Search Images Maps Play YouTube News Gmail Drive More »
Sign in
Screen reader users: click this link for accessible mode. Accessible mode has the same essential features but works better with your reader.

Patents

  1. Advanced Patent Search
Publication numberUS20040018788 A1
Publication typeApplication
Application numberUS 10/620,791
Publication date29 Jan 2004
Filing date16 Jul 2003
Priority date22 Dec 1997
Also published asDE69827751D1, DE69827751T2, EP0924239A1, EP0924239B1, US6630415, US20020061406
Publication number10620791, 620791, US 2004/0018788 A1, US 2004/018788 A1, US 20040018788 A1, US 20040018788A1, US 2004018788 A1, US 2004018788A1, US-A1-20040018788, US-A1-2004018788, US2004/0018788A1, US2004/018788A1, US20040018788 A1, US20040018788A1, US2004018788 A1, US2004018788A1
InventorsChristine Phillips, Susan Nye
Original AssigneePhillips Christine J., Nye Susan A.
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Durable hydrophilic coating for textiles
US 20040018788 A1
Abstract
Low molecular weight silicone polyether ABA type block copolymer treatments wherein a linear polysiloxane is terminated at each end by a polyether moiety derived from ethylene oxide are useful to imparting a hydrophilic coating to the surface of either woven or non-woven textiles.
Images(7)
Previous page
Next page
Claims(16)
Having described the invention that which is claimed is:
1. A polymeric fabric treated with a silicone compound selected from the group consisting of:
1) polysiloxane polyethers having the formula:
where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about 1 to about 8; the subscript b ranges from about 1 to about 10; the subscript c ranges from zero to 2; the subscript d ranges from about to 1 to about 10; and the number average molecular weight ranging from ranges from about to 300 to about 1,000.
2) polysiloxane polyethers having the formula:
where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8; the subscript b ranges from about 1 to about 10; the subscript c ranges from zero to 2; the subscript d ranges from about to 1 to about 10; and the number average molecular weight ranging from ranges from about to 300 to about 1,000;
3) polysiloxane polyethers having the formula:
where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8; the subscript b ranges from about 1 to about 10; the subscript c ranges from zero to 2; the subscript d ranges from about to 1 to about 10; the subscript e ranges from about to 1 to about 10; and the number average molecular weight ranging from ranges from about to 300 to about 1,000; and
4) mixtures thereof
whereby said fabric is rendered durably hydrophilic.
2. The silicone compound of claim 1 wherein said silicone is:
3. The treatment silicone compound of claim 1 wherein said silicone is:
4. The silicone compound of claim 1 wherein said silicone is:
5. A polymeric fabric wherein said fabric has been treated with the treatment silicone of claim 1.
6. A polymeric fabric wherein said fabric has been treated with the treatment silicone of claim 2.
7. A polymeric fabric wherein said fabric has been treated with the treatment silicone of claim 3.
8. A polymeric fabric wherein said fabric has been treated with the treatment silicone of claim 4.
9. The polymeric fabric of claim 5 comprising a polymer wherein said polymer is selected from the group consisting of:
alkyd resins, ophthalmic anhydride-glycerol resins, maleic acid-glycerol resins, adipic acid-glycerol resins, phthalic anhydride-pentaerythritol resins; allylic resins cross-linked by diallyl phthalate, diallyl isophthalate diallyl maleate, or diallyl chlorendate; aniline-formaldehyde resins, ethylene urea-formaldehyde resins, dicyandiamide-formaldehyde resins, melamine-formaldehyde resins, sulfonamide-formaldehyde resins, and urea-formaldehyde resins; epoxy resins, epichlorohydrin-bisphenol A resins; phenolic resins, phenol-formaldehyde resins, end-capped polyacetals, poly(oxymethylene), polyformaldehyde, poly(trichloroacetaldehyde), poly(n-valeraldehyde), poly(acetaldehyde), poly(propionaldehyde), acrylic polymers, polyacrylamide, poly(acrylic acid), poly(methacrylic acid), poly(ethyl acrylate), poly(methyl methacrylate), fluorocarbon polymers, poly(tetrafluoroethylene), perfluorinated ethylene-propylene copolymers, ethylene-tetrafluoroethylene copolymers, poly(chlorotrifluoroethylene), ethylene-chlorotrifluoroethylene copolymers, poly(vinylidene fluoride), poly(vinyl fluoride), polyamides, such as poly(6-aminocaproic acid) or poly(epsilon-caprolactam), poly(hexamethylene adipamide), poly(hexamethylene sebacamide), poly(11-amino-undecanoic acid), polyaramides, poly(imino-1,3-phenyleneiminoisophthaloyl) or poly(m-phenylene isophthalamide), parylenes, poly-p-xylylene, poly(chloro-p-xylylene), polyaryl ethers, poly(oxy-2,6-dimethyl-1,4-phenylene), poly(p-phenylene oxide), polyaryl sulfones, poly(oxy-1,4-phenylenesulfonyl-1,4-phenyleneoxy-1,4-phenylene-isopropylidene-1,4-phenylene), poly(sulfonyl-1,4-phenyleneoxyl,4-phenylenesulfonyl-4,4′-biphenylene), polycarbonates, poly(bisphenolA)orpoly(carbonyldioxy-1,4-phenyleneisopropylidene-1,4-phenylene), polyesters, poly(ethylene terephthalate), poly(tetramethylene terephthalate), poly(cyclohexylene-1,4-dimethylene terephthalate), poly(oxymethylene-1,4-cyclohexylenemethyleneoxyterephthaloyl), polyaryl sulfides, poly(p-phenylene sulfide), poly(thio-1,4-phenylene), polyimides, poly(pyromellitimido-1,4-phenylene), polyolefins, polyethylene, polypropylene, poly(1-butene), poly(2-butene), poly(1-pentene), poly(2-pentene), poly(3-methyl-1-pentene), poly(4-methyl-1-pentene), 1,2-poly-1,3-butadiene, 1,4-poly-1,3-butadiene, polyisoprene, polychloroprene, polyacrylonitrile, poly(vinyl acetate), poly(vinylidene chloride), polystyrene, copolymers of the foregoing, acrylonitrile-butadiene-styrene (ABS) copolymers, and mixtures thereof.
