EP1059980B1 - Antimicrobial filter cartridge - Google Patents
Antimicrobial filter cartridge Download PDFInfo
- Publication number
- EP1059980B1 EP1059980B1 EP98908818A EP98908818A EP1059980B1 EP 1059980 B1 EP1059980 B1 EP 1059980B1 EP 98908818 A EP98908818 A EP 98908818A EP 98908818 A EP98908818 A EP 98908818A EP 1059980 B1 EP1059980 B1 EP 1059980B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- filter cartridge
- yarn
- antimicrobial
- core
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 33
- 239000004599 antimicrobial Substances 0.000 claims abstract description 26
- 239000012982 microporous membrane Substances 0.000 claims abstract description 22
- 239000012528 membrane Substances 0.000 claims description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 18
- 239000011148 porous material Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- -1 polypropylene Polymers 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 238000004804 winding Methods 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 229920000433 Lyocell Polymers 0.000 claims description 3
- 239000004677 Nylon Substances 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000002964 rayon Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 claims 6
- 239000004698 Polyethylene Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 48
- 238000001914 filtration Methods 0.000 abstract description 23
- 244000005700 microbiome Species 0.000 abstract description 12
- 239000012530 fluid Substances 0.000 abstract description 7
- 239000011162 core material Substances 0.000 description 23
- 241000894006 Bacteria Species 0.000 description 15
- 239000000356 contaminant Substances 0.000 description 10
- 239000000835 fiber Substances 0.000 description 10
- 229920001944 Plastisol Polymers 0.000 description 8
- 239000004999 plastisol Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000001223 reverse osmosis Methods 0.000 description 4
- 239000003053 toxin Substances 0.000 description 4
- 231100000765 toxin Toxicity 0.000 description 4
- 108700012359 toxins Proteins 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- 241000282414 Homo sapiens Species 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000004694 iodide salts Chemical class 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229920002118 antimicrobial polymer Polymers 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100001223 noncarcinogenic Toxicity 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 230000001235 sensitizing effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/11—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with bag, cage, hose, tube, sleeve or like filtering elements
- B01D29/13—Supported filter elements
- B01D29/15—Supported filter elements arranged for inward flow filtration
- B01D29/21—Supported filter elements arranged for inward flow filtration with corrugated, folded or wound sheets
- B01D29/216—Supported filter elements arranged for inward flow filtration with corrugated, folded or wound sheets with wound sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D29/00—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
- B01D29/50—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition
- B01D29/56—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition in series connection
- B01D29/58—Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor with multiple filtering elements, characterised by their mutual disposition in series connection arranged concentrically or coaxially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/16—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres
- B01D39/1607—Other self-supporting filtering material ; Other filtering material of organic material, e.g. synthetic fibres the material being fibrous
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/04—Feed pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/10—Accessories; Auxiliary operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/18—Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
- B01D63/06—Tubular membrane modules
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
- C02F1/003—Processes for the treatment of water whereby the filtration technique is of importance using household-type filters for producing potable water, e.g. pitchers, bottles, faucet mounted devices
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/48—Antimicrobial properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
Definitions
- This invention relates generally to filters for the purification of liquids.
- the present invention relates to an antimicrobial filter cartridge for a filtration system for removing microorganisms from water and which is formed from layers of yarns and nonwoven webs or mats wound or wrapped in varying patterns and treated with an antimicrobial agent to enable the filter cartridge to trap and remove low micron organic contaminant particles and prevent the growth of the trapped microorganisms on the filter cartridge media to significantly reduce the level of contaminants and bacteria within the water flowing through the filtration system.
- Reverse osmosis systems are one of the most common solutions for the improvement of water quality.
- these systems use a sediment removal filter in conjunction with activated carbon and bacteriostatic membrane coated with oxides and halide of silver, as described in detail by Nishino in U.S. Patent 3,872,013, placed between the filter and the water outlet.
- the membrane will prevent certain bacteria from leaving the filter and will retard their growth on the surface of the membrane, but will not check their growth on the activated carbon and their ability to multiply and produce toxins. This also holds true for other mechanical filters such as ceramic filter cartridges that filter out bacteria of about 1 ⁇ m in size, but are ineffective in retarding bacteria growth as the bacteria are collected on the surface of the filter.
- Medlin Another type of biocidal reverse osmosis system is described in detail by Medlin in U.S. Patent 5,269,919.
- Medlin describes how a polyiodide resin releases iodide upon contact with bacteria and viral organisms and uses granular metal alloys and activated carbon to remove iodides released in the water. If not removed, these iodides would be harmful internally to human beings.
- the EPA "Policy on Iodine Disinfection" is that iodine disinfection is for short-term only, whenever iodine-containing species remain in the drinking water.
- EP 0989898 A which is a prior art document in accordance with Article 54(3)(4) EPC describes an antimicrobial filter cartridge having a perforated core member wrapped with a first microporous membrane, which is in turn overwrapped with a second and a third microporous membrane. The membranes are covered with a crisscrossed wrapping of antimicrobial treated yarn.
- the filter cartridge is sized to fit tightly into a cartridge housing of a fluid filtration system.
- JP-A-01274814 describes a filter for purification which is made of a filter medium with an adhered antibacterial agent.
- the filter medium is produced by winding a copper wire or a fiber with adhered copper sulfate and a fiber of PP or the like around a water-permeable cylindrical core material so as to leave voids.
- the present invention comprises a filter cartridge for a water filtration system for safely and effectively filtering microorganisms from drinking water and prevents the further growth of the microorganisms trapped by the filter.
- the filter cartridge includes an inner tubular-shaped perforated core of a metal, plastic or ceramic material, or formed from activated carbon.
- the core is covered with a microporous membrane having nominal pores of approximately 0.45 ⁇ m to 0.10 ⁇ m.
- the membrane is tightly wrapped around the core, and preferably is slightly wider than the length of the core so as to overlap the two opposing ends of the core.
- a yarn or nonwoven material that has been impregnated or otherwise treated with an antimicrobial agent is typically, spirally wound about the membrane so that there are no spaces between the turns or layers of the yarn and thus there are no voids between the yarn and the microporous membrane, forming a primary spiral yarn layer. Thereafter, another layer of antimicrobial yarn is then wrapped around the spiral layer in the standard criss-cross or diamond-wrap pattern, creating diamond-shaped openings through which water can travel.
