CA2713022A1 - A system for purging non-fuel material from fuel cell anodes - Google Patents
A system for purging non-fuel material from fuel cell anodes Download PDFInfo
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- CA2713022A1 CA2713022A1 CA2713022A CA2713022A CA2713022A1 CA 2713022 A1 CA2713022 A1 CA 2713022A1 CA 2713022 A CA2713022 A CA 2713022A CA 2713022 A CA2713022 A CA 2713022A CA 2713022 A1 CA2713022 A1 CA 2713022A1
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- purge
- fuel cell
- fuel
- valve
- passive
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/247—Arrangements for tightening a stack, for accommodation of a stack in a tank or for assembling different tanks
- H01M8/2475—Enclosures, casings or containers of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/30—Fuel cells in portable systems, e.g. mobile phone, laptop
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04067—Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/1097—Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02B90/10—Applications of fuel cells in buildings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
A fuel cell gas purge system is provided that includes at least one fuel cell, such as a fuel cell stack or a fuel cell array, a fuel supply, and an adjustable fuel cell current load. The system further includes at least one passive purge valve disposed to purge accumulated non-fuel matter in the fuel cell, and operates according to a pressure differential across the valve. The valve can be a passive bi-directional valve, such as a dome valve, or a passive unidirectional valve. Further included is a purge management module that has a purge request module to determine when to increase the pressure of the hydrogen fuel to initiate the purge, and a purge complete module to determine when to adjust the pressure of the hydrogen fuel to complete the purge. The non-fuel matter can include non-fuel gases or condensed water.
Description
A SYSTEM FOR PURGING NON-FUEL MATERIAL FROM FUEL CELL
ANODES
FIELD OF THE INVENTION
The invention relates generally fuel cells. More particularly, the invention relates to a system for purging hydrogen fuel cells and determining when the purge is necessary and when it is complete.
BACKGROUND
Fuel cell systems where oxygen is supplied from ambient air accumulate the non-reactive components of air (primarily nitrogen and some water vapor or condensation) in the fuel stream due to finite diffusion rates of gases through the fuel cell electrolyte. The inert gas accumulation eventually lowers the fuel cell output voltage due to drop of fuel concentration. As a consequence, continuous operation requires periodic purging of the fuel compartment. Additionally, fuel cell systems often employ safety valves that allow gas to escape if the internal pressure or vacuum builds to unsafe levels, preventing damage to the device and/or hazards to users. Two types of methods for addressing these issues include active and passive purge valves. In active purge systems, an electrically or mechanically controlled valve is employed at the outlet of the fuel gas flow path to allow the fuel and accumulated nitrogen to escape when necessary. In smaller micro-fuel cell systems, miniature valves are often used when minimum size and weight is desired, such as the X-Valve available from Parker Hannefin. These active valves suffer from a number of problems including high cost and high power consumption. Additionally, they are unreliable as a safety purge valve, as they require proper external control in order to function properly. Passive purge valve systems allow gas pressure or vacuum to be released at a specified pressure. Accumulated non-reactive gases can be purged by increasing the operating pressure of the system above the purge pressure of the valve, allowing gas to escape. These valves tend to be less expensive than active valves and do not require external control, making them more reliable. These passive valves include poppet valves, like those available from Smart Products and duck bill valves, like those available from Vernay. Nevertheless a purge system that is based on passive valves requires a good control of the pressure upstream of the purge valve to avoid fuel loss as well as excessive purging. In many hydrogen fuel cell systems, for example, hydrogen is generated on demand such as using binary chemical reactions. The response time of such systems is often characterized by latency and long time constants that are due to finite thermal mass and mass transfer limitations of the chemical hydrogen reactor systems.
These limitations make frequent rapid pressure changes impossible and thus purging based on passive purge valves impractical.
Additionally, the current purge methods do not allow for detecting when all of the accumulated non-fuel gases have been purged from the system. To compensate for this ambiguity, systems with passive purge valves either need to purge excess fuel, creating a safety hazard and/or wasting fuel, or risk unsuccessful purges, resulting in reduced system power output and/or erratic performance.
Accordingly, there is a need to develop a simple, low-cost and effective purge system for fuel cells that minimizes system complexity while it maintains high fuel utilization.
ANODES
FIELD OF THE INVENTION
The invention relates generally fuel cells. More particularly, the invention relates to a system for purging hydrogen fuel cells and determining when the purge is necessary and when it is complete.
BACKGROUND
Fuel cell systems where oxygen is supplied from ambient air accumulate the non-reactive components of air (primarily nitrogen and some water vapor or condensation) in the fuel stream due to finite diffusion rates of gases through the fuel cell electrolyte. The inert gas accumulation eventually lowers the fuel cell output voltage due to drop of fuel concentration. As a consequence, continuous operation requires periodic purging of the fuel compartment. Additionally, fuel cell systems often employ safety valves that allow gas to escape if the internal pressure or vacuum builds to unsafe levels, preventing damage to the device and/or hazards to users. Two types of methods for addressing these issues include active and passive purge valves. In active purge systems, an electrically or mechanically controlled valve is employed at the outlet of the fuel gas flow path to allow the fuel and accumulated nitrogen to escape when necessary. In smaller micro-fuel cell systems, miniature valves are often used when minimum size and weight is desired, such as the X-Valve available from Parker Hannefin. These active valves suffer from a number of problems including high cost and high power consumption. Additionally, they are unreliable as a safety purge valve, as they require proper external control in order to function properly. Passive purge valve systems allow gas pressure or vacuum to be released at a specified pressure. Accumulated non-reactive gases can be purged by increasing the operating pressure of the system above the purge pressure of the valve, allowing gas to escape. These valves tend to be less expensive than active valves and do not require external control, making them more reliable. These passive valves include poppet valves, like those available from Smart Products and duck bill valves, like those available from Vernay. Nevertheless a purge system that is based on passive valves requires a good control of the pressure upstream of the purge valve to avoid fuel loss as well as excessive purging. In many hydrogen fuel cell systems, for example, hydrogen is generated on demand such as using binary chemical reactions. The response time of such systems is often characterized by latency and long time constants that are due to finite thermal mass and mass transfer limitations of the chemical hydrogen reactor systems.