10. The polymeric fabric of claim 5 comprising a polymer wherein said polymer is a natural polymer selected from the group consisting of cotton, silk, wool, and cellulose.
11. The polymeric fabric of claim 9 wherein said polymer is selected from the group consisting of polyethylene, polypropylene, poly(1-butene), poly(2-butene), poly(1-pentene), poly(2-pentene), poly(3-methyl-1-pentene), poly(4-methyl-1-pentene), 1,2-poly-1,3-butadiene, 1,4-poly-1,3-butadiene, polyisoprene, polychloroprene, polyacrylonitrile, poly(vinyl acetate), poly(vinylidene chloride), polystyrene, copolymers of the foregoing, acrylonitrile-butadiene-styrene (ABS) copolymers, and mixtures thereof.
12. The polymeric fabric of claim 11 wherein said polymer is selected from the group consisting of polyethylene and polypropylene.
13. The polymeric fabric of claim 12 wherein said polymer is polyethylene.
14. The polymeric fabric of claim 13 wherein said polymer is polypropylene.
15. The polymeric fabric of claim 10 wherein said polymer is cellulose.
16. The polymeric fabric of claim 15 wherein said cellulose is paper.
Description
    CROSS-REFERENCE TO RELATED APPLICATIONS
  • [0001]
    This application is a divisional of U.S. Ser. No. 09/997,939 filed Nov. 29, 2001 which is a continuation-in-part application of U.S. Ser. No. 09/443,182 filed Nov. 19, 1999 which is a continuation of U.S. Ser. No. 08/995,389 filed Dec. 22, 1997.
  • FIELD OF THE INVENTION
  • [0002]
    The present invention relates to low molecular weight silicone polyether ABA type block copolymers that are useful to imparting a hydrophilic coating to the surface of either woven or non-woven textiles.
  • BACKGROUND OF THE INVENTION
  • [0003]
    Textiles are made from a variety of materials both natural and man made. Natural textiles include cotton, wool, silk, linen and the like while synthetic textiles are derived from various high polymers such as polyesters, polyamides, polyimides, and the various polyolefins, e.g. polyethylene, polypropylene, polybutylene. While polymers are used extensively to make a variety of products ranging from blown and cast films, extruded sheets, injection molded articles, foams, blow molded articles, extruded pipe, monofilaments and non-woven webs many of the polymers used for such materials are hydrophobic. In many cases this property is an advantage.
  • [0004]
    There are a number of uses to which polymers may be put where their hydrophobic nature either limits their usefulness or requires some modification. This is particularly true of polyolefins such as polyethylene and polypropylene which are used to manufacture polymeric fabrics which are used in disposable absorbent articles such as diapers, training pants, incontinence products, wipes, feminine care products and the like. These polymeric fabrics are typically non-woven webs prepared by meltblowing, coforming or spunbonding. For uses such as the foregoing these non-woven fabrics need to be wettable. Frequently wettability can be obtained by coating the fabric in some fashion with a treatment solution during or after formation of the fabric web and drying the web.
  • [0005]
    Some of the more commonly applied topically applied treatments are nonionic treatments, for example polyethoxylated octylphenols and the condensation products of propylene oxide with propylene glycol. These types of treatments are effective in rendering normally hydrophobic polymeric fabrics wettable or hydrophilic. However, the treatment is readily removed from the fabric, often after only a single exposure to an aqueous liquid.
