DE69905962T2 - Synthese von Triethylendiamin und Piperazine mit Hilfe von mit Silicium enthaltende Verbindungen modifizierten Zeolith Katalysatoren - Google Patents

Synthese von Triethylendiamin und Piperazine mit Hilfe von mit Silicium enthaltende Verbindungen modifizierten Zeolith Katalysatoren

Info

Publication number
DE69905962T2
DE69905962T2 DE69905962T DE69905962T DE69905962T2 DE 69905962 T2 DE69905962 T2 DE 69905962T2 DE 69905962 T DE69905962 T DE 69905962T DE 69905962 T DE69905962 T DE 69905962T DE 69905962 T2 DE69905962 T2 DE 69905962T2
Authority
DE
Germany
Prior art keywords
piperazines
triethylenediamine
synthesis
silicon
containing compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69905962T
Other languages
English (en)
Other versions
DE69905962D1 (de
Inventor
Hong-Xin Li
Jose Guadalupe Santiesteban
Lenore Ann Emig
John Nelson Armor
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Application granted granted Critical
Publication of DE69905962D1 publication Critical patent/DE69905962D1/de
Publication of DE69905962T2 publication Critical patent/DE69905962T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/64—Preparation of compounds containing amino groups bound to a carbon skeleton by disproportionation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/08—Bridged systems
DE69905962T 1998-04-09 1999-04-08 Synthese von Triethylendiamin und Piperazine mit Hilfe von mit Silicium enthaltende Verbindungen modifizierten Zeolith Katalysatoren Expired - Fee Related DE69905962T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/057,662 US6084096A (en) 1998-04-09 1998-04-09 Triethylenediamine and piperazine synthesis using zeolite catalysts modified with a silicon-containing compound

Publications (2)

Publication Number Publication Date
DE69905962D1 DE69905962D1 (de) 2003-04-24
DE69905962T2 true DE69905962T2 (de) 2003-09-11

Family

ID=22011989

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69905962T Expired - Fee Related DE69905962T2 (de) 1998-04-09 1999-04-08 Synthese von Triethylendiamin und Piperazine mit Hilfe von mit Silicium enthaltende Verbindungen modifizierten Zeolith Katalysatoren

Country Status (6)

Country Link
US (1) US6084096A (de)
EP (1) EP0952152B1 (de)
JP (1) JP3883326B2 (de)
KR (1) KR100322780B1 (de)
CN (1) CN1121400C (de)
DE (1) DE69905962T2 (de)

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US6350874B1 (en) * 1999-04-01 2002-02-26 Tosoh Corporation Method for producing triethylenediamines and piperazines
DE19930736C2 (de) * 1999-07-05 2001-07-05 Performance Chemicals Handels Verfahren zur Herstellung von Triethylendiamin unter Einsatz von Ethylendiamin
WO2001032593A1 (en) 1999-11-02 2001-05-10 California Institute Of Technology Acylation of an organic group over a zeolite
JP4496633B2 (ja) * 2000-09-29 2010-07-07 東ソー株式会社 トリエチレンジアミン製造用成形体触媒とその製造法及びトリエチレンジアミンの製造方法
DE10061863A1 (de) * 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Triethylendiamin (TEDA)
US6864200B2 (en) * 2001-01-23 2005-03-08 Indian Petrochemicals Corporation Limited Selectivated metallosilicate catalyst composite for alkylaromatic conversion, process for the preparation thereof, and use thereof in hydrocarbon conversion
DE10132499A1 (de) * 2001-07-05 2003-01-23 Basf Ag Verfahren zur selektiven Synthese von Triethylendiamin
JP4170735B2 (ja) * 2002-11-13 2008-10-22 信越化学工業株式会社 ゼオライトゾルとその製造方法、多孔質膜形成用組成物、多孔質膜とその製造方法、層間絶縁膜及び半導体装置
JP4170734B2 (ja) * 2002-11-13 2008-10-22 信越化学工業株式会社 多孔質膜形成用組成物、多孔質膜とその製造方法、層間絶縁膜及び半導体装置
DE10303696A1 (de) 2003-01-30 2004-08-12 Basf Ag Entfärbung und Farbstabilisierung von TEDA-Lösung
US7049260B2 (en) * 2003-06-03 2006-05-23 Chevron Phillips Chemical Company Lp Selective para-xylene production via methylation of toluene with methanol in the presence of modified HZSM-5 catalyst
DE10326137A1 (de) * 2003-06-06 2004-12-23 Basf Ag Verfahren zur Erhöhung der Schneidhärte eines Formkörpers enthaltend ein kristallines Alumosilikat und Verwendung dieser Formkörper mit erhöhter Schneidhärte in chemischen Syntheseverfahren, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA) durch Umsetzung von Ethylendiamin (EDA) und/oder Piperazin (PIP)
KR20060054397A (ko) 2003-08-01 2006-05-22 바스프 악티엔게젤샤프트 에틸렌아민의 제조 방법
DE10356184A1 (de) * 2003-12-02 2005-07-07 Basf Ag Zeolithisches Material vom Pentasil-Strukturtyp, seine Herstellung und seine Verwendung
DE102004024274A1 (de) 2004-05-15 2005-12-01 Basf Ag Verfahren zur Herstellung einer Lösung von reinem Triethylendiamin (TEDA)
DE102004029544A1 (de) * 2004-06-18 2006-01-05 Basf Ag Formkörper enthaltend ein mikroporöses Material und mindestens ein siliciumhaltiges Bindemittel, Verfahren zu seiner Herstellung und seine Verwendung als Katalysator, insbesondere in einem Verfahren zur Herstellung von Triethylendiamin (TEDA)
CN100425342C (zh) * 2005-04-21 2008-10-15 上海华谊丙烯酸有限公司 一种沸石催化剂在二氢吡喃衍生物水解反应中的应用
KR101098495B1 (ko) * 2005-08-15 2011-12-26 상하이 리서치 인스티튜트 오브 페트로케미칼 테크놀로지 시노펙 톨루엔 형태 선택성 알킬화반응에 의한 파라-자일렌 제조용촉매의 제조방법
CN102600884A (zh) * 2012-03-13 2012-07-25 河北科技大学 一种乙二胺合成哌嗪催化剂的制备方法
CN103240116B (zh) * 2013-04-24 2015-04-29 北京化工大学 一种用于生产哌嗪和三乙烯二胺的催化剂及制备方法
JP2017516754A (ja) * 2014-04-03 2017-06-22 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト触媒上でのアミン混合物の反応によるｔｅｄａの製造
CN106831794B (zh) * 2017-01-20 2019-03-05 万华化学集团股份有限公司 一种制备哌嗪和三乙烯二胺的方法
CN109422705B (zh) * 2017-08-22 2022-11-08 中国科学院大连化学物理研究所 无溶剂条件下由乙二胺催化合成哌嗪和三乙烯二胺的方法
CN108465485B (zh) * 2018-03-26 2021-10-22 泉州师范学院 用于乙醇胺环化合成三乙烯二胺的催化剂及其制备方法和应用
CN111099615B (zh) * 2018-10-25 2021-11-30 中国石油化工股份有限公司 介孔y分子筛的制备方法
CN116060101A (zh) * 2021-10-31 2023-05-05 中国石油化工股份有限公司 一种合成二苯胺的催化剂、其制备方法和应用

