, Paris, France, a corporation of France Filed July 25, 1966, Ser. No. 567,431 Claims priority, application France, Aug. 13, 1965, 2 23 6 Claims. (01. -159 ABSTRACT OF THE DISCLOSURE This invention relates to paintbrushes consisting at least partly of synthetic bristles.
Synthetic bristles, that is to say bristles of artificial or synthetic origin, have for some decades been more and more used in brushes, partly because of difficulties of supply of natural materials and an increase in the demand for brushware, and partly, especially in the field of paintbrushes, because of the low water absorption and the durability of these synthetic materials.
Attempts have been made to obtain articles whose properties resemble those of natural materials, especially as regards stiffness, and the pick-up, retention and release of liquids. For this purpose it was first of all suggested that the synthetic bristles should be crimped.
In order to produce products which are even closer to those which are manufactured from natural bristles, especially as regards progressive stiffness, it has been suggested to replace the normal cylindrical synthetic bristles partly or completely by bristles of the same type but of a truncated conical shape and of circular cross-section. These bristles, which have often been described by the term tapered filaments, are generally manufactured by forming by extrusion, by various processes, filaments of alternately diverging and converging surfaces.
Bundles of the filaments so obtained, of different or identical maximum and minimum diameters and/or periodicity, are cut into short lengths at the points of maximum and minimum diameter, and thereafter one or more bundles of bristles so obtained are fixed to a handle by means of a collar or sleeve or other device. In practice, the ends of the short lengths of hair or bristle intended to form the free ends of the bristles are treated, before being fixed into the handle, either so as to tip them (increasing the conical nature of the thin end of the bristles) or so as to flag them (splitting this end into a number of small unequal branches). The majority of paintbrushes manufactured today from synthetic bristles are made from tapered bristles.
The present invention relates to a new paintbrush consisting at least partly of synthetic bristles, characterised by the said bristles being of essentially tapered shape and of essentially cruciform transverse section. Such cross-sections are readily obtainable by using spinneret orifices of suitable cross-section.
As a result of this combination of features, it is possible to manufacture paintbrushes which have characparticularly in the examples, the paintbrushes of the in- 3,344,451 Patented Oct. 3, 1967 vention have the advantages of the earlier paintbrushes of tapered bristles of circular section (paint pick-up, progressive stiifness, etc.) and also those of cylindrical cruciform bristles of longitudinal cylindrical section (improved stiffness). Furthermore they also have the unexpected inherent advantage of considerably improved pick-up and release of paint, and above all improved covering power. Moreover, the same level of other use characteristics can be obtained with a considerably lower weight of bristles than that needed with tapered bristles of circular crosssection. Finally, it has been observed that the tapered cruciform bristles can be tipped and flagged simultaneously, and this can be carried out directly on the filament carding machine, by contrast with the tapered bristles of circular cross-section, with which these two operations must be carried out separately if the same result is desired; furthermore, With the bristles of the invention this treatment is with advantage carried out on the assembled paintbrush.
In the present specification the term cruciform is to be understood in the sense that the transverse crosssection of the bristles has a central portion and three (T- shaped or Y-shaped cross) or four branches, or even more, the length and thickness of these branches being at least equal to the diameter of the central portion. It has for example been observed that bristles of non-circular cross-sections other than cruciform section, such as a multi-lobed cross-section or a trefoil cross-section, do
not give the same remarkable results. In practice, espepolymer used for the manufacture of brush bristles. For
example they may be made of synthetic materials such as polycondensates, including polya'mides (of type 6, 6-6, 6-10, 6-12, 11, etc.) polyesters (polyethylene terephthalate), and polyurethanes; or of addition polymers, e.g. polyolefins (polyethylene, polypropylene) or polyvinyls (polyvinyl chloride) and their derivatives (polystyrene), and others. Of these the polyamides, and especially polyamide 6-10, are preferred.
The .known methods may be used to incorporate the bristles in the paint brushes. A particularly advantageous process consists of cutting the bundles of alternating tapered cruciform filaments at the thickest and thinnest points, mixing the short lengths so obtained, setting them by means of glue into the ferrule of the paintbrush and finally tipping and/ or flagging the free ends of the said bristles. Preferably the bristles are so arranged in the paintbrush that cross-sections of the .same diameter lie :in substantially the same plane perpendicular to the length natural bristles etc, or of a mixture of any of these.
It has been found preferable that the minimum diameter of the bristles should be greater than 0.1 mm. and the maximum diameter below 0.5 mm.
In the illustrative examples the following determinations were made:
Stiffness (or pliability): this is the force in grams which has to be used to bend the brush over a given length measured by means of a pan balance.
Paint pick-up: this is the amount of an emulsion paint,