  • [0006]
    There have been several different approaches to increasing the durability of treatments that are topically applied to the surface of a fabric. Among these approaches have been:
  • [0007]
    (1) the use of a composition that includes water, a primary treatment, and a co-treatment that functions to wet the fabric with the treatment composition and that provides for a substantially uniform distribution of the primary treatment onto the fabric;
  • [0008]
    (2) the use of a treatment, with or without a nonionic co-treatment that is the reaction product of an acid anhydride derivative with a polyhydroxy compound, polyethylene glycol, triethanolamine, a polyhydroxyamine, and certain unsaturated aliphatic sulfo compounds;
  • [0009]
    (3) the use of a treatment, with or without a nonionic co-treatment that is the reaction product of certain unsaturated aliphatic sulfo compounds with the reaction product of an acid anhydride derivative with a polyamine having at least one NH group capable of addition to a double bond;
  • [0010]
    (4) the use of a treatment mixture that includes an ester acid, ester salt, or a mixture thereof, and an amide-acid, amide-salt or mixture thereof with or without a nonionic co-treatment;
  • [0011]
    (5) the use of a treatment mixture that includes a sorbitol succinate treatment and a co-wetting aid that can be a silicone polyether or a primary or secondary alcohol; and
  • [0012]
    (6) the use of a silicone polyether treatment having the formula:
  • [0013]
    where R1 and R6 are selected from the group of hydrogen and C1-8 alkyl and aryl, R2, R3, R4 and R5 are selected from the group of C1-8 alkyl and aryl, the subscript a represents an integer ranging from about 8 to about 25, the subscript b represents an integer ranging from about 8 to about 25, the ratio of b to a is in a range of from about 0.7 to about 1.5, the subscript c represents an integer from 1 to about 10, the subscript d represents an integer of from about 40 to about 70 the ratio of d to two times the sum of a and b is in a range of from about 0.7 to about 1.5 and the number average molecular weight is preferably in a range of from about 5,000 to about 35,000, more preferably from about 6,500 to about 18,500 and most preferably about 7,000.
  • [0014]
    The examples of U.S. Pat. No. 5,540,984 ('984) teach that silicone polyether treatments having a molecular weight below about 7,000 do not provide the durability provided by patentee's invention. Further, the polyether endgroups on the silicone treatments employed by the '984 patent ranged from about 50 to 80 weight percent propylene oxide and from about 50 to about 20 weight percent ethylene oxide. The '984 patent specifically teaches that reversing this weight ratio of polyether end groups to 85 weight percent ethylene oxide and 15 weight percent propylene oxide (patentee's example P) does not provide a durable hydrophilic coating as defined by patentee. This is emphasized by patentee's results for a silicone polyether treatment having 100 weight percent ethylene oxide polyether groups wherein the treatment was not durable (patentee's example J). Thus, the '984 patent teaches that the polyether substituents of the silicone polyether treatment must contain a mix of ethylene oxide and propylene oxide groups or preferably all propylene oxide groups. These results were obtained for copolymers terminated with the respective polyether moieties.
  • [0015]
    Notwithstanding the advances that have been made in rendering fabrics wettable by providing for a hydrophilic coating there remains a need for further improvement in these areas.
  • SUMMARY OF THE INVENTION
  • [0016]
    The present invention provides for a treatment silicone compound selected from the group consisting of:
  • [0017]
    1) polysiloxane polyethers having the formula:
  • [0018]
    where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about 1 to about 8; the subscript b ranges from about 1 to about 10; the subscript c ranges from zero to 2; the subscript d ranges from about to 1 to about 10; and the number average molecular weight ranging from ranges from about to 300 to about 1,000.
  • [0019]
    2) polysiloxane polyethers having the formula:
  • [0020]
    where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8; the subscript b ranges from about 1 to about 10; the subscript c ranges from zero to 2; the subscript d ranges from about to 1 to about 10; and the number average molecular weight ranging from ranges from about to 300 to about 1,000;
  • [0021]
    3) polysiloxane polyethers having the formula:
  • [0022]
    where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8; the subscript b ranges from about 1 to about 10; the subscript c ranges from zero to 2; the subscript d ranges from about to 1 to about 10; the subscript e ranges from about to 1 to about 10; and the number average molecular weight ranging from ranges from about to 300 to about 1,000; and
  • [0023]
    4) mixtures thereof.
  • [0024]
    Such treatment silicone compositions are useful for treating fabrics comprised of natural or synthetic polymeric materials to render the fabrics hydrophilic, i.e. capable of picking up and absorbing quantities of water. Such treatment silicone compositions are useful for treating cellulosic materials such as paper.
  • DETAILED DESCRIPTION OF THE INVENTION
  • [0025]
    As used herein, the term “polymeric fabric” means a fabric prepared from any polymeric material capable of being formed into a fabric and includes fabric webs such as paper. Thus, such material can be synthetic or natural, although the former are more likely to be employed in the present invention. Examples of natural polymeric materials include, cotton, silk, wool, and cellulose, by way of illustration only. Synthetic polymeric materials, in turn, can be either thermosetting or thermoplastic materials, with thermoplastic materials being more common. As used herein fabric means any textile, non-woven or woven, or any web such as paper or felt.
