DE69710359T2 - Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen - Google Patents

Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen

Info

Publication number
DE69710359T2
DE69710359T2 DE69710359T DE69710359T DE69710359T2 DE 69710359 T2 DE69710359 T2 DE 69710359T2 DE 69710359 T DE69710359 T DE 69710359T DE 69710359 T DE69710359 T DE 69710359T DE 69710359 T2 DE69710359 T2 DE 69710359T2
Authority
DE
Germany
Prior art keywords
alkylation
organic compounds
alkylatable organic
alkylatable
compounds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69710359T
Other languages
English (en)
Other versions
DE69710359D1 (de
Inventor
Broekhoven Hermanus Van
Cabre Rene Mas
Pieter Bogaard
Gijsbertus Klaver
Marco Vonhof
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albemarle Netherlands BV
Original Assignee
Akzo Nobel NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from NL1004623A external-priority patent/NL1004623C2/nl
Application filed by Akzo Nobel NV filed Critical Akzo Nobel NV
Publication of DE69710359D1 publication Critical patent/DE69710359D1/de
Application granted granted Critical
Publication of DE69710359T2 publication Critical patent/DE69710359T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • C07C2529/12—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE69710359T 1996-11-27 1997-11-14 Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen Expired - Lifetime DE69710359T2 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
NL1004623A NL1004623C2 (nl) 1996-11-27 1996-11-27 Werkwijze voor het alkyleren van koolwaterstoffen.
US3154296P 1996-12-02 1996-12-02
EP97202951 1997-09-25
PCT/EP1997/006401 WO1998023560A1 (en) 1996-11-27 1997-11-14 Process for alkylating hydrocarbons

Publications (2)

Publication Number Publication Date
DE69710359D1 DE69710359D1 (de) 2002-03-21
DE69710359T2 true DE69710359T2 (de) 2002-08-14

Family

ID=27238509

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69710359T Expired - Lifetime DE69710359T2 (de) 1996-11-27 1997-11-14 Verfahren zur Alkylierung von alkylierbaren organischen Verbindungen

Country Status (11)

Country Link
US (1) US5986158A (de)
EP (1) EP0941211B1 (de)
JP (1) JP4278067B2 (de)
KR (1) KR100533754B1 (de)
CN (1) CN1088449C (de)
AU (1) AU5750598A (de)
BR (1) BR9713441B1 (de)
CA (1) CA2273333C (de)
DE (1) DE69710359T2 (de)
ES (1) ES2172035T3 (de)
WO (1) WO1998023560A1 (de)

