US20090233056A1 - Polypropylene Laminate Wallcovering - Google Patents

Polypropylene Laminate Wallcovering Download PDF

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Publication number
US20090233056A1
US20090233056A1 US12/045,941 US4594108A US2009233056A1 US 20090233056 A1 US20090233056 A1 US 20090233056A1 US 4594108 A US4594108 A US 4594108A US 2009233056 A1 US2009233056 A1 US 2009233056A1
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Prior art keywords
wallcovering
oriented polypropylene
polypropylene film
mil
laminate
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US12/045,941
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Andy W. Anderson, Sr.
Michael Winchester
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Individual
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/16Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/028Net structure, e.g. spaced apart filaments bonded at the crossing points
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06Vegetal fibres
    • B32B2262/062Cellulose fibres, e.g. cotton
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14Mixture of at least two fibres made of different materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514Oriented
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/75Printability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/14Printing or colouring
    • B32B38/145Printing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Definitions

  • the present invention relates to wallcoverings. More particularly, the present invention relates to a polypropylene laminate wallcovering.
  • Polyvinyl chloride is a standard material for producing commercial wallcoverings.
  • PVC wallcoverings are relatively low cost, have high durability properties relative to weight, have good printing properties and embossing properties, and are flexible from an installation perspective.
  • PVC wallcoverings have drawbacks. The most serious drawback is the environmental hazard that polyvinyl chloride poses. PVC wallcoverings produce environmental hazards during the manufacturing stage, when the finished PVC wallcovering is installed, and when the PVC wallcoverings are eventually discarded.
  • PVC wallcoverings have failed in one or all of the following categories: Too expensive, poor print registration, poor grain capture (does not emboss well), does not meet Type II wallcovering protocol, which includes the ASTM E-84 Class A flammability requirements, and many other performance criteria as stated in CCC-W-408 A and CCC-W-408-D.
  • a wallcovering comprising a laminate of three layers including: (1) a scrim backing layer, (2) a specially formulated, oriented polypropylene (OPP) film forming a substrate layer that is printable, and (3) a top layer comprising either a clear, ultraviolet (UV) cured coating (an over print varnish (OPV)) or an oriented polypropylene film.
  • the oriented polypropylene film used for the substrate layer has good print registration and excellent grain capture when embossed and is comparable in cost, if not less expensive, than standard Type II PVC film.
  • the oriented polypropylene film used as a substrate in the laminate wallcovering of the present invention has been specially engineered to accept printing inks and adhesives for laminating purposes.
  • the wallcovering, constructed in accordance with the present invention, also has a Class A flame rating.
  • FIG. 1 is a cross-section view of the wallcovering in accordance with the present invention.
  • FIG. 2 is an exploded, cross-section view of the wallcovering in accordance with the present invention.
  • a polypropylene laminate wallcovering 10 comprises a scrim backing layer 12 , a specially formulated, oriented polypropylene (OPP) film forming a substrate layer 14 , and a top layer 16 comprising either a UV cured, clear coating or a clear oriented polypropylene film.
  • OPP specially formulated, oriented polypropylene
  • the backing layer 12 of the laminate wallcovering 10 is a ‘scrim” or woven fabric.
  • the backing layer 12 is conventional scrim fabric commonly used for wallcovering backing and is generally a 100% polyester, although polyester/cotton blends are commonly used as a backing for wallcoverings as well. Based on testing, the scrim construction that provided the best performance and finished weight was a scrim having 68 ends ⁇ 38 picks. Lighter weight woven scrims can be utilized, depending on the finished weight that is required for the laminate wallcovering 10 . A range of woven scrim constructions and fiber combinations were tested in order to maximize the performance and weight of the finished laminate wallcovering 10 .
  • the substrate layer 14 of the laminate wallcovering 10 is a white oriented polypropylene film, ranging in thickness from 1.00 mil to 12.00 mil with a preferred thickness of 8.00 mil.
  • Oriented polypropylene film inherently repels foreign matter, like dirt and stains. This repellency characteristic of oriented polypropylene film normally includes printing inks.
  • the oriented polypropylene film of the present invention is specially formulated to bond permanently with a variety of printing media (inks) 18 and the adhesives used for lamination. Both the face and back surfaces of the oriented polypropylene film forming substrate layer 14 are given a functional treatment to specifically capture and hold ink and adhesive.
  • the process used to enhance the bonding property of the oriented polypropylene film of substrate layer 14 involves both an oxidative treatment and a surface primer applied to the film after the extrusion stage. This process alters the dyne level of the surface of the oriented polypropylene film, allowing inks and adhesive to bond permanently to the treated oriented polypropylene film.