3 in grams, retained by the paintbrush every time it is immersed in the paint for a given time and over a given length.
Paint release: this is the amount of the emulsion paint, in grams, released by a paint brush onto a substrate after four to and fro movements, and is obtained as the ditfercross-section; paintbrush B of tapered bristles of crosssection essentially in the form of a Greek cross (FIG- URE 1); paintbrush C of tapered bristles of cross-section essentially in the form of a potent cross (FIGURE 2).
The test results obtained with these paintbrushes are summarised in Table 1.
TABLE 1 Weight of Stiffness or force, in grams, to Paint Paint Covered Paintbrush bristles bend the paint brush overpick-up release area in used, in g. in g. in g. cm!
mm. mm. mm.
*Measurement carried out when stable conditions have been reached, that is to say after 3 or 4 tests.
**Mean value of 5 tests.
ence between the paint pick-up and the paint retention (see below).
Paint retention: this is the amount of the emulsion paint not released by the paintbrush under the same conditions, and is obtained by weighing the brush before and after the four to and fro movements. (In an ideal paintbrush, the paint retention is substantially nil.)
Covered area: this is the area of a substrate which can be completely covered after each immersion of the paint brush and with a given number of to and fro movements; it is expressed in cm. and is determined by counting the number of 1 cm. squares of a graph paper which have been entirely filled.
The invention is further illustrated in the accompanying drawing, in which:
FIGURE 1 shows the approximate Greek cross crosssection of the bristles of paintbrushes B and E of EX- amples I and II respectively;
FIGURE 2 shows the approximate potent cross crosssection of the bristles of paintbrushes C and F of Examples I and II respectively;
FIGURE 3 is a schematic representation (not to scale) of part of a bristle illustrated in FIGURE 1; and
FIGURE 4 shows the trefoil cross-section of a known bristle, D of Example II.
Example 1 Three flat paint brushes A, B and C were made having the following common characteristics:
Type of bristle: polyhexamethylene sebacamide (polyamide 610).
Length of bristles: 70 mm.
Conicity ratio of the bristles (ratio of the largest to the smallest diameter): approximately 1.8.
Maximum cross-section of the bristles (at the handle end): 0.043 mm Minimum cross-section of the bristles (at the free end): 0.014 mm This table shows the improvement achieved by the products of the invention. For a lower material weight, they have a greater paint pick-up and release than brushes made of tapered bristles of circular cross-section. Also, while at least as stifi if not stiffer, they have better performance in use. Finally, and most surprisingly, the paint brushes of the invention make it possible, under given conditions, to paint a considerably larger area than can be covered with the earlier paint brushes of tapered bristles of circular cross-section.
Example 11 Three further flat paintbrushes D, E, and F were made, having the following common characteristics:
Type of bristle: polyhexamethylene sebacamide (polyamide 6-10).
Length of bristles: 95.25 mm.
Conicity ratio of the bristles: 1.8.
Maximum cross-section of the bristles (at the handle end): 0.083 mm Minimum cross-section of the bristles (at the free end): 0.025 mm.
Width of paint brush: 80 mm.
Thickness of paintbrush: 19 mm.
Length out of the ferrule: 88 mm.
The free ends of all the bristles had been treated to flag them.
Paintbrush D was made of tapered bristles of substantially trefoil cross-section. Such a brush is described in United States Patent No. "2,508,799 of Pittsburgh, Plate Glass Company, and the cross-section is illustrated in FIGURE 4 of the drawing.
Paintbrush E was made of tapered bristles Whose crosssection is essentially in the form of a Greek cross (FIG- URE 1), and paintbrush F of bristles whose cross-section 5 is essentially in the form of a potent cross (FIGURE 2).
The stiflness coetfieient is the figure in grams obtained by plotting the bending or fiexion in mm. against the force in grams required to cause it, and drawing a tangent to the resulting curve through the origin, the point at which the tangent touches the curve giving the coefiicient on the force axis.
Width of paintbrush: 50 mm.
Thickness of paintbrush: 15 mm.
In each paint brush the free ends of the bristles were carded to flag them.
For the same volume, the paintbrushes of the invention (E and F) contain a smaller weight of bristle and give paint pick-up and release figures better than those of brushes with tapered filaments of multi-lobal cross- Paiutbrush A was made of tapered bristles of circular section. Furthermore they enable a large area to be covered than was possible with the previously proposed paintbrushes. This was unexpected and unforeseen.
I claim:
1. A new paintbrush consisting at least partly of synthetic polymer bristles having an essentially tapered longitudinal cross-section and an essentially cruciform transverse cross-section, whose free end is flagged, said bristles being inserted into a ferrule at their point of greatest cross-section, and the cross-sections of the same diameter of the bristles of the same length being arranged essentially in the same plane.
2. A new paintbrush according to claim 1, in which at least part of the bristles are made of a polyamide.
3. A new paintbrush according to claim 1, in which the bristles are made of polyhexamethylene sebacamide.
4. A new paintbrush according to claim 1, in which the cross-section of the bristles is essentially in the shape of a Greek cross.
References Cited UNITED STATES PATENTS 2,341,823 2/1944 Smith t 15--159.1 3,121,040 2/1964 Shaw et al. 15159.1
FOREIGN PATENTS 955,778 4/ 1964 Great Britain.
CHARLES A. WILLMUTH, Primary Examiner.
PETER FELDMAN, Assistant Examiner.