- the criss-cross layer can be covered with a second microporous membrane, also having a nominal pore size of 0.45 ⁇ m or less, followed by a second spiral layer of antimicrobial yarn and a second or outer criss-cross wound section of antimicrobial yarn.
- the outer criss-cross wound section is formed with sufficient thickness so that the filter cartridge can be tightly inserted into a cartridge housing, with minimal space between the filter cartridge and the housing walls.
- the ends of the membrane and yarn layers of the finished filter thereafter are sealed with an antimicrobial polymer or resin, forming end caps at the opposite ends of the filter, to ensure the fluids will pass through the entire filter before exiting the system.
- the filter cartridge is installed within a housing for a filtration system connected to a water supply. As water flows into the housing, the water flows down and through the filter cartridge, and exits the housing through an outlet port.
- the filter cartridge of the present invention removes microorganisms and other impurities from water flowing through the cartridge. Large impurities generally are removed by the criss-cross layers or by the microporous membranes. Microorganisms retained by one of the membranes are forced into contact with the antimicrobial agent in the yarn because the tight spiral wrapping creates minimal void spaces between the yarn and the membrane. Thus, sufficient contact between the contaminants and the antimicrobial treated yarn to remove and treat the contaminants is achieved without requiring long contact times between the fluid flow and filter cartridge.
- An equally effective antimicrobial filter further can be obtained using a microporous ceramic candle or an extruded activated carbon core, without a microporous membrane as described above, so long as the effective nominal size of the pores of the ceramic candle or carbon core is less than 0.45 ⁇ m.
- an antimicrobial filter cartridge is provided that overcomes the above-discussed and other deficiencies of the prior art by providing a filter cartridge that substantially completely filters microorganisms from water and prevents the growth of the microorganisms within the filter media.
- an antimicrobial filter cartridge is provided that does not release harmful toxins into the water that must be removed from the water before the water can be safely consumed.
- an antimicrobial filter cartridge is provided that can be used in presently available filtration system housings including those used in reverse osmosis systems that will inhibit the growth of microorganisms and subsequent toxin production and will protect the activated carbon filter commonly used in reverse osmosis filtering systems.
- an antimicrobial filter cartridge is provided wherein nearly all of the water flowing into the filter cartridge comes into contact with an antimicrobial agent.
- Fig. 1 illustrates a preferred embodiment of a filter cartridge 10 constructed in accordance with the present invention.
- the filter cartridge 10 includes a hollow central perforated core 12 having open ends 13 and 14, and which can be formed from plastic, paper, or metal. Alternatively, the core can be manufactured of compressed activated carbon or ceramic candles, which are inherently perforated.
- the core is formed as a tube or cylinder approximately 12,7 - 76,2 cm (5 to 30 inches) in length and generally having a diameter of approximately 2,54 - 5,08 cm (1 to 2 inches), although larger or smaller diameters can be used if necessary.
- a series of pores or perforations 16 are formed through the core along its length.
- a first microporous membrane 17 is wrapped tightly around the core so as to cover it completely.
- the membrane 17 is a thin film having a width slightly greater than the length of the core 12 so that the membrane overlaps each of the open ends 13 and 14 of the core by approximately 0,3175 cm (0.125 inches).
- the microporous membrane has a series of pores of nominal size of about between approximately 5.0 ⁇ m to 0.10 ⁇ m, preferably 0.45 ⁇ m to 0.10 ⁇ m or less, so that it will effectively keep most gram positive and gram negative bacteria and containment particles larger than 0.1 ⁇ m from flowing through the membrane into the interior of the perforated core.
- the membrane can be one such as a polysufone sold by Memtec America Corp. under the trade name Filtrite®.
- the microporous membrane potentially can be eliminated if the effective size of the pores or perforations inherently formed in the carbon and/or ceramic cores are less than 0.45 ⁇ m.
- a fibrous yarn 18 is wrapped in a close, tight spiral winding over the microporous membrane 17 along the length of the underlying perforated core to form a first spiral wound layer 18.
- the yarn typically is formed from spun 3dpf, 5,08 cm (2") fibers of polypropylene, cellulose acetate, rayon, lyocell, acrylic, polyester or any other fibrous material that will support the antimicrobial agent.
- the yarn further can be formed from nylon, cotton, or a fibrillated filament yarn material.
- a yarn made from combinations of these polymers can be used to form the primary spiral wound yarn layer.
- the yarn is impregnated with an antimicrobial agent which is mixed with the yarn during formation of the fibers so that it is dispersed throughout the yarn fibers and will diffuse to the surface of the fibers during use of the filter cartridge.
- the yarn used in the filter cartridge of the present invention can be between 10/1 c.c. to 0.3/1 c.c., preferably between 3/1 c.c. to 0.4/1 c.c.
- the yarn further can be made from fibers such as polypropylene, acrylic, cellulose acetate, nylon, polyester rayon, lyocell, cotton or combinations and blends thereof.
- the deniers of these fibers can be between 0.3 dpf to 10 dpf, the preferable range based on cost and performance being 1.5 dpf to 6 dpf.
- These fibers typically are rendered antimicrobial, either by treating them topically or by impregnating them with antimicrobial agent during their extrusion.
- the concentration of the antimicrobial agent in the fibers generally is between 100 to 10,000 ppm, preferably between 2000 ppm to 8000 ppm.
- the antimicrobial content of the final filter cartridge based on the yarn content should be between 100 ppm to 10,000 ppm, preferably between 2500 ppm to 7500 ppm.
- the antimicrobial agent is practically insoluble in the water passing through and over the filter cartridge, and is safe, non-toxic, non-carcinogenic, non-sensitizing to human and animal skin and does not accumulate in the human body when ingested.
- the antimicrobial is a broad spectrum antimicrobial agent, i.e., it is equally effective against the majority of harmful bacteria encountered in water.
- an antimicrobial agent such as 2,4,4'-trichloro-2'-hydroxy diphenol ether, or 5-chloro-2phenol (2,4-dichlorophenoxy) commonly sold under the trademark MICROBAN®B, by Microban Products Co. generally is used.