These limitations make frequent rapid pressure changes impossible and thus purging based on passive purge valves impractical.
Additionally, the current purge methods do not allow for detecting when all of the accumulated non-fuel gases have been purged from the system. To compensate for this ambiguity, systems with passive purge valves either need to purge excess fuel, creating a safety hazard and/or wasting fuel, or risk unsuccessful purges, resulting in reduced system power output and/or erratic performance.
Accordingly, there is a need to develop a simple, low-cost and effective purge system for fuel cells that minimizes system complexity while it maintains high fuel utilization.
SUMMARY OF THE INVENTION
The present invention provides a fuel cell gas purge system. The gas purge system includes at least one fuel cell, a fuel supply, and an adjustable fuel cell current load. The gas purge system further includes at least one passive purge valve disposed to purge accumulated non-fuel matter in the fuel cell, where the passive purge valve operates according to a pressure differential across the passive purge valve and a purge management module, where the purge management module includes a purge request module and a purge complete module. The purge request module determines when to increase the pressure of the fuel to initiate the purge and the purge complete module determines when to decrease the pressure of the hydrogen fuel to complete the purge.
In one aspect of the invention, the fuel cell can include a hydrogen fuel cell, a propane fuel cell, a butane fuel cell or a methane fuel cell.
In one aspect of the invention, the at least one fuel cell can be a single fuel cell, a fuel cell stack, a fuel cell array or any combination thereof.
In a further aspect of the invention, the non-fuel matter can include non-fuel gases or condensed water.
According to another aspect of the invention, when not purging, the adjustable fuel cell load is adjusted to keep the pressure upstream of the passive purge valve below a cracking pressure of the passive purge valve, while during the purge, the adjustable fuel cell load is adjusted to increase the pressure upstream of the passive purge valve above the cracking pressure.
In another aspect, the adjustable fuel cell load includes a battery charger circuit attached to a battery, where a charging current of the battery can be adjusted.
In yet another aspect, the passive purge valve can include a passive bi-directional valve or a passive unidirectional valve. Here, the bi-directional valve can include a dome valve.
According to one aspect, a cracking pressure of the passive purge valve is as low as 1 PSI.
In a further aspect of the invention, the passive purge valve is disposed at a distal end of at least two fuel cells having the fuel connected in series, where a source of the fuel is disposed at a proximal end of the array.
According to one aspect, the purge request module determines when the non-fuel matter needs to be purged by sensing when a voltage of any of the fuel cells drop below a predetermined threshold. Here, the purge request module can determine when the non-fuel matter needs to be purged by sensing when a voltage in the fuel cell that is most proximal to the passive purge valve drops below a predetermined threshold.
In another aspect of the invention, the purge complete module determines when the non-fuel material has been purged from at least one fuel cell by sensing when the purge gas is primarily the fuel gas.
The present invention provides a fuel cell gas purge system. The gas purge system includes at least one fuel cell, a fuel supply, and an adjustable fuel cell current load. The gas purge system further includes at least one passive purge valve disposed to purge accumulated non-fuel matter in the fuel cell, where the passive purge valve operates according to a pressure differential across the passive purge valve and a purge management module, where the purge management module includes a purge request module and a purge complete module. The purge request module determines when to increase the pressure of the fuel to initiate the purge and the purge complete module determines when to decrease the pressure of the hydrogen fuel to complete the purge.
In one aspect of the invention, the fuel cell can include a hydrogen fuel cell, a propane fuel cell, a butane fuel cell or a methane fuel cell.
In one aspect of the invention, the at least one fuel cell can be a single fuel cell, a fuel cell stack, a fuel cell array or any combination thereof.
In a further aspect of the invention, the non-fuel matter can include non-fuel gases or condensed water.
According to another aspect of the invention, when not purging, the adjustable fuel cell load is adjusted to keep the pressure upstream of the passive purge valve below a cracking pressure of the passive purge valve, while during the purge, the adjustable fuel cell load is adjusted to increase the pressure upstream of the passive purge valve above the cracking pressure.
In another aspect, the adjustable fuel cell load includes a battery charger circuit attached to a battery, where a charging current of the battery can be adjusted.
In yet another aspect, the passive purge valve can include a passive bi-directional valve or a passive unidirectional valve. Here, the bi-directional valve can include a dome valve.
According to one aspect, a cracking pressure of the passive purge valve is as low as 1 PSI.
In a further aspect of the invention, the passive purge valve is disposed at a distal end of at least two fuel cells having the fuel connected in series, where a source of the fuel is disposed at a proximal end of the array.
According to one aspect, the purge request module determines when the non-fuel matter needs to be purged by sensing when a voltage of any of the fuel cells drop below a predetermined threshold. Here, the purge request module can determine when the non-fuel matter needs to be purged by sensing when a voltage in the fuel cell that is most proximal to the passive purge valve drops below a predetermined threshold.
In another aspect of the invention, the purge complete module determines when the non-fuel material has been purged from at least one fuel cell by sensing when the purge gas is primarily the fuel gas.
In a further aspect of the invention, the purged non-fuel matter from the passive purge valve is directed across a cathode of one the fuel cells in an array of fuel cells, where the purge complete module determines when the non-fuel matter has been purged by sensing when a voltage of the one fuel cell drops below a threshold voltage.
In yet another aspect, the purged non-fuel matter from the passive purge valve is directed to a catalyst bed in the presence of ambient air, where the purge complete module determines when the non-fuel matter has been purged by sensing when a temperature of the catalyst bed exceeds a threshold level. Here the catalyst can include Platinum, Palladium, Ruthenium, Manganese oxide, Silver oxide and Cobalt oxide.
