EP0891758B1

EP0891758B1 - Method for producing liquid absorbing articles, and articles so produced

Info

Publication number: EP0891758B1
Application number: EP98303411A
Authority: EP
Inventors: John Gent
Original assignee: Bristol Myers Squibb Co
Current assignee: Bristol Myers Squibb Co
Priority date: 1997-05-21
Filing date: 1998-04-30
Publication date: 2003-06-25
Anticipated expiration: 2018-04-30
Also published as: DE69815764D1; DK0891758T3; EP0891758A1; CA2238248A1; AU739242B2; JPH1120058A; US6054631A; JP4171102B2; GB9710473D0; CA2238248C; GB2325432A; AU6601398A; GB2325432B; ES2206838T3; DE69815764T2

Description

This invention relates to a product for absorbing aqueous matter and to a method of making such a product.
Many products and devices have been tried and used to absorb aqueous matter for various purposes, for example ostomy, incontinence, diapers, wound care, napkins including bibs for oral spillage/dribbling, horticultural, fruit and meat packaging and other purposes.
In 1970 in British Patent Specification No. 1,193,433 a sanitary aid was disclosed which comprised a fibrous cover containing as filling material a water soluble cellulose ether in fibre, powder or granular form.
US Patent No. 4,055,180 of 1977 taught that an absorbent article should include a hydrocolloid material which is retained in a fixed position within the article, in order to improve its performance. The absorbent pad assembly has an absorbent pad, and a first retaining sheet. The sheet is attached to the pad or a second retaining sheet in areas and is free of attachment in regions between the areas to define pocket means. The pad assembly has a hydrocolloid material positioned in the pocket means.
In 1981, Chemische Fabrik Stockhausen & Cie in DE-3,002,136A disclosed an absorbent body, for use as a bandage etc., which has a supporting layer to which a liquid-absorbent layer is secured. The supporting layer is coated with swelling absorbent powder and thermoplastic material in powder form, over which is a layer of covering material. The supporting and/or covering layers can be cloths of cellular or synthetic fibre materials, typically creped.
International PCT Application No. WO 90/05513 (Mitchell et al) discloses an absorbent product for personal use which embodies a so-called superabsorbent. To produce the product, a laminated assembly is subjected to embossing.
UK published Application No. 2,049,553A discloses a water-absorbent sheet assembly which comprises two sheets at least one of which is a water-permeable sheet, and a polymeric absorbent inserted between said two sheets. Parts of the two sheets have been bonded together by pressing. Apparatus for preparing such a sheet includes a smooth roll and an embossing roll having convexities, concavities, and flat portions.
US Patent No. 5,030,314 relates to an article including particles which are of superabsorbent material. These are disposed between a permeable cover layer and a composite web containing discrete areas of superabsorbent material. Hence there is formed an absorbent structure such as a diaper, incontinent garment or feminine pad. In the manufacture of such a composite web, a roll is used having cavities suitable for retaining small quantities of superabsorbent. By rotating the roll, these quantities are deposited on the web, which has an impermeable backing. The permeable cover layer is joined to the web by lines of adhesive.
US Patent No. 5,118,376 is concerned with the incorporation of superabsorbent material in the fibre padding of disposable hygiene articles. A procedure used consists in compressing locally the fibre padding by means of a profiled tool, and in placing the powdery product in the impression left by the tool. According to an additional characteristic of the procedure, a compression force is then applied on the product in order to set it in the fibrous mass.
In PCT Application NO. WO 95/03019 there is disclosed a process and apparatus for manufacturing a continuous web-like intermediate absorbent product comprising an absorbent material in powder, granule or fibre form, placed between containing sheets. Such a process comprises the steps of:
a. depositing onto a web-like supporting sheet fed from a feeding reel, a predetermined pattern of absorbent material in powder, granule or fibre form;
b. bonding, by means of heat, said deposited absorbent material to the supporting sheet;
c. depositing longitudinal strips of an adhesive material onto said web-like sheet;
d. applying at least a further web-like sheet over the assembly and joining said further sheet to the former sheet in the region of said adhesive strips by compression;
e. if required, carrying out one or more times the steps from a. to d. using a latest applied web-like sheet as supporting sheet;
f. longitudinally slitting the web-like composite assembly so obtained, and
g. separately winding into rolls the narrower webs so obtained which comprise adjacent absorbent cores.
U.S. Patent No. 5,494,622 relates to forming a composite web having selected discrete pocket regions which are distributed on a carrier layer and contain high-absorbency material. The invention includes a pattern chamber having opposed side walls, an entrance end wall and an exit end wall. A particulate supplying mechanism provides particles of high-absorbency material into the pattern chamber, and a web supplying mechanism provides a gas permeable carrier layer. A foraminous forming mechanism moves the carrier layer through the pattern chamber, and the forming mechanism includes a pattern of openings which are formed therethrough and are arranged to provide for a selected pattern of the discrete pocket regions. A vacuum supplying mechanism provides a selected level of relatively low gas pressure at an underside region of the forming mechanism to produce a selected gasflow through the carrier layer and the foraminous forming mechanism to form the pocket regions. A covering mechanism provides a layer of liquid-permeable covering material to sandwich said pocket regions of high-absorbency material between said carrier layer and said covering layer. The aim of the inventors is to achieve a zoned placement of superabsorbent material within a composite web. Though this patent discloses the application of vacuum to provide gas flow through a layer, in order to form pocket regions, it is not concerned with compressing the composite web only in selected areas prior to removal of loose superabsorbent powder.