- MICROBAN®B MICROBAN®B
- the yarn 18 is wrapped in a single tight spiral wrapping or winding layer 19, wrapped so that there is no space between each of the individual turns or layers and so that there are no spaces between the first spiral wrapping or winding 19 and the microporous membrane 17.
- the same strand of antimicrobial impregnated yarn 18 can be used to wrap the filter cartridge in standard criss-cross or diamond-shaped wrapping wound in a standard pattern to form a first criss-cross wrapping layer 21.
- the criss-cross wrapping layer 21 does not have to be impregnated with the same antimicrobial agent impregnated yarn and can be made from non-antimicrobial impregnated yarn. Additionally, the criss-cross wrapping layer can be applied directly over the membrane without the spiral wrapping layer of yarn being applied.
- the thickness of the criss-cross wrapping layer will determine the thickness of the filter cartridge.
- the criss-cross wrapping layer is approximately 0,635 cm (1/4") thick, although the total thickness of the criss-cross wrapping layer 21 can be of greater or lesser thicknesses, depending on the size of the filtration system housing in which the filter cartridge is to be installed, so as to enable the filter cartridge to fit tightly into a housing of a filtration system.
- the first criss-cross wrapping layer 21 can be wrapped with a second microporous membrane 22, a second spiral wrapping layer 24, and a second section of criss-cross wrapping 26 wound in a standard pattern.
- a second microporous membrane 22 can be wrapped with a second microporous membrane 22, a second spiral wrapping layer 24, and a second section of criss-cross wrapping 26 wound in a standard pattern.
- the antimicrobial membranes 17 and 22 overlap the ends 13 and 14 of the core.
- End caps 27 and 28 are applied over the open ends 13 and 14 of the core and the cartridge filter to seal the ends of the filter cartridges.
- the end caps 27 and 28, generally comprise a polyvinyl chloride (PVC) plastisol material containing an antimicrobial agent such as MICROBAN®B.
- PVC polyvinyl chloride
- the plastisol is poured in a liquid form into a shallow mold having an opened inside tube.
- a first end of the filter cartridge 10 is then set into the mold containing the plastisol liquid heated to a recommended temperature, for example 126,6 °C (260°F), for approximately seven minutes or until the plastisol has sufficiently permeated the yarn at the ends of the filter.
- the filter cartridge is removed and its opposite or second end is dipped into the plastisol liquid.
- the plastisol liquid is allowed to cool and solidify over the ends of the filter cartridge, whereupon the plastisol adheres to the fibrous yarn and to the protruding edges of the microporous membrane to seal the edges of the yarn and membrane at the ends of the filter cartridge, while still leaving the center of the cartridge open as shown in Fig. 5.
- preformed end caps may be used in place of the end caps formed from the plastisol liquid to form the end caps.
- Such preformed caps generally are formed from a plastic material; such as polypropylene or similar material, treated with an antimicrobial agent. The caps are formed to ensure sealing of the ends of the microporous membrane and applied to the ends of the filter cartridge, preferably with an antimicrobial adhesive.
- the end caps seal and cover the ends of the microporous membrane spiral wrapping yarn layer and criss-cross wrapping layer of the filter cartridge of each end thereof. This forces the water or other fluid being filtered through the filtration system to pass through the sides of the filter cartridge to ensure that the water or other fluid will pass through and contact the antimicrobial yarn of the criss-cross and spiral wrapping layers of yarn about the filter and through the microporous membrane so that contaminants of at least 0,1 ⁇ m or larger are trapped and removed from the flow of water passing through the filter cartridge, and the bacteria and other microorganisms therein will be eliminated by contact with the antimicrobial surfaces of the yarn layers to substantially clean the water flow of bacteria and other contaminants.
- the filter cartridge of the present invention still provides a substantial cleaning of the water flow passing therethrough without a significant reduction in the amount of contaminants and bacteria removed from the water flow.
- the filter cartridge 10 typically is mounted within the housing of a conventional water filtration system such as an undersink system 30 as shown in Fig. 6 or in a faucet mounted filtration system 31 as shown in Fig. 7.
- a conventional water filtration system such as an undersink system 30 as shown in Fig. 6 or in a faucet mounted filtration system 31 as shown in Fig. 7.
- the filter cartridge 10 is fitted snugly inside a filter cartridge housing 32 and the filtration system 30 is connected to a water source 35 at the inlet end 34 of the housing.
- the water is supplied to the filtration system at the desired flow rate and flows into the upstream or inlet end of the housing as indicated by arrows 36.
- the water flows through the filter cartridge and out of the housing, whereupon the filter cartridge traps and removes particulate contaminants and bacteria within the water flow to clean and purify the water flow before the water flow exits the housing 32 through an outlet port 37.
- An additional filter cartridge 32 housing can be mounted downstream from the housing 32 for further cleaning.
- the faucet mounted filtration system includes a housing 37 through which is formed internal flow passages 38 and 39.
- An outlet port or spout 41 is formed at the base of the housing and communicates with the outlet flow passage 39.
- the housing is connected to a faucet 42 by connecting portion 43 which fits over the outlet end of the faucet and which channels a flow of water therethrough and into the housing.
- Fig. 9 illustrates, as the water flows into the filtration system from the faucet 42, it is directed along inlet flow passages 38, as indicated by arrows 44, through the filter 10 and out through the outlet flow passage 39 through the outlet port 41 with the water having been substantially cleaned and purified by the filter cartridge.
- the flow of water is illustrated as passing through the sides of the filter cartridge and out the open ends of the core. It will, however, be understood by those skilled in the art that the filter cartridge of the present invention functions equally well if the water flow were to be reversed so as to flow in through the ends of the cartridge and out through the sides of the cartridge, without affecting the ability of the cartridge to trap and retard bacteria within the flow. Under the alternate flow conditions the sequence of membrane and antimicrobial yarn may have to be altered.
Abstract
Description
- This invention relates generally to filters for the purification of liquids. In particular, the present invention relates to an antimicrobial filter cartridge for a filtration system for removing microorganisms from water and which is formed from layers of yarns and nonwoven webs or mats wound or wrapped in varying patterns and treated with an antimicrobial agent to enable the filter cartridge to trap and remove low micron organic contaminant particles and prevent the growth of the trapped microorganisms on the filter cartridge media to significantly reduce the level of contaminants and bacteria within the water flowing through the filtration system.