According to another aspect, the purge complete module determines when the non-fuel material has been purged by using a timer. Here, a duration of the timer is determined according to a current load in one of the fuel cells before the purge was initiated.
In a further aspect, the purged non-fuel matter from the passive purge valve is directed to the anode of an auxiliary fuel cell, where the purge complete module determines when the non-fuel matter has been purged by sensing when the output of the fuel cell exceeds a threshold level, where the output can be either voltage or current.
BRIEF DESCRIPTION OF THE FIGURES
The objectives and advantages of the present invention will be understood by reading the following detailed description in conjunction with the drawing, in which:
FIG. 1 shows a fuel cell gas purge system having detection for a completed purge based on a timer, according to the current invention.
FIG. 2 shows a fuel cell gas purge system having completed purge detection according to the present invention.
FIG. 3 shows a multiple discrete cell system that has the purge exhaust routed to one or more different cells in the system according to the present invention.
FIG. 4 shows a flow diagram of a software algorithm to monitor the system and use the voltage data from the purge cell to determine when a purge has been effectively completed, according to the current invention.
FIG. 5 shows a fuel cell gas purge system that has the purge exhaust routed to an anode of an auxiliary fuel cell, according to the current invention.
FIG. 6 shows a fuel cell gas purge system that has the purge exhaust routed to a catalyst bed in the presence of ambient air, according to the current invention.
DETAILED DESCRIPTION OF THE INVENTION
Although the following detailed description contains many specifics for the purposes of illustration, anyone of ordinary skill in the art will readily appreciate that many variations and alterations to the following exemplary details are within the scope of the invention.
Accordingly, the following preferred embodiment of the invention is set forth without any loss of generality to, and without imposing limitations upon, the claimed invention.
Referring to the figures, FIG. 1 shows a timer-based fuel cell purge system 100 according one embodiment of the current invention. A hydrogen fuel cell 102 is shown that uses an air source 104 for oxygen input to the cathodes (not shown) and exhausted through an air output 106 in the form of humidified air, where the air source can be driven by a fan, for example. Here an exemplary hydrogen fuel cell 102 is shown, but it is understood throughout this description that the hydrogen fuel cell 102 can be any one of the many types of gas fuel cells, for example a propane fuel cell, a butane fuel cell or a methane fuel cell. It is further understood that the fuel cell can be a single fuel cell a fuel cell stack, an array of fuel cells or any combination thereof. The present embodiment is a hydrogen fuel cell gas purge system 100 that includes at least one hydrogen fuel cell 102.
The system 100 further includes a hydrogen fuel supply 108, and an adjustable hydrogen fuel cell current load 116. The gas purge system 100 further includes at least one passive purge valve 112 disposed to purge accumulated non-fuel matter 110 in the fuel compartment of the hydrogen fuel cell 102, where the passive purge valve 112 operates according to a pressure differential across the passive purge valve 112. It is understood throughout this document that the non-fuel matter 110 can include non-fuel gases or condensed water. It is further understood in this document that the passive purge valve 112 can be a passive bi-directional valve, such as a dome valve, or a passive unidirectional valve. Further included is a purge management module 118 that includes a purge request module 120 and a purge complete module 122. The purge request module 120 determines when to increase the pressure of the hydrogen fuel to initiate the purge, and the purge complete module 122 determines when to decrease the pressure of the hydrogen fuel to complete the purge.
Here, the non-fuel matter 110 can include non-fuel gases or condensed water. According to the current invention many methods exist to determine when purge gases comprise primarily the fuel.
In the current embodiment, the purge complete module 122 can determine when the non-fuel material 110 has been purged, by using a timer 124. Here, the duration of the timer 124 is determined according to a current load in one hydrogen fuel cell before the purge was initiated. The current load before purge is indicative of the hydrogen flow-rate before purge occurred. Based on the hydrogen flow-rate and known volume of fuel cell anode, the necessary duration of the purge can be determined.
FIG. 2 shows a hydrogen fuel cell gas purge system having detection for a completed purge 200. The end of purge detection fuel cell gas purge system 200 includes at least one hydrogen fuel cell 102, a hydrogen fuel supply 108, and an adjustable hydrogen fuel cell current load 116. The system 200 further includes at least one passive purge valve 112 disposed to purge accumulated non-fuel matter 110 in the hydrogen fuel cell 102. Further included is a purge management module 118 that includes a purge request module 120 and a purge complete module 122. The purge request module 120 determines when to increase the pressure of the hydrogen fuel to initiate the purge, and the purge complete module 122 determines when to decrease the pressure of the hydrogen fuel to complete the purge.
According to the current embodiment, the purge request module 120 determines when the non-fuel matter 110 needs to be purged by sensing when a voltage in the fuel cell 102, for example the voltage of one fuel cell of a fuel cell stack, drops below a predetermined threshold.
While not purging, the adjustable hydrogen fuel cell load 116 is adjusted to keep the pressure that is upstream of the passive purge valve 112 below its cracking pressure, effectively matching the fuel flow-rate consumed by the fuel cell 102 to the fuel flow-rate of the fuel generator 108, while during the purge, the adjustable hydrogen fuel cell load 116 is adjusted to increase the pressure upstream of the passive purge valve 112 above the cracking pressure. This can be done by decreasing the fuel consumption by the fuel cell 102 (reducing the fuel cell load current) while keeping the generated fuel flow-rate constant, which leads to fuel pressure buildup. The adjustments of the current load can be done rapidly, and thus rapid variations of the fuel pressure are possible, which means that quick, controlled purges are possible.
