DE69502480T2 - Zweidonokatalysatorsystem zur olefinpolymerisation - Google Patents

Zweidonokatalysatorsystem zur olefinpolymerisation

Info

Publication number
DE69502480T2
DE69502480T2 DE69502480T DE69502480T DE69502480T2 DE 69502480 T2 DE69502480 T2 DE 69502480T2 DE 69502480 T DE69502480 T DE 69502480T DE 69502480 T DE69502480 T DE 69502480T DE 69502480 T2 DE69502480 T2 DE 69502480T2
Authority
DE
Germany
Prior art keywords
catalyst system
donocatalyst
olefin polymerization
polypropylene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69502480T
Other languages
English (en)
Other versions
DE69502480D1 (de
Inventor
Nemesio Miro
George Byron Georgellis
Homer Swei
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of DE69502480D1 publication Critical patent/DE69502480D1/de
Publication of DE69502480T2 publication Critical patent/DE69502480T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
DE69502480T 1994-02-04 1995-02-06 Zweidonokatalysatorsystem zur olefinpolymerisation Expired - Fee Related DE69502480T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US19221794A 1994-02-04 1994-02-04
PCT/US1995/001499 WO1995021203A1 (en) 1994-02-04 1995-02-06 Dual donor catalyst system for the polymerization of olefins

Publications (2)

Publication Number Publication Date
DE69502480D1 DE69502480D1 (de) 1998-06-18
DE69502480T2 true DE69502480T2 (de) 1998-12-10

Family

ID=22708732

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69502480T Expired - Fee Related DE69502480T2 (de) 1994-02-04 1995-02-06 Zweidonokatalysatorsystem zur olefinpolymerisation

Country Status (11)