- In recent years, the public has been increasingly aware of the deteriorating quality of our nation's water supply. Municipalities are requesting the EPA to lower the standards of tap water to a much lower quality. Medical patients with low immunity are requested not to drink tap water. The major part of the contamination of the drinking water is bacterial in nature.
- All over the world, countries with increasing populations are concerned that the water quality has deteriorated to an all time low. However, many known solutions that exist to purify water are too expensive or are not feasible in certain locations.
- Reverse osmosis systems are one of the most common solutions for the improvement of water quality. Generally, these systems use a sediment removal filter in conjunction with activated carbon and bacteriostatic membrane coated with oxides and halide of silver, as described in detail by Nishino in U.S. Patent 3,872,013, placed between the filter and the water outlet. The membrane will prevent certain bacteria from leaving the filter and will retard their growth on the surface of the membrane, but will not check their growth on the activated carbon and their ability to multiply and produce toxins. This also holds true for other mechanical filters such as ceramic filter cartridges that filter out bacteria of about 1 µm in size, but are ineffective in retarding bacteria growth as the bacteria are collected on the surface of the filter.
- Another type of biocidal reverse osmosis system is described in detail by Medlin in U.S. Patent 5,269,919. Medlin describes how a polyiodide resin releases iodide upon contact with bacteria and viral organisms and uses granular metal alloys and activated carbon to remove iodides released in the water. If not removed, these iodides would be harmful internally to human beings. The EPA "Policy on Iodine Disinfection", initially developed in 1973 and reaffirmed in 1982, is that iodine disinfection is for short-term only, whenever iodine-containing species remain in the drinking water.
- In view of the foregoing, it would appear that present water purification systems become a breeding ground for bacteria and toxins or would subject users to the possibility of trace metals such as silver and copper, and other contaminants not filtered out of the water.
- EP 0989898 A, which is a prior art document in accordance with Article 54(3)(4) EPC describes an antimicrobial filter cartridge having a perforated core member wrapped with a first microporous membrane, which is in turn overwrapped with a second and a third microporous membrane. The membranes are covered with a crisscrossed wrapping of antimicrobial treated yarn. The filter cartridge is sized to fit tightly into a cartridge housing of a fluid filtration system.
- JP-A-01274814 describes a filter for purification which is made of a filter medium with an adhered antibacterial agent. The filter medium is produced by winding a copper wire or a fiber with adhered copper sulfate and a fiber of PP or the like around a water-permeable cylindrical core material so as to leave voids.
- It is the object of the present invention to provide a water filter cartridge to filter microscopic organisms and prevent their growth within the filter media, without releasing life harming biocides that have to be further filtered out.
- This object is achieved by a cartridge according to
claim 1. - Briefly described, the present invention comprises a filter cartridge for a water filtration system for safely and effectively filtering microorganisms from drinking water and prevents the further growth of the microorganisms trapped by the filter. The filter cartridge includes an inner tubular-shaped perforated core of a metal, plastic or ceramic material, or formed from activated carbon. The core is covered with a microporous membrane having nominal pores of approximately 0.45 µm to 0.10 µm. The membrane is tightly wrapped around the core, and preferably is slightly wider than the length of the core so as to overlap the two opposing ends of the core.
- A yarn or nonwoven material that has been impregnated or otherwise treated with an antimicrobial agent is typically, spirally wound about the membrane so that there are no spaces between the turns or layers of the yarn and thus there are no voids between the yarn and the microporous membrane, forming a primary spiral yarn layer. Thereafter, another layer of antimicrobial yarn is then wrapped around the spiral layer in the standard criss-cross or diamond-wrap pattern, creating diamond-shaped openings through which water can travel.
- In addition, the criss-cross layer can be covered with a second microporous membrane, also having a nominal pore size of 0.45 µm or less, followed by a second spiral layer of antimicrobial yarn and a second or outer criss-cross wound section of antimicrobial yarn. The outer criss-cross wound section is formed with sufficient thickness so that the filter cartridge can be tightly inserted into a cartridge housing, with minimal space between the filter cartridge and the housing walls. The ends of the membrane and yarn layers of the finished filter thereafter are sealed with an antimicrobial polymer or resin, forming end caps at the opposite ends of the filter, to ensure the fluids will pass through the entire filter before exiting the system.
- The filter cartridge is installed within a housing for a filtration system connected to a water supply. As water flows into the housing, the water flows down and through the filter cartridge, and exits the housing through an outlet port. The filter cartridge of the present invention removes microorganisms and other impurities from water flowing through the cartridge. Large impurities generally are removed by the criss-cross layers or by the microporous membranes. Microorganisms retained by one of the membranes are forced into contact with the antimicrobial agent in the yarn because the tight spiral wrapping creates minimal void spaces between the yarn and the membrane. Thus, sufficient contact between the contaminants and the antimicrobial treated yarn to remove and treat the contaminants is achieved without requiring long contact times between the fluid flow and filter cartridge. An equally effective antimicrobial filter further can be obtained using a microporous ceramic candle or an extruded activated carbon core, without a microporous membrane as described above, so long as the effective nominal size of the pores of the ceramic candle or carbon core is less than 0.45 µm.
- It is an advantage of the present invention that an antimicrobial filter cartridge is provided that overcomes the above-discussed and other deficiencies of the prior art by providing a filter cartridge that substantially completely filters microorganisms from water and prevents the growth of the microorganisms within the filter media.
- It is another advantage of the present invention that an antimicrobial filter cartridge is provided that does not release harmful toxins into the water that must be removed from the water before the water can be safely consumed.
- It is an advantage of the present invention that an antimicrobial filter cartridge is provided that can be used in presently available filtration system housings including those used in reverse osmosis systems that will inhibit the growth of microorganisms and subsequent toxin production and will protect the activated carbon filter commonly used in reverse osmosis filtering systems.
- It is a further advantage of the present invention that an antimicrobial filter cartridge having very little dead space but with sufficient water flow is provided.
