DE69720998D1 - Herstellung von para-xylol durch methylierung von toluol - Google Patents

Herstellung von para-xylol durch methylierung von toluol

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Publication number
DE69720998D1
DE69720998D1 DE69720998T DE69720998T DE69720998D1 DE 69720998 D1 DE69720998 D1 DE 69720998D1 DE 69720998 T DE69720998 T DE 69720998T DE 69720998 T DE69720998 T DE 69720998T DE 69720998 D1 DE69720998 D1 DE 69720998D1
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Germany
Prior art keywords
toluol
xylol
methylating
para
production
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Expired - Lifetime
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DE69720998T
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English (en)
Inventor
D Mohr
S Smith
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ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/005Mixtures of molecular sieves comprising at least one molecular sieve which is not an aluminosilicate zeolite, e.g. from groups B01J29/03 - B01J29/049 or B01J29/82 - B01J29/89
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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    • C07C5/2702Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
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    • C07C5/393Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
DE69720998T 1996-05-29 1997-05-29 Herstellung von para-xylol durch methylierung von toluol Expired - Lifetime DE69720998D1 (de)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US1854796P 1996-05-29 1996-05-29
US1858396P 1996-05-29 1996-05-29
US1855096P 1996-05-29 1996-05-29
US1854696P 1996-05-29 1996-05-29
US1855196P 1996-05-29 1996-05-29
US1839096P 1996-05-29 1996-05-29
PCT/US1997/009609 WO1997045387A1 (en) 1996-05-29 1997-05-29 Methylation of toluene to para-xylene

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AU737003B2 (en) 2001-08-09
CN1224408A (zh) 1999-07-28
EP0912473A1 (de) 1999-05-06
EA199801061A1 (ru) 1999-06-24
EA002376B1 (ru) 2002-04-25
US5994603A (en) 1999-11-30
AU3228997A (en) 1998-01-05
JP2001504084A (ja) 2001-03-27
BR9709620A (pt) 1999-08-10
CN1083412C (zh) 2002-04-24
EP0912473B1 (de) 2003-04-16
CA2255873A1 (en) 1997-12-04
WO1997045387A1 (en) 1997-12-04

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