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US6579821B1 (en) 2000-06-14 2003-06-17 Bechtel Bwxt Idaho, Llc Method for reactivating solid catalysts used in alkylation reactions
US7407905B2 (en) 2000-06-14 2008-08-05 Battelle Energy Alliance, Llc Method for reactivating catalysts and a method for recycling supercritical fluids used to reactivate the catalysts
US6844479B2 (en) * 2000-10-20 2005-01-18 Abb Lummus Global Inc. Alkylation process
DK1392627T3 (da) * 2001-06-08 2009-12-07 Albemarle Netherlands Bv Fremgangsmåde til den katalytiske alkylering af carbonhydrider
EP1527035B1 (de) 2001-06-08 2015-03-04 Albemarle Netherlands B.V. Kontinuierliches verfahren zur alkylierung von kohlenwasserstoffen
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US6924407B2 (en) * 2001-08-27 2005-08-02 The University Of Kansas Pressure-tuned solid catalyzed heterogeneous chemical reactions
EP1308207B1 (de) 2001-11-06 2011-08-10 Albemarle Netherlands B.V. Schwefel enthaltender Alkylierungskatalysator und dessen Verwendung
US7361797B2 (en) * 2002-02-05 2008-04-22 Abb Lummus Global Inc. Hydrocarbon conversion using nanocrystalline zeolite Y
JP2005520828A (ja) * 2002-03-18 2005-07-14 アクゾ　ノーベル　ナムローゼ　フェンノートシャップ 中間蒸留を使用する飽和炭化水素のアルキル化
US20040158113A1 (en) * 2003-02-06 2004-08-12 Girish Srinivas Catalysts and process for converting fuel gases to gasoline
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US7145049B2 (en) * 2003-07-25 2006-12-05 Catalytic Distillation Technologies Oligomerization process
JP4508617B2 (ja) * 2003-11-28 2010-07-21 薫 藤元 イソパラフィン−オレフィンアルキル化用ゼオライト触媒および該触媒を用いたアルキル化法
JP5016927B2 (ja) 2004-02-09 2012-09-05 アルベマーレ ネザーランズ ビー．ブイ． 固体酸および水素化金属を含む触媒を使用するアルキル化方法
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
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US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7592282B2 (en) 2004-11-11 2009-09-22 Battelle Energy Alliance, Llc Enhancement of alkylation catalysts for improved supercritical fluid regeneration
US20060101712A1 (en) * 2004-11-15 2006-05-18 Burnett Don E Small off-road engine green fuel
EP1993951B1 (de) 2006-02-03 2014-07-30 GRT, Inc. Trennung von lichtgasen von brom
EP2457887A1 (de) 2006-02-03 2012-05-30 GRT, Inc. Kontinuierliches Verfahren zur Umwandlung von Erdgas in flüssige Kohlenwasserstoffe
US7875754B2 (en) * 2006-07-27 2011-01-25 Lummus Technology Inc. Method of improving alkylate yield in an alkylation reaction
CA2666718C (en) * 2006-10-17 2012-06-26 Lummus Technology Inc. Bimetallic alkylation catalysts
TWI433829B (zh) * 2007-01-26 2014-04-11 Albemarle Netherlands Bv 使用含稀土元素之沸石及氫化金屬之催化劑的烷化法
CN101765574A (zh) 2007-05-24 2010-06-30 Grt公司 使卤化氢可逆性俘获与释放相结合的区域反应器
EP2197817A1 (de) * 2007-10-17 2010-06-23 Albemarle Netherlands B.V. Alkylierungsverfahren unter verwendung von einen seltene erden umfassenden katalysator enthaltenden zeolithen und einer verminderten menge an edelmetall
WO2009058522A2 (en) * 2007-11-02 2009-05-07 Exxonmobil Chemical Patents Inc. A process for rejuvenating a catalyst composition
WO2009061303A1 (en) * 2007-11-08 2009-05-14 Lummus Technology Inc. Method of improving alkylate yield in an alkylation reaction
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
AU2009270801B2 (en) 2008-07-18 2014-04-24 Reaction 35, Llc Continuous process for converting natural gas to liquid hydrocarbons
CN102333744A (zh) 2009-02-11 2012-01-25 阿尔比马尔欧洲有限公司 烷基化催化剂和相关方法
US8791301B2 (en) * 2010-02-04 2014-07-29 University-Industry Cooperation Group Of Kyunghee University Method of preparing secondary amine compound using microflow reactor
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
KR20130132954A (ko) 2010-12-30 2013-12-05 바이렌트, 아이엔씨. 유기-촉매적 바이오매스 분해
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9415385B2 (en) 2011-11-21 2016-08-16 Exxonmobil Research And Engineering Company Activation of dual catalyst systems
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CA2954346C (en) * 2014-07-07 2020-06-30 Albemarle Europe Sprl Alkylation process using a catalyst comprising cerium rich rare earth containing zeolites and a hydrogenation metal
US9963403B2 (en) * 2014-10-27 2018-05-08 Exxonmobil Chemical Patents Inc. Process and apparatus for the conversion of hydrocarbons
PL3310480T3 (pl) 2015-06-22 2020-11-16 Exelus, Inc. Ulepszone katalizowane alkilowanie, katalizatory alkilowania i sposoby wytwarzania katalizatorów alkilowania
CN105195177B (zh) * 2015-09-18 2017-12-26 宁波海越新材料有限公司 一种烷基化汽油催化剂及其制备方法
CN106631655B (zh) * 2015-10-28 2019-05-21 中国石油化工股份有限公司 一种烷基化反应方法
CN106631656B (zh) * 2015-10-28 2019-09-24 中国石油化工股份有限公司 一种烷基化反应方法
RU2637922C2 (ru) * 2016-06-02 2017-12-08 Публичное акционерное общество "Электрогорский институт нефтепереработки" (ПАО "ЭлИНП") Способ алкилирования изобутана в трехфазном реакторе с неподвижным слоем катализатора
AU2018226543B2 (en) 2017-03-01 2023-03-30 Albemarle Europe Srl Alkylation process with improved octane number
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CN110538675A (zh) * 2018-05-28 2019-12-06 中国石油化工股份有限公司 固体酸烷基化催化剂及其制备方法和应用
CN110872529B (zh) * 2018-09-04 2022-06-28 中国石油化工股份有限公司 固体酸烷基化反应方法和反应系统
CN110876854B (zh) 2018-09-06 2021-05-14 中国石油化工股份有限公司 一种低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置
CN110876855B (zh) 2018-09-06 2021-05-14 中国石油化工股份有限公司 低碳烯烃和烷烃烷基化产物的分离方法、低碳烯烃和烷烃烷基化反应分离方法及装置
JP7444894B2 (ja) 2019-01-25 2024-03-06 中国石油化工股▲ふん▼有限公司 固体酸触媒、その製造、及びその使用
CN111482193B (zh) * 2019-01-25 2021-08-06 中国石油化工股份有限公司 一种固体酸催化剂的制备方法
CN111482195B (zh) * 2019-01-25 2021-05-14 中国石油化工股份有限公司 一种固体酸催化剂
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Also Published As

Publication number Publication date
ES2172035T3 (es) 2002-09-16
DE69710359D1 (de) 2002-03-21
CA2273333C (en) 2007-05-01
EP0941211B1 (de) 2002-02-06
JP4278067B2 (ja) 2009-06-10
BR9713441B1 (pt) 2009-01-13
KR100533754B1 (ko) 2005-12-06
BR9713441A (pt) 2000-02-01
KR20000052722A (ko) 2000-08-25
AU5750598A (en) 1998-06-22
CA2273333A1 (en) 1998-06-04
US5986158A (en) 1999-11-16
EP0941211A1 (de) 1999-09-15
JP2001504504A (ja) 2001-04-03
WO1998023560A1 (en) 1998-06-04
CN1238747A (zh) 1999-12-15
CN1088449C (zh) 2002-07-31

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Owner name: ALBEMARLE NETHERLANDS B.V., AMERSFOORT, NL