- It is a still further advantage of the present invention that an antimicrobial filter cartridge is provided wherein nearly all of the water flowing into the filter cartridge comes into contact with an antimicrobial agent.
- Other objects, features, and advantages of the present invention will become apparent to one with skill in the art upon examination of the drawings and the detailed description.
-
- Fig. 1 is a side elevational view of a preferred embodiment of the present invention, with portions cut away.
- Fig. 2 is a side elevational view of a second embodiment of the present invention, with portions cut away.
- Fig. 3 is a cross-sectional view of one end of the embodiment of the filter cartridge of Fig. 2.
- Fig. 4 is a side elevational view of the filter cartridge of the present invention.
- Fig. 5 is an end view of the filter cartridge of the present invention with an end cap installed.
- Fig. 6 is a schematic illustration of the filter cartridge of the present invention, showing the filter cartridge installed and used in an undersink filtration system.
- Fig. 7 is a schematic illustration of the filter cartridge of the present invention showing the filter cartridge installed and used in a faucet filtration system.
-
- Referring now to the drawings in which like numerals indicate like parts throughout the several views, Fig. 1 illustrates a preferred embodiment of a
filter cartridge 10 constructed in accordance with the present invention. Thefilter cartridge 10 includes a hollow central perforatedcore 12 havingopen ends perforations 16 are formed through the core along its length. - A first
microporous membrane 17 is wrapped tightly around the core so as to cover it completely. Preferably, themembrane 17 is a thin film having a width slightly greater than the length of thecore 12 so that the membrane overlaps each of theopen ends - A
fibrous yarn 18 is wrapped in a close, tight spiral winding over themicroporous membrane 17 along the length of the underlying perforated core to form a firstspiral wound layer 18. The yarn typically is formed from spun 3dpf, 5,08 cm (2") fibers of polypropylene, cellulose acetate, rayon, lyocell, acrylic, polyester or any other fibrous material that will support the antimicrobial agent. For some applications, the yarn further can be formed from nylon, cotton, or a fibrillated filament yarn material. In addition, a yarn made from combinations of these polymers can be used to form the primary spiral wound yarn layer. The yarn is impregnated with an antimicrobial agent which is mixed with the yarn during formation of the fibers so that it is dispersed throughout the yarn fibers and will diffuse to the surface of the fibers during use of the filter cartridge. - The yarn used in the filter cartridge of the present invention can be between 10/1 c.c. to 0.3/1 c.c., preferably between 3/1 c.c. to 0.4/1 c.c. The yarn further can be made from fibers such as polypropylene, acrylic, cellulose acetate, nylon, polyester rayon, lyocell, cotton or combinations and blends thereof. The deniers of these fibers can be between 0.3 dpf to 10 dpf, the preferable range based on cost and performance being 1.5 dpf to 6 dpf. These fibers typically are rendered antimicrobial, either by treating them topically or by impregnating them with antimicrobial agent during their extrusion. The concentration of the antimicrobial agent in the fibers generally is between 100 to 10,000 ppm, preferably between 2000 ppm to 8000 ppm. The antimicrobial content of the final filter cartridge based on the yarn content should be between 100 ppm to 10,000 ppm, preferably between 2500 ppm to 7500 ppm.
- Preferably, the antimicrobial agent is practically insoluble in the water passing through and over the filter cartridge, and is safe, non-toxic, non-carcinogenic, non-sensitizing to human and animal skin and does not accumulate in the human body when ingested. Generally, the antimicrobial is a broad spectrum antimicrobial agent, i.e., it is equally effective against the majority of harmful bacteria encountered in water. For example, an antimicrobial agent such as 2,4,4'-trichloro-2'-hydroxy diphenol ether, or 5-chloro-2phenol (2,4-dichlorophenoxy) commonly sold under the trademark MICROBAN®B, by Microban Products Co. generally is used. However, it will be understood various other antimicrobial agents can be used in the present invention.
- The
yarn 18 is wrapped in a single tight spiral wrapping or windinglayer 19, wrapped so that there is no space between each of the individual turns or layers and so that there are no spaces between the first spiral wrapping or winding 19 and themicroporous membrane 17. - After the
first wrapping layer 19 has been applied, the same strand of antimicrobial impregnatedyarn 18 can be used to wrap the filter cartridge in standard criss-cross or diamond-shaped wrapping wound in a standard pattern to form a first criss-cross wrapping layer 21. The criss-cross wrapping layer 21 does not have to be impregnated with the same antimicrobial agent impregnated yarn and can be made from non-antimicrobial impregnated yarn. Additionally, the criss-cross wrapping layer can be applied directly over the membrane without the spiral wrapping layer of yarn being applied. - The thickness of the criss-cross wrapping layer will determine the thickness of the filter cartridge. Preferably the criss-cross wrapping layer is approximately 0,635 cm (1/4") thick, although the total thickness of the criss-
cross wrapping layer 21 can be of greater or lesser thicknesses, depending on the size of the filtration system housing in which the filter cartridge is to be installed, so as to enable the filter cartridge to fit tightly into a housing of a filtration system. Once the filter has been wrapped to the desired finished thickness, the yarn is cut and the end is tucked under or otherwise secured to a previous strand to prevent the yarn from unraveling. - In an additional embodiment, shown in Fig. 2 and 3, the first criss-
cross wrapping layer 21 can be wrapped with asecond microporous membrane 22, a secondspiral wrapping layer 24, and a second section of criss-cross wrapping 26 wound in a standard pattern. In this way, greater filtration ability is provided and if one of the microporous membranes is punctured or otherwise made permeable to particles under 0.45 µm in size, the other membrane will act to trap and remove such particles. - As shown in Fig. 4, the
antimicrobial membranes ends filter cartridge 10 is then set into the mold containing the plastisol liquid heated to a recommended temperature, for example 126,6 °C (260°F), for approximately seven minutes or until the plastisol has sufficiently permeated the yarn at the ends of the filter. The filter cartridge is removed and its opposite or second end is dipped into the plastisol liquid. The plastisol liquid is allowed to cool and solidify over the ends of the filter cartridge, whereupon the plastisol adheres to the fibrous yarn and to the protruding edges of the microporous membrane to seal the edges of the yarn and membrane at the ends of the filter cartridge, while still leaving the center of the cartridge open as shown in Fig. 5. - In an alternative embodiment, preformed end caps may be used in place of the end caps formed from the plastisol liquid to form the end caps. Such preformed caps generally are formed from a plastic material; such as polypropylene or similar material, treated with an antimicrobial agent. The caps are formed to ensure sealing of the ends of the microporous membrane and applied to the ends of the filter cartridge, preferably with an antimicrobial adhesive.