According to the embodiment shown in FIG. 2, the passive purge valve 112 is disposed at the distal end of the fuel cell stack 102 having the hydrogen fuel 108 connected in parallel, where hydrogen fuel source 108 is disposed at a proximal end of the fuel stack 102. Here, the purge request module 120 determines when the non-fuel material 110 needs to be purged by sensing when a voltage of any of the fuel cells in the stack 102 drop below a predetermined threshold when under a load. For example, the purge request module 120 can determine when the non-fuel matter 110 needs to be purged by sensing when a voltage in the fuel cell 102 that is most proximal to the passive purge valve 112 drops below a predetermined threshold.
FIG. 2 shows a hydrogen fuel cell gas purge system 200 having purge detection, where the purge valve outlet 202 is routed over the cathode (not shown) of one or more of the cells 102 in the fuel cell system 200, having an adjustable load 116. Initially, when inert gas and other non-fuel matter 110 such as water vapor/condensation, is being purged over the cell cathode the cell voltage is minimally affected, in particular at low or no loads. Once all of the non-fuel matter 110 has been purged and instead pure hydrogen is being purged, it catalytically reacts with the air-present oxygen at the cathode catalyst layer; effectively starving the cell of oxygen. This creates a detectable decrease in cell voltage particularly in passive natural convection driven cathode flow systems (see FIG. 3), which can be used to confirm that a successful purge occurred, as hydrogen will only be released after the accumulated non-fuel matter 110 is purged, where nitrogen, for example, tends to collect at the end of the flow path. Purging hydrogen over the cell cathode also has beneficial effects on the operation of the cell 102, since hydrogen reduces catalyst contaminants -such as oxides.
According to one embodiment, the purge exhaust 202 can be directed over the open cathode of the fuel cell 102 by a variety of means included but not limited to tubing routing the gas from the purge valve 112 to the surface of the cell 102 or positioning the purge valve 112 such that the exhaust 202 directed over the cell 102 is used for detecting purges.
The output of the purge valve 202 placed over the cathode of the fuel cell 102 can be placed in many positions over the cathode including on the center of the cell and closer to the edges. When the exhaust is placed closer to the edge of a cell 102, it is less sensitive to detecting purges, as the purged fuel gas can escape more readily. This can be advantageous in cases when there is limited control of the pressure of the fuel gas, potentially leading to excessive amounts of gas to be purged over the cell 102, and thus limiting the power output of that cell 102.
FIG. 3 shows a multiple discrete cell system 300, according to the current invention, that has the purge exhaust 202 routed to one or more different cells 304 in the system 300. In many fuel cell systems, such as with a fuel cell array 102, multiple cells are connected with serial fuel-gas flow 302, with a pressure sensor 310, and have a natural convection driven cathode flow systems. When the purged non-fuel matter 110 from the passive purge valve 112 is directed across one fuel cell 304 in the array 102 that is upstream from the passive purge valve 112, the purge complete module 118 determines when the non-fuel matter 110 has been purged by sensing when a voltage of the upstream fuel cell 304 drops below a threshold voltage. As shown, the passive purge valve 112 is disposed at a distal end of at least two hydrogen fuel cells 102 having the hydrogen fuel connected in series, where a source 108 of the hydrogen fuel is disposed at a proximal end of the array. In the types of systems shown in FIG. 3, nitrogen gas will accumulate in the last cell 306 over time, eventually causing its voltage and power output to fall. As a result, routing the purge exhaust 202 over the last cell 306 in the array 102 can be problematic, as the purge detection module cannot distinguish between a voltage drop due to needing a purge (due to accumulated nitrogen on the anode side) or having successfully completed a purge (due to catalytic oxygen starvation a the air side). According to one embodiment, it is preferable to use one of the first cells 304 in the array 102 (in order of receiving gas flow).
According to one embodiment, the adjustable hydrogen fuel cell load 116 can include a battery charger circuit attached to a battery 308, where a charging current of the battery 308 can be adjusted. One aspect here is that the battery 308 is not charged based on what it should be charged, for example with constant current etc., rather based on how much hydrogen is generated. Here, the battery 308 serves as a readily available energy storage needed to keep the pressure upstream of the purge valve 112 below cracking pressure as well as a hybridizing device that can support continuous (no power output interrupts during purges) as well as peak power output from the fuel cell system to an external user load.
According to the current invention, a number of methods exist for detecting the presence of hydrogen gas over the cathode of a fuel cell, a fuel cell stack or a fuel cell array. One method involves measuring the voltage of one cell and comparing it to surrounding cells.
When the voltage of the cell receiving the purge output is substantially lower than its neighboring cells and the system pressure is within the range in which a purge is expected, it can be reliably concluded that the purge was successful.
In yet another aspect, the purged non-fuel matter from the passive purge valve is directed to a catalyst bed in the presence of ambient air, where the purge complete module determines when the non-fuel matter has been purged by sensing when a temperature of the catalyst bed exceeds a threshold level. Here the catalyst can include Platinum, Palladium, Ruthenium, Manganese oxide, Silver oxide and Cobalt oxide.
According to another aspect, the purge complete module determines when the non-fuel material has been purged by using a timer. Here, a duration of the timer is determined according to a current load in one of the fuel cells before the purge was initiated.
In a further aspect, the purged non-fuel matter from the passive purge valve is directed to the anode of an auxiliary fuel cell, where the purge complete module determines when the non-fuel matter has been purged by sensing when the output of the fuel cell exceeds a threshold level, where the output can be either voltage or current.
BRIEF DESCRIPTION OF THE FIGURES
The objectives and advantages of the present invention will be understood by reading the following detailed description in conjunction with the drawing, in which:
FIG. 1 shows a fuel cell gas purge system having detection for a completed purge based on a timer, according to the current invention.
FIG. 2 shows a fuel cell gas purge system having completed purge detection according to the present invention.
FIG. 3 shows a multiple discrete cell system that has the purge exhaust routed to one or more different cells in the system according to the present invention.
FIG. 4 shows a flow diagram of a software algorithm to monitor the system and use the voltage data from the purge cell to determine when a purge has been effectively completed, according to the current invention.
FIG. 5 shows a fuel cell gas purge system that has the purge exhaust routed to an anode of an auxiliary fuel cell, according to the current invention.
