US20030072915A1 - Low contaminant wiper - Google Patents

Low contaminant wiper Download PDF

Info

Publication number
US20030072915A1
US20030072915A1 US09/976,412 US97641201A US2003072915A1 US 20030072915 A1 US20030072915 A1 US 20030072915A1 US 97641201 A US97641201 A US 97641201A US 2003072915 A1 US2003072915 A1 US 2003072915A1
Authority
US
United States
Prior art keywords
wiper
wiper according
perimeter
perimeter edge
segment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US09/976,412
Inventor
Creighton Kelly
David Hildreth
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Milliken and Co
Original Assignee
Milliken and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Milliken and Co filed Critical Milliken and Co
Priority to US09/976,412 priority Critical patent/US20030072915A1/en
Assigned to MILLIKEN & COMPANY reassignment MILLIKEN & COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HILDRETH, DAVID D., KELLY, CREIGHTON C.
Priority to IL16107202A priority patent/IL161072A0/en
Priority to PCT/US2002/028775 priority patent/WO2003033799A1/en
Priority to CNA028201566A priority patent/CN1568384A/en
Priority to EP20020801625 priority patent/EP1434903A1/en
Priority to JP2003536514A priority patent/JP2005505706A/en
Priority to MXPA04003028A priority patent/MXPA04003028A/en
Priority to KR10-2004-7005363A priority patent/KR20040054713A/en
Priority to TW91122405A priority patent/TWI244519B/en
Publication of US20030072915A1 publication Critical patent/US20030072915A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00Woven fabrics designed to make specified articles
    • D03D1/0017Woven household fabrics
    • D03D1/0023Mobs or wipes
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/49Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads textured; curled; crimped
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/04Heat-responsive characteristics
    • D10B2401/041Heat-responsive characteristics thermoplastic; thermosetting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/2419Fold at edge
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/40Knit fabric [i.e., knit strand or strip material]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]