- The end caps seal and cover the ends of the microporous membrane spiral wrapping yarn layer and criss-cross wrapping layer of the filter cartridge of each end thereof. This forces the water or other fluid being filtered through the filtration system to pass through the sides of the filter cartridge to ensure that the water or other fluid will pass through and contact the antimicrobial yarn of the criss-cross and spiral wrapping layers of yarn about the filter and through the microporous membrane so that contaminants of at least 0,1 µm or larger are trapped and removed from the flow of water passing through the filter cartridge, and the bacteria and other microorganisms therein will be eliminated by contact with the antimicrobial surfaces of the yarn layers to substantially clean the water flow of bacteria and other contaminants.
- Additionally, if the water flow through the filter cartridge is to be reversed, flowing from inside of the cartridge out the sides thereof, the layering of the antimicrobial yarn/nonwoven material and the microporous membrane over the core is reversed. Thus, the core first is wrapped with the antimicrobial yarn/nonwoven mat, then overlaid with the microporous membrane. As a result, the water first will contact the antimicrobial yarn, to kill bacteria therein and thereafter contacts the microporous membrane, which traps and removes contaminant particles from the water flow. With such a construction, the filter cartridge of the present invention still provides a substantial cleaning of the water flow passing therethrough without a significant reduction in the amount of contaminants and bacteria removed from the water flow.
- In use, the
filter cartridge 10 typically is mounted within the housing of a conventional water filtration system such as anundersink system 30 as shown in Fig. 6 or in a faucetmounted filtration system 31 as shown in Fig. 7. In the system of Fig. 8, thefilter cartridge 10 is fitted snugly inside afilter cartridge housing 32 and thefiltration system 30 is connected to a water source 35 at theinlet end 34 of the housing. The water is supplied to the filtration system at the desired flow rate and flows into the upstream or inlet end of the housing as indicated byarrows 36. The water flows through the filter cartridge and out of the housing, whereupon the filter cartridge traps and removes particulate contaminants and bacteria within the water flow to clean and purify the water flow before the water flow exits thehousing 32 through anoutlet port 37. Anadditional filter cartridge 32 housing can be mounted downstream from thehousing 32 for further cleaning. - In the
water filtration system 31 of Fig. 7, the faucet mounted filtration system includes ahousing 37 through which is formedinternal flow passages outlet flow passage 39. The housing is connected to afaucet 42 by connectingportion 43 which fits over the outlet end of the faucet and which channels a flow of water therethrough and into the housing. As Fig. 9 illustrates, as the water flows into the filtration system from thefaucet 42, it is directed alonginlet flow passages 38, as indicated byarrows 44, through thefilter 10 and out through theoutlet flow passage 39 through theoutlet port 41 with the water having been substantially cleaned and purified by the filter cartridge. - In the use of the
filter cartridge 10 of the present invention in both of the filtration systems discussed above, the flow of water, indicated by arrows 36 (Fig. 6) and 38 (Fig. 7), is illustrated as passing through the sides of the filter cartridge and out the open ends of the core. It will, however, be understood by those skilled in the art that the filter cartridge of the present invention functions equally well if the water flow were to be reversed so as to flow in through the ends of the cartridge and out through the sides of the cartridge, without affecting the ability of the cartridge to trap and retard bacteria within the flow. Under the alternate flow conditions the sequence of membrane and antimicrobial yarn may have to be altered.
Claims (6)
- A bactericidal filter cartridge, comprising:a core (12) formed from an activated carbon material and having an outer side surface and an inner side surface;a microporous membrane (17) applied to said inner and outer side surfaces of said core (12);a layer of antimicrobial yarn (18) spirally wound about said membrane (17) applied to said outer side surface of said core (12);a layer of antimicrobial yarn (21) wound about said core (12) in a substantially criss-cross winding pattern having pores formed therethrough; andend caps (27,28) applied at opposite ends of said core (12).
- The bactericidal filter cartridge of claim 1 and wherein said microporous membranes (17) project over said opposite ends of said core (12) approximately 0,3175 cm (0.125 inches).
- The bactericidal filter cartridge of claim 1 or 2 and said antimicrobial yarn (18,21) of said spiral wound and said criss-cross wound layers is formed from a polymer selected from the group consisting of nylon, polypropylene, cellulose acetate, rayon, lyocell, acrylic, polyester, polyethylene and combinations thereof.
- The bactericidal filter cartridge of one of claims 1 to 3 and wherein said microporous membrane (17) includes nominal pores of approximately 0.1 to 5 µm.
- The bactericidal filter cartridge of one of claims 1 to 4 and wherein the antimicrobial yarn comprises a fibrillated filament yarn.