  • [0026]
    Examples of thermosetting polymers include, by way of illustration only, alkyd resins, such as phthalic anhydride-glycerol resins, maleic acid-glycerol resins, adipic acid-glycerol resins, and phthalic anhydride-pentaerythritol resins; allylic resins, in which such monomers as diallyl phthalate, diallyl isophthalate diallyl maleate, and diallyl chlorendate serve as nonvolatile cross-linking agents in polyester compounds; amino resins, such as aniline-formaldehyde resins, ethylene urea-formaldehyde resins, dicyandiamide-formaldehyde resins, melamine-formaldehyde resins, sulfonamide-formaldehyde resins, and urea-formaldehyde resins; epoxy resins, such as cross-linked epichlorohydrin-bisphenol A resins; phenolic resins, such as phenol-formaldehyde resins, including Novolacs and resols; and thermosetting polyesters, silicones, and urethanes.
  • [0027]
    Examples of thermoplastic polymers include, by way of illustration only, end-capped polyacetals, such as poly(oxymethylene) or polyformaldehyde, poly(trichloroacetaldehyde), poly(n-valeraldehyde), poly(acetaldehyde), poly(propionaldehyde), and the like; acrylic polymers, such as polyacrylamide, poly(acrylic acid), poly(methacrylic acid), poly(ethyl acrylate), poly(methyl methacrylate), and the like; fluorocarbon polymers, such as poly(tetrafluoroethylene), perfluorinated ethylene-propylene copolymers, ethylene-tetrafluoroethylene copolymers, poly(chlorotrifluoroethylene), ethylene-chlorotrifluoroethylene copolymers, poly(vinylidene fluoride), poly(vinyl fluoride), and the like; polyamides, such as poly(6-aminocaproic acid) or poly(epsilon-caprolactam), poly(hexamethylene adipamide), poly(hexamethylene sebacamide), poly(11-amino-undecanoic acid), and the like; polyaramides, such as poly(imino-1,3-phenyleneiminoisophthaloyl) or poly(m-phenylene isophthalamide), and the like; parylenes, such as poly-p-xylylene, poly(chloro-p-xylylene), and the like; polyaryl ethers, such as poly(oxy-2,6-dimethyl-1,4-phenylene) or poly(p-phenylene oxide), and the like; polyaryl sulfones, such as poly(oxy-1,4-phenylenesulfonyl-1,4-phenyleneoxy-1,4-phenylene-isopropylidene-1,4-phenylene), poly(sulfonyl-1,4-phenyleneoxyl, 4-phenylenesulfonyl-4,4′-biphenylene), and the like; polycarbonates, such as poly(bisphenolA)orpoly(carbonyldioxy-1,4-phenyleneisopropylidene-1,4-phenylene), and the like; polyesters, such as poly(ethylene terephthalate), poly(tetramethylene terephthalate), poly(cyclohexylene-1,4-dimethylene terephthalate) or poly(oxymethylene-1,4-cyclohexylenemethyleneoxyterephthaloyl), and the like; polyaryl sulfides, such as poly(p-phenylene sulfide) or poly(thio-1,4-phenylene), and the like; polyimides, such as poly(pyromellitimido-1,4-phenylene), and the like; polyolefins, such as polyethylene, polypropylene, poly(1-butene), poly(2-butene), poly(1-pentene), poly(2-pentene), poly(3-methyl-1-pentene), poly(4-methyl-1-pentene), 1,2-poly-1,3-butadiene, 1,4-poly-1,3-butadiene, polyisoprene, polychloroprene, polyacrylonitrile, poly(vinyl acetate), poly(vinylidene chloride), polystyrene, and the like: copolymers of the foregoing, such as acrylonitrile-butadiene-styrene (ABS) copolymers, and the like; and the like. In certain embodiments, the polymeric fabric will be prepared from a polyolefin. In other embodiments, the polyolefin will be polypropylene or polyethylene.
  • [0028]
    The term “fabric” is used broadly herein to mean any fibrous material which has been formed into a sheet or web. That is, the fabric is composed, at least in part, of fibers of any length. Thus, the fabric can be a woven or nonwoven sheet or web, all of which are readily prepared by methods well-known to those having ordinary skill in the art. For example, nonwoven webs are prepared by such processes as meltblowing, coforming, spunbonding, carding, air laying, and wet laying. Moreover, the fabric can consist of a single layer or multiple layers. In addition, a multilayered fabric can include films, scrim, and other nonfibrous materials.
  • [0029]
    As used herein, the term “durable” means that the polymeric fabric to which a treatment has been applied can be subjected to the rigorous washing procedure described hereinafter or to multiple exposures to water and remain wettable.