Definitions

  • This invention relates to the manufacturing of fabric wipers, in particular, wipers that release fewer and/or less offensive particulate contaminants while nonetheless exhibiting good sorbency and strength.
  • Wipers may be made from knitted, woven or non-woven fabrics of materials such as polyester and the like.
  • the typical manufacturing process begins with drawing and texturing continuous filament yarn.
  • the textured yarn is knitted or woven to construct a fabric, and the fabric is washed or scoured to remove spinning oils.
  • the fabric may be chemically modified in order to improve its wettability and performance.
  • the fabric is then dried in a “tenter frame” oven to remove moisture and heat set the fabric. Heat setting dissipates stress in the polyester fibers and stabilizes the fabric.
  • the fabric is cut into wipers, typically 9 inch by 9 inch squares.
  • the wipers may remain unlaundered or may be washed in a cleanroom laundry, employing special surfactants and highly-filtered and purified water, to reduce the contamination present on the fabric.
  • the wipers may be packaged dry in air-tight plastic bags, or pre-saturated with a suitable solvent before being packaged.
  • Diaber et al. U.S. Pat. No. 5,229,181 (incorporated by reference) describes a knit fabric tube, only two edges of which must be cut and sealed, thereby reducing the contamination caused by loose fibers from the edges.
  • Paley et al. U.S. Pat. No. 5,271,995, (incorporated by reference) describes a wiper for a cleanroom environment that has reduced inorganic contaminants through the use of a specific yarn, namely “nylon bright”.
  • Reynolds U.S. Pat. No. 5,069,735 (incorporated by reference) describes a procedure to cut the fabric into pieces using a hot air jet in the range of 600 to 800° F. to melt the fibers, forming a sealed edge product with reduced loose fiber contamination.
  • a low contaminant wiping cloth suitable for a wide range of applications is provided.
  • the wiper meets substantially all of the specifications for use in cleanrooms, particularly those specifications for Class 100 clean rooms and below.
  • a cleanroom wiper having a high liquid sorbency capacity is provided.
  • a wiping cloth which has substantially stable edges that do not undergo substantial particulate generating fracture upon application of tensile stresses applied during normal use.
  • a wiping cloth which incorporates yarns of substantially reduced inorganic ion content so as to reduce the effects of any particles which may be released.
  • FIG. 1 is an elevation plan view of one embodiment of a wiper according to the present invention
  • FIG. 2 is a view taken along line 2 - 2 in FIG. 1;
  • FIG. 3 is an elevation plan view of another embodiment of a wiper according to the present invention.
  • FIG. 4 is an elevation plan view of yet another embodiment of a wiper according to the present invention.
  • FIG. 5 is a view taken along line 5 - 5 in FIG. 4.
  • the wipers of the present invention may be constructed from a multiplicity of woven or knitted yarns of polyester fiber, preferably fibers of poly(ethylene terephthalate). Such yarn is preferably a continuous filament polyester yarn although other yarn types and constructions may likewise be utilized if necessary. It is contemplated that yarns having a wide variety of denier and filament count characteristics may be employed. Examples of useful yarns may include those having a denier to filament ratio of about 0.1 to about 10, incorporating deniers of about 15 to about 250. A wide range of fabric weights may be employed in the wipers of the present invention. Typically, the fabrics used for cleanroom wipers have a weight of about 1 to about 9 ounces per square yard, and more preferably about 3 to about 7 ounces per square yard.
  • the yarn employed in the fabric may be a textured polyester yarn.
  • Such yarns are commercially available and their manufacture is well known to those of skill in the art.
  • POY partially oriented yarn
  • a general description of the texturing process may be found in the Encyclopedia of Textiles, Fibers, and Non-woven Fabrics, Encyclopedia Reprint Series, Ed. Martin Grayson, pages 381-398, John Wylie and Sons (1984) and Dictionary of Fiber and Textile Technology, Hoechst Celanese (1989).
  • the yarn is preferably not heated above a temperature of 300° F. and is generally not heated above about 225° F.
  • the fabric is preferably subjected to washing and heat setting procedures as described in U.S. Pat. No. 6,189,189 to Morin et al. (incorporated by reference).
  • the fabric is preferably dried and heat set at a temperature from about 180° F. to about 300° F. and more preferably from 200° F. to 275° F. and most preferably from 225° F. to 265° F.
  • the heat set temperature is preferably set at a temperature higher than that which the yarns have previously experienced.
  • Such heat set treatment is believed to improve performance criteria applied to wipers for use in cleanroom environments including sorbency, as well as both the quantity and size of generated particles.
  • cleanroom wipers exhibit high levels of sorbency while generating low levels of particulate contaminants during use.
  • those particulate contaminants which may be generated have low levels of inorganic ionic constituents such as metallic constituents which may influence the performance of small scale integrated circuitry.
  • a wiper 10 formed of knitted polyester yarns is provided. While a knitted construction of substantially 100% polyester may be preferred, it is also contemplated that other constructions including woven and nonwoven constructions and other fibers including nylon and the like may also be utilized if desired.
  • the wiper 10 includes an interior wiping surface 12 and a multiplicity of perimeter edges.
  • the wiper 10 is of a substantially quadrilateral geometry such that the wiper 10 includes a first perimeter edge 14 and an opposing second perimeter edge 16 as well as a third perimeter edge 18 and a fourth perimeter edge 20 extending in a generally right angled relation between the first perimeter edge 14 and the second perimeter edge 16 .
  • wiper 10 is illustrated as being substantially square in configuration, it is likewise to be understood that the wiper 10 may take on any number of other geometries including by way of example only, and not limitation, a rectangular configuration or some other convenient multi-sided configuration such as a triangular, pentagonal, hexagonal, or octagonal geometry as may be desired.
  • the wiper 10 is cut from a much larger web of fabric having an extended length and a width sufficient to yield multiple wipers.
  • the wiper 10 is cut from such larger web of fabric according to a pattern such that the first and second perimeter edges 14 , 16 extend in the so called “cross-machine direction” disposed substantially transverse to the elongate direction of the fabric web.
  • the third and fourth perimeter edges 18 , 20 are preferably cut substantially along the so-called “machine direction” of the fabric generally parallel to the elongate direction of the fabric web.
  • first perimeter edge 14 and the second perimeter edge 16 extending in the cross-machine direction are each preferably provided along their length with a sealed edge 24 , 26 formed by a hot knife or laser cutting operation so as to seal the fibers along the raw cut edge of the wiper 10 .
  • first and second perimeter edges 14 , 16 are each preferably provided with an inwardly extending discontinuous fused border 28 , 30 extending inwardly from the adjacent sealed edges 24 , 26 towards the interior wiping surface 12 .
  • the discontinuous fused borders 28 , 30 are preferably made up of a multiplicity of discrete bond points 34 , 36 at which thermoplastic fibers such as polyester forming the wiper 10 have undergone localized melting thereby fusing together upon resolidification.
  • the bond points 34 , 36 extending in the cross-machine direction may be applied in a predefined repeating pattern utilizing a patterned embossing element such as an ultrasonic horn operating on one side of the fabric forming the wiper 10 in opposing relation to a surface patterned anvil disposed on the opposite side of the fabric forming the wiper 10 within a width corresponding to the desired width for the inwardly extending discontinuous fused borders 28 , 30 .
  • a patterned embossing element such as an ultrasonic horn operating on one side of the fabric forming the wiper 10 in opposing relation to a surface patterned anvil disposed on the opposite side of the fabric forming the wiper 10 within a width corresponding to the desired width for the inwardly extending discontinuous fused borders 28 , 30 .
  • other patterned fusion techniques may also be utilized such as using a patterned support on one side of the fabric and applying a hot ironing element across the opposing side so as to apply the series of bond points 34 ,
  • the discontinuous fused borders 28 , 30 extending in the cross-machine direction preferably have a relatively narrow width in the range of about 0.3 mm to about 1.6 mm and will most preferably have a width in the range of about 1.0 mm to about 1.4 mm although greater or lesser depths may likewise be utilized if desired.
  • the bond points 34 , 36 may be substantially rectangular in configuration arranged in a brick-like pattern within the discontinuous fused borders 28 , 30 such that the length dimension of the bond points 34 , 36 extends generally parallel to the outer sealed edges 24 , 26 .
  • the bond points may also be arranged in a pattern in the form of a message conveying icon such as a corporate logo, patent number or the like.
  • the rectangles forming the bond points are preferably in the range of about 0.75 mm wide by about 3 mm long and are spaced about 1 mm apart in defined rows. The rows are preferably about 0.5 mm apart with the bond points in adjacent rows being slightly offset from one another in another in a staggered relationship.
  • discontinuous fused borders 28 , 30 reduces the generation of particulate matter upon the application of tension in the direction parallel to such borders by allowing the force to be spread more evenly through the matrix formed by the interstitial areas between the bond points 34 , 36 thereby reducing the concentration of force which may lead to the localized breakage of fibers.
