DE69313354T2 - Verfahren zur Herstellung von einem Ethylencopolymeren - Google Patents
Verfahren zur Herstellung von einem EthylencopolymerenInfo
- Publication number
- DE69313354T2 DE69313354T2 DE69313354T DE69313354T DE69313354T2 DE 69313354 T2 DE69313354 T2 DE 69313354T2 DE 69313354 T DE69313354 T DE 69313354T DE 69313354 T DE69313354 T DE 69313354T DE 69313354 T2 DE69313354 T2 DE 69313354T2
- Authority
- DE
- Germany
- Prior art keywords
- production
- ethylene copolymer
- copolymer
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001038 ethylene copolymer Polymers 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14394192 | 1992-06-04 |
Publications (3)
Publication Number | Publication Date |
---|---|
DE69313354D1 DE69313354D1 (de) | 1997-10-02 |
DE69313354T2 true DE69313354T2 (de) | 1998-02-26 |
DE69313354T3 DE69313354T3 (de) | 2001-01-18 |
Family
ID=15350628
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69313354T Expired - Fee Related DE69313354T3 (de) | 1992-06-04 | 1993-06-02 | Verfahren zur Herstellung von einem Ethylencopolymeren |
Country Status (3)
Country | Link |
---|---|
US (1) | US5652315A (de) |
EP (1) | EP0572990B2 (de) |
DE (1) | DE69313354T3 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19711339B4 (de) * | 1996-03-19 | 2008-09-11 | Denki Kagaku Kogyo K.K. | Copolymer aus Ethylen und aromatischer Vinylverbindung, Verfahren zu dessen Herstellung, Formkörper daraus sowie Zusammensetzung umfassend das Copolymer |
Families Citing this family (43)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW408155B (en) * | 1989-08-31 | 2000-10-11 | Dow Chemical Co | Blends of <alpha>-olefin/vinylidene aromatic monomer or hindered aliphatic vinylidene monomer interpolymers with polymers of vinylidene aromatic monomers |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US6087447A (en) * | 1989-08-31 | 2000-07-11 | The Dow Chemical Company | Blends of substantially random interpolymers with vinyl or vinylidene aromatic polymers |
US5658625A (en) | 1994-05-25 | 1997-08-19 | W.R. Grace & Co.-Conn. | Film containing alpha-olefin/vinyl aromatic copolymer |
US5977271A (en) * | 1994-09-02 | 1999-11-02 | The Dow Chemical Company | Process for preparing thermoset interpolymers and foams |
BR9509193A (pt) * | 1994-09-02 | 1997-10-21 | Dow Chemical Co | Elastômero termofixo processo para preparar um elastômero termofixo vulcanizado termoplástico processo para fazer um vulcanizado termoplástico e peça fabricada |
US5869591A (en) * | 1994-09-02 | 1999-02-09 | The Dow Chemical Company | Thermoset interpolymers and foams |
US6506866B2 (en) | 1994-11-17 | 2003-01-14 | Dow Global Technologies Inc. | Ethylene copolymer compositions |
EP0718323A3 (de) * | 1994-12-19 | 1998-01-14 | Sumitomo Chemical Company Limited | Quanternärer Ethylen-Copolymerkautschuk |
US6884480B2 (en) | 1995-05-19 | 2005-04-26 | Cryovac, Inc. | Film containing alpha-olefin/vinyl aromatic copolymer |
DE19542356A1 (de) * | 1995-11-14 | 1997-05-15 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten aus vinylaromatischen und olefinischen Verbindungen durch Dispersionspolymerisation in Gegenwart von Metallocenkatalysatorsystemen |
US5914289A (en) * | 1996-02-19 | 1999-06-22 | Fina Research, S.A. | Supported metallocene-alumoxane catalysts for the preparation of polyethylene having a broad monomodal molecular weight distribution |
JPH09309926A (ja) | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
EP0920463A1 (de) | 1996-08-26 | 1999-06-09 | Basf Aktiengesellschaft | Sternpolymere und verfahren zu deren herstellung |
US6254956B1 (en) | 1996-09-04 | 2001-07-03 | The Dow Chemical Company | Floor, wall or ceiling covering |
AR009521A1 (es) * | 1996-09-04 | 2000-04-26 | Dow Chemical Co | Mezclas de interpolimeros de alfa-olefinas/monomeros aromaticos de vinilideno y/o monomeros de vinilideno alifaticos o cicloalifaticos impedidos ysistemas adhesivos o de sellado y laminas, peliculas, partes moldeadas, fibras, latex o espumas y articulados fabricados con dichas mezclas. |