Country Link
US (1) US6111039A (de)
EP (1) EP0743960B1 (de)
JP (1) JP3095177B2 (de)
CN (1) CN1085219C (de)
AT (1) ATE166074T1 (de)
CA (1) CA2182717A1 (de)
DE (1) DE69502480T2 (de)
ES (1) ES2119401T3 (de)
FI (1) FI963081A (de)
NO (1) NO963236L (de)
WO (1) WO1995021203A1 (de)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6686433B1 (en) 1994-02-04 2004-02-03 Exxonmobil Chemical Patents Inc. Dual donor catalyst system for the polymerization of olefins
EP0743960B1 (de) * 1994-02-04 1998-05-13 Exxon Chemical Patents Inc. Zweidonokatalysatorsystem zur olefinpolymerisation
US5854354A (en) * 1994-04-11 1998-12-29 Mitsui Petrochemical Industries, Ltd. Process for preparing propylene polymer composition and propylene polymer composition
JP3595864B2 (ja) * 1995-06-07 2004-12-02 住友化学工業株式会社 α−オレフィン重合用触媒ならびにα−オレフィン重合体の製造方法
FI104080B (fi) * 1996-05-15 1999-11-15 Borealis As Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi ja monivaiheiset polymerointiprosessit, joissa tätä systeemiä käytetään
US6057407A (en) * 1997-01-08 2000-05-02 Bp Amoco Corporation High melt flow propylene polymer produced by gas-phase polymerization
WO1999020663A2 (en) * 1997-10-17 1999-04-29 Exxon Chemical Patents Inc. High impact, flexural moduli polymeric materials formed using sequential donors
EP1080122B1 (de) * 1998-05-14 2004-01-07 ExxonMobil Chemical Patents Inc. Polymermaterialen hergestellt durch die verwendung von elektronendonormischungen
US6087459A (en) * 1998-05-14 2000-07-11 Exxon Chemical Patents Inc. Polymeric materials formed using blends of electron donors
CN1137156C (zh) * 1999-12-06 2004-02-04 中国石油化工集团公司 用于烯烃聚合的催化剂组分、烯烃聚合催化剂及其用途
US6399707B1 (en) 2000-09-29 2002-06-04 Exxonmobil Chemical Patents Inc. Impact copolymer and plastomer blend
US6566294B2 (en) 2000-12-21 2003-05-20 Exxonmobil Chemical Patents Inc. Multi-donor catalyst system for the polymerization of olefins
KR100421553B1 (ko) * 2000-12-27 2004-03-09 삼성아토피나주식회사 알파 올레핀 중합 방법
JP4174425B2 (ja) * 2002-01-03 2008-10-29 イネオス・ユーエスエイ・エルエルシー 二重供与体触媒系を用いる気相オレフィン重合
EP1515996A2 (de) 2002-06-14 2005-03-23 Union Carbide Chemicals & Plastics Technology Corporation Katalysatorzusammensetzung und verfahren zur polymerisation mit einer mischung von elektrondonoren
US7652092B2 (en) * 2002-08-12 2010-01-26 Exxonmobil Chemical Patents Inc. Articles from plasticized thermoplastic polyolefin compositions
US7531594B2 (en) 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7622523B2 (en) * 2002-08-12 2009-11-24 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
CA2492839C (en) 2002-08-12 2011-02-01 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7652094B2 (en) 2002-08-12 2010-01-26 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
US7521512B2 (en) 2003-06-24 2009-04-21 Union Carbide Chemicals & Plastics Technology Llc Catalyst composition and polymerization process using mixture of silane electron donors
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
KR20060099512A (ko) * 2003-09-23 2006-09-19 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 코포레이션 혼합된 선택성 조절제를 갖는 촉매 조성물 및 프로필렌중합 방법
US7393806B2 (en) 2003-09-23 2008-07-01 Dow Global Technologies Inc. Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
KR101114748B1 (ko) 2003-09-23 2012-03-05 다우 글로벌 테크놀로지스 엘엘씨 자가 제한 촉매 조성물 및 프로필렌 중합 방법
ATE547438T1 (de) 2003-09-23 2012-03-15 Union Carbide Chem Plastic Selbstlöschende katalysatorzusammensetzung mit monocarbonsäure als internem donator und propylenpolymerisationsverfahren
JP5248774B2 (ja) 2003-09-23 2013-07-31 ダウ グローバル テクノロジーズ エルエルシー ジカルボン酸エステル内部供与体を有する自己制限性触媒組成物及びプロピレン重合方法
EP1544218A1 (de) * 2003-12-19 2005-06-22 Borealis Technology Oy Verfahren zur Herstellung von Polymeren
US20050234172A1 (en) * 2004-04-19 2005-10-20 Fina Technology, Inc. Random copolymer-impact copolymer blend
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
BRPI0615488B1 (pt) * 2005-07-01 2017-07-04 Basell Poliolefine Italia S.R.L Polymers of propylene having a large distribution of molecular weight
ATE555166T1 (de) 2005-07-15 2012-05-15 Exxonmobil Chem Patents Inc Elastomere zusammensetzungen
US7977435B2 (en) * 2006-07-12 2011-07-12 Lin Chon-Yie Propylene polymer compositions and processes for making the same
KR101040388B1 (ko) 2007-01-30 2011-06-09 주식회사 엘지화학 트리옥사실로칸을 포함하는 올레핀 중합용 촉매 및 이를이용한 올레핀 중합 방법
CN101627058B (zh) * 2007-03-06 2012-11-07 伊内奥斯美国公司 利用烷基铝的分阶段加入的气相丙烯聚合法
CN101125898A (zh) 2007-07-19 2008-02-20 中国科学院长春应用化学研究所 一种用于合成宽分子量分布聚丙烯的催化剂
RU2486208C2 (ru) * 2008-08-21 2013-06-27 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Композиция катализатора со смешанным агентом, регулирующим селективность, и способ полимеризации, использующий ее
US7851554B2 (en) * 2008-10-27 2010-12-14 Exxonmobil Chemical Patents Inc. Propylene impact copolymers with balanced impact strength and stiffness
CN101735351B (zh) * 2008-11-07 2011-10-05 中国石油天然气股份有限公司 一种制备高流动宽分布聚丙烯的方法及产品
WO2011088754A1 (zh) 2010-01-22 2011-07-28 中国石油化工股份有限公司 一种具有高熔体强度的丙烯均聚物及其制备方法
CN102134291B (zh) * 2010-01-22 2013-12-04 中国石油化工股份有限公司 一种高熔体强度聚丙烯的制备方法
JP5640402B2 (ja) * 2010-03-08 2014-12-17 住友化学株式会社 α−オレフィン重合用触媒
EP2588504B1 (de) * 2010-06-10 2015-02-18 Ineos Technologies USA LLC Steuerung der h2-verteilung in einem horizontalen rührkessel
WO2014070385A1 (en) 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Articles comprising broad molecular weight distribution polypropylene resins
CN103540020B (zh) * 2013-10-29 2018-08-28 中国石油化工股份有限公司 一种锂离子电池阻隔膜均聚聚丙烯专用料生产方法
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9399686B2 (en) 2014-02-07 2016-07-26 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US10759883B2 (en) 2015-08-07 2020-09-01 Sabin Global Technologies B.V. Process for the polymerization of olefins
WO2017025327A1 (en) * 2015-08-07 2017-02-16 Sabic Global Technologies B.V. Process for the polymerization of olefins
US10696756B2 (en) 2015-08-07 2020-06-30 Sabic Global Technologies B.V. Process for the polymerization of olefins
SG11202008074SA (en) * 2018-04-20 2020-11-27 Toho Titanium Co Ltd Olefin polymer and method for producing olefin polymer
CN114426596A (zh) * 2020-10-15 2022-05-03 中国石油化工股份有限公司 用于烯烃聚合的催化剂及应用和烯烃聚合方法与聚合物
CN114437263B (zh) * 2020-10-20 2023-12-08 中国石油化工股份有限公司 一种低voc低气味聚丙烯树脂及其制备方法和应用
WO2024025742A1 (en) 2022-07-25 2024-02-01 Exxonmobil Chemical Patents Inc. Purged polymer, process and apparatus for production thereof