  • pre-stressing of the fabric may be carried out by stretching the fabric forming the wiper 10 during the introduction of the bond points 34 , 36 thereby essentially locking in a stretched relationship. Such stretching may be carried out by use of a stretching frame or by other means as will be well known to those of skill in the art. Upon release of the fabric following the introduction of bond points 34 , 36 a portion of the extension is relieved within the body of the wiper 10 but the bond points 34 , 36 serve to substantially lock in stretch along the perimeter edges 14 , 16 .
  • the third and fourth perimeter edges 18 , 20 extending in the machine direction preferably have a slightly different configuration.
  • the perimeter edges 18 , 20 extending in the machine direction of the wiper 10 are preferably formed by folding the edges inwardly so as to form double layer borders 38 , 40 .
  • melt fused attachment zones 48 , 50 are applied to thereby seal the double layer borders 38 , 40 in place.
  • the attachment zones 48 , 50 may be made up of a pattern of fusion bond points 44 , 46 formed by localized patterned melting of polyester or other thermoplastic fiber constituent in the manner described above.
  • the attachment zones 48 , 50 may also be in the form of solid melt fused strips extending inwardly from the inboard edge of the double layered borders 38 , 40 .
  • the double layer borders 38 , 40 which are preferably smooth and substantially free of fusion bond points provide an edge structure which is not substantially susceptible to fiber fracture upon stretching and is thus believed to promote the integrity of the edges during stretching thereby reducing the generation of particulates.
  • the attachment zones 48 , 50 are preferably broad enough such that a stable fusion bond relationship is established.
  • the attachment zones are made up of discrete bond points 44 , 46 as shown wherein the bond points 44 , 46 are of a substantially rectangular configuration having a width in the range of about 0.75 mm and a length in the range of about 3 mm arranged in an off-set brick pattern in rows approximately 0.5 mm apart, it is contemplated that at least about 3 and more preferably about 4 or more such rows are utilized.
  • the bond points 44 , 46 as described above in the relation to the fused borders 28 , 30 extending in the cross-machine direction may also be utilized if desired.
  • the bond points 44 , 46 disposed along the machine direction may be applied by use of any suitable patterned melt fusion device including by way of example only, and not limitation, an ultrasonic bonding apparatus using a rotating patterned anvil wheel or a patterned heat sink support used in conjunction with an ironing heat source.
  • the formation of the wiper 10 may be carried out in a highly efficient and automated manner by continuously slitting an elongate web of fabric to yield multiple parallel strips of desired width. This cutting may be carried out using a laser or hot knife to seal the lateral edges.
  • the strips are conveyed along a travel path through an edge folding apparatus at which a blade or paddle element is used to continuously fold the lateral edges of the strips so as to form the desired double layer borders 38 , 40 .
  • the strips are thereafter passed through ultrasonic bonding stations arranged generally transverse to the travel path of the strips at which the bond points 44 , 46 forming the fusion zones 48 , 50 along the lateral perimeter edges are applied.
  • the ultrasonic bonding stations used to form the bond points 44 , 46 within the fusion zones 48 , 50 may be generally similar to the device illustrated and described in U.S. Pat. No. 6,001,442 to Rockwell, Jr. (incorporated by reference) incorporating elongated horns and rail-like patterned anvils oriented in the direction of travel of the strips.
  • the inwardly extending discontinuous fused borders 28 , 30 extending in the cross machine direction are thereafter applied across the width of the segmented strips by ultrasonic bonding units incorporating an elongated horn and rail-like patterned backing anvil oriented generally transverse to the travel path of the strips.
  • the wiper 10 is segmented from the strip by use of a hot knife or laser, which serves to form the sealed edges 24 , 26 .
  • any number of other automated or manual techniques may likewise be utilized if desired.
  • FIG. 3 one such alternative construction is illustrated in FIG. 3 wherein elements corresponding to those described in relation to FIG. 1 are designated by like reference numerals increased by 100.
  • the embodiment of FIG. 3 is substantially identical to that of FIG. 1 except that the double layer borders 38 , 40 have been replaced by extended discontinuous fusion zones 148 , 150 which extend substantially to the adjacent perimeter edges 118 , 120 .
  • FIG. 4 there is illustrated yet another embodiment of the present invention wherein elements corresponding to those previously described in relation to FIG. 1 are designated by like reference numerals increased by 200.
  • the double layer folded edge structures are applied along each of the perimeter edges 214 , 216 , 218 , and 220 .
  • This configuration results in the occurrence of double layer borders 260 , 262 extending in the cross-machine direction along the first and second perimeter edges 214 , 216 with discontinuous fused borders 228 , 230 disposed inboard thereof as shown in FIG. 5.
  • Such a configuration is believed to further reduce the potential for the generation of particulates during use of the wiping cloth 210 .
  • the discontinuous fused borders 228 , 230 may be replaced by substantially continuous fusion zones such as strips extending inwardly from the double layer borders 260 , 262 .
  • the wipers of the present invention are formed from polymeric fibers incorporating very low levels of inorganic additives.
  • the fibers forming the wiper of the present invention are preferably formed of so-called “bright” or “clear” polyester.
  • Such fiber is substantially free of titanium dioxide (TiO 2 ) or other metal-based opasifying agent as is normally used to impart the traditional brilliant white character associated with polyester.
  • Titanium dioxide and other metallic ion compounds are prone to leeching into solution when placed in a highly acidic environment.
  • highly concentrated acid solutions such as sulfuric acid (H 2 SO 4 ) it has been recognized by the applicants that it may be desirable to reduce the presence of such ionic constituents within any particles which may be generated so as to avoid the accumulation and potential concentration of such ions within cleanroom acid solutions which may be used a number of times.
  • the fiber forming the wiper according to the present invention is preferably characterized by a concentration of inorganic ionic constituents at a level such that upon complete combustion of the fiber, the remaining ash content is in the range of less than about 0.30% of the initial fiber weight and is more preferably in the range of about zero to about 0.1% of the initial fiber weight and is most preferably in the range of about zero to about 0.3% of the initial fiber weight.
  • One such fiber which may be desirable in the formation of the wiper according to the present invention is believed to be available from E. I. DuPont de Nemours which is believed to have a place of business in Wilmington, Del.
  • the level of particulate generation associated with cleanroom wiper edges of various constructions has been determined by stretching a 6 centimeter segment of the wiper edge of interest to a length corresponding to the elongation occurring upon application of tension of 6 pounds force. This stretching takes place with the wiper edge held in the vertical position over a 14 cm funnel mounted on the end of an isokinetic probe linked to an airborne particle counter. The inverted wiper segment was stretched and held in tension for a period of 2 seconds and was removed while still taut. Resulting count of generated particles greater than or equal to about 0.3 microns was recorded upon stabilization of the counter.
  • Cleanroom wiper style “A” having edge constructions substantially as illustrated and described in relation to FIGS. 1 and 2 with double layer folded edges in the machine direction and discontinuous fused edges in the cross machine direction was formed from tightly constructed balanced knit fabric of double knit construction made up of 70 denier 36 filament polyester yarn with 41 wales per inch ⁇ 40 courses per inch and a weight of 3.7 ounces per square yard. Segments of both the double layer folded edges in the machine direction and the discontinuous edges in the cross-machine direction in thirty-one of the wipers were tested for particle generation under application of tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.
  • a cleanroom wiper style “B” formed of fabric as described in Example 1 was formed having thermally sealed edges in both the machine direction and the cross-machine direction. Thermal sealing was carried out in accordance with the teachings of U.S. Pat. No. 5,069,735. Edge segments in the machine direction and in the cross-machine direction in thirty-one of the wipers were tested for particle generation under tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.
  • a cleanroom wiper style “C” having inwardly extending fused edges as described in U.S Pat. No. 4,888,229 to Paley et al. in both the machine direction and the cross-machine direction was obtained from a commercial source.
  • the fabric forming the wiper was made up of 70 denier 34 filament polyester yarn in a double knit construction with 37 wales per inch ⁇ 47 courses per inch with a weight of 4.2 ounces per square yard. Edge segments in the machine direction and in the cross-machine direction in thirty-one of the wipers were tested for particle generation under application of tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.
  • a cleanroom wiper style “D” was formed having thermally sealed edges in both the machine direction and in the cross-machine direction. Thermal sealing was carried out in accordance with the teachings of U.S. Pat. No. 5,069,735.
  • the fabric forming the wiper was a double knit construction of 70 denier 36 filament polyester yarns having 43 wales per inch ⁇ 37 courses per inch and a weight of 3.52 ounces per square yard. Edge segments in the machine direction and in the cross-machine direction in thirty-one of the wipers were tested for particle generation under application of tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.