Claims (1)

1. A NEW PAINTBRUSH CONSITING AT LEAST PARTLY OF SYNTHETIC POLYMER BRISTLES HAVING AN ESSSENTIALLY TAPERED LONGITUDINAL CROSS-SECTION AND AN ESSENTIALLY CRUCIFORM TRANSVERSE CORSS-SECTION, WHOSE FREE END IS FLAGGED, SAID BRISTLES BEING INSERTED INTO A FERRULE AT THEIR POINT OF GREATEST CROSS-SECTION, AND THE CROSS-SECTIONS OF THE SAME DIAMETER OF THE BRISTLES OF THE SAME LENGTH BEING ARRANGED ESSENTIALLY IN THE SAME PLANE.
US567431A 1965-08-13 1966-07-25 Paintbrushes Expired - Lifetime US3344457A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR28323A FR1453512A (en) 1965-08-13 1965-08-13 New brush

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US3344457A true US3344457A (en) 1967-10-03

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US567431A Expired - Lifetime US3344457A (en) 1965-08-13 1966-07-25 Paintbrushes

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AT (1) AT286227B (en)
BE (1) BE685495A (en)
CH (1) CH434187A (en)
DE (1) DE1253229B (en)
FI (1) FI42699B (en)
FR (1) FR1453512A (en)
GB (1) GB1137407A (en)
NL (1) NL6611093A (en)
SE (1) SE307121B (en)