  • the oriented polypropylene film used in connection with the present invention as the substrate layer 14 also has excellent grain capture when embossed.
  • substrate layers 14 having the following thicknesses were tested: 1.0 mil, 2.20 mil, 4.25 mil, 8.00 mil and 12.00 mil thickness. (See Table 1.)
  • the lesser thicknesses of the oriented polypropylene films for the substrate layer 14 exhibited somewhat reduced “hiding” properties when installed and somewhat reduced resistance to impact.
  • the higher thicknesses (12.00 mil) of the oriented polypropylene film exhibited increased stiffness requiring the wallcovering installer to “fight” the wallcovering to get it on the wall.
  • the 8.00 mil thick oriented polypropylene film provided good performance while maintaining an acceptable hand, enabling the paper hanger to install the wallcovering with ease.
  • the source for the oriented polypropylene film used for the substrate layer 14 is Applied Extrusion Technologies, Inc. (AET), located at 115 Read's Way, New Castle, Del. 19720.
  • AET is the only independent global supplier dedicated solely to the manufacturing of oriented polypropylene films, and it currently provides 25% of North America's oriented polypropylene film needs.
  • the specific AET 8.00 mil film is sold by AET under the product designation 8SPM.
  • the top layer 16 of the wallcovering 10 is a 0.35 mil to 1.30 mil ultra violet (UV) cured clear coating with a matte or gloss outer finish.
  • UV clear coating has been formulated by Environmental Inks & Coatings, 31 Quality Products Road, Morganton, N.C. 28655 and sold under the product designations Matte UF 170689, UV 175 Matte OPV and Gloss UF 170690, UV 80gloss OPV.
  • This UV clear coating has been formulated to provide chemical and abrasion resistance that exceeds standard Type II PVC wallcovering finishes currently being offered in the market. This coating also provides dry erase properties.
  • a range of coating weights for the UV cured top layer 16 were tested on different weights of the oriented polypropylene film substrate layer 14 as noted in Table 1. The same qualifications (performance, hand, and cost) were used to determine that the UV coating at the 0.35 mil thickness, applied with a 200 anilox cylinder provided a good balance of performance, hand, and value. Suitable performance, however, was achieved with coating weights from 0.35 mil to 1.30 mil.
  • the top layer 16 of the wallcovering 10 is a 0.75 mil-7.00 mil clear oriented polypropylene film with a matte outer finish.
  • the oriented polypropylene film used for the top layer 16 protects the finished laminate wallcovering 10 .
  • the oriented polypropylene film for the top layer 16 is supplied by AET under the designation RLS Mat XZ811.
  • the back side of the clear oriented polypropylene film top layer 16 facing the substrate layer 14 , has been given an oxidative treatment to enhance the oriented polypropylene film's acceptance of adhesives used for laminating purposes.
  • the face (matte) side of the oriented polypropylene film has been treated with a blend of polymers that create a release property.
  • a range of weights for the oriented polypropylene film top layer 16 were tested on different weights of the oriented polypropylene film substrate layer 14 as noted in Table 1. The same qualifications (performance, hand, and cost) were used to determine that the 0.75 mil oriented polypropylene film provided a good balance of performance, hand, and value although the other thicknesses, 0.075 mil to 7.00 mil, provided adequate performance.
  • the oriented polypropylene film substrate layer 14 is first printed on its outer surface with the desired ink pattern 18 .
  • the desired pattern can be printed on the inner surface of the clear, oriented polypropylene film top layer 16 .
  • the oriented polypropylene film substrate layer 14 can be printed on existing gravure printing equipment using standard water based ink systems, or digitally printed using UV cured ink systems, and laminate wallcovering 10 can be embossed on equipment like that currently used for standard PVC wallcovering production.
  • the UV cured clear coating is applied over the printed oriented polypropylene film substrate layer 14 .
  • the scrim layer 12 is then laminated by means of heat and/or adhesive to the oriented polypropylene film substrate layer 14 .
  • the entire laminate wallcovering 10 now consisting of a) the woven scrim backing layer 12 , b) the printed polypropylene film substrate layer 14 , and c) the UV cured clear coating top layer 16 , is run through an embossing roller imparting the pattern of choice to the top surface of the laminate wallcovering 10 .
  • the clear oriented polypropylene film top layer 16 is wet laminated to the printed polypropylene film substrate layer 14 .
  • the scrim layer 12 is then laminated by means of heat and/or adhesive to the oriented polypropylene film substrate layer 14 .
  • the entire laminate wallcovering 10 now consisting of a) the woven scrim backing layer 12 , b) the printed polypropylene film substrate layer 14 , and c) the clear oriented polypropylene film top layer 16 , is run through an embossing roller imparting the pattern of choice to the top surface of the laminate wallcovering 10 .
  • the finished laminate wallcovering 10 has the appearance and hand of standard Type II PVC wallcovering, and can be produced at a lower cost than the PVC wallcovering.
  • the performance properties of the polypropylene laminate wallcovering 10 exceed those of the PVC based product, in particular the abrasion and stain resistance properties.
  • a substantial advantage of the polypropylene laminate wallcovering 10 is the energy and labor savings compared to that required for production of conventional PVC wallcoverings.