Abstract

A low particle generating wiper for use in a particle sensitive environment. The wiper is constructed at least partly of a textile fabric formed from a multiplicity of yarns including thermoplastic filaments. The wiper includes an interior surrounded by perimeter edges. The perimeter edges are constructed such that filaments within the yarns at the perimeter edge undergo a reduced occurrence of fracture under tension thereby potentially reducing particle generation during use.

Description

    TECHNICAL FIELD
  • This invention relates to the manufacturing of fabric wipers, in particular, wipers that release fewer and/or less offensive particulate contaminants while nonetheless exhibiting good sorbency and strength. [0001]
  • BACKGROUND OF THE INVENTION
  • Wipers may be made from knitted, woven or non-woven fabrics of materials such as polyester and the like. The typical manufacturing process begins with drawing and texturing continuous filament yarn. The textured yarn is knitted or woven to construct a fabric, and the fabric is washed or scoured to remove spinning oils. The fabric may be chemically modified in order to improve its wettability and performance. The fabric is then dried in a “tenter frame” oven to remove moisture and heat set the fabric. Heat setting dissipates stress in the polyester fibers and stabilizes the fabric. [0002]
  • Next, the fabric is cut into wipers, typically 9 inch by 9 inch squares. The wipers may remain unlaundered or may be washed in a cleanroom laundry, employing special surfactants and highly-filtered and purified water, to reduce the contamination present on the fabric. After washing, the wipers may be packaged dry in air-tight plastic bags, or pre-saturated with a suitable solvent before being packaged. [0003]
  • These wipers are utilized for a number of different applications, including cleaning within cleanrooms, automotive painting rooms and other environments in which particulate contaminants are undesirable. Each different application emphasizes certain standards these types of wipers should attain. For example, for wipers utilized in cleanrooms, stringent performance standards must be met. These standards are related to sorbency and contamination, including maximum allowable particulates, unspecified extractable matter and individual ionic contaminants. The standards for particular contaminant release are especially rigorous and various methods have been devised to meet them. For example, Paley et al., U.S. Pat. No. 4,888,229 (incorporated by reference) describes a wiper having fused borders, the sealed edge of the wipers being present to reduce contamination caused by small fibers. Diaber et al., U.S. Pat. No. 5,229,181 (incorporated by reference) describes a knit fabric tube, only two edges of which must be cut and sealed, thereby reducing the contamination caused by loose fibers from the edges. Paley et al., U.S. Pat. No. 5,271,995, (incorporated by reference) describes a wiper for a cleanroom environment that has reduced inorganic contaminants through the use of a specific yarn, namely “nylon bright”. Reynolds, U.S. Pat. No. 5,069,735 (incorporated by reference) describes a procedure to cut the fabric into pieces using a hot air jet in the range of 600 to 800° F. to melt the fibers, forming a sealed edge product with reduced loose fiber contamination. [0004]
  • Despite advantages made in reducing particulate contamination release from cleanroom wipers, further reductions in particulate release are, nevertheless, highly desirable. [0005]
  • SUMMARY OF THE INVENTION
  • According to one aspect of the invention, a low contaminant wiping cloth suitable for a wide range of applications is provided. The wiper meets substantially all of the specifications for use in cleanrooms, particularly those specifications for Class 100 clean rooms and below. [0006]
  • According to another aspect of the invention, a cleanroom wiper having a high liquid sorbency capacity is provided. [0007]
  • According to still another aspect of the invention, a wiping cloth is provided which has substantially stable edges that do not undergo substantial particulate generating fracture upon application of tensile stresses applied during normal use. [0008]
  • According to still another aspect of the invention, a wiping cloth is provided which incorporates yarns of substantially reduced inorganic ion content so as to reduce the effects of any particles which may be released.[0009]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The present invention will now be described by way of example only, with reference to the accompanying drawings which constitute a part of this specification and in which: [0010]
  • FIG. 1 is an elevation plan view of one embodiment of a wiper according to the present invention; [0011]
  • FIG. 2 is a view taken along line [0012] 2-2 in FIG. 1;
  • FIG. 3 is an elevation plan view of another embodiment of a wiper according to the present invention; [0013]
  • FIG. 4 is an elevation plan view of yet another embodiment of a wiper according to the present invention; and [0014]
  • FIG. 5 is a view taken along line [0015] 5-5 in FIG. 4.
  • While the invention has been illustrated and will hereinafter be described in detail in connection with certain potentially preferred embodiments and practices, it is to be understood that the foregoing general description as well as the following detailed description and accompanying drawings are exemplary and explanatory only and in no event is the invention intended to be limited thereby. On the contrary, it is intended that the present invention shall extend to all alternatives, modifications and equivalents as may embrace the broad principles of this invention within the true spirit and scope thereof. [0016]
  • DESCRIPTION OF PREFERRED EMBODIMENTS
  • Reference will now be made to the drawings, wherein to the extent possible, like elements are designated by like reference numerals throughout the various views. All of the United States patents cited within the specification are hereby incorporated by reference in their entirety as if fully set forth herein. [0017]
  • According to the potentially preferred practice, the wipers of the present invention may be constructed from a multiplicity of woven or knitted yarns of polyester fiber, preferably fibers of poly(ethylene terephthalate). Such yarn is preferably a continuous filament polyester yarn although other yarn types and constructions may likewise be utilized if necessary. It is contemplated that yarns having a wide variety of denier and filament count characteristics may be employed. Examples of useful yarns may include those having a denier to filament ratio of about 0.1 to about 10, incorporating deniers of about 15 to about 250. A wide range of fabric weights may be employed in the wipers of the present invention. Typically, the fabrics used for cleanroom wipers have a weight of about 1 to about 9 ounces per square yard, and more preferably about 3 to about 7 ounces per square yard. [0018]
  • If desired, it is contemplated that the yarn employed in the fabric may be a textured polyester yarn. Such yarns are commercially available and their manufacture is well known to those of skill in the art. Briefly, partially oriented yarn (POY) is modified by crimping, imparting random loops, or otherwise modifying the bulk or surface texture of the yarn to increase cover, absorbency, resilience, abrasion resistance, warmth, insulation and/or to improve aesthetics. A general description of the texturing process may be found in the Encyclopedia of Textiles, Fibers, and Non-woven Fabrics, Encyclopedia Reprint Series, Ed. Martin Grayson, pages 381-398, John Wylie and Sons (1984) and Dictionary of Fiber and Textile Technology, Hoechst Celanese (1989). During the texturing process the yarn is preferably not heated above a temperature of 300° F. and is generally not heated above about 225° F. [0019]
  • According to one potentially preferred practice of the present invention, once formed, the fabric is preferably subjected to washing and heat setting procedures as described in U.S. Pat. No. 6,189,189 to Morin et al. (incorporated by reference). In particular, the fabric is preferably dried and heat set at a temperature from about 180° F. to about 300° F. and more preferably from 200° F. to 275° F. and most preferably from 225° F. to 265° F. The heat set temperature is preferably set at a temperature higher than that which the yarns have previously experienced. Such heat set treatment is believed to improve performance criteria applied to wipers for use in cleanroom environments including sorbency, as well as both the quantity and size of generated particles. [0020]
  • In general, it is desired that cleanroom wipers exhibit high levels of sorbency while generating low levels of particulate contaminants during use. Moreover, it is desired that those particulate contaminants which may be generated have low levels of inorganic ionic constituents such as metallic constituents which may influence the performance of small scale integrated circuitry. [0021]
  • It has been recognized that during use of a wiper, the edges of the wiper may give rise to a disproportionately high level of particulate generation. It is theorized that such disproportionate particulate generation arises from the breaking of fiber elements along the high-energy surfaces at the perimeter edges of the wiper. To alleviate this problem it has been proposed to fuse the borders of the wipers either just along the edge or in a substantially solid fusion zone extending a distance inwardly from the edge towards the interior of the wiper. Such fused zones may be imparted by melting the fibers within the zones by use of energy delivered from a directional heat application source. However, fused edges or extended borders may tend to reduce elasticity in those areas relative to the remainder of the wiper. Thus, upon a stretching of the wiper, the fused edges or extended borders may tend to undergo premature localized fracture thereby releasing potentially undesired particulate matter. [0022]