- The bactericidal filter cartridge of one of claims 1 to 5 and wherein the antimicrobial yarn comprises a fibrillated filament yarn is impregnated with an antimicrobial agent in a concentration of approximately 100 to 10,000 ppm.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/573,067 US5762797A (en) | 1995-12-15 | 1995-12-15 | Antimicrobial filter cartridge |
CA002200292A CA2200292C (en) | 1995-12-15 | 1997-03-18 | Antimicrobial filter cartridge |
PCT/US1998/003982 WO1999044712A1 (en) | 1995-12-15 | 1998-03-02 | Antimicrobial filter cartridge |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1059980A1 EP1059980A1 (en) | 2000-12-20 |
EP1059980A4 EP1059980A4 (en) | 2001-09-19 |
EP1059980B1 true EP1059980B1 (en) | 2004-05-12 |
Family
ID=27170309
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98908818A Expired - Lifetime EP1059980B1 (en) | 1995-12-15 | 1998-03-02 | Antimicrobial filter cartridge |
Country Status (9)
Country | Link |
---|---|
US (1) | US5762797A (en) |
EP (1) | EP1059980B1 (en) |
CN (1) | CN1150959C (en) |
AT (1) | ATE266455T1 (en) |
AU (1) | AU6675998A (en) |
CA (1) | CA2200292C (en) |
DE (1) | DE69823881T2 (en) |
ES (1) | ES2221157T3 (en) |
WO (1) | WO1999044712A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102020213346A1 (en) | 2020-10-22 | 2022-04-28 | Filtration Group Gmbh | Filter element and double switching filter |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4343226A1 (en) * | 1993-12-17 | 1995-06-22 | Schenk Filterbau Gmbh | Depth filter for killing microorganisms and inactivating viruses and their use |
US6171496B1 (en) * | 1995-12-15 | 2001-01-09 | Microban Products Company | Antimicrobial filter cartridge |
US6854601B2 (en) * | 1995-12-15 | 2005-02-15 | Microban Products Company | Bacteriostatic filter cartridge |
US6283308B1 (en) * | 1998-06-17 | 2001-09-04 | Microban Products Company | Bacteriostatic filter cartridge |
US6331354B1 (en) | 1996-08-23 | 2001-12-18 | Weyerhaeuser Company | Alkaline pulp having low average degree of polymerization values and method of producing the same |
US6471727B2 (en) | 1996-08-23 | 2002-10-29 | Weyerhaeuser Company | Lyocell fibers, and compositions for making the same |
US6306334B1 (en) | 1996-08-23 | 2001-10-23 | The Weyerhaeuser Company | Process for melt blowing continuous lyocell fibers |
US6235392B1 (en) * | 1996-08-23 | 2001-05-22 | Weyerhaeuser Company | Lyocell fibers and process for their preparation |
ATE316814T1 (en) | 1998-06-29 | 2006-02-15 | Microban Products | ANTI-MICROBIAL SEMIPERMEABLE MEMBRANE |
US6537614B1 (en) | 1998-12-18 | 2003-03-25 | Kimberly-Clark Worldwide, Inc. | Cationically charged coating on hydrophobic polymer fibers with poly (vinyl alcohol) assist |
US6274041B1 (en) | 1998-12-18 | 2001-08-14 | Kimberly-Clark Worldwide, Inc. | Integrated filter combining physical adsorption and electrokinetic adsorption |
US7168574B2 (en) * | 1999-04-22 | 2007-01-30 | King Technology | Dual filter |
US6652751B1 (en) * | 1999-04-27 | 2003-11-25 | National Research Council Of Canada | Intrinsically bacteriostatic membranes and systems for water purification |
CN1168669C (en) * | 1999-05-20 | 2004-09-29 | 宝洁公司 | Method for removal of nano-sized pathogens from liquids |
US7163625B1 (en) * | 1999-12-16 | 2007-01-16 | Kimberly-Clark Worldwide, Inc. | Filtration device |
US6645388B2 (en) | 1999-12-22 | 2003-11-11 | Kimberly-Clark Corporation | Leukocyte depletion filter media, filter produced therefrom, method of making same and method of using same |
US20020030008A1 (en) * | 2000-03-31 | 2002-03-14 | Kimberly-Clark Worldwide, Inc. | Multi-component filter design |
DE10051266A1 (en) * | 2000-10-16 | 2002-04-25 | Basf Ag | Filter aid used for filtering fruit and fermented drinks comprising polystyrene and silicate, carbonate, oxide, silica gel, diatomaceous earth and/or polymers |
US7614508B2 (en) | 2001-08-23 | 2009-11-10 | Pur Water Purification Products Inc. | Water filter materials, water filters and kits containing silver coated particles and processes for using the same |
KR100777951B1 (en) | 2001-08-23 | 2007-11-28 | 더 프록터 앤드 갬블 캄파니 | Water filter materials, corresponding water filters and processes for using the same |
US7615152B2 (en) * | 2001-08-23 | 2009-11-10 | Pur Water Purification Products, Inc. | Water filter device |
US20050279696A1 (en) | 2001-08-23 | 2005-12-22 | Bahm Jeannine R | Water filter materials and water filters containing a mixture of microporous and mesoporous carbon particles |
US7614507B2 (en) | 2001-08-23 | 2009-11-10 | Pur Water Purification Products Inc. | Water filter materials, water filters and kits containing particles coated with cationic polymer and processes for using the same |
US7296691B2 (en) * | 2003-07-18 | 2007-11-20 | Kx Technologies Llc | Carbon or activated carbon nanofibers |
DE10215147A1 (en) * | 2002-04-05 | 2003-10-16 | Basf Ag | Use of polymerization containing thermoplastic polymers as filter aids and / or stabilizers |
US7346938B2 (en) * | 2002-08-02 | 2008-03-25 | Roy W. Mattson, Jr. | Retrofit suction sanitation safety cover |
US6760931B1 (en) * | 2002-08-02 | 2004-07-13 | Roy W. Mattson, Jr. | Non-electric sanitation water vessel system |
US7147625B2 (en) * | 2003-07-01 | 2006-12-12 | Icet, Inc. | Leg bag accessory |
US6944893B1 (en) | 2003-07-22 | 2005-09-20 | Roy W. Mattson, Jr. | Combination sanitation suction device and high flow antimicrobial dispenser |
US20050211612A1 (en) * | 2004-03-25 | 2005-09-29 | Mattson Roy W Jr | Water suction purification device |
ES1059313Y (en) * | 2005-01-19 | 2005-07-16 | Pridesa Proyectos Y Servicios | MULTI-PAD FILTER CARTRIDGE FOR LIQUID FILTRATION |