Reference is also made to US 4,747,960 which describes a water absorbent packet and a method of using the packet in liquids to be kept free of invasive water. The packets are made of sheets of material which allow the water in the liquid to penetrate into the packet and contact the water absorbent material. Any water present in the liquid which contacts the absorbent material is absorbed from the liquid.
The packets of US 4,747,960 can be manufactured to the size desired for use in the system to be kept water free and the desired number of compartments of absorbent material. The amount of absorbent material in the compartments can be measured so that upon water absorption the compartment becomes swollen, giving a visual check for the presence of water. The absorbent compound of this invention can be sodium poly-2-propenoate, carboxy-methyl cellulose or other form of the super absorbent composition or polymers which will not migrate through the sheets of material when placed in the liquid and when water is absorbed from the liquid. The packets can be constructed from sheets of polyester cotton fabric bonded so that compartments are formed enclosing the super absorbent material. Reference is further made to WO93/02861, which describes a method and apparatus for manufacturing a continuous quilt-like sheet containing superabsorbent material in discrete cells formed between two sheets of fluid permeable fabric. The cells are formed by fusion of the two fabric sheets at selected locations in a continuous pattern through application of pressure and heat, completely enclosing individual localized deposits of material placed between the fabric sheets.
According to one aspect of the present invention, there is provided a method of making articles capable of absorbing aqueous matter comprising:
a. arranging loose high-absorbent powder (preferably a "superabsorbent" powder) generally uniformly between upper and lower sheets;
b. compressing the powder and sheets in specific areas (not over the entire area of the sheet), so as to structurally consolidate the powder in the compressed areas, while the powder in the surrounding areas remains loose; and
c. extracting the loose powder.
Preferably, the method further comprises cutting and/or sealing the regions around the consolidated areas, for example, to form individual packet-like articles or a strip of such articles.
According to another aspect of the invention, there is provided a sealed packet-like article capable of absorbing aqueous matter, comprising a consolidated structure of high-absorbent powder compressed and consolidated with upper and lower layers, the powder being disposed between and in direct contact with the upper and lower layers with which it is consolidated, the layers each including a peripheral region not consolidated with the powder, the peripheral regions of the layers and being sealed to each other around the periphery of the article.
Preferred and advantageous features of the invention will now be discussed. In UK Patent Application No. 2,301,350 there is described a method of compressing upper and lower sheets sandwiching a formulation including superabsorbent, water and glycerol to consolidate the formulation. The method is a continuous roll or sheet preparation method which necessitates cutting the superabsorbent pad to the desired size for the end application. The cutting operation leads to a certain amount of shedding of formulated superabsorbent particles, and depending upon size of superabsorbent product required, the cutting operation may lead to significant percentages of scrap. Clearly it would be desirable to avoid wastage since superabsorbents are relatively expensive materials.
In the making of sealed packet-like articles in accordance with an embodiment of the invention, the superabsorbent powder is metered onto a suitable web, e.g. a web of paper tissue, by the use of a doctor blade to provide a desired weight per unit area thereon. A second web, which may but need not be paper tissue, is then placed over the powder on the first web. The resulting laminate is subjected to pressure at the nip of a pair of specially designed rollers. These rollers are constructed that pressure is applied only at chosen regularly-spaced zones. In these zones, the first and second webs and the powder therebetween are compacted, but in the remaining areas no compaction occurs and the powder remains loose and powdery. This loose powder is removed, either by vacuum suction or by gravity. Removal by gravity may be achieved by causing the laminated and intermittently-compressed webs to adopt a vertical or near-vertical planar position, whereupon the loose powder falls out and is collected for re-use. Alternatively, removal of the loose powder by suction can be achieved in a conventional manner.
The laminate is then caused to take up a generally flat orientation, and passes to a sealing station where the sealing and cutting takes place, so producing packet-like articles. If desired the laminate may be left in a strip form as illustrated in Fig. 5 (i.e. without physically detaching the individual articles from each other). In such a strip, the articles may be divided by a weakened or perforated region so that an article may be torn off the strip later by a user. Alternatively, the individual articles may be separated as illustrated in Fig. 6.
The high-absorbency material can comprise absorbent gelling materials, such as superabsorbents. The absorbent gelling materials can be natural, synthetic and modified natural polymers and materials. In addition, or alternatively, the absorbent gelling materials can be inorganic materials, such as silica gels, or organic compounds such as cross-linked polymers; or alginates, reticular carboxymethylcelluloses, grafted starches, or synthetic derivatives of acrylamides or polyacrylates. . Other high-absorbing materials which may be used are those specified in column 6 of U.S. Patent No. 5,030,314.
A particular embodiment of the present invention will now be described with reference to the accompanying drawings, in which:
Figure 1 is a diagrammatic side view of an apparatus for making packet-like articles for absorbing aqueous matter; and
Figures 2-6 diagrammatically illustrate stages in the manufacture of packet-like articles.