FIG. 6 shows a fuel cell gas purge system that has the purge exhaust routed to a catalyst bed in the presence of ambient air, according to the current invention.
DETAILED DESCRIPTION OF THE INVENTION
Although the following detailed description contains many specifics for the purposes of illustration, anyone of ordinary skill in the art will readily appreciate that many variations and alterations to the following exemplary details are within the scope of the invention.
Accordingly, the following preferred embodiment of the invention is set forth without any loss of generality to, and without imposing limitations upon, the claimed invention.
Referring to the figures, FIG. 1 shows a timer-based fuel cell purge system 100 according one embodiment of the current invention. A hydrogen fuel cell 102 is shown that uses an air source 104 for oxygen input to the cathodes (not shown) and exhausted through an air output 106 in the form of humidified air, where the air source can be driven by a fan, for example. Here an exemplary hydrogen fuel cell 102 is shown, but it is understood throughout this description that the hydrogen fuel cell 102 can be any one of the many types of gas fuel cells, for example a propane fuel cell, a butane fuel cell or a methane fuel cell. It is further understood that the fuel cell can be a single fuel cell a fuel cell stack, an array of fuel cells or any combination thereof. The present embodiment is a hydrogen fuel cell gas purge system 100 that includes at least one hydrogen fuel cell 102.
The system 100 further includes a hydrogen fuel supply 108, and an adjustable hydrogen fuel cell current load 116. The gas purge system 100 further includes at least one passive purge valve 112 disposed to purge accumulated non-fuel matter 110 in the fuel compartment of the hydrogen fuel cell 102, where the passive purge valve 112 operates according to a pressure differential across the passive purge valve 112. It is understood throughout this document that the non-fuel matter 110 can include non-fuel gases or condensed water. It is further understood in this document that the passive purge valve 112 can be a passive bi-directional valve, such as a dome valve, or a passive unidirectional valve. Further included is a purge management module 118 that includes a purge request module 120 and a purge complete module 122. The purge request module 120 determines when to increase the pressure of the hydrogen fuel to initiate the purge, and the purge complete module 122 determines when to decrease the pressure of the hydrogen fuel to complete the purge.
Here, the non-fuel matter 110 can include non-fuel gases or condensed water. According to the current invention many methods exist to determine when purge gases comprise primarily the fuel.
In the current embodiment, the purge complete module 122 can determine when the non-fuel material 110 has been purged, by using a timer 124. Here, the duration of the timer 124 is determined according to a current load in one hydrogen fuel cell before the purge was initiated. The current load before purge is indicative of the hydrogen flow-rate before purge occurred. Based on the hydrogen flow-rate and known volume of fuel cell anode, the necessary duration of the purge can be determined.
FIG. 2 shows a hydrogen fuel cell gas purge system having detection for a completed purge 200. The end of purge detection fuel cell gas purge system 200 includes at least one hydrogen fuel cell 102, a hydrogen fuel supply 108, and an adjustable hydrogen fuel cell current load 116. The system 200 further includes at least one passive purge valve 112 disposed to purge accumulated non-fuel matter 110 in the hydrogen fuel cell 102. Further included is a purge management module 118 that includes a purge request module 120 and a purge complete module 122. The purge request module 120 determines when to increase the pressure of the hydrogen fuel to initiate the purge, and the purge complete module 122 determines when to decrease the pressure of the hydrogen fuel to complete the purge.
According to the current embodiment, the purge request module 120 determines when the non-fuel matter 110 needs to be purged by sensing when a voltage in the fuel cell 102, for example the voltage of one fuel cell of a fuel cell stack, drops below a predetermined threshold.
While not purging, the adjustable hydrogen fuel cell load 116 is adjusted to keep the pressure that is upstream of the passive purge valve 112 below its cracking pressure, effectively matching the fuel flow-rate consumed by the fuel cell 102 to the fuel flow-rate of the fuel generator 108, while during the purge, the adjustable hydrogen fuel cell load 116 is adjusted to increase the pressure upstream of the passive purge valve 112 above the cracking pressure. This can be done by decreasing the fuel consumption by the fuel cell 102 (reducing the fuel cell load current) while keeping the generated fuel flow-rate constant, which leads to fuel pressure buildup. The adjustments of the current load can be done rapidly, and thus rapid variations of the fuel pressure are possible, which means that quick, controlled purges are possible.
According to the embodiment shown in FIG. 2, the passive purge valve 112 is disposed at the distal end of the fuel cell stack 102 having the hydrogen fuel 108 connected in parallel, where hydrogen fuel source 108 is disposed at a proximal end of the fuel stack 102. Here, the purge request module 120 determines when the non-fuel material 110 needs to be purged by sensing when a voltage of any of the fuel cells in the stack 102 drop below a predetermined threshold when under a load. For example, the purge request module 120 can determine when the non-fuel matter 110 needs to be purged by sensing when a voltage in the fuel cell 102 that is most proximal to the passive purge valve 112 drops below a predetermined threshold.
FIG. 2 shows a hydrogen fuel cell gas purge system 200 having purge detection, where the purge valve outlet 202 is routed over the cathode (not shown) of one or more of the cells 102 in the fuel cell system 200, having an adjustable load 116. Initially, when inert gas and other non-fuel matter 110 such as water vapor/condensation, is being purged over the cell cathode the cell voltage is minimally affected, in particular at low or no loads. Once all of the non-fuel matter 110 has been purged and instead pure hydrogen is being purged, it catalytically reacts with the air-present oxygen at the cathode catalyst layer; effectively starving the cell of oxygen. This creates a detectable decrease in cell voltage particularly in passive natural convection driven cathode flow systems (see FIG. 3), which can be used to confirm that a successful purge occurred, as hydrogen will only be released after the accumulated non-fuel matter 110 is purged, where nitrogen, for example, tends to collect at the end of the flow path. Purging hydrogen over the cell cathode also has beneficial effects on the operation of the cell 102, since hydrogen reduces catalyst contaminants -such as oxides.