Abstract

The present invention provides a wallcovering comprising a laminate of three layers including: (1) a scrim backing layer, (2) a specially formulated, oriented polypropylene (OPP) film forming a substrate layer that is printable, and (3) a UV Cured Clear Coating or an oriented polypropylene film as a top layer forming a top layer.

Description

    FIELD OF THE INVENTION
  • The present invention relates to wallcoverings. More particularly, the present invention relates to a polypropylene laminate wallcovering.
  • BACKGROUND OF THE INVENTION
  • Polyvinyl chloride (PVC) is a standard material for producing commercial wallcoverings. PVC wallcoverings are relatively low cost, have high durability properties relative to weight, have good printing properties and embossing properties, and are flexible from an installation perspective. PVC wallcoverings, however, have drawbacks. The most serious drawback is the environmental hazard that polyvinyl chloride poses. PVC wallcoverings produce environmental hazards during the manufacturing stage, when the finished PVC wallcovering is installed, and when the PVC wallcoverings are eventually discarded.
  • Alternatives to PVC wallcoverings have failed in one or all of the following categories: Too expensive, poor print registration, poor grain capture (does not emboss well), does not meet Type II wallcovering protocol, which includes the ASTM E-84 Class A flammability requirements, and many other performance criteria as stated in CCC-W-408 A and CCC-W-408-D.
  • A need therefore exists for an improved, environmentally friendly wallcovering that is low cost, has good printing and embossing characteristics, and meets standard performance criteria, including flammability requirements.
  • SUMMARY OF THE INVENTION
  • The present invention answers this need by providing a wallcovering comprising a laminate of three layers including: (1) a scrim backing layer, (2) a specially formulated, oriented polypropylene (OPP) film forming a substrate layer that is printable, and (3) a top layer comprising either a clear, ultraviolet (UV) cured coating (an over print varnish (OPV)) or an oriented polypropylene film. The oriented polypropylene film used for the substrate layer has good print registration and excellent grain capture when embossed and is comparable in cost, if not less expensive, than standard Type II PVC film. The oriented polypropylene film used as a substrate in the laminate wallcovering of the present invention has been specially engineered to accept printing inks and adhesives for laminating purposes.
  • It is thus an object of the present invention to provide a polypropylene laminate wallcovering that has the look, feel, and performance characteristics of conventional PVC wallcoverings without the environmental drawbacks associated with PVC wallcoverings. The wallcovering, constructed in accordance with the present invention, also has a Class A flame rating.
  • Further objects, features and advantages will become apparent upon consideration of the following detailed description of the invention when taken in conjunction with the drawings and the appended claims.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a cross-section view of the wallcovering in accordance with the present invention.
  • FIG. 2 is an exploded, cross-section view of the wallcovering in accordance with the present invention.
  • DETAILED DESCRIPTION OF THE INVENTION
  • Turning to FIGS. 1 and 2, a polypropylene laminate wallcovering 10 comprises a scrim backing layer 12, a specially formulated, oriented polypropylene (OPP) film forming a substrate layer 14, and a top layer 16 comprising either a UV cured, clear coating or a clear oriented polypropylene film.
  • The backing layer 12 of the laminate wallcovering 10 is a ‘scrim” or woven fabric. The backing layer 12 is conventional scrim fabric commonly used for wallcovering backing and is generally a 100% polyester, although polyester/cotton blends are commonly used as a backing for wallcoverings as well. Based on testing, the scrim construction that provided the best performance and finished weight was a scrim having 68 ends×38 picks. Lighter weight woven scrims can be utilized, depending on the finished weight that is required for the laminate wallcovering 10. A range of woven scrim constructions and fiber combinations were tested in order to maximize the performance and weight of the finished laminate wallcovering 10. Much of the tensile and tear performance of the laminate wallcovering 10 is predicated on the woven backing layer 12, or scrim. Table 1 shows the range of wallcoverings tested. Ultimately, the 68×38 polyester scrim provided the best balance of weight, flexibility, performance, and cost, although the other scrims shown in Table 1 performed satisfactorily.
  • TABLE 1
    Materials Tested:
    A 1.00 mil WHITE OPP (substrate layer 14)
    B 2.20 mil WHITE OPP (substrate layer 14)
    C 4.25 mil WHITE OPP (substrate layer 14)