Cited By (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3706111A (en) * 1970-08-21 1972-12-19 Du Pont Brush bristles
US3783468A (en) * 1972-01-20 1974-01-08 L Saloutos Paint brush with bristle cartridge
US3914488A (en) * 1973-09-24 1975-10-21 Du Pont Polyester filaments for fur-like fabrics
EP0025358A1 (en) * 1979-09-10 1981-03-18 Toray Industries, Inc. Liquid retaining synthetic fibre, process for producing the same, and products
US4733425A (en) * 1986-06-16 1988-03-29 Sanderson-Macleod, Inc. Mascara brush
FR2607372A1 (en) * 1986-11-28 1988-06-03 Oreal BRUSH FOR THE APPLICATION OF COSMETICS, PARTICULARLY MASCARA
US5020551A (en) * 1988-10-12 1991-06-04 L'oreal Method for manufacturing a make-up brush
US5022112A (en) * 1987-08-03 1991-06-11 Newell Operating Company Paint brush with microcellular synthetic bristles
US5032456A (en) * 1987-09-11 1991-07-16 Newell Operating Company Microcellular synthetic paintbrush bristles
US5088950A (en) * 1990-05-14 1992-02-18 Toy Orginators, Inc. High fluid capacity brushes and bubble blowing system
WO1994009677A1 (en) * 1992-11-02 1994-05-11 Gillette Canada Inc. Toothbrush
WO1995019120A2 (en) * 1994-01-17 1995-07-20 The Procter & Gamble Company Toothbrush with non-circular cross section filaments
US5567072A (en) * 1995-06-07 1996-10-22 Risdon Corporation Mascara applicator having slotted bristles
US5595198A (en) * 1995-06-07 1997-01-21 Risdon Corporation Mascara applicator and method of making the same
WO1997003589A1 (en) 1995-07-19 1997-02-06 Specialty Filaments, Inc. Hollow brush bristle with radiating spokes
US5678899A (en) * 1993-10-18 1997-10-21 Tucel Industries, Inc. Pre-configured brushware and method of fusing
WO1998004167A1 (en) * 1996-07-25 1998-02-05 Whitehill Oral Technologies, Inc. Toothbrush with improved cleaning and abrasion efficiency
US5762432A (en) * 1995-06-07 1998-06-09 Risdon Corporation Mascara applicator having slotted bristles
US5786087A (en) * 1995-02-22 1998-07-28 Specialty Filaments, Inc. Honeycomb brush bristles and brush made therefrom
US5815876A (en) * 1995-09-01 1998-10-06 Overseth; Elmo R. Apparatus for cleaning and polishing a surface
WO1999035935A1 (en) * 1998-01-13 1999-07-22 The Sherwin-Williams Company Paint brush having crinkle filaments and natural filaments
US5947807A (en) * 1997-02-28 1999-09-07 Overseth; Elmo R. Apparatus for cleaning and polishing a surface
WO1999045820A1 (en) * 1998-03-09 1999-09-16 Gillette Canada Company A notched dental hygiene article
US5993784A (en) * 1997-07-24 1999-11-30 Whitehill Oral Technologies Low foaming therapeutic toothpastes with improved cleaning and abrasion performance
US6280113B1 (en) * 1999-07-22 2001-08-28 L'oreal Application device and system having helical bristles, and method for applying a product
US6450177B1 (en) 1999-03-12 2002-09-17 Avon Products, Inc. Applicator brush
US20060080799A1 (en) * 2004-10-18 2006-04-20 Frank Lucente Toothbrush featuring bristles with raised annular portions
US7059006B1 (en) 2003-02-24 2006-06-13 Innovate Llc Brush with removable plates of tines
JP2007289579A (en) * 2006-04-27 2007-11-08 Sankoo:Kk Baby bottle washer
US20070289078A1 (en) * 2006-06-16 2007-12-20 Georges Driesen Toothbrush, toothbrush head and tooth cleaning bristle
US20090139044A1 (en) * 2007-11-29 2009-06-04 Merry Chance Industries, Ltd. Corrugated Bristle Brush
US20090297238A1 (en) * 2008-05-30 2009-12-03 Hiroki Matsuura Brush roller, image forming apparatus, and process cartridge
US20100306944A1 (en) * 2009-03-04 2010-12-09 Braun Gmbh Toothbrush bristle and method for manufacturing such a bristle
USD666786S1 (en) * 2011-08-10 2012-09-11 Sunshine Mills, Inc. Dog food product
USD785901S1 (en) * 2015-12-18 2017-05-09 Societe Des Produits Nestle S.A. Pet treat
USD789651S1 (en) * 2016-07-07 2017-06-20 Societe Des Produits Nestle S.A. Pet treat
USD804741S1 (en) * 2016-11-28 2017-12-05 Shin Park Dog chew
USD804742S1 (en) * 2016-11-28 2017-12-05 Shin Park Dog chew
USD805728S1 (en) 2016-09-06 2017-12-26 Mars, Incorporated Food product
USD806351S1 (en) 2016-09-06 2018-01-02 Mars, Incorporated Food product
USD837357S1 (en) * 2016-09-15 2019-01-01 Ngk Insulators, Ltd. Catalyst carrier for exhaust gas purification
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US10251470B1 (en) 2017-10-10 2019-04-09 The Procter & Gamble Company Head for an oral care implement and oral care implement
US20190104840A1 (en) * 2016-06-03 2019-04-11 The Procter & Gamble Company Filament for an oral care implement and oral care implement
US10856646B2 (en) 2014-07-15 2020-12-08 The Procter & Gamble Company Oral-care implement having color-communicative element
US10869545B2 (en) 2017-10-10 2020-12-22 The Procter & Gamble Company Filament for an oral care implement and oral care implement
US10869546B2 (en) 2017-10-10 2020-12-22 The Procter & Gamble Company Tuft and head for an oral care implement and oral care implement
US10874205B2 (en) 2016-06-03 2020-12-29 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11219302B2 (en) 2017-10-10 2022-01-11 The Procter & Gamble Company Head for an oral care implement and oral care implement
USD949513S1 (en) * 2020-12-16 2022-04-26 Central Garden & Pet Company Pellet feed for an animal
US11425991B2 (en) 2014-03-11 2022-08-30 The Procter & Gamble Company Head for an oral care implement
EP4018880B1 (en) 2017-03-07 2022-11-23 Orkla House Care AB Paint brush comprising a bristle blend of three different types of bristles
USD972808S1 (en) * 2021-04-26 2022-12-20 J.R. Simplot Compan Formed potato product
USD998280S1 (en) * 2021-09-20 2023-09-12 Paragon Pet Products Europe B.V. Dog chew
USD1018060S1 (en) * 2023-11-01 2024-03-19 Xiaohong Wu Toothbrush head
USD1018058S1 (en) * 2023-10-31 2024-03-19 Xiaohong Wu Toothbrush head