According to one embodiment, the purge exhaust 202 can be directed over the open cathode of the fuel cell 102 by a variety of means included but not limited to tubing routing the gas from the purge valve 112 to the surface of the cell 102 or positioning the purge valve 112 such that the exhaust 202 directed over the cell 102 is used for detecting purges.
The output of the purge valve 202 placed over the cathode of the fuel cell 102 can be placed in many positions over the cathode including on the center of the cell and closer to the edges. When the exhaust is placed closer to the edge of a cell 102, it is less sensitive to detecting purges, as the purged fuel gas can escape more readily. This can be advantageous in cases when there is limited control of the pressure of the fuel gas, potentially leading to excessive amounts of gas to be purged over the cell 102, and thus limiting the power output of that cell 102.
FIG. 3 shows a multiple discrete cell system 300, according to the current invention, that has the purge exhaust 202 routed to one or more different cells 304 in the system 300. In many fuel cell systems, such as with a fuel cell array 102, multiple cells are connected with serial fuel-gas flow 302, with a pressure sensor 310, and have a natural convection driven cathode flow systems. When the purged non-fuel matter 110 from the passive purge valve 112 is directed across one fuel cell 304 in the array 102 that is upstream from the passive purge valve 112, the purge complete module 118 determines when the non-fuel matter 110 has been purged by sensing when a voltage of the upstream fuel cell 304 drops below a threshold voltage. As shown, the passive purge valve 112 is disposed at a distal end of at least two hydrogen fuel cells 102 having the hydrogen fuel connected in series, where a source 108 of the hydrogen fuel is disposed at a proximal end of the array. In the types of systems shown in FIG. 3, nitrogen gas will accumulate in the last cell 306 over time, eventually causing its voltage and power output to fall. As a result, routing the purge exhaust 202 over the last cell 306 in the array 102 can be problematic, as the purge detection module cannot distinguish between a voltage drop due to needing a purge (due to accumulated nitrogen on the anode side) or having successfully completed a purge (due to catalytic oxygen starvation a the air side). According to one embodiment, it is preferable to use one of the first cells 304 in the array 102 (in order of receiving gas flow).
According to one embodiment, the adjustable hydrogen fuel cell load 116 can include a battery charger circuit attached to a battery 308, where a charging current of the battery 308 can be adjusted. One aspect here is that the battery 308 is not charged based on what it should be charged, for example with constant current etc., rather based on how much hydrogen is generated. Here, the battery 308 serves as a readily available energy storage needed to keep the pressure upstream of the purge valve 112 below cracking pressure as well as a hybridizing device that can support continuous (no power output interrupts during purges) as well as peak power output from the fuel cell system to an external user load.
According to the current invention, a number of methods exist for detecting the presence of hydrogen gas over the cathode of a fuel cell, a fuel cell stack or a fuel cell array. One method involves measuring the voltage of one cell and comparing it to surrounding cells.
When the voltage of the cell receiving the purge output is substantially lower than its neighboring cells and the system pressure is within the range in which a purge is expected, it can be reliably concluded that the purge was successful.
One scheme for using the output of the purge detection method disclosed is to use a software algorithm to monitor the system and use the voltage data from the purge cell to determine when a purge has been effectively completed. One possible control scheme, without limitation, is the flow diagram 400 shown in FIG. 4. In this scheme the system CPU would first detect the need for a purge 402, generally looking for a voltage decrease in the last cell. The system CPU would then increase the system pressure 404. The means for doing this vary with the type of system. In one representative hydrogen fueled system, in which the hydrogen is produced on demand using a binary chemical reaction between a liquid and a solid, the system pressure can be increased by increasing the rate with which the hydrogen is produced, which is in turn done by increasing the rate that the fluid is pumped into the chamber containing the reactive solid. Alternatively, the system pressure can be increased by keeping the rate of hydrogen production constant, and decreasing the rate with which the hydrogen is consumed by reducing the load on the fuel cell system, which is accomplished with the adjustable load 116 shown in FIG. 2 and FIG. 3.
In systems where there is a significant degree of latency in the hydrogen production rate, reducing the load to increase system pressure is the preferred embodiment.
Once the pressure has increased above a minimum threshold purge pressure, the system CPU waits to see a voltage drop 406 in the purge detection cell, indicating a successful purge. The system can then either reduce the pumping rate or increase the load on the fuel cells to bring the system pressure back 408 below the purge pressure in order to prevent the purging of excess hydrogen.
The present invention uses at least one passive valve that allows flow in two directions at predetermined pressures. In one possible embodiment, a dome type valve is used as a passive purge valve in the fuel cell system. Dome valves allow flow in both directions once predetermined pressure thresholds are reached, enabling a single valve to be used for pressure relief, purging, and vacuum relief. A preferred cracking pressure for purging can be as low as 1 PSI.
The purge valve assembly can be a standalone part or integrated into another assembly. In one embodiment, the dome valve could be a silicone quadricuspid dome valve.
These valves offer the additional benefits of being low cost and sealing reliably at very low pressures. Dome valves offer an additional benefit of some hysteresis in closing. This enables more rapid purges, which can be beneficial in fuel cell systems with parallel flow field structures.
FIG. 5 shows an auxiliary fuel cell embodiment 500 that includes a purge exhaust 202 routed to an anode of an auxiliary fuel cell 502, while the cathode of the auxiliary fuel cell 502 is supplied with oxygen by air, either from an active air-move 506 such as a fan or preferably passively by diffusion. The purge exhaust 202 from the passive purge valve 112 is directed to a hydrogen sensor such as an anode of an auxiliary fuel cell 502, where the purge complete module 122 determines when the non-fuel matter 110 has been purged by sensing when the output 504 of the auxiliary fuel cell 502 exceeds a threshold level, where the output 504 can be either voltage or current. Initially when inert gas and other non-fuel matter 110 such as water vapor/condensation, is being purged into the anode the open cell voltage of the auxiliary fuel cell 502 is low and cell current when loaded is minimal. Once all of the inert gas 110 has been purged and instead pure hydrogen is being purged the open cell voltage of the auxiliary cell 502 increases and the cell current under load increases appreciably. Comparing the load current of the auxiliary cell 502 to a threshold value can indicate hydrogen purity in the purge stream.