    D 8.00 mil WHITE OPP (substrate layer 14)
    E 12.00 mil WHITE OPP (substrate layer 14)
    F(UV) 0.35 mil CLEAR PROTECTIVE UV COATING (top layer 16)
    G(UV) 0.50 mil CLEAR PROTECTIVE UV COATING (top layer 16)
    H(UV) 0.60 mil CLEAR PROTECTIVE UV COATING (top layer 16)
    I(UV) 1.30 mil CLEAR PROTECTIVE UV COATING (top layer 16)
    F(OPP) 0.75 mil CLEAR PROTECTIVE OPP (top layer 16)
    G(OPP) 2.20 mil CLEAR PROTECTIVE OPP (top layer 16)
    H(OPP) 4.25 mil CLEAR PROTECTIVE OPP (top layer 16)
    I(OPP) 7.00 mil CLEAR PROTECTIVE OPP (top layer 16)
    K 68 × 38 Polyester Scrim (backing layer 12)
    L 39 × 26 Polyester Scrim (backing layer 12)
    M 54 × 42 Polyester/Cotton Scrim (backing layer 12)
    Combinations Tested:
    TOP LAYER 16
    SUBSTRATE (UV COATING or OPP
    LAYER
    14 FILM) BACKING LAYER 12
    White OPP Layer Clear Protective Layer Woven Scrim Layer
    A F(UV) or F(OPP) K-L-M
    A G(UV) or G(OPP) K-L-M
    A H(UV) or H(OPP) K-L-M
    A I(UV) or I(OPP) K-L-M
    B F(UV) or F(OPP) K-L-M
    B G(UV) or G(OPP) K-L-M
    B H(UV) or H(OPP) K-L-M
    B I(UV) or I(OPP) K-L-M
    C F(UV) or F(OPP) K-L-M
    C G(UV) or G(OPP) K-L-M
    C H(UV) or H(OPP) K-L-M
    C I(UV) or I(OPP) K-L-M
    D F(UV) or F(OPP) K-L-M
    D G(UV) or G(OPP) K-L-M
    D H(UV) or H(OPP) K-L-M
    D I(UV) or I(OPP) K-L-M
    E F(UV) or F(OPP) K-L-M
    E G(UV) or G(OPP) K-L-M
    E H(UV) or H(OPP) K-L-M
    E I(UV) or I(OPP) K-L-M
  • The substrate layer 14 of the laminate wallcovering 10 is a white oriented polypropylene film, ranging in thickness from 1.00 mil to 12.00 mil with a preferred thickness of 8.00 mil. Oriented polypropylene film inherently repels foreign matter, like dirt and stains. This repellency characteristic of oriented polypropylene film normally includes printing inks. The oriented polypropylene film of the present invention is specially formulated to bond permanently with a variety of printing media (inks) 18 and the adhesives used for lamination. Both the face and back surfaces of the oriented polypropylene film forming substrate layer 14 are given a functional treatment to specifically capture and hold ink and adhesive. The process used to enhance the bonding property of the oriented polypropylene film of substrate layer 14 involves both an oxidative treatment and a surface primer applied to the film after the extrusion stage. This process alters the dyne level of the surface of the oriented polypropylene film, allowing inks and adhesive to bond permanently to the treated oriented polypropylene film. The oriented polypropylene film used in connection with the present invention as the substrate layer 14 also has excellent grain capture when embossed.
  • In connection with the present invention, substrate layers 14 having the following thicknesses were tested: 1.0 mil, 2.20 mil, 4.25 mil, 8.00 mil and 12.00 mil thickness. (See Table 1.) The lesser thicknesses of the oriented polypropylene films for the substrate layer 14 exhibited somewhat reduced “hiding” properties when installed and somewhat reduced resistance to impact. The higher thicknesses (12.00 mil) of the oriented polypropylene film exhibited increased stiffness requiring the wallcovering installer to “fight” the wallcovering to get it on the wall. The 8.00 mil thick oriented polypropylene film provided good performance while maintaining an acceptable hand, enabling the paper hanger to install the wallcovering with ease. The thicknesses for the oriented polypropylene film for the substrate layer 14 shown in Table 1, however, are all considered within the scope of the invention. The source for the oriented polypropylene film used for the substrate layer 14 is Applied Extrusion Technologies, Inc. (AET), located at 115 Read's Way, New Castle, Del. 19720. AET is the only independent global supplier dedicated solely to the manufacturing of oriented polypropylene films, and it currently provides 25% of North America's oriented polypropylene film needs. The specific AET 8.00 mil film is sold by AET under the product designation 8SPM.
  • The top layer 16 of the wallcovering 10 is a 0.35 mil to 1.30 mil ultra violet (UV) cured clear coating with a matte or gloss outer finish. This UV clear coating has been formulated by Environmental Inks & Coatings, 31 Quality Products Road, Morganton, N.C. 28655 and sold under the product designations Matte UF 170689, UV 175 Matte OPV and Gloss UF 170690, UV 80gloss OPV. This UV clear coating has been formulated to provide chemical and abrasion resistance that exceeds standard Type II PVC wallcovering finishes currently being offered in the market. This coating also provides dry erase properties.
  • A range of coating weights for the UV cured top layer 16 were tested on different weights of the oriented polypropylene film substrate layer 14 as noted in Table 1. The same qualifications (performance, hand, and cost) were used to determine that the UV coating at the 0.35 mil thickness, applied with a 200 anilox cylinder provided a good balance of performance, hand, and value. Suitable performance, however, was achieved with coating weights from 0.35 mil to 1.30 mil.