  • According to a first embodiment of the present invention as illustrated in FIG. 1, a [0023] wiper 10 formed of knitted polyester yarns is provided. While a knitted construction of substantially 100% polyester may be preferred, it is also contemplated that other constructions including woven and nonwoven constructions and other fibers including nylon and the like may also be utilized if desired.
  • As shown, the [0024] wiper 10 includes an interior wiping surface 12 and a multiplicity of perimeter edges. In the illustrated and potentially preferred embodiment the wiper 10 is of a substantially quadrilateral geometry such that the wiper 10 includes a first perimeter edge 14 and an opposing second perimeter edge 16 as well as a third perimeter edge 18 and a fourth perimeter edge 20 extending in a generally right angled relation between the first perimeter edge 14 and the second perimeter edge 16. While the wiper 10 is illustrated as being substantially square in configuration, it is likewise to be understood that the wiper 10 may take on any number of other geometries including by way of example only, and not limitation, a rectangular configuration or some other convenient multi-sided configuration such as a triangular, pentagonal, hexagonal, or octagonal geometry as may be desired.
  • As will be appreciated, the [0025] wiper 10 is cut from a much larger web of fabric having an extended length and a width sufficient to yield multiple wipers. According to a potentially preferred practice, the wiper 10 is cut from such larger web of fabric according to a pattern such that the first and second perimeter edges 14, 16 extend in the so called “cross-machine direction” disposed substantially transverse to the elongate direction of the fabric web. Correspondingly, the third and fourth perimeter edges 18, 20 are preferably cut substantially along the so-called “machine direction” of the fabric generally parallel to the elongate direction of the fabric web.
  • As illustrated, the [0026] first perimeter edge 14 and the second perimeter edge 16 extending in the cross-machine direction are each preferably provided along their length with a sealed edge 24, 26 formed by a hot knife or laser cutting operation so as to seal the fibers along the raw cut edge of the wiper 10. In addition, the first and second perimeter edges 14, 16 are each preferably provided with an inwardly extending discontinuous fused border 28, 30 extending inwardly from the adjacent sealed edges 24, 26 towards the interior wiping surface 12. As shown, the discontinuous fused borders 28, 30 are preferably made up of a multiplicity of discrete bond points 34, 36 at which thermoplastic fibers such as polyester forming the wiper 10 have undergone localized melting thereby fusing together upon resolidification.
  • It is contemplated that the bond points [0027] 34, 36 extending in the cross-machine direction may be applied in a predefined repeating pattern utilizing a patterned embossing element such as an ultrasonic horn operating on one side of the fabric forming the wiper 10 in opposing relation to a surface patterned anvil disposed on the opposite side of the fabric forming the wiper 10 within a width corresponding to the desired width for the inwardly extending discontinuous fused borders 28, 30. Of course, other patterned fusion techniques may also be utilized such as using a patterned support on one side of the fabric and applying a hot ironing element across the opposing side so as to apply the series of bond points 34, 36.
  • According to the illustrated and potentially preferred practice, the discontinuous fused [0028] borders 28, 30 extending in the cross-machine direction preferably have a relatively narrow width in the range of about 0.3 mm to about 1.6 mm and will most preferably have a width in the range of about 1.0 mm to about 1.4 mm although greater or lesser depths may likewise be utilized if desired. As shown, according to one embodiment, the bond points 34, 36 may be substantially rectangular in configuration arranged in a brick-like pattern within the discontinuous fused borders 28, 30 such that the length dimension of the bond points 34, 36 extends generally parallel to the outer sealed edges 24, 26. Of course, it is contemplated that any number of other geometric arrangements may be likewise be utilized including, by way of example only, and not limitation, discrete substantially circular bond points, elongate elliptical bond points, square bond points, and other geometries. Moreover, due to their discontinuous nature, the bond points may also be arranged in a pattern in the form of a message conveying icon such as a corporate logo, patent number or the like. According to the illustrated practice wherein the bond points are substantially rectangular in configuration, the rectangles forming the bond points are preferably in the range of about 0.75 mm wide by about 3 mm long and are spaced about 1 mm apart in defined rows. The rows are preferably about 0.5 mm apart with the bond points in adjacent rows being slightly offset from one another in another in a staggered relationship.
  • It is believed that the utilization of the discontinuous fused [0029] borders 28, 30 reduces the generation of particulate matter upon the application of tension in the direction parallel to such borders by allowing the force to be spread more evenly through the matrix formed by the interstitial areas between the bond points 34, 36 thereby reducing the concentration of force which may lead to the localized breakage of fibers.
  • It is contemplated that load distribution may be further enhanced by pre-stressing the [0030] wiper 10 in the cross-machine direction prior to introduction of the discontinuous fused borders 28, 30. According to one potentially preferred practice, pre-stressing of the fabric may be carried out by stretching the fabric forming the wiper 10 during the introduction of the bond points 34, 36 thereby essentially locking in a stretched relationship. Such stretching may be carried out by use of a stretching frame or by other means as will be well known to those of skill in the art. Upon release of the fabric following the introduction of bond points 34, 36 a portion of the extension is relieved within the body of the wiper 10 but the bond points 34, 36 serve to substantially lock in stretch along the perimeter edges 14, 16.
  • As shown, the third and fourth perimeter edges [0031] 18, 20 extending in the machine direction preferably have a slightly different configuration. As best seen by simultaneous reference to FIGS. 1 and 2, the perimeter edges 18, 20 extending in the machine direction of the wiper 10 are preferably formed by folding the edges inwardly so as to form double layer borders 38, 40. Inboard of the double layer borders 38, 40 melt fused attachment zones 48, 50 are applied to thereby seal the double layer borders 38, 40 in place. As shown, according to one embodiment, the attachment zones 48, 50 may be made up of a pattern of fusion bond points 44, 46 formed by localized patterned melting of polyester or other thermoplastic fiber constituent in the manner described above. However, if desired, the attachment zones 48, 50 may also be in the form of solid melt fused strips extending inwardly from the inboard edge of the double layered borders 38, 40.
  • The double layer borders [0032] 38, 40 which are preferably smooth and substantially free of fusion bond points provide an edge structure which is not substantially susceptible to fiber fracture upon stretching and is thus believed to promote the integrity of the edges during stretching thereby reducing the generation of particulates. The attachment zones 48, 50 (whether solid or discontinuous in nature) are preferably broad enough such that a stable fusion bond relationship is established. By way of example only, and not limitation, in the event that the attachment zones are made up of discrete bond points 44, 46 as shown wherein the bond points 44, 46 are of a substantially rectangular configuration having a width in the range of about 0.75 mm and a length in the range of about 3 mm arranged in an off-set brick pattern in rows approximately 0.5 mm apart, it is contemplated that at least about 3 and more preferably about 4 or more such rows are utilized. Of course other geometries for the bond points 44, 46 as described above in the relation to the fused borders 28, 30 extending in the cross-machine direction may also be utilized if desired.
  • As with the bond points [0033] 34, 36 extending along the cross-machine direction of the wiper 10, it is contemplated that the bond points 44, 46 disposed along the machine direction may be applied by use of any suitable patterned melt fusion device including by way of example only, and not limitation, an ultrasonic bonding apparatus using a rotating patterned anvil wheel or a patterned heat sink support used in conjunction with an ironing heat source.
  • According to one practice, it is contemplated that the formation of the [0034] wiper 10 may be carried out in a highly efficient and automated manner by continuously slitting an elongate web of fabric to yield multiple parallel strips of desired width. This cutting may be carried out using a laser or hot knife to seal the lateral edges. The strips are conveyed along a travel path through an edge folding apparatus at which a blade or paddle element is used to continuously fold the lateral edges of the strips so as to form the desired double layer borders 38, 40. The strips are thereafter passed through ultrasonic bonding stations arranged generally transverse to the travel path of the strips at which the bond points 44, 46 forming the fusion zones 48, 50 along the lateral perimeter edges are applied. By way of example only, it is contemplated that the ultrasonic bonding stations used to form the bond points 44,46 within the fusion zones 48, 50 may be generally similar to the device illustrated and described in U.S. Pat. No. 6,001,442 to Rockwell, Jr. (incorporated by reference) incorporating elongated horns and rail-like patterned anvils oriented in the direction of travel of the strips. The inwardly extending discontinuous fused borders 28, 30 extending in the cross machine direction are thereafter applied across the width of the segmented strips by ultrasonic bonding units incorporating an elongated horn and rail-like patterned backing anvil oriented generally transverse to the travel path of the strips. The wiper 10 is segmented from the strip by use of a hot knife or laser, which serves to form the sealed edges 24, 26. Of course, any number of other automated or manual techniques may likewise be utilized if desired.