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DE423526C (de) * 1923-07-07 1926-01-05 Georges Emile Massin Drehbarer Scheinwerfer fuer Kraftfahrzeuge
JPS5337876B2 (de) * 1973-07-19 1978-10-12
JPS60260574A (ja) * 1984-04-10 1985-12-23 ユニオン・カ−バイド・コ−ポレ−シヨン １−アザビシクロ〔２．２．２〕オクタン又は１，４−ジアザビシクロ〔２．２．２〕オクタンの合成
DE3690621T (de) * 1985-12-05 1987-11-19
US4804758A (en) * 1986-10-08 1989-02-14 Basf Aktiengesellschaft Preparation of 1,4-diazabicyclo[2.2.2]octanes
JPH0633266B2 (ja) * 1986-11-10 1994-05-02 出光興産株式会社 トリエチレンジアミン類の製造方法
DE3735212A1 (de) * 1987-10-17 1989-04-27 Huels Chemische Werke Ag Verfahren zur herstellung von gemischen aus 1,4-diazabicyclo(2.2.2)-octan und piperazin
DE3735214A1 (de) * 1987-10-17 1989-04-27 Huels Chemische Werke Ag Verfahren zur herstellung von 1,4-diazabicyclo(2.2.2)-octan aus piperazin
US5382696A (en) * 1992-10-16 1995-01-17 Mitsui Toatsu Chemicals, Incorporated Method for preparing methylamines
US5365004A (en) * 1993-05-28 1994-11-15 Mobil Oil Corp. Selective toluene disproportionation process (STDP) with ex situ selectivated zeolite catalysts
US5567666A (en) * 1995-05-15 1996-10-22 Mobil Oil Corporation Selectivated zeolite catalyst treated with a dealuminizing agent
US5731449A (en) * 1996-09-23 1998-03-24 Air Products And Chemicals, Inc. Triethylendiamine synthesis with base-treated zeolites as catalysts
US5741906A (en) * 1996-11-15 1998-04-21 Air Products And Chemicals, Inc. Production of triethylenediamine using surface acidity deactivated zeolite catalysts

Also Published As

Publication number Publication date
CN1234401A (zh) 1999-11-10
KR19990082983A (ko) 1999-11-25
DE69905962D1 (de) 2003-04-24
KR100322780B1 (ko) 2002-03-18
EP0952152B1 (de) 2003-03-19
US6084096A (en) 2000-07-04
JPH11349578A (ja) 1999-12-21
JP3883326B2 (ja) 2007-02-21
EP0952152A3 (de) 2000-02-23
CN1121400C (zh) 2003-09-17
EP0952152A2 (de) 1999-10-27

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