  • In an alternative embodiment, the top layer 16 of the wallcovering 10 is a 0.75 mil-7.00 mil clear oriented polypropylene film with a matte outer finish. The oriented polypropylene film used for the top layer 16 protects the finished laminate wallcovering 10. The oriented polypropylene film for the top layer 16 is supplied by AET under the designation RLS Mat XZ811. The back side of the clear oriented polypropylene film top layer 16, facing the substrate layer 14, has been given an oxidative treatment to enhance the oriented polypropylene film's acceptance of adhesives used for laminating purposes. The face (matte) side of the oriented polypropylene film has been treated with a blend of polymers that create a release property.
  • A range of weights for the oriented polypropylene film top layer 16 were tested on different weights of the oriented polypropylene film substrate layer 14 as noted in Table 1. The same qualifications (performance, hand, and cost) were used to determine that the 0.75 mil oriented polypropylene film provided a good balance of performance, hand, and value although the other thicknesses, 0.075 mil to 7.00 mil, provided adequate performance.
  • In order to construct the polypropylene laminate wallcovering 10, the oriented polypropylene film substrate layer 14 is first printed on its outer surface with the desired ink pattern 18. Where the oriented polypropylene film is used for the top layer 16 instead of the UV clear coating, the desired pattern can be printed on the inner surface of the clear, oriented polypropylene film top layer 16. Better printing results, however, were achieved by printing the oriented polypropylene film substrate layer 14 as compared to printing of the oriented polypropylene film top layer 16. The oriented polypropylene film substrate layer 14 can be printed on existing gravure printing equipment using standard water based ink systems, or digitally printed using UV cured ink systems, and laminate wallcovering 10 can be embossed on equipment like that currently used for standard PVC wallcovering production.
  • Once the polypropylene film substrate layer 14 has been printed, the UV cured clear coating is applied over the printed oriented polypropylene film substrate layer 14. The scrim layer 12 is then laminated by means of heat and/or adhesive to the oriented polypropylene film substrate layer 14. After the layers been laminated, the entire laminate wallcovering 10, now consisting of a) the woven scrim backing layer 12, b) the printed polypropylene film substrate layer 14, and c) the UV cured clear coating top layer 16, is run through an embossing roller imparting the pattern of choice to the top surface of the laminate wallcovering 10. Because polypropylene has a relatively low melt temperature, a balance of heat and pressure is required in the embossing process to maximize the grain capture. Although not considered critical to the present invention, the good embossing results were achieved within the following ranges of temperature, speed, and pressure:
  • Web temperature: 240 F.-250 F.
    Line Speed: 35-40 yds/minute
    Pressure: 2800-3100 PSI
  • With the alternative embodiment using the clear oriented polypropylene film for the top layer 16, the clear oriented polypropylene film top layer 16 is wet laminated to the printed polypropylene film substrate layer 14. The scrim layer 12 is then laminated by means of heat and/or adhesive to the oriented polypropylene film substrate layer 14. After the layers been laminated, the entire laminate wallcovering 10, now consisting of a) the woven scrim backing layer 12, b) the printed polypropylene film substrate layer 14, and c) the clear oriented polypropylene film top layer 16, is run through an embossing roller imparting the pattern of choice to the top surface of the laminate wallcovering 10.
  • With either embodiment of top layer 16, the finished laminate wallcovering 10 has the appearance and hand of standard Type II PVC wallcovering, and can be produced at a lower cost than the PVC wallcovering. The performance properties of the polypropylene laminate wallcovering 10 exceed those of the PVC based product, in particular the abrasion and stain resistance properties. A substantial advantage of the polypropylene laminate wallcovering 10 is the energy and labor savings compared to that required for production of conventional PVC wallcoverings.
  • Although the invention herein has been described with reference to particular embodiments, it is to be understood that these embodiments are merely illustrative of the principals and applications of the present invention. Accordingly, while the invention has been described with reference to the structures and processes disclosed, it is not confined to the details set forth, but is intended to cover such modifications or changes as may fall within the scope of the following claims.