  • [0030]
    The term “treatment” is used herein to mean any active agent that is capable of durably rendering a polymeric fabric (i.e. a fabric either woven or non-woven made from a polymeric fiber) wettable. In some embodiments, the treatment is a linear polysiloxane that is terminated at each end by a polyether moiety derived from ethylene oxide, commonly referred to as an A-B-A polymer. In one embodiment, the treatment is a polysiloxane polyether having the general formula:
  • [0031]
    where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8, preferably from about to 1.5 to about 6, more preferably from about to 1.5 to about 5, and most preferably from about to 1.5 to about 4; the subscript b ranges from about 1 to about 10, preferably from about 1 to about 7, more preferably from about 1 to about 5, and most preferably from about to 1 to about 3; the subscript c ranges from zero to 2, more preferably from 1 to 2, and is most preferably 2; the subscript d ranges from about to 1 to about 10, preferably from about to 2 to about 8, more preferably from about to 2 to about 7, and most preferably from about to 3 to about 5; and the number average molecular weight ranging from ranges from about to 300 to about 1,000, preferably from about to 400 to about 900, more preferably from about to 500 to about 900, and most preferably from about to 600 to about 800.
  • [0032]
    In a second embodiment, the treatment is a polysiloxane polyether having the general formula:
  • [0033]
    where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8, preferably from about to 1.5 to about 6, more preferably from about to 1.5 to about 5, and most preferably from about to 1.5 to about 4; the subscript b ranges from about 1 to about 10, preferably from about 1 to about 7, more preferably from about 1 to about 5, and most preferably from about to 1 to about 3; the subscript c ranges from zero to 2, more preferably from 1 to 2, and is most preferably 2; the subscript d ranges from about to 1 to about 10, preferably from about to 2 to about 8, more preferably from about to 2 to about 7, and most preferably from about to 3 to about 5; and the number average molecular weight ranging from ranges from about to 300 to about 1,000, preferably from about to 400 to about 900, more preferably from about to 500 to about 900, and most preferably from about to 600 to about 800.
  • [0034]
    In a third embodiment, the treatment is a polysiloxane polyether having the general formula:
  • [0035]
    where R1 is selected from the group consisting of hydrogen and alkyls and R2 and R3 are each independently selected from the group consisting of one to forty carbon atom monovalent hydrocarbon radicals; the subscript a ranges from about to 1 to about 8, preferably from about to 1.5 to about 6, more preferably from about to 1.5 to about 5, and most preferably from about to 1.5 to about 4; the subscript b ranges from about 1 to about 10, preferably from about 1 to about 7, more preferably from about 1 to about 5, and most preferably from about to 1 to about 3; the subscript c ranges from zero to 2, more preferably from 1 to 2, and is most preferably 2; the subscript d ranges from about to 1 to about 10, preferably from about to 2 to about 8, more preferably from about to 2 to about 7, and most preferably from about to 3 to about 5; the subscript e ranges from about to 1 to about 10, preferably from about to 2 to about 8, more preferably from about to 2 to about 7, and most preferably from about to 3 to about 5; and the number average molecular weight ranging from ranges from about to 300 to about 1,000, preferably from about to 400 to about 900, more preferably from about to 500 to about 900, and most preferably from about to 600 to about 800.
  • [0036]
    In a fourth embodiment the treatment of the present invention is a mixture comprising two or more of the first, second and third embodiments. It should be noted that for molecular species the subscripts a, b, c, d etc. will assume integral values. When a mixture of compounds is employed as the treatment component, the values of the subscripts will assume non-integral values depending on the population fraction for a given molecular weight, i.e. molar averaged stoichiometric subscripts will be non-integral in the case of mixtures as opposed to pure compounds.
  • [0037]
    The advantages of the present invention are that the silicone polyether compounds of the present invention do not require a co-treatment. The materials also are effective at extremely low levels and maintain effectiveness after as many as five washings. Thus the materials maintain effectiveness after one, two, three, four and five washings. Effectiveness as to the hydrophilic coating is defined in the experimental section.
  • [0038]
    The hydrophilic coatings or treatments of the present invention typically comprise from about 0.01 to about 20.00 weight percent of the total weight of the treated fabric, preferably from about 0.10 to about 10.00 weight percent of the total weight of the treated fabric, more preferably from about 0.50 to about 5.00 weight percent of the total weight of the treated fabric, and most preferably from about 0.75 to about 2.50 weight percent of the total weight of the treated fabric.
  • [0039]
    Depending on the means employed to coat the fabric, the coated fabric may demonstrate a greater or lesser hydrophilic behavior for a given treatment composition depending on whether the coating is applied from an aqueous solution or dispersion or an alcoholic solution or dispersion. The greatest hydrophilic behavior is observed when the hydrophilic coating is applied from an aqueous dispersion, particularly when water is the only solvent employed. Textiles treated by the treatment of the present invention are useful for disposable absorbent articles such as diapers, training pants, incontinence products, wipes, feminine care products and the like. Wipes may be personal care wipes, floor care wipes, household care wipes, automotive care wipes and the like. In one embodiment, the treatment of the present invention, heretofore referred to as a coating, which coating may be a partial coating or a complete coating, involves depositing the treating agent, the compounds used in the present invention, onto the textile or fabric being treated to render it hydrophilic, preferably durably hydrophilic.
  • [0040]
    All U.S. patents referenced herein are specifically herewith and hereby incorporated by reference.