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4340704A (en) * 1974-02-15 1982-07-20 Montedison S.P.A. Thermoplastic rubbers and process for preparing same
IT1078995B (it) * 1977-05-24 1985-05-08 Montedison Spa Catalizzatori per la polimeriazzazione di olefine
JPS5571712A (en) * 1978-11-24 1980-05-30 Mitsubishi Petrochem Co Ltd Preparation of modified polypropylene
IT1127222B (it) * 1979-11-14 1986-05-21 Montedison Spa Componenti di catalizzatori per la polimerizzazione di olefine
IT1141295B (it) * 1980-04-22 1986-10-01 Montedison Spa Componenti e catalizzatori per la polimerizzazione delle alfaolefine
IT1190682B (it) * 1982-02-12 1988-02-24 Montedison Spa Catalizzatori per la polimerizzazione di olefine
US4535068A (en) * 1983-09-20 1985-08-13 Shell Oil Company Olefin polymerization catalyst compositions and polymerization process
US4563512A (en) * 1984-02-28 1986-01-07 Shell Oil Company Olefin polymerization process utilizing a combination of selectivity control agents
US4493923A (en) * 1984-03-27 1985-01-15 Shell Oil Company High notched impact toughness propylene polymer compositions
US4927797A (en) * 1987-04-09 1990-05-22 Fina Technology, Inc. Catalyst system for the polymerization of olefins
CA1306579C (en) * 1987-12-15 1992-08-18 Mamoru Kioka Process for producing polypropylene and stretched polypropylene film
DE3819577A1 (de) * 1988-06-09 1989-12-14 Hoechst Ag Verfahren zur herstellung eines polypropylens
ES2052004T5 (es) * 1988-06-17 2002-05-16 Mitsui Chemicals Inc Procedimiento de preparacion de poliolefinas y catalizador de polimerizacion.
CA1334841C (en) * 1988-09-13 1995-03-21 Mamoru Kioka Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalysts, and process for polymerizing olefins
EP0385765B1 (de) * 1989-03-02 1995-05-03 Mitsui Petrochemical Industries, Ltd. Verfahren zur Polymerisation von Olefinen und Katalysator für Olefinpolymerisation
US5173536A (en) * 1990-12-11 1992-12-22 Union Carbide Chemicals & Plastics Technology Corporation Impact polymer blend
JP3132030B2 (ja) * 1991-03-22 2001-02-05 東ソー株式会社 立体規則性ポリオレフィンの製造方法
JP3089713B2 (ja) * 1991-07-04 2000-09-18 住友化学工業株式会社 エチレン−プロピレンブロック共重合体の製造方法
TW300235B (de) * 1992-12-04 1997-03-11 Mitsui Petroleum Chemicals Ind
US5338801A (en) * 1993-10-20 1994-08-16 Himont Incorporated Compositions of propylene polymer materials and olefin polymer materials with reduced gloss
EP0743960B1 (de) * 1994-02-04 1998-05-13 Exxon Chemical Patents Inc. Zweidonokatalysatorsystem zur olefinpolymerisation
ES2125612T3 (es) * 1994-04-06 1999-03-01 Exxon Chemical Patents Inc Copolimeros de bloques de etileno y alfa-olefina y metodos para su produccion.
US5455303A (en) * 1994-06-20 1995-10-03 Montell North America Inc. Linear low density polyethylene based compositions with improved optics
US5552482A (en) * 1995-09-08 1996-09-03 Montell North America Inc. Thermoplastic elastomers with improved extrusion performance
EP2385765A1 (de) * 2009-01-07 2011-11-16 Chr. Hansen A/S Zusatzmittel zu nahrungsmitteln oder trinkwasser, das pflanzliche antioxidantien gemeinsam mit probiotischen mikroorganismen enthält

Also Published As

Publication number Publication date
CN1156999A (zh) 1997-08-13
FI963081A (fi) 1996-10-03
NO963236D0 (no) 1996-08-02
CN1085219C (zh) 2002-05-22
JPH09508657A (ja) 1997-09-02
NO963236L (no) 1996-09-25
JP3095177B2 (ja) 2000-10-03
DE69502480D1 (de) 1998-06-18
ATE166074T1 (de) 1998-05-15
FI963081A0 (fi) 1996-08-05
EP0743960A1 (de) 1996-11-27
MX9603216A (es) 1997-07-31
WO1995021203A1 (en) 1995-08-10
CA2182717A1 (en) 1995-08-10
ES2119401T3 (es) 1998-10-01
US6111039A (en) 2000-08-29
EP0743960B1 (de) 1998-05-13

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