Families Citing this family (3)

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US5052070A (en) * 1988-09-20 1991-10-01 Alkinco (Alfred Klugmann International Corporation) Hairbrush
DE19640852A1 (en) * 1996-10-02 1998-04-16 Braun Ag Bristle for a toothbrush
DE19829611A1 (en) * 1998-07-02 2000-01-13 Braun Gmbh Process for producing a tuft of bristles, in particular a toothbrush

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US3121040A (en) * 1962-10-19 1964-02-11 Polymers Inc Unoriented polyolefin filaments
GB955778A (en) * 1961-09-06 1964-04-22 Rhodiaceta Brushes and process for producing the same

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US2637893A (en) * 1949-03-12 1953-05-12 Shaw Gilbert Artificial filament
CH317066A (en) * 1954-06-02 1956-11-15 Bodone Alfredo hairbrush
CH345632A (en) * 1956-02-14 1960-04-15 Bodone Alfredo hairbrush
FR1341026A (en) * 1962-10-03 1963-10-25 Advanced brush and process for its manufacture

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US2341823A (en) * 1941-06-13 1944-02-15 Du Pont Artificial filament
GB955778A (en) * 1961-09-06 1964-04-22 Rhodiaceta Brushes and process for producing the same
US3121040A (en) * 1962-10-19 1964-02-11 Polymers Inc Unoriented polyolefin filaments