According to another embodiment FIG. 6 shows a catalyst bed embodiment 600 that includes a purge exhaust 202 routed to a catalyst bed 602 in the presence of ambient air 604. Here the purge complete module 122 determines when the non-fuel matter 110 has been purged by sensing when the temperature 606 of the catalyst bed 602 exceeds a threshold level. The structure of the catalyst bed allows mixing of the purge exhaust 202 with ambient air 604 e.g. by diffusion, or venturi entraining. Initially, when inert gas and other non-fuel matter 110 such as water vapor/condensation, is being purged into the catalyst bed the gases pass through the catalyst bed without any reaction.
Once all of the inert gas 110 has been purged and instead pure hydrogen is being purged, the hydrogen mixed with oxygen from ambient air catalytically combust at the catalyst bed, releasing heat and water vapor. The measured temperature increase 606 of the catalyst bed 602 is a good indication of hydrogen purity in the purge stream. The catalysts suitable for this method are selected from the Platinum group, oxides of silver, cobalt, manganese or any other catalyst with suitable catalytic reactivity at room temperature.
The present invention has now been described in accordance with several exemplary embodiments, which are intended to be illustrative in all aspects, rather than restrictive.
Thus, the present invention is capable of many variations in detailed implementation, which may be derived from the description contained herein by a person of ordinary skill in the art. All such variations are considered to be within the scope and spirit of the present invention as defined by the following claims and their legal equivalents.
In systems where there is a significant degree of latency in the hydrogen production rate, reducing the load to increase system pressure is the preferred embodiment.
Once the pressure has increased above a minimum threshold purge pressure, the system CPU waits to see a voltage drop 406 in the purge detection cell, indicating a successful purge. The system can then either reduce the pumping rate or increase the load on the fuel cells to bring the system pressure back 408 below the purge pressure in order to prevent the purging of excess hydrogen.
The present invention uses at least one passive valve that allows flow in two directions at predetermined pressures. In one possible embodiment, a dome type valve is used as a passive purge valve in the fuel cell system. Dome valves allow flow in both directions once predetermined pressure thresholds are reached, enabling a single valve to be used for pressure relief, purging, and vacuum relief. A preferred cracking pressure for purging can be as low as 1 PSI.
The purge valve assembly can be a standalone part or integrated into another assembly. In one embodiment, the dome valve could be a silicone quadricuspid dome valve.
These valves offer the additional benefits of being low cost and sealing reliably at very low pressures. Dome valves offer an additional benefit of some hysteresis in closing. This enables more rapid purges, which can be beneficial in fuel cell systems with parallel flow field structures.
FIG. 5 shows an auxiliary fuel cell embodiment 500 that includes a purge exhaust 202 routed to an anode of an auxiliary fuel cell 502, while the cathode of the auxiliary fuel cell 502 is supplied with oxygen by air, either from an active air-move 506 such as a fan or preferably passively by diffusion. The purge exhaust 202 from the passive purge valve 112 is directed to a hydrogen sensor such as an anode of an auxiliary fuel cell 502, where the purge complete module 122 determines when the non-fuel matter 110 has been purged by sensing when the output 504 of the auxiliary fuel cell 502 exceeds a threshold level, where the output 504 can be either voltage or current. Initially when inert gas and other non-fuel matter 110 such as water vapor/condensation, is being purged into the anode the open cell voltage of the auxiliary fuel cell 502 is low and cell current when loaded is minimal. Once all of the inert gas 110 has been purged and instead pure hydrogen is being purged the open cell voltage of the auxiliary cell 502 increases and the cell current under load increases appreciably. Comparing the load current of the auxiliary cell 502 to a threshold value can indicate hydrogen purity in the purge stream.
According to another embodiment FIG. 6 shows a catalyst bed embodiment 600 that includes a purge exhaust 202 routed to a catalyst bed 602 in the presence of ambient air 604. Here the purge complete module 122 determines when the non-fuel matter 110 has been purged by sensing when the temperature 606 of the catalyst bed 602 exceeds a threshold level. The structure of the catalyst bed allows mixing of the purge exhaust 202 with ambient air 604 e.g. by diffusion, or venturi entraining. Initially, when inert gas and other non-fuel matter 110 such as water vapor/condensation, is being purged into the catalyst bed the gases pass through the catalyst bed without any reaction.
Once all of the inert gas 110 has been purged and instead pure hydrogen is being purged, the hydrogen mixed with oxygen from ambient air catalytically combust at the catalyst bed, releasing heat and water vapor. The measured temperature increase 606 of the catalyst bed 602 is a good indication of hydrogen purity in the purge stream. The catalysts suitable for this method are selected from the Platinum group, oxides of silver, cobalt, manganese or any other catalyst with suitable catalytic reactivity at room temperature.
The present invention has now been described in accordance with several exemplary embodiments, which are intended to be illustrative in all aspects, rather than restrictive.
Thus, the present invention is capable of many variations in detailed implementation, which may be derived from the description contained herein by a person of ordinary skill in the art. All such variations are considered to be within the scope and spirit of the present invention as defined by the following claims and their legal equivalents.