  • As will be appreciated, the present invention is susceptible to a wide range of alternative constructions. By way of example only, one such alternative construction is illustrated in FIG. 3 wherein elements corresponding to those described in relation to FIG. 1 are designated by like reference numerals increased by 100. As shown, the embodiment of FIG. 3 is substantially identical to that of FIG. 1 except that the double layer borders [0035] 38, 40 have been replaced by extended discontinuous fusion zones 148, 150 which extend substantially to the adjacent perimeter edges 118, 120.
  • In FIG. 4 there is illustrated yet another embodiment of the present invention wherein elements corresponding to those previously described in relation to FIG. 1 are designated by like reference numerals increased by 200. As shown, in this embodiment, the double layer folded edge structures are applied along each of the perimeter edges [0036] 214, 216, 218, and 220. This configuration results in the occurrence of double layer borders 260, 262 extending in the cross-machine direction along the first and second perimeter edges 214, 216 with discontinuous fused borders 228, 230 disposed inboard thereof as shown in FIG. 5. Such a configuration is believed to further reduce the potential for the generation of particulates during use of the wiping cloth 210. Of course, if desired, the discontinuous fused borders 228, 230 may be replaced by substantially continuous fusion zones such as strips extending inwardly from the double layer borders 260, 262.
  • Aside from the reduction in the potential for particle generation as the edges of the wiper are stretched, the present invention further contemplates that the relative impact of such particles may be reduced substantially through selection of the materials of construction forming the wiper. According to a potentially preferred practice, the wipers of the present invention are formed from polymeric fibers incorporating very low levels of inorganic additives. In particular, the fibers forming the wiper of the present invention are preferably formed of so-called “bright” or “clear” polyester. Such fiber is substantially free of titanium dioxide (TiO[0037] 2) or other metal-based opasifying agent as is normally used to impart the traditional brilliant white character associated with polyester. Titanium dioxide and other metallic ion compounds are prone to leeching into solution when placed in a highly acidic environment. In view of the fact that many electronic fabrication procedures utilize highly concentrated acid solutions such as sulfuric acid (H2SO4) it has been recognized by the applicants that it may be desirable to reduce the presence of such ionic constituents within any particles which may be generated so as to avoid the accumulation and potential concentration of such ions within cleanroom acid solutions which may be used a number of times.
  • According to the potentially preferred practice, the fiber forming the wiper according to the present invention is preferably characterized by a concentration of inorganic ionic constituents at a level such that upon complete combustion of the fiber, the remaining ash content is in the range of less than about 0.30% of the initial fiber weight and is more preferably in the range of about zero to about 0.1% of the initial fiber weight and is most preferably in the range of about zero to about 0.3% of the initial fiber weight. One such fiber which may be desirable in the formation of the wiper according to the present invention is believed to be available from E. I. DuPont de Nemours which is believed to have a place of business in Wilmington, Del. [0038]
  • Testing
  • The level of particulate generation associated with cleanroom wiper edges of various constructions has been determined by stretching a 6 centimeter segment of the wiper edge of interest to a length corresponding to the elongation occurring upon application of tension of 6 pounds force. This stretching takes place with the wiper edge held in the vertical position over a 14 cm funnel mounted on the end of an isokinetic probe linked to an airborne particle counter. The inverted wiper segment was stretched and held in tension for a period of 2 seconds and was removed while still taut. Resulting count of generated particles greater than or equal to about 0.3 microns was recorded upon stabilization of the counter. [0039]
  • The invention may be further understood by reference to the following comparative examples. [0040]
  • EXAMPLE 1
  • Cleanroom wiper style “A” having edge constructions substantially as illustrated and described in relation to FIGS. 1 and 2 with double layer folded edges in the machine direction and discontinuous fused edges in the cross machine direction was formed from tightly constructed balanced knit fabric of double knit construction made up of 70 [0041] denier 36 filament polyester yarn with 41 wales per inch×40 courses per inch and a weight of 3.7 ounces per square yard. Segments of both the double layer folded edges in the machine direction and the discontinuous edges in the cross-machine direction in thirty-one of the wipers were tested for particle generation under application of tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.
  • EXAMPLE 2
  • A cleanroom wiper style “B” formed of fabric as described in Example 1 was formed having thermally sealed edges in both the machine direction and the cross-machine direction. Thermal sealing was carried out in accordance with the teachings of U.S. Pat. No. 5,069,735. Edge segments in the machine direction and in the cross-machine direction in thirty-one of the wipers were tested for particle generation under tension according to the testing procedure as described above. The results of such testing are set forth in Table 1. [0042]
  • EXAMPLE 3
  • A cleanroom wiper style “C” having inwardly extending fused edges as described in U.S Pat. No. 4,888,229 to Paley et al. in both the machine direction and the cross-machine direction was obtained from a commercial source. The fabric forming the wiper was made up of 70 [0043] denier 34 filament polyester yarn in a double knit construction with 37 wales per inch×47 courses per inch with a weight of 4.2 ounces per square yard. Edge segments in the machine direction and in the cross-machine direction in thirty-one of the wipers were tested for particle generation under application of tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.
  • EXAMPLE 4
  • A cleanroom wiper style “D” was formed having thermally sealed edges in both the machine direction and in the cross-machine direction. Thermal sealing was carried out in accordance with the teachings of U.S. Pat. No. 5,069,735. The fabric forming the wiper was a double knit construction of 70 [0044] denier 36 filament polyester yarns having 43 wales per inch×37 courses per inch and a weight of 3.52 ounces per square yard. Edge segments in the machine direction and in the cross-machine direction in thirty-one of the wipers were tested for particle generation under application of tension according to the testing procedure as described above. The results of such testing are set forth in Table 1.
    TABLE 1
    A B C D
    A Cross- B Cross- C Cross- D Cross-
    Machine Machine Machine Machine Machine Machine Machine Machine
    Wiper Style Direction Direction Direction Direction Direction Direction Direction Direction
    Average 409 1357 3702 1433 2875 3731 2030 1598
    Particle Count
    Measurement
    High Particle 936 2205 5955 2754 6018 7173 3712 2601
    Count
    Measurement
    Low Particle 84 203 1471 402 1020 1643 879 682
    Count
    Measurement
    Standard 233 604 1455 556 1251 1634 721 614
    Deviation
    Statistical 301 1078 3029 1176 2296 2975 1697 1314
    Mean Lower
    Confidence
    limit 99%
    Statistical 516 1636 4375 1690 3454 4487 2363 1882
    Mean Upper
    Confidence
    limit (99%)
  • This data is believed to confirm that the double edge construction of wiper style “A” results in a dramatic improvement in both the average and actual number of particles generated in tension over that which is believed to have been available heretofore. Likewise, in regions where a non-folded extended border zone is utilized, the inwardly extending discontinuous fused border edge construction of wiper style “A” provides much lower particle generation than the inwardly extending solid fused border of wiper style “C”. [0045]
  • While the present invention has been illustrated and described in relation to certain potentially preferred embodiments, constructions, and procedures, it is to be understood and appreciated that such embodiments, constructions, and procedures are illustrative and exemplary only and that the present invention is in no event to be limited thereto. Rather, it is contemplated that modifications and variations embodying the principles of the present invention will no doubt occur to those of skill in the art to which the invention pertains. It is therefore contemplated and intended that the present invention shall extend to all such modifications and variations as may incorporate the broad principles of the invention in the full spirit and scope thereof. [0046]