Cited By (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3706111A (en) * 1970-08-21 1972-12-19 Du Pont Brush bristles
US3783468A (en) * 1972-01-20 1974-01-08 L Saloutos Paint brush with bristle cartridge
US3914488A (en) * 1973-09-24 1975-10-21 Du Pont Polyester filaments for fur-like fabrics
EP0025358A1 (en) * 1979-09-10 1981-03-18 Toray Industries, Inc. Liquid retaining synthetic fibre, process for producing the same, and products
US4381325A (en) * 1979-09-10 1983-04-26 Toray Industries, Inc. Liquid retaining synthetic fiber, process for producing the same, and products
US4733425A (en) * 1986-06-16 1988-03-29 Sanderson-Macleod, Inc. Mascara brush
BE1004394A4 (en) * 1986-11-28 1992-11-17 Oreal Brush for applying cosmetic in particular mascara.
FR2607372A1 (en) * 1986-11-28 1988-06-03 Oreal BRUSH FOR THE APPLICATION OF COSMETICS, PARTICULARLY MASCARA
US4993440A (en) * 1986-11-28 1991-02-19 L'oreal Brush for the application of cosmetic products, mascara in particular
US5022112A (en) * 1987-08-03 1991-06-11 Newell Operating Company Paint brush with microcellular synthetic bristles
US5032456A (en) * 1987-09-11 1991-07-16 Newell Operating Company Microcellular synthetic paintbrush bristles
US5063947A (en) * 1988-10-12 1991-11-12 L'oreal Brush for applying a make-up product
US5020551A (en) * 1988-10-12 1991-06-04 L'oreal Method for manufacturing a make-up brush
US5088950A (en) * 1990-05-14 1992-02-18 Toy Orginators, Inc. High fluid capacity brushes and bubble blowing system
WO1994009677A1 (en) * 1992-11-02 1994-05-11 Gillette Canada Inc. Toothbrush
US5396678A (en) * 1992-11-02 1995-03-14 The Gillette Company Toothbrush with rectangular bristles
US5678899A (en) * 1993-10-18 1997-10-21 Tucel Industries, Inc. Pre-configured brushware and method of fusing
WO1995019120A2 (en) * 1994-01-17 1995-07-20 The Procter & Gamble Company Toothbrush with non-circular cross section filaments
WO1995019120A3 (en) * 1994-01-17 1995-09-21 Procter & Gamble Toothbrush with non-circular cross section filaments
US5786087A (en) * 1995-02-22 1998-07-28 Specialty Filaments, Inc. Honeycomb brush bristles and brush made therefrom
US5567072A (en) * 1995-06-07 1996-10-22 Risdon Corporation Mascara applicator having slotted bristles
US5762432A (en) * 1995-06-07 1998-06-09 Risdon Corporation Mascara applicator having slotted bristles
US5595198A (en) * 1995-06-07 1997-01-21 Risdon Corporation Mascara applicator and method of making the same
US5701629A (en) * 1995-07-19 1997-12-30 Speciality Filaments, Inc. Hollow brush bristle with radiating spokes
WO1997003589A1 (en) 1995-07-19 1997-02-06 Specialty Filaments, Inc. Hollow brush bristle with radiating spokes
US5815876A (en) * 1995-09-01 1998-10-06 Overseth; Elmo R. Apparatus for cleaning and polishing a surface
US6138314A (en) * 1996-07-25 2000-10-31 Whitehill Oral Technologies, Inc. Toothbrush with improved cleaning and abrasion efficiency
US6086373A (en) * 1996-07-25 2000-07-11 Schiff; Thomas Method of cleaning teeth with a toothbrush with improved cleaning and abrasion efficiency
WO1998004167A1 (en) * 1996-07-25 1998-02-05 Whitehill Oral Technologies, Inc. Toothbrush with improved cleaning and abrasion efficiency
US5947807A (en) * 1997-02-28 1999-09-07 Overseth; Elmo R. Apparatus for cleaning and polishing a surface
US5993784A (en) * 1997-07-24 1999-11-30 Whitehill Oral Technologies Low foaming therapeutic toothpastes with improved cleaning and abrasion performance
WO1999035935A1 (en) * 1998-01-13 1999-07-22 The Sherwin-Williams Company Paint brush having crinkle filaments and natural filaments
US6367114B1 (en) 1998-01-13 2002-04-09 The Sherwin-Williams Company Paint brush having crinkle filaments and natural bristles
WO1999045820A1 (en) * 1998-03-09 1999-09-16 Gillette Canada Company A notched dental hygiene article
US6018840A (en) * 1998-03-09 2000-02-01 Gillette Canada Inc. Notched dental hygiene article
US6450177B1 (en) 1999-03-12 2002-09-17 Avon Products, Inc. Applicator brush
US6280113B1 (en) * 1999-07-22 2001-08-28 L'oreal Application device and system having helical bristles, and method for applying a product
US7059006B1 (en) 2003-02-24 2006-06-13 Innovate Llc Brush with removable plates of tines
US20060080799A1 (en) * 2004-10-18 2006-04-20 Frank Lucente Toothbrush featuring bristles with raised annular portions
JP2007289579A (en) * 2006-04-27 2007-11-08 Sankoo:Kk Baby bottle washer
US20070289078A1 (en) * 2006-06-16 2007-12-20 Georges Driesen Toothbrush, toothbrush head and tooth cleaning bristle
US8453288B2 (en) * 2006-06-16 2013-06-04 Braun Gmbh Toothbrush, toothbrush head and tooth cleaning bristle
US20090139044A1 (en) * 2007-11-29 2009-06-04 Merry Chance Industries, Ltd. Corrugated Bristle Brush
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Also Published As

Publication number Publication date
BE685495A (en) 1967-02-13
GB1137407A (en) 1968-12-18
NL6611093A (en) 1967-02-14
FI42699B (en) 1970-06-30
FR1453512A (en) 1966-06-03
SE307121B (en) 1968-12-23
CH434187A (en) 1967-04-30
DE1253229B (en) 1967-11-02
AT286227B (en) 1970-11-25

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