  • [0041]
    The following experiments are to be regarded as illustrative only and are not intended by their presentation to constitute any limitations upon the appended claims.
  • [0042]
    Experimental
  • [0043]
    The base fabric used in evaluating the coating compositions of the present invention was a spunbound polypropylene nonwoven web having a basis weight of 15.5 g per square meter. The fabric was cut into test swatches having dimensions of 22±5 cm×28±5 cm and an average weight ranging from 0.9 to 1.1 g (1.00±0.10 g). The silicone polyether compounds evaluated had the following structural formulas:
  • [0044]
    The silicone polyether compounds evaluated for the purposes of the present invention are listed in Table 1.
    TABLE 1
    Structural Parameters for Silicone Polyethers
    Sample
    No. Type R1 R2 R3 a b c d e
    1 A H CH3 CH3 1.8 3 2 3 0
    2 A H CH3 CH3 4 3 2 0 0
    3 A H CH3 CH3 4 3 2 3 0
    4 A H CH3 CH3 4 3 2 4 0
    5 A H CH3 CH3 4 3 2 5 0
    6 A H CH3 CH3 8 3 2 3 0
    7 A H CH3 CH3 8 3 2 5 0
    8 A H CH3 CH3 8 3 2 10 0
    9 A H CH3 CH3 12 3 2 15 0
    10 A H CH3 CH3 20 3 2 25 0
    11 B H CH3 CH3 1.7 3 2 3 0
    12 C H CH3 CH3 12 3 3 20 3
  • [0045]
    The silicone polyethers listed in Table 1 were suspended or dissolved in a 50 weight percent aqueous solution of isopropanol (2-propanol) or water at levels of 2.0, 0.5, 0.4 and 0.1 weight percent. Samples of the nonwoven spunbonded polypropylene fabric were treated by soaking them in the water-alcohol-silicone polyether mixture for 1-2 hours followed by drying in a forced air oven for 30 minutes at 105° C. The treated fabrics, having swatch dimensions of 22×28 cm. and weighing on average 0.95 g each were tested for hydrophilicity by pouring 100 g of water onto the fabric samples while the fabric sample was supported at a 35° angle above horizontal with an absorbent pad directly underneath the sample, which is known in the art as a run-off test. The absorbent pad was obtained by placing ten layers of commercially available paper towels one on top of each other; the paper towels having essentially the same dimensions as the fabric test swatch. Any of the water that ran off the fabric and was not absorbed was collected and measured. The treated fabric was judged effective or as having an effective hydrophilic coating if the fabric swatch and the absorbent pad thereunder retained 80 g of the 100 g poured onto the fabric, i.e. 80%. Conversely, if 20 g of water or more was recovered from the test the fabric sample was deemed to have failed the test. Fabrics that were treated with a water solution or dispersion of the compounds of the present invention tended to perform better than fabrics treated with alcoholic solutions or dispersions. The amount of coating it is possible to impart to the treated fabric tends to be a function of how the fabric is treated, i.e. whether the external surfaces of the fabric are treated or whether the entire fabric is immersed into the impregnating solution or dispersion.
    TABLE 2
    Coating Weights of Hydrophilic Silicone Coating
    on Textile Samples
    Solution Concentra- Coating
    Concentra- tion of Weight
    tion of Aqueous of Silicone,
    Sample No. A D Silicone, wt. % iso-Pr-OH wt. %
    A-1 1.8 3 0.05 0 4.67
    A-3 4 3 2.00 50 6.59
    A-3 4 3 0.50 50 0.66
    A-3 4 3 0.40 50 1.20
    A-3 4 3 0.40 0 15.03
    A-3 4 3 0.30 0 6.88
    A-3 4 3 0.20 0 4.64
    A-3 4 3 0.10 0 1.75
    A-3 4 3 0.05 0 1.68
    A-5 4 5 2.00 50 8.01
    A-5 4 5 0.50 50 1.30
    A-5 4 5 0.05 0 1.25
    A-6 8 3 0.05 0 0
    A-7 8 5 2.00 50 3.44
    A-8 8 10 2.00 50 3.78
    A-8 8 10 0.05 28 0
    A-9 12 15 0.05 28 0
    A-10 20 25 0.05 28 0.02
    B-1 1.7 2 2.00 50 9.01
    B-1 1.7 3 0.50 50 1.31
    C-1 8 1 0.05 0 0
    C-2 12 3 2.00 50 5.39
    C-2 12 3 0.05 28 0.05
  • [0046]
    The coated textiles when coated with the compounds of the present invention will pick up varying amounts of water depending on how extensively the textile is treated. If only the external surfaces of the textile are treated at very low levels, the total amount of water absorbed by the treated textile will be very low and may be indistinguishable from an untreated fabric. However, if the entire body of the fabric, exterior and interior, has been treated, the treated fabric can absorb as much as 300 to 400 weight percent.