Claims (36)

What is claimed is:
1. A wiper suitable for use in a cleanroom environment and being constructed at least partly of a textile fabric having a machine direction and a cross-machine direction, said fabric being formed from a multiplicity of yarns including thermoplastic filaments, the wiper comprising: an interior and a plurality of perimeter edges disposed in surrounding relation to the interior and at least one discontinuous fused border zone disposed inboard of and extending substantially parallel to at least one of the perimeter edges, wherein said discontinuous fused border zone comprises a plurality of substantially discrete fusion points formed by localized melt fusion of said thermoplastic filaments such that said discrete fusion points are disposed within a matrix of unmelted material.
2. The wiper according to claim 1, wherein said thermoplastic filaments are polyester.
3. The wiper according to claim 2, wherein said textile fabric is formed substantially entirely of polyester.
4. The wiper according to claim 3, wherein said textile fabric is subjected to heat setting at a temperature of from 180 to 300 degrees Fahrenheit and wherein said yarns have not been heated above a temperature of 300 degrees Fahrenheit.
5. The wiper according to claim 3, wherein said polyester is substantially free of inorganic ionic additives such that complete combustion of said polyester, yields an ash content of not greater than about zero to about 0.1% of the initial weight of said polyester.
6. The wiper according to claim 5, wherein said textile fabric is selected from the group consisting of knit fabric, woven fabric and nonwoven fabric.
7. The wiper according to claim 6, wherein the yarns forming the textile fabric have a linear density in the range of about 15 to about 250 denier.
8. The wiper according to claim 7, wherein said substantially discrete fusion points within said discontinuous fused border zone are ultrasonically induced.
9. The wiper according to claim 7, wherein said substantially discrete fusion points are of elongate geometry arranged in end to end relation in a plurality of rows extending substantially parallel to said perimeter edge.
10. The wiper according to claim 9, wherein the discrete fusion points are staggered in relation to the discrete fusion points in adjacent rows such that a brickwork pattern is formed.
11. The wiper according to claim 1, wherein the wiper is quadrilateral in configuration and wherein a first discontinuous fused border zone is disposed inboard of and substantially parallel to a first perimeter edge and wherein a second discontinuous fused border zone is disposed inboard of and substantially parallel to a second perimeter edge in opposing relation to said first perimeter edge.
12. The wiper according to claim 11, wherein the first and second perimeter edges extend in the cross-machine direction of the textile fabric.
13. The wiper according to claim 11, wherein a third discontinuous fused border zone is disposed inboard of and substantially parallel to a third perimeter edge and wherein a fourth discontinuous fused border zone is disposed inboard of and substantially parallel to a fourth perimeter edge in opposing relation to said third perimeter edge.
14. The wiper according to claim 13, wherein the first and second perimeter edges extend in the cross-machine direction of the textile fabric and wherein the third and fourth perimeter edges extend in the machine direction of the textile fabric.
15. A wiper suitable for use in a cleanroom environment and being constructed at least partly of a textile fabric having a machine direction and a cross-machine direction, said fabric being formed from a multiplicity of yarns including thermoplastic filaments, the wiper comprising: an interior and a plurality of perimeter edges disposed in surrounding relation to the interior wherein at least one of said perimeter edges comprises a folded double layer border and a fused attachment zone disposed inboard of the folded double layer border, wherein said fused attachment zone is formed by melt fusion of said thermoplastic filaments.
16. The wiper according to claim 15, wherein said thermoplastic filaments are polyester.
17. The wiper according to claim 16, wherein said textile fabric is formed substantially entirely of polyester.
18. The wiper according to claim 17, wherein said textile fabric is subjected to heat setting at a temperature of from 180 to 300 degrees Fahrenheit and wherein said yarns have not been heated above a temperature of 300 degrees Fahrenheit.
19. The wiper according to claim 17, wherein said polyester is substantially free of inorganic ionic additives such that complete combustion of said polyester, yields an ash content of not greater than about zero to about 0.1% of the initial weight of said polyester.
20. The wiper according to claim 19, wherein said textile fabric is selected from the group consisting of knit fabric, woven fabric and nonwoven fabric.
21. The wiper according to claim 20, wherein the yarns forming the textile fabric have a linear density in the range of about 15 to about 250 denier.
22. The wiper according to claim 21, wherein said fused attachment zone is ultrasonically induced.
23. The wiper according to claim 15, wherein said fused attachment zone comprises a plurality of substantially discrete fusion points formed by localized melt fusion of said thermoplastic filaments such that said discrete fusion points are disposed within a matrix of unmelted material.
24. The wiper according to claim 23, wherein said substantially discrete fusion points are of elongate geometry arranged in end to end relation in a plurality of rows extending substantially parallel to said double layer border.
25. The wiper according to claim 24, wherein the discrete fusion points are staggered in relation to the discrete fusion points in adjacent rows such that a brickwork pattern is formed.
26. The wiper according to claim 15, wherein the wiper is quadrilateral in configuration and wherein a first folded double layer border defines a first perimeter edge and wherein a second folded double layer border defines a second perimeter edge in opposing relation to said first perimeter edge.
27. The wiper according to claim 26, wherein the first and second perimeter edges extend in the machine direction of the textile fabric.
28. The wiper according to claim 26, wherein a third folded double layer border defines a third perimeter edge and wherein a fourth folded double layer border defines a fourth perimeter edge in opposing relation to said third perimeter edge.
29. A wiper suitable for use in a cleanroom environment and being constructed at least partly of a textile fabric having a machine direction and a cross-machine direction, said fabric being formed from a multiplicity of yarns including thermoplastic filaments, the wiper comprising: an interior and four perimeter edges disposed in surrounding relation to the interior wherein at least one of said perimeter edges comprises a folded double layer border and a fused attachment zone disposed inboard of the folded double layer border, wherein said fused attachment zone is formed by melt fusion of said thermoplastic filaments and wherein at least one other of said perimeter edges comprises a thermally sealed edge and a discontinuous fused border zone extending inwardly from said thermally sealed edge wherein said discontinuous fused border zone comprises a plurality of substantially discrete fusion points formed by localized patterned melt fusion of said thermoplastic filaments such that said discrete fusion points are disposed within a matrix of unmelted material.
30. The wiper according to claim 29, wherein the wiper is of substantially right-angled quadrilateral configuration and wherein a first discontinuous fused border zone is disposed inboard of and substantially parallel to a first perimeter edge and wherein a second discontinuous fused border zone is disposed inboard of and substantially parallel to a second perimeter edge in opposing relation to said first perimeter edge and wherein a first folded double layer border defines a third perimeter edge extending between said first perimeter edge and said second perimeter edge and wherein a second folded double layer border defines a fourth perimeter edge in opposing relation to said third perimeter edge.
31. The wiper according to claim 30, wherein the first and second perimeter edges extend in the cross-machine direction of the textile fabric and wherein the third and fourth perimeter edges extend in the machine direction of the textile fabric.
32. A cleanroom wiper constructed at least partly of a textile fabric formed from a multiplicity of filament containing yarns, the wiper comprising: an interior and plurality of perimeter edges disposed in surrounding relation to the interior wherein at least one of said perimeter edges is characterized by a low discharge of particles under tension such that on average less than about 1000 particles of size greater than or equal to 0.3 microns are generated during a use simulation procedure wherein a substantially untensioned six centimeter segment of said at least one perimeter edge is stretched in a vertical direction within a particle collection environment such that said segment is under a tension of six pounds force, said segment is retained within the particle collection environment in the stretched condition for a period of 2 seconds and said segment is thereafter removed from the particle collection environment prior to relief of the stretched condition.
33. The wiper according to claim 32 wherein at least one of said perimeter edges is characterized by a low discharge of particles under tension such that on average less than about 900 particles of size greater than or equal to 0.3 microns are generated during a use simulation procedure wherein a substantially untensioned six centimeter segment of said at least one perimeter edge is stretched in a vertical direction within a particle collection environment such that said segment is under a tension of six pounds force, said segment is retained within the particle collection environment in the stretched condition for a period of 2 seconds and said segment is thereafter removed from the particle collection environment prior to relief of the stretched condition.
34. The wiper according to claim 32 wherein at least one of said perimeter edges is characterized by a low discharge of particles under tension such that on average less than about 800 particles of size greater than or equal to 0.3 microns are generated during a use simulation procedure wherein a substantially untensioned six centimeter segment of said at least one perimeter edge is stretched in a vertical direction within a particle collection environment such that said segment is under a tension of six pounds force, said segment is retained within the particle collection environment in the stretched condition for a period of 2 seconds and said segment is thereafter removed from the particle collection environment prior to relief of the stretched condition.
35. The wiper according to claim 32 wherein at least one of said perimeter edges is characterized by a low discharge of particles under tension such that on average less than about 700 particles of size greater than or equal to 0.3 microns are generated during a use simulation procedure wherein a substantially untensioned six centimeter segment of said at least one perimeter edge is stretched in a vertical direction within a particle collection environment such that said segment is under a tension of six pounds force, said segment is retained within the particle collection environment in the stretched condition for a period of 2 seconds and said segment is thereafter removed from the particle collection environment prior to relief of the stretched condition.
36. The wiper according to claim 32 wherein at least one of said perimeter edges is characterized by a low discharge of particles under tension such that on average less than about 600 particles of size greater than or equal to 0.3 microns are generated during a use simulation procedure wherein a substantially untensioned six centimeter segment of said at least one perimeter edge is stretched in a vertical direction within a particle collection environment such that said segment is under a tension of six pounds force, said segment is retained within the particle collection environment in the stretched condition for a period of 2 seconds and said segment is thereafter removed from the particle collection environment prior to relief of the stretched condition.
US09/976,412 2001-10-12 2001-10-12 Low contaminant wiper Abandoned US20030072915A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US09/976,412 US20030072915A1 (en) 2001-10-12 2001-10-12 Low contaminant wiper
KR10-2004-7005363A KR20040054713A (en) 2001-10-12 2002-09-10 Low contaminant wiper
EP20020801625 EP1434903A1 (en) 2001-10-12 2002-09-10 Low contaminant wiper
PCT/US2002/028775 WO2003033799A1 (en) 2001-10-12 2002-09-10 Low contaminant wiper
CNA028201566A CN1568384A (en) 2001-10-12 2002-09-10 Low contaminant wiper
IL16107202A IL161072A0 (en) 2001-10-12 2002-09-10 Low contaminant wiper
JP2003536514A JP2005505706A (en) 2001-10-12 2002-09-10 Low-contamination cloth
MXPA04003028A MXPA04003028A (en) 2001-10-12 2002-09-10 Low contaminant wiper.
TW91122405A TWI244519B (en) 2001-10-12 2002-09-27 Low contaminant wiper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/976,412 US20030072915A1 (en) 2001-10-12 2001-10-12 Low contaminant wiper