Claims (19)
1. A fuel cell purge system comprising:
a. at least one fuel cell;
b. a fuel supply;
c. an adjustable fuel cell current load;
d. at least one passive purge valve disposed to purge accumulated non-fuel matter in said fuel cell, wherein said passive purge valve operates according to a pressure differential across said passive purge valve; and e. a purge management module, wherein said purge management module comprises a purge request module and a purge complete module, wherein said purge request module determines when to increase a pressure of said fuel to initiate said purge and said purge complete module determines when to decrease said pressure of said fuel to complete said purge.
a. at least one fuel cell;
b. a fuel supply;
c. an adjustable fuel cell current load;
d. at least one passive purge valve disposed to purge accumulated non-fuel matter in said fuel cell, wherein said passive purge valve operates according to a pressure differential across said passive purge valve; and e. a purge management module, wherein said purge management module comprises a purge request module and a purge complete module, wherein said purge request module determines when to increase a pressure of said fuel to initiate said purge and said purge complete module determines when to decrease said pressure of said fuel to complete said purge.
2. The fuel cell purge system of claim 1, wherein said fuel cell is selected from the group consisting of hydrogen fuel cell, propane fuel cell, butane fuel cell and methane fuel cell.
3. The fuel cell purge system of claim 1, wherein said at least one fuel cell is selected from the group consisting of a single fuel cell, a fuel cell stack and a fuel cell array.
4. The fuel cell purge system of claim 1, wherein said non-fuel matter is selected from the group consisting of non-fuel gases and condensed water.
5. The fuel cell purge system of claim 1, wherein during normal operation said adjustable fuel cell load is adjusted to keep said pressure that is upstream of said passive purge valve below a cracking pressure of said passive purge valve, wherein during said purge said adjustable fuel cell load is adjusted to increase said pressure upstream of said passive purge valve above said cracking pressure.
6. The fuel cell purge system of claim 1, wherein said adjustable fuel cell load comprises a battery charger circuit attached to a battery, wherein a charging current of said battery can be adjusted.
7. The fuel cell purge system of claim 1, wherein said passive purge valve is selected from the group consisting of a passive bi-directional valve and a passive unidirectional valve.
8. The fuel cell purge system of claim 7, wherein said bi-directional valve comprises a dome valve.
9. The fuel cell purge system of claim 1, wherein a cracking pressure of said passive purge valve is as low as 1 PSI.
10. The fuel cell purge system of claim 1, wherein said passive purge valve is disposed at a distal end of at least two said fuel cells having said fuel connected in series, wherein a source of said fuel is disposed at a proximal end of said array.
11. The fuel cell purge system of claim 1, wherein said purge request module determines when said non-fuel matter needs to be purged by sensing when a voltage of any of said fuel cells drop below a predetermined threshold.
12. The fuel cell purge system of claim 11, wherein said purge request module determines when said non-fuel matter needs to be purged by sensing when a voltage in said fuel cell that is most proximal to said passive purge valve drops below a predetermined threshold.
13. The fuel cell purge system of claim 1, wherein said purge complete module determines when said non-fuel material has been purged from at least one said fuel cell by sensing when said purge comprises primarily said fuel.
14. The fuel cell purge system of claim 1, wherein said purged non-fuel matter from said passive purge valve is directed across a cathode of one said fuel cell in an array of said fuel cells, wherein said purge complete module determines when said non-fuel matter has been purged by sensing when a voltage of said upstream fuel cell drops below a threshold voltage.
15. The fuel cell purge system of claim 1, wherein said purged non-fuel matter from said passive purge valve is directed to a catalyst bed in the presence of ambient air, wherein said purge complete module determines when said non-fuel matter has been purged by sensing when a temperature of said catalyst bed exceeds a threshold level.
16. The fuel cell purge system of claim 15, wherein said catalyst is selected from the group consisting of Platinum, Palladium, Ruthenium, Manganese oxide, Silver oxide and Cobalt oxide.
17. The fuel cell purge system of claim 1, wherein said purge complete module determines when said non-fuel material has been purged by using a timer.
18. The fuel cell purge system of claim 17, wherein a duration of said timer is determined according to a current load in one said fuel cell before said purge was initiated.
19. The fuel cell purge system of claim 1, wherein said purged non-fuel matter from said passive purge valve is directed to the anode of an auxiliary fuel cell, wherein said purge complete module determines when said non-fuel matter has been purged by sensing when an output of said fuel cell exceeds a threshold level, wherein said output comprises a current or a voltage.
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| US61/062,961 | 2008-01-29 | ||
| PCT/US2009/000642 WO2009097146A1 (en) | 2008-01-29 | 2009-01-29 | A system for purging non-fuel material from fuel cell anodes |
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| CA2713022A1 true CA2713022A1 (en) | 2009-08-06 |
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| CA2713022A Abandoned CA2713022A1 (en) | 2008-01-29 | 2009-01-29 | A system for purging non-fuel material from fuel cell anodes |
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| EP (1) | EP2248213A1 (en) |
| JP (1) | JP2011511416A (en) |
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- 2009-01-29 WO PCT/US2009/000642 patent/WO2009097146A1/en active Application Filing
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- 2009-01-29 WO PCT/US2009/000648 patent/WO2009097149A1/en active Application Filing
- 2009-01-29 US US12/322,337 patent/US20090269634A1/en not_active Abandoned
- 2009-01-29 US US12/322,352 patent/US8192890B2/en active Active
- 2009-01-29 EP EP09705894A patent/EP2248213A1/en not_active Withdrawn
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2013
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9169976B2 (en) | 2011-11-21 | 2015-10-27 | Ardica Technologies, Inc. | Method of manufacture of a metal hydride fuel supply |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2011511416A (en) | 2011-04-07 |
| US8192890B2 (en) | 2012-06-05 |
| EP2248213A1 (en) | 2010-11-10 |
| US20130224611A1 (en) | 2013-08-29 |
| US20090305112A1 (en) | 2009-12-10 |
| CN101971402A (en) | 2011-02-09 |
| WO2009097146A1 (en) | 2009-08-06 |
| WO2009097149A1 (en) | 2009-08-06 |
| US20090269634A1 (en) | 2009-10-29 |
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