Patent Citations
Cited PatentFiling datePublication dateApplicantTitle
US452671 *14 Nov 189019 May 1891 Desk-cabinet
US2803619 *23 Dec 195420 Aug 1957Dow CorningLow compression set siloxane elastomers containing a vinyl organosiloxane
US3271331 *10 Oct 19636 Sep 1966Union Carbide CorpPhenolic foams stabilized by siloxane-oxyalkylene copolymers
US3280160 *30 Mar 196518 Oct 1966Union Carbide CorpSiloxane-oxyalkylene block copolymers
US3654215 *26 Dec 19674 Apr 1972Gen ElectricFiller cross-linked polysiloxanes
US3817910 *2 Jan 197318 Jun 1974Stauffer Chemical CoLow compression set siloxane elastomers
US3984200 *2 Apr 19755 Oct 1976Dow Corning CorporationCarpet dyeing antifoam
US4105567 *4 Jan 19778 Aug 1978Th. Goldschmidt AgOrganosilicon compounds and textile fiber finishes containing them
US4287261 *24 Mar 19801 Sep 1981Reeves Brothers, Inc.Fabric coating process and product thereof
US4351871 *23 Feb 198128 Sep 1982Lewis Edward JDecorating textile fabrics
US4369231 *4 Aug 198118 Jan 1983Reeves Brothers, Inc.Method of application, and product thereof
US4376149 *10 Jul 19818 Mar 1983Sws Silicones CorporationSilicone polymer compositions
US4539357 *29 Aug 19843 Sep 1985General Electric CompanyPeroxide curing polysiloxane compositions having a high tear strength
US4554147 *2 Apr 198419 Nov 1985General Electric CompanyMethod for treating fumed silica
US4690967 *21 Dec 19841 Sep 1987Rhone-Poulenc Specialites ChimiquesHeat-curable organopolysiloxane compositions
US4740528 *18 Jul 198626 Apr 1988Kimberly-Clark CorporationSuperwicking crosslinked polyurethane foam composition containing amino acid
US4818421 *17 Sep 19874 Apr 1989Colgate-Palmolive Co.Fabric softening detergent composition and article comprising such composition
US4857251 *14 Apr 198815 Aug 1989Kimberly-Clark CorporationMethod of forming a nonwoven web from a surface-segregatable thermoplastic composition
US4921622 *17 Nov 19881 May 1990Takemoto Yushi Kabushiki KaishaFluid-permeable agent for non-woven sheets of polyolefin fibers and method of application thereof: N,N-di-hydroxyethyl amide and polyoxyalkylene-modified silicone
US5004643 *10 Mar 19892 Apr 1991Sili-Tex, Inc.Silicone polymer-internally coated webs
US5010883 *8 May 198930 Apr 1991Smith & Nephew Associated Companies PlcSurgical dressing
US5045387 *28 Jul 19893 Sep 1991Hercules IncorporatedRewettable polyolefin fiber and corresponding nonwovens
US5051259 *5 Dec 198824 Sep 1991Coloplast A/SSkin barrier product with discontinuous adhesive layer
US5057361 *17 Nov 198915 Oct 1991Kimberly-Clark CorporationWettable polymeric fabrics
US5081172 *13 Dec 198914 Jan 1992Dow Corning CorporationMethod to reduce compression set in silanol-containing silicone elastomer bases
US5104919 *15 Mar 199014 Apr 1992Shin-Etsu Chemical Co., Ltd.Curable silicone composition
US5110845 *3 Dec 19905 May 1992Dow Corning CorporationExtrudable curable organosiloxane compositions
US5112885 *26 Apr 199012 May 1992Shin-Etsu Chemical Co., Ltd.Room temperature vulcanizable silicon rubber composition
US5122562 *25 Sep 199016 Jun 1992General Electric CompanyHeat curable silicone rubber compositions
US5132047 *4 Feb 199121 Jul 1992Shin-Etsu Chemical Co., Ltd.Organopolysiloxane emulsion composition
US5153244 *19 Oct 19906 Oct 1992Dow Corning Toray Silicone Company, Ltd.Curable organosiloxane composition yielding elastomers exhibiting reduced compression set values
US5183702 *3 Apr 19912 Feb 1993Dover CorporationBarrier fabrics
US5200440 *31 Oct 19906 Apr 1993Shin-Etsu Chemical Co., Ltd.Organosilicone-treated silica and a composition containing it
US5209965 *2 Apr 199111 May 1993Sili-Tex, Inc.Internally coated webs
US5210133 *15 Jun 199211 May 1993Siltech Inc.Silicone polyester polymers as delivery systems
US5219922 *24 Apr 199115 Jun 1993Bayer AktiengesellschaftSilicone elastomers having reduced compression set and a process for their production
US5236532 *22 Sep 199217 Aug 1993Standard Textile Company, Inc.Barrier fabrics and methods of making same
US5248715 *30 Jul 199228 Sep 1993Dow Corning CorporationSelf-adhering silicone rubber with low compression set