Publications (1)

Publication Number Publication Date
US20030072915A1 true US20030072915A1 (en) 2003-04-17

Family

ID=25524073

Family Applications (1)

Application Number Title Priority Date Filing Date
US09/976,412 Abandoned US20030072915A1 (en) 2001-10-12 2001-10-12 Low contaminant wiper

Country Status (9)

Country Link
US (1) US20030072915A1 (en)
EP (1) EP1434903A1 (en)
JP (1) JP2005505706A (en)
KR (1) KR20040054713A (en)
CN (1) CN1568384A (en)
IL (1) IL161072A0 (en)
MX (1) MXPA04003028A (en)
TW (1) TWI244519B (en)
WO (1) WO2003033799A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060217021A1 (en) * 2005-03-22 2006-09-28 Illinois Tool Woks Inc. Clean-room wipers
CN102337624A (en) * 2010-07-21 2012-02-01 深圳市新纶科技股份有限公司 High-density low-dust-generation wiping cloth used for dust-free room and manufacture method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019509082A (en) * 2016-01-22 2019-04-04 スリーエム イノベイティブ プロパティズ カンパニー Polishing pad and polishing method
MX2019011276A (en) * 2017-03-23 2020-01-13 Foamtec Int Co Ltd Cleanroom wiper and method for making same.
CN108977978B (en) * 2018-09-17 2020-12-22 临沂市美添生活用品有限公司 Decontamination fabric and processing technology

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4493868A (en) * 1982-12-14 1985-01-15 Kimberly-Clark Corporation High bulk bonding pattern and method
US4938817A (en) * 1988-12-30 1990-07-03 Kappler Safety Group Method of forming bonded seams of spunbonded polyolefin fabric and cleanroom garments including such seams
US6139954A (en) * 1997-08-28 2000-10-31 Eastman Chemical Company Polyesters containing neopentyl glycol and fibers formed therefrom

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4888229A (en) * 1988-04-08 1989-12-19 The Texwipe Company Wipers for cleanroom use
US5271995A (en) * 1990-02-23 1993-12-21 The Texwipe Company Particulate contamination control in cleanrooms
US5229181A (en) * 1990-10-30 1993-07-20 Amber Technologies Tubular knit cleanroom wiper
US6189189B1 (en) * 1997-11-21 2001-02-20 Milliken & Company Method of manufacturing low contaminant wiper
US6308538B1 (en) * 1999-07-22 2001-10-30 Berkshire Corporation Method and apparatus for manufacturing individual wipers having finished edges

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4493868A (en) * 1982-12-14 1985-01-15 Kimberly-Clark Corporation High bulk bonding pattern and method
US4938817A (en) * 1988-12-30 1990-07-03 Kappler Safety Group Method of forming bonded seams of spunbonded polyolefin fabric and cleanroom garments including such seams
US6139954A (en) * 1997-08-28 2000-10-31 Eastman Chemical Company Polyesters containing neopentyl glycol and fibers formed therefrom

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060217021A1 (en) * 2005-03-22 2006-09-28 Illinois Tool Woks Inc. Clean-room wipers
CN102337624A (en) * 2010-07-21 2012-02-01 深圳市新纶科技股份有限公司 High-density low-dust-generation wiping cloth used for dust-free room and manufacture method thereof

Also Published As

Publication number Publication date
KR20040054713A (en) 2004-06-25
TWI244519B (en) 2005-12-01
JP2005505706A (en) 2005-02-24
IL161072A0 (en) 2004-08-31
MXPA04003028A (en) 2004-07-05
WO2003033799A1 (en) 2003-04-24
EP1434903A1 (en) 2004-07-07
CN1568384A (en) 2005-01-19

Similar Documents

Publication Publication Date Title
ES2369687T3 (en) TEXTILE MATERIAL NOT WOVEN MULTICOMPONENT WITH OPENINGS.
US8410007B2 (en) Hydroengorged spunmelt nonwovens
JP6080319B2 (en) Nonwoven fabric, method for producing the same, and wiping material
US5310590A (en) Stitchbonded articles
FI74503B (en) TORKVIRA MED LAOG GENOMTRAENGLIGHET OCH FOERFARANDE FOER DESS FRAMSTAELLNING.
US6872274B2 (en) Method of making nonwoven with non-symmetrical bonding configuration
US6537644B1 (en) Nonwoven with non-symmetrical bonding configuration
US20070298214A1 (en) Nonwoven fabric
EP3187635A1 (en) Soft nonwoven fabric
KR100223388B1 (en) Nonwoven cloth of ultrafine fibers and method of manufacturing the same
US2880112A (en) Textile-like fabric and method
KR20180119555A (en) Nonwoven fabric having improved abrasion resistance and method for manufacturing the same
US20030072915A1 (en) Low contaminant wiper
US5525393A (en) Method for the manufacture of a plush-type cleaning cloth and cleaning cloth or cleaning glove thereby obtained
EP0763616A1 (en) Dust-control mat having excellent dimensional stability and method of producing the same
KR0137883B1 (en) Wipers for cleanroom use and method of manufacturing the same
EP1467648B1 (en) Washable floor mat
JPH0967748A (en) Bulky nonwoven fabric and its production
JPH10273865A (en) Filament nonwoven fabric, its production, base cloth for tufted carpet and tufted carpet
KR20080104702A (en) Complex synthetic multifilament
JP2023143231A (en) Nonwoven fabric and manufacturing method thereof
JP2000017556A (en) Nonwoven fabric of polyester short fiber for padding cloth
JP2021171434A (en) Extraction sheet material and extraction bag
JP2019167656A (en) Thermally adhesive conjugated fiber and nonwoven fabric
JP2001248049A (en) Nonwoven fabric and soft goods using the same

Legal Events

Date Code Title Description
AS Assignment

Owner name: MILLIKEN & COMPANY, SOUTH CAROLINA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KELLY, CREIGHTON C.;HILDRETH, DAVID D.;REEL/FRAME:012664/0513

Effective date: 20011129

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION