CN102648542A - 有机电子器件、组合物和方法 - Google Patents
有机电子器件、组合物和方法 Download PDFInfo
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- CN102648542A CN102648542A CN2010800533970A CN201080053397A CN102648542A CN 102648542 A CN102648542 A CN 102648542A CN 2010800533970 A CN2010800533970 A CN 2010800533970A CN 201080053397 A CN201080053397 A CN 201080053397A CN 102648542 A CN102648542 A CN 102648542A
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- polythiophene
- layer
- execution mode
- polymer
- sulfonate
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/81—Electrodes
- H10K30/82—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
- H10K30/83—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes comprising arrangements for extracting the current from the cell, e.g. metal finger grid systems to reduce the serial resistance of transparent electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/81—Electrodes
- H10K30/82—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/111—Organic polymers or oligomers comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
- H10K85/113—Heteroaromatic compounds comprising sulfur or selene, e.g. polythiophene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Abstract
Description
实验和器件编号 | Jsc | Voc(V) | FF | η(%) | 最佳η |
6-1(对照)* | 9.88 | 0.60 | 0.54 | 3.27 | 3.66 |
6-2 | 2.51 | 0.09 | 0.25 | 0.06 | 0.08 |
6-3 | 2.56 | 0.10 | 0.25 | 0.07 | 0.08 |
6-4 | 2.89 | 0.12 | 0.26 | 0.09 | 0.13 |
6-5 | 3.30 | 0.16 | 0.26 | 0.14 | 0.17 |
实验和器件编号 | Jsc | Voc(V) | FF | η(%) | 最佳η |
7-1(对照)* | 10.36 | 0.61 | 0.58 | 3.44 | 3.76 |
7-2 | 6.95E-04 | 0.51 | 0.23 | 8.26E-05 | 1.02E-04 |
7-3 | 7.78E-04 | 0.52 | 0.23 | 9.51E-05 | 1.33E-04 |
7-4 | 6.39E-04 | 0.49 | 0.24 | 7.52E-05 | 1.17E-04 |
7-5 | 8.30E-04 | 0.53 | 0.23 | 1.01E-04 | 1.30E-04 |
7-6 | 2.29E-03 | 0.58 | 0.24 | 3.21E-04 | 3.63E-04 |
实验和器件编号 | Jsc | Voc(V) | FF | η(%) | 最佳η |
8-1(对照)* | 6.43 | 0.51 | 0.54 | 1.86 | 2.70 |
8-2 | 6.03 | 0.55 | 0.55 | 1.83 | 1.90 |
8-3 | 5.69 | 0.55 | 0.58 | 1.82 | 1.91 |
8-4 | 5.61 | 0.55 | 0.55 | 1.68 | 1.75 |
8-5 | 5.64 | 0.55 | 0.55 | 1.72 | 1.74 |
实验和器件编号 | Jsc | Voc(V) | FF | η(%) | 最佳η |
9-1(对照)* | 10.08 | 0.61 | 0.60 | 3.71 | 3.77 |
9-2pH 5 | 9.84 | 0.60 | 0.49 | 2.87 | 3.02 |
9-3pH 5 | 9.65 | 0.60 | 0.46 | 2.70 | 2.92 |
9-4pH 5 | 9.44 | 0.55 | 0.38 | 1.96 | 2.10 |
9-5pH 5 | 9.36 | 0.60 | 0.44 | 2.46 | 2.63 |
9-8pH 3 | 8.55 | 0.85 | 0.51 | 3.66 | 3.79 |
9-9pH 3 | 8.45 | 0.85 | 0.54 | 3.86 | 3.92 |
实验和器件编号 | Jsc | Voc(V) | FF | η(%) | 最佳η |
10-1(对照)* | 9.58 | 0.61 | 0.62 | 3.63 | 3.69 |
10-2HIL | 9.48 | 0.60 | 0.58 | 3.32 | 3.37 |
10-3HIL | 9.21 | 0.60 | 0.58 | 3.20 | 3.28 |
10-4HIL | 9.48 | 0.60 | 0.58 | 3.32 | 3.46 |
10-5HIL | 9.64 | 0.61 | 0.58 | 3.38 | 3.48 |
实验和器件编号 | 层1 | 层2 | 层3 | 层4 | 层5 | 层6 |
11-1 | pH5 HIL | (无) | 中间层 | 发射层 | Ba | Al |
11-2 | pH5 | (无) | 中间层 | 发射层 | Ba | Al |
11-3 | pH5 | Plexcore OC HIL B | 中间层 | 发射层 | Ba | Al |
11-4 | pH5 | Plexcore OC HIL B | 中间层 | 发射层 | Ba | Al |
器件 | CIEy | Cd/A(效率) | 电压(V) |
11-1和11-2的平均值 | 0.22 | 5.18 | 9.36 |
11-3和11-4的平均值 | 0.23 | 3.65 | 8.41 |
HIL系统 | 组成 | 配方中的wt% |
HIL | 磺化聚合物* | 0.204 |
P4VP | 0.948 | |
PSS | 0.012 | |
Nafion | 0.036 | |
水 | 32.340 | |
1,2-丙二醇 | 14.700 | |
IPA | 11.760 | |
甲醇 | 40.000 |
TC | JSC | VOC(V) | FF | E(%) |
ITO | 9.70 | 0.84 | 0.64 | 5.23 |
ITO | 9.84 | 0.84 | 0.63 | 5.23 |
Ag纳米线 | 6.94 | 0.84 | 0.60 | 3.48 |
Ag纳米线 | 7.42 | 0.84 | 0.66 | 4.14 |
Ag纳米线 | 6.87 | 0.84 | 0.66 | 3.84 |
Claims (11)
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US24691309P | 2009-09-29 | 2009-09-29 | |
US61/246,913 | 2009-09-29 | ||
PCT/US2010/050250 WO2011041232A1 (en) | 2009-09-29 | 2010-09-24 | Organic electronic devices, compositions, and methods |
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JP (1) | JP5667195B2 (zh) |
KR (1) | KR101797783B1 (zh) |
CN (2) | CN102648542A (zh) |
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Also Published As
Publication number | Publication date |
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CN107104186B (zh) | 2020-06-30 |
JP5667195B2 (ja) | 2015-02-12 |
CN107104186A (zh) | 2017-08-29 |
TW201124434A (en) | 2011-07-16 |
KR20120099216A (ko) | 2012-09-07 |
EP2471117B1 (en) | 2017-11-15 |
US8431925B2 (en) | 2013-04-30 |
JP2013506262A (ja) | 2013-02-21 |
KR101797783B1 (ko) | 2017-11-14 |
TWI499602B (zh) | 2015-09-11 |
SG10201709677PA (en) | 2017-12-28 |
WO2011041232A1 (en) | 2011-04-07 |
US20110095275A1 (en) | 2011-04-28 |
EP2471117A1 (en) | 2012-07-04 |
US20130320313A1 (en) | 2013-12-05 |
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