Claims (12)

1. A laminate wallcovering comprising:
a. a scrim backing layer:
b. a printable, oriented polypropylene film substrate layer; and
c. a ultraviolet cured clear coating as the top layer.
2. The laminate wallcovering of claim 1, wherein the ultraviolet cured clear coating has a thickness is 0.35 mil or greater.
3. The laminate wallcovering of claim 1, wherein the ultraviolet cured clear coating has a thickness between 0.35 mil and 1.30 mil.
4. The laminate wallcovering of claim 1, wherein the printable, oriented polypropylene film substrate layer has surfaces oxidized and coated with a primer.
5. The laminate wallcovering of claim 1, wherein the printable, oriented polypropylene film substrate layer has a thickness between 1 mil and 12 mil.
6. The laminate wallcovering of claim 5, wherein the printable, oriented polypropylene film substrate layer has a thickness 8.00 mil.
7. A laminate wallcovering comprising:
a. a scrim backing layer:
b. a printable, oriented polypropylene film substrate layer; and
c. an oriented polypropylene film top layer.
8. The laminate wallcovering of claim 7, wherein the oriented polypropylene film top layer has a thickness is 0.75 mil or greater.
9. The laminate wallcovering of claim 7, wherein oriented polypropylene film top layer has a thickness between 0.75 mil and 7.00 mil.
10. The laminate wallcovering of claim 7, wherein the printable, oriented polypropylene film substrate layer has surfaces oxidized and coated with a primer.
11. The laminate wallcovering of claim 7, wherein the printable, oriented polypropylene film substrate layer has a thickness between 1 mil and 12 mil.
12. The laminate wallcovering of claim 11, wherein the printable, oriented polypropylene film substrate layer has a thickness of 8.00 mil.
US12/045,941 2008-03-11 2008-03-11 Polypropylene Laminate Wallcovering Abandoned US20090233056A1 (en)

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US20150024370A1 (en) * 2013-07-17 2015-01-22 Shurtech Brands, Llc Dry-wipe whiteboard capable of pasting repeatedly for both solvent-based pen and water-based pen
EP2969562A4 (en) * 2013-03-14 2016-08-10 Hewlett Packard Development Co Wall covering

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
EP2969562A4 (en) * 2013-03-14 2016-08-10 Hewlett Packard Development Co Wall covering
US20150024370A1 (en) * 2013-07-17 2015-01-22 Shurtech Brands, Llc Dry-wipe whiteboard capable of pasting repeatedly for both solvent-based pen and water-based pen

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