EXAMPLE

A formulation comprising sodium polyacrylate 100 pbw, 0.5 to 6 pbw glycerol and 0.5 to 6 pbw water is mixed to a powder consistency in a conventional mixer 20 (see Figure 1 of the accompanying drawings), and is fed onto a travelling sheet 21 of tissue paper which is pulled off a supply roll 22. A second (overhead) sheet 23 of tissue paper is fed from a second supply roll 24 and these two sheets sandwich the powder between them. The product passes between a first pair of rolls 26 which form a first nip 27 and to a second pair of rolls 28 forming a second nip 29. The inter-roll spacing at the second nip 29 may be for example 1.0 to 2.0 mm. That at the first nip 27 may be 0.75 to 4 mm. No external heat is applied. As described above, by employing specially-designed rolls, compressed zones are formed, and then loose superabsorbent powder located between these zones is removed, e.g. by suction or gravity. The resulting product may then be cut into suitable shapes, e.g. rectangles 32, by a conventional cutter 30, and, if desired, can be directly placed in an ostomy bag or incontinence pouch. It has been found to rapidly absorb a liquid such as urine. In tests of this product, at least 50 ml of synthetic urine was absorbed in under 60 seconds, usually under 40 seconds, by a product of one square centimetre area and 2 mm. in thickness.
Although the drawings illustrate production of the packet-like articles in a linear strip, it will be appreciated that the same principles may be used to produce a two-dimensional strip of such articles, for example, in a grid or other arrangement.

Claims

A method of making one or more articles capable of absorbing aqueous matter comprising :

a. arranging loose high-absorbent powder generally uniformly between upper and lower sheets (23, 21) ;

b. compressing the powder and sheets in specific areas but not over the entire area of the sheet, so as to structurally consolidate the powder in the compressed areas, while the powder in the surrounding areas remains loose; and

c. extracting the loose powder.
A method according to claim 1, further comprising sealing the regions of the upper and lower sheets around the periphery of the consolidated areas to form sealed packet-like regions.
A method according to claim 1 or 2, further comprising cutting (at 30) the regions around the consolidated areas.
A method according to claim 1, 2 or 3 in which the high-absorbency material comprises one or more of: superabsorbents, absorbent gelling materials, natural, synthetic and modified natural polymers and materials; inorganic materials, silica gels, and organic compounds such as cross-linked polymers.
A method according to claim 1, 2, 3 or 4, wherein the high-absorbent material is an alkali metal polyacrylate.
A method according to claim 1, 2, 3 or 4, wherein the high absorbent material comprises one or more of alginates, reticular carboxymethylcelluloses, grafted starches, or synthetic derivatives of acrylamides or polyacrylates.
A sealed packet-like article (32) capable of absorbing aqueous matter, comprising a consolidated structure of high-absorbent powder compressed and consolidated with upper and lower layers (23, 21), the powder being disposed between and in direct contact with the upper and lower layers (23, 21) with which it is consolidated, the layers (23, 21) each including a peripheral region not consolidated with the powder, the peripheral regions of the layers (23, 21) being sealed to each other around the periphery of the article.
An article (32) according to claim 7 in which at least one of the layers (23, 21) comprises paper tissue.
An article according to claim 7 or 8, wherein the high-absorbent material is an alkali metal polyacrylate.
An article according to claim 7 or 8, wherein the high absorbent material comprises one or more of alginates, reticular carboxymethylcelluloses, grafted starches, or synthetic derivatives of acrylamides or polyacrylates.
A strip comprising a plurality of integrally joined packet-like articles (32), each packet-like article being an article as defined in claim 7, 8, 9 or 10.
A strip according to claim 11, comprising lines or regions of weakness between the adjacent packet-like articles (32), to permit individual articles to be torn from the strip.