US5741857A (en) * | 1996-10-15 | 1998-04-21 | The Dow Chemical Company | Blends of elastomer block copolymer and aliphatic α-olefin/monovinylidene aromatic monomer and/or hindered aliphatic vinylidene monomer interpolymer |
JP3858397B2 (ja) * | 1997-01-30 | 2006-12-13 | 三井化学株式会社 | 芳香族ポリマー用顔料分散剤 |
US6329479B1 (en) | 1997-04-17 | 2001-12-11 | Denki Kagaku Kogyo Kabushiki Kaisha | Transition metal compound as catalyst component for polymerization, aromatic vinyl compound-olefin copolymer having stereoregularity and method for its preparation by means of the transition metal compound as catalyst component |
US6489424B2 (en) | 1997-04-17 | 2002-12-03 | Denki Kagaku Kogyo Kabushiki Kaisha | Transition metal catalyst component for polymerization, aromatic vinyl compound polymer having stereoregularity and method for its preparation by means of the catalyst component |
EP0872492B1 (de) * | 1997-04-17 | 2003-12-03 | Denki Kagaku Kogyo Kabushiki Kaisha | Übergangsmetallverbindung als Katalysatorbestandteil für die Polymerisation, Copolymer mit Stereoregularität aus einer aromatischen Vinyl-Verbindung und einem Olefin und Verfahren zu seiner Herstellung mit Hilfe der Übergangsmetallverbindung als Katalysatorbestandteil |
US6191245B1 (en) | 1997-09-04 | 2001-02-20 | The Dow Chemical Company | α-Olefin/vinylidene aromatic monomer and/or hindered aliphatic or cycloaliphatic vinylidene monomer interpolymers |
DE69839662D1 (de) * | 1997-10-01 | 2008-08-14 | Denki Kagaku Kogyo Kk | Folie und Folie zum Spannverpacken |
AU1085999A (en) | 1997-10-17 | 1999-05-10 | Dow Chemical Company, The | Compositions of interpolymers of alpha-olefin monomers with one or more vinyl orvinylidene aromatic monomers |
CN1065881C (zh) * | 1998-03-30 | 2001-05-16 | 中国石油化工总公司 | 用于制备间规聚苯乙烯与聚乙烯嵌段共聚物的催化剂 |
CN1073124C (zh) * | 1998-03-30 | 2001-10-17 | 中国石油化工总公司 | 制备间规聚苯乙烯与聚乙烯嵌段共聚物的催化剂 |
EP1041092B1 (de) * | 1998-10-19 | 2005-11-02 | Denki Kagaku Kogyo Kabushiki Kaisha | Ethylen/aromatisches vinylcopolymer und verfahren zu dessen herstellung |
US6231795B1 (en) * | 1998-12-04 | 2001-05-15 | The Dow Chemical Company | Soft and flexible foams made from blends of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic and/or sterically hindered aliphatic or cycloaliphatic vinyl or vinylidene interpolymers |
US6187232B1 (en) | 1998-12-04 | 2001-02-13 | The Dow Chemical Company | Acoustical insulation foams |
EP1159351A1 (de) | 1998-12-08 | 2001-12-05 | The Dow Chemical Company | Schmelzklebende polypropylen/ethylenpolymerfasern und zusammensetzung zu ihrer herstellung |
US6277916B1 (en) | 1999-02-25 | 2001-08-21 | The Dow Chemical Company | Process for preparing thermoplastic vulcanizates |
US6232415B1 (en) | 1999-03-31 | 2001-05-15 | Phillips Petroleum Company | Process to produce a monovinylaromatic/ monoolefin polymer and said monovinylaromatic/monoolefin polymer |
US6362270B1 (en) | 1999-08-12 | 2002-03-26 | The Dow Chemical Company | Thermoplastic compositions for durable goods applications |
US6852787B1 (en) | 1999-08-17 | 2005-02-08 | Mcmichael James W. | Free-flowing polymer composition |
WO2001051547A1 (en) | 2000-01-07 | 2001-07-19 | Dow Global Technologies Inc. | Thermoformable ethylene/styrene interpolymer-based polymer blend film for three-dimensional transfer finish foil |
US6160029A (en) * | 2000-03-08 | 2000-12-12 | The Dow Chemical Company | Olefin polymer and α-olefin/vinyl or α-olefin/vinylidene interpolymer blend foams |
US6649671B2 (en) | 2000-03-13 | 2003-11-18 | Dow Global Technologies Inc. | Concrete and process to make same |
US20020137859A1 (en) * | 2000-04-13 | 2002-09-26 | Kiyohiko Yokota | Process for producing alpha-olefin/aromatic vinyl copolymer |
US6767931B2 (en) | 2000-07-20 | 2004-07-27 | Dow Global Technologies Inc. | Foam compositions from blend of alkenyl aromatic polymers and alpha-olefin/vinyl or vinylidene aromatic interpolymers |