US20070295667A1 (en) * | 2006-01-19 | 2007-12-27 | Ruprecht John C | Water filter apparatus and methodology |
US7938276B2 (en) * | 2006-02-01 | 2011-05-10 | Mechanical Manufacturing Corporation | Filtration architecture for optimized performance |
AU2007241055A1 (en) * | 2006-03-31 | 2007-11-01 | Perry Equipment Corporation | Layered filter for treatment of contaminated fluids |
US7485225B2 (en) * | 2006-03-31 | 2009-02-03 | Perry Equipment Corporation | Composite adsorbent block for the treatment of contaminated fluids |
US8062523B2 (en) * | 2006-12-01 | 2011-11-22 | Perry Equipment Corporation | Filter element and methods of manufacturing and using same |
EP2158029B1 (en) * | 2007-04-10 | 2019-05-29 | Gea Process Engineering Inc. | Process gas filter and process for cleaning the same |
US20080302713A1 (en) * | 2007-06-05 | 2008-12-11 | Gilbert Patrick | Antimicrobial filter cartridge |
US20090032472A1 (en) * | 2007-07-31 | 2009-02-05 | Perry Equipment Corporation | Systems and methods for removal of heavy metal contaminants from fluids |
US7993520B2 (en) * | 2007-10-18 | 2011-08-09 | Mechanical Manufacturing Corp. | Selective partitioning capacity based filter media |
US8257591B2 (en) * | 2007-10-30 | 2012-09-04 | Mechanical Manufacturing Corp. | Methodology for filtering a fluid using a plurality of surface filtration mediums |
US8926840B2 (en) | 2008-03-18 | 2015-01-06 | Rubbermaid Incorporated | Drinking container and filter assembly |
EP2297043A2 (en) * | 2008-07-09 | 2011-03-23 | Pur Water Purification Products, Inc. | Multi-stage water filters |
MX2011005333A (en) | 2008-11-20 | 2011-08-15 | Water Visions International Inc | Antimicrobial device and materials for fluid treatment. |
US20110086078A1 (en) * | 2009-10-14 | 2011-04-14 | Water Visions International, Inc. | Fibrous antimicrobial materials, structures, and barrier applications |
DE202009016240U1 (en) | 2009-11-27 | 2010-04-29 | Weihmann, Andreas, Dipl.-Designer | Water recovery system technology |
US8678201B2 (en) * | 2010-06-04 | 2014-03-25 | Goodrich Corporation | Aircraft potable water system |
US9427710B2 (en) * | 2013-03-15 | 2016-08-30 | Bemis Company, Inc. | Radial filtration vent and medical device packaging |
CN103435193B (en) * | 2013-09-10 | 2014-09-24 | 苏州新区枫桥净化设备厂 | Tubular water purifying plant |
CN203874594U (en) * | 2014-06-12 | 2014-10-15 | 百朗楼宇电气用品(惠州)有限公司 | Air purifier directly suspended on wall |
CN204034442U (en) * | 2014-08-15 | 2014-12-24 | 百朗楼宇电气用品(惠州)有限公司 | A kind of duct-type air purifier |
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Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL128051C (en) * | 1958-04-29 | |||
US3327859A (en) * | 1963-12-30 | 1967-06-27 | Pall Corp | Portable unit for potable water |
US3828934A (en) * | 1972-02-03 | 1974-08-13 | Carborundum Co | Media for wound filter elements |
US4032688A (en) * | 1973-08-31 | 1977-06-28 | Pall Corporation | Seamless tubular nonwoven webs and filters thereof |
US4048075A (en) * | 1974-05-06 | 1977-09-13 | The Carborundum Company | Filter cartridge |
US3998740A (en) * | 1974-07-26 | 1976-12-21 | J. P. Stevens & Co., Inc. | Apparatus for treatment of textile desizing effluent |
US4104170A (en) * | 1975-08-28 | 1978-08-01 | Met-Pro Corporation | Liquid filter having improved extended polypropylene element |
US4660779A (en) * | 1984-04-11 | 1987-04-28 | Dorr-Oliver Incorporated | Multilayer precision wound filter cartridge |
US4769096A (en) * | 1986-02-13 | 1988-09-06 | H.B. Fuller Company | Process of bonding fluted filter media to end caps |
US4902427A (en) * | 1988-04-25 | 1990-02-20 | Ebonex Corporation | Filter for removing heavy metals from drinking water |
JPH01274814A (en) * | 1988-04-28 | 1989-11-02 | Matsushita Electric Ind Co Ltd | Filter for purification |
US5006267A (en) * | 1989-11-08 | 1991-04-09 | The Dow Chemical Company | Biocidal fluid filters |
US5868933A (en) * | 1995-12-15 | 1999-02-09 | Patrick; Gilbert | Antimicrobial filter cartridge |
-
1995
- 1995-12-15 US US08/573,067 patent/US5762797A/en not_active Expired - Lifetime
-
1997
- 1997-03-18 CA CA002200292A patent/CA2200292C/en not_active Expired - Lifetime
-
1998
- 1998-03-02 AU AU66759/98A patent/AU6675998A/en not_active Abandoned
- 1998-03-02 EP EP98908818A patent/EP1059980B1/en not_active Expired - Lifetime
- 1998-03-02 WO PCT/US1998/003982 patent/WO1999044712A1/en active IP Right Grant
- 1998-03-02 ES ES98908818T patent/ES2221157T3/en not_active Expired - Lifetime
- 1998-03-02 CN CNB988140101A patent/CN1150959C/en not_active Expired - Lifetime
- 1998-03-02 AT AT98908818T patent/ATE266455T1/en not_active IP Right Cessation
- 1998-03-02 DE DE69823881T patent/DE69823881T2/en not_active Expired - Lifetime
Cited By (2)
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DE102020213346A1 (en) | 2020-10-22 | 2022-04-28 | Filtration Group Gmbh | Filter element and double switching filter |
DE102020213346B4 (en) | 2020-10-22 | 2023-07-27 | Filtration Group Gmbh | Filter element, use of the filter element, double changeover filter and liquid circuit |
Also Published As
Publication number | Publication date |
---|---|
EP1059980A1 (en) | 2000-12-20 |
US5762797A (en) | 1998-06-09 |
AU6675998A (en) | 1999-09-20 |
CA2200292A1 (en) | 1998-09-18 |
DE69823881T2 (en) | 2005-04-21 |
DE69823881D1 (en) | 2004-06-17 |
CN1150959C (en) | 2004-05-26 |
ES2221157T3 (en) | 2004-12-16 |
CA2200292C (en) | 2002-05-21 |
EP1059980A4 (en) | 2001-09-19 |
CN1301189A (en) | 2001-06-27 |
WO1999044712A1 (en) | 1999-09-10 |
ATE266455T1 (en) | 2004-05-15 |
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