US5258129 *15 Oct 19912 Nov 1993Takemoto Yushi Kabushiki KaishaFluid-permeable agent for non-woven sheets of polyolefin fibers and method of application thereof
US5260364 *7 Aug 19929 Nov 1993Wacker Silicones CorporationSilicone rubber having reduced compression set
US5276123 *3 Sep 19924 Jan 1994Dow Corning CorporationAlkoxy endblocked polydiorganosiloxane and room temperature vulcanizable silicone elastomers made therefrom
US5283023 *3 Jan 19921 Feb 1994Kimberly-Clark CorporationMethod of imparting delayed wettability to a nonwoven web
US5380260 *9 Nov 199310 Jan 1995Smith & Nephew PlcMedical paddings
US5380770 *9 Apr 199210 Jan 1995General Electric CompanyHeat cured silicone rubber compositions containing a potassium aluminosilicate filler which provides resistance to hydrocarbon oils and adjustable shrinkage
US5391679 *17 May 199321 Feb 1995Th. Goldschmidt AgMethod for the synthesis of polyether siloxanes
US5418051 *16 Feb 199323 May 1995Fabric Coating CorporationInternally coated webs
US5447783 *26 Jan 19955 Sep 1995E. I. Du Pont De Nemours And CompanyVapor-permeable, water resistant multicomponent film structure
US5474839 *13 Dec 199312 Dec 1995Matsushita Electric Industrial Co., Ltd.Surface-treated apparel material
US5486551 *3 Jan 199523 Jan 1996Dow Corning CorporationMethod for preparing a finely divided, free flowing organosiloxane elastomer base exhibiting reduced compression set following curing
US5500254 *21 Dec 199319 Mar 1996Kimberly-Clark CorporationCoated polymeric fabric having durable wettability and reduced adsorption of protein
US5519082 *12 Apr 199521 May 1996Shin-Etsu Chemical Co., Ltd.Curable silicone rubber composition and method for preparing silicone rubber
US5540984 *20 Mar 199530 Jul 1996Kimberly-Clark CorporationCoated polymeric fabric having durable wettability and reduced adsorption of protein
US5556919 *7 Jun 199517 Sep 1996Nippon Zeon Co., Ltd.Rubber composition comprising nitrile group-containing highly saturated copolymer rubber and ethylenically saturated copolymer rubber
US5569688 *20 Oct 199429 Oct 1996Shin-Etsu Chemical Co., Ltd.Heat-curable silicone rubber compositions
US5597853 *7 Nov 199428 Jan 1997Shin-Etsu Chemical Co., Ltd.Silicone rubber compositions
US5607992 *23 Feb 19964 Mar 1997Toshiba Silicone Co., Ltd.Silicone rubber composition for injection molding
US5610213 *30 Jun 199511 Mar 1997General Electric CompanyHeat cured rubbers
US5620788 *16 Jul 199315 Apr 1997Kimberly-Clark CorporationWettable polymeric fabrics with durable surfactant treatment
US5623028 *1 Dec 199522 Apr 1997General Electric CompanyHeat cured rubbers
US5633007 *20 Jul 199427 May 1997Smith & Nephew PlcSurgical dressing
US5698303 *7 Jun 199516 Dec 1997Nextec Applications, Inc.Controlling the porosity and permeation of a web
US5811482 *17 Jul 199622 Sep 1998Osi Specialties, Inc.Non-migrating hydrophilic silicone finish for hydrophobic substrates such as nonwovens
US6211284 *22 Jun 19993 Apr 2001Dow Corning Toray Silicone Co.Highly storage-stable organopolysiloxane composition
USRE25727 *9 Feb 1965 Organosiloxane ethers
Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US78969291 Jun 20071 Mar 2011Dow Corning CorporationTreating textiles with silicone polyether-amide block copolymers
US20090113637 *1 Jun 20077 May 2009Kimmai Thi NguyenTreating textiles with silicone polyether-amide block copolymers
Classifications
U.S. Classification442/76
International ClassificationD06M13/51, D06M101/32, D06M101/16, D06M101/10, D06M101/18, D06M101/34, D06M101/00, D06M101/02, D06M13/513, D06M13/02, D06M101/30, D06M101/06, C08G77/46, C07F7/08, D06M15/647, D21H19/32
Cooperative ClassificationY10T442/2139, D06M15/647, D06M2101/06, Y10T428/31663, D06M2200/00, Y10T442/2492, D06M2101/18, C08G77/46, Y10T428/31659, D06M2101/12, D21H19/32, C07F7/0852
European ClassificationC08G77/46, C07F7/08D4H4F, D06M15/647
Legal Events
DateCodeEventDescription
3 Jul 2007ASAssignment
Owner name: JPMORGAN CHASE BANK, N.A. AS ADMINISTRATIVE AGENT,
Free format text: SECURITY AGREEMENT;ASSIGNORS:MOMENTIVE PERFORMANCE MATERIALS HOLDINGS INC.;MOMENTIVE PERFORMANCE MATERIALS GMBH & CO. KG;MOMENTIVE PERFORMANCE MATERIALS JAPAN HOLDINGS GK;REEL/FRAME:019511/0166
Effective date: 20070228