US6479138B1 (en) | 2001-02-27 | 2002-11-12 | Cryovac, Inc. | Low shrink tension film |
US6740724B2 (en) * | 2002-09-20 | 2004-05-25 | Nova Chemicals (International) S. A. | Ethylene styrene copolymer with isolated styrene |
US7324847B2 (en) * | 2003-02-06 | 2008-01-29 | Axelgaard Manufacturing Co., Ltd. | Reverse current controlling electrode |
KR101141359B1 (ko) * | 2005-09-09 | 2012-05-03 | 에스케이이노베이션 주식회사 | 에틸렌 단독중합체 또는 α-올레핀과의 공중합체 제조용균일 촉매계 |
Family Cites Families (25)
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US2952670A (en) * | 1957-08-26 | 1960-09-13 | Shell Oil Co | Polymerization and catalyst therefor |
DE3127133A1 (de) * | 1981-07-09 | 1983-01-27 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polyolefinen und deren copolymerisaten |
DE3443087A1 (de) * | 1984-11-27 | 1986-05-28 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von polyolefinen |
PL276385A1 (en) * | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
US5055438A (en) * | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
IL85097A (en) * | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
JPH0742301B2 (ja) * | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
US5229478A (en) * | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
KR920006464B1 (ko) * | 1988-09-14 | 1992-08-07 | 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 | 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법 |
KR930002411B1 (ko) * | 1988-09-14 | 1993-03-30 | 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 | 벤젠불용성 유기알루미늄 옥시화합물 및 그 제조방법 |
DE3907965A1 (de) * | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
DE3907964A1 (de) * | 1989-03-11 | 1990-09-13 | Hoechst Ag | Verfahren zur herstellung eines syndiotaktischen polyolefins |
ATE130859T1 (de) * | 1989-03-20 | 1995-12-15 | Idemitsu Kosan Co | Styrencopolymer und verfahren zur herstellung. |
JPH02247201A (ja) * | 1989-03-20 | 1990-10-03 | Toyo Stauffer Chem Co | オレフィン重合用触媒成分 |
JP2836188B2 (ja) * | 1989-06-26 | 1998-12-14 | 住友化学工業株式会社 | エチレン―芳香族ビニル化合物交互共重合体及びその製造方法 |
NZ235032A (en) † | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
JPH03103407A (ja) * | 1989-09-18 | 1991-04-30 | Idemitsu Kosan Co Ltd | オレフィン系重合体の製造法 |
US5340892A (en) * | 1989-09-29 | 1994-08-23 | Idemitsu Kosan Co., Ltd. | Process for producing styrene polymers |
MY107639A (en) * | 1990-04-18 | 1996-05-30 | Mitsui Chemicals Incorporated | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation |
JPH0469394A (ja) * | 1990-07-09 | 1992-03-04 | Mitsui Toatsu Chem Inc | 新規遷移金属化合物及びこれを用いたシンジオタクチックポリ―α―オレフィンの製造方法 |
TW218884B (de) * | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
JP3193066B2 (ja) * | 1991-05-02 | 2001-07-30 | 三菱化学株式会社 | プロピレンランダム共重合体の製造法 |
DE69226564T3 (de) * | 1991-05-20 | 2004-04-08 | Mitsui Chemicals, Inc. | Katalysator und Verfahren für Olefinpolymerisation |
US5543484A (en) * | 1994-11-18 | 1996-08-06 | The Penn State Research Foundation | α-olefin/para-alkylstyrene copolymers |
-
1993
- 1993-06-02 DE DE69313354T patent/DE69313354T3/de not_active Expired - Fee Related
- 1993-06-02 EP EP93108824A patent/EP0572990B2/de not_active Expired - Lifetime
-
1996
- 1996-06-14 US US08/663,596 patent/US5652315A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19711339B4 (de) * | 1996-03-19 | 2008-09-11 | Denki Kagaku Kogyo K.K. | Copolymer aus Ethylen und aromatischer Vinylverbindung, Verfahren zu dessen Herstellung, Formkörper daraus sowie Zusammensetzung umfassend das Copolymer |
Also Published As
Publication number | Publication date |
---|---|
US5652315A (en) | 1997-07-29 |
EP0572990A3 (en) | 1994-07-06 |
EP0572990A2 (de) | 1993-12-08 |
DE69313354D1 (de) | 1997-10-02 |
EP0572990B1 (de) | 1997-08-27 |
DE69313354T3 (de) | 2001-01-18 |
EP0572990B2 (de) | 2000-08-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8363 | Opposition against the patent | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP |
|
8366 | Restricted maintained after opposition proceedings | ||
8339 | Ceased/non-payment of the annual fee |