CA2621723C - Microwave energy interactive insulating structure - Google Patents
Microwave energy interactive insulating structure Download PDFInfo
- Publication number
- CA2621723C CA2621723C CA2621723A CA2621723A CA2621723C CA 2621723 C CA2621723 C CA 2621723C CA 2621723 A CA2621723 A CA 2621723A CA 2621723 A CA2621723 A CA 2621723A CA 2621723 C CA2621723 C CA 2621723C
- Authority
- CA
- Canada
- Prior art keywords
- layer
- support layer
- polymer film
- polymer
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package
- B65D81/3446—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within the package specially adapted to be heated by microwaves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3439—Means for affecting the heating or cooking properties
- B65D2581/3445—Microwave reactive adhesives, e.g. also used in valves or lids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3439—Means for affecting the heating or cooking properties
- B65D2581/3447—Heat attenuators, blocking agents or heat insulators for temperature control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3471—Microwave reactive substances present in the packaging material
- B65D2581/3472—Aluminium or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3471—Microwave reactive substances present in the packaging material
- B65D2581/3477—Iron or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3471—Microwave reactive substances present in the packaging material
- B65D2581/3479—Other metallic compounds, e.g. silver, gold, copper, nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D2581/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D2581/34—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within
- B65D2581/3437—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging foodstuffs or other articles intended to be cooked or heated within specially adapted to be heated by microwaves
- B65D2581/3486—Dielectric characteristics of microwave reactive packaging
- B65D2581/3494—Microwave susceptor
Abstract
A microwave energy interactive structure for heating, browning, and/or crisping a food item in a microwave oven comprises a plurality of layers including a layer of microwave energy interactive material and a substantially continuous tie layer. The tie layer comprises a thermoplastic material. Upon sufficient exposure to microwave energy, the tie layer softens and allows the adjacent layers to separate from one another to define a void between the respective layers.
Description
, , MICROWAVE ENERGY INTERACTIVE INSULATING STRUCTURE
TECHNICAL FIELD
This application discloses various microwave energy interactive structures for heating, browning, and/or crisping a food item in a microwave oven.
BACKGROUND
Microwave ovens have become a principle form of heating food in a rapid and effective manner. Various attempts have been made to provide microwave food materials, structures, and packages that produce effects associated with foods cooked in a conventional oven. Such materials, structures, and packages must be capable of controlling the distribution of energy around the food item, utilizing the energy in the most efficient manner, and ensuring that the food item and the material, structure, or package has a pleasant and acceptable appearance.
BRIEF DESCRIPTION OF THE DRAWINGS
The description refers to the accompanying drawings, some of which are schematic, in which like reference characters refer to like parts throughout the several views, and in which:
, , CA 02621723 2008-02-15 FIG. 1A schematically illustrates a cross-sectional view of an microwave energy interactive structure according to various aspects of the invention;
FIG. 1B schematically illustrates the structure of FIG. 1A after sufficient exposure to microwave energy; and FIG. 2 schematically illustrates a cross-sectional view of another microwave energy interactive structure according to various aspects of the invention.
SUMMARY
This application generally discloses various microwave energy interactive structures or materials. The structures may be used to form heating sheets, sleeves, disks, trays, cartons, pouches, packages, and other constructs (collectively "constructs") that enhance the heating, browning, and/or crisping of a food item in a microwave oven. The various structures generally comprise a plurality of components or layers assembled and/or joined to one another in a facing, substantially contacting, layered configuration. Such layers may include a microwave energy interactive element and a tie layer joining a pair of adjacent layers. The tie layer may comprise a thermoplastic material.
Typically, the microwave energy interactive element comprises a thin layer of microwave energy interactive material (i.e., a "susceptor") (generally less than about 100 angstroms in thickness, for example, from about 60 to about 100 angstroms in thickness) that tends to absorb at least a portion of impinging microwave energy and convert it to thermal energy (i.e., heat) at the interface with a food item. Susceptors often are used to promote browning and/or crisping of the surface of a food item.
The susceptor may be supported on a microwave energy transparent
TECHNICAL FIELD
This application discloses various microwave energy interactive structures for heating, browning, and/or crisping a food item in a microwave oven.
BACKGROUND
Microwave ovens have become a principle form of heating food in a rapid and effective manner. Various attempts have been made to provide microwave food materials, structures, and packages that produce effects associated with foods cooked in a conventional oven. Such materials, structures, and packages must be capable of controlling the distribution of energy around the food item, utilizing the energy in the most efficient manner, and ensuring that the food item and the material, structure, or package has a pleasant and acceptable appearance.
BRIEF DESCRIPTION OF THE DRAWINGS
The description refers to the accompanying drawings, some of which are schematic, in which like reference characters refer to like parts throughout the several views, and in which:
, , CA 02621723 2008-02-15 FIG. 1A schematically illustrates a cross-sectional view of an microwave energy interactive structure according to various aspects of the invention;
FIG. 1B schematically illustrates the structure of FIG. 1A after sufficient exposure to microwave energy; and FIG. 2 schematically illustrates a cross-sectional view of another microwave energy interactive structure according to various aspects of the invention.
SUMMARY
This application generally discloses various microwave energy interactive structures or materials. The structures may be used to form heating sheets, sleeves, disks, trays, cartons, pouches, packages, and other constructs (collectively "constructs") that enhance the heating, browning, and/or crisping of a food item in a microwave oven. The various structures generally comprise a plurality of components or layers assembled and/or joined to one another in a facing, substantially contacting, layered configuration. Such layers may include a microwave energy interactive element and a tie layer joining a pair of adjacent layers. The tie layer may comprise a thermoplastic material.
Typically, the microwave energy interactive element comprises a thin layer of microwave energy interactive material (i.e., a "susceptor") (generally less than about 100 angstroms in thickness, for example, from about 60 to about 100 angstroms in thickness) that tends to absorb at least a portion of impinging microwave energy and convert it to thermal energy (i.e., heat) at the interface with a food item. Susceptors often are used to promote browning and/or crisping of the surface of a food item.
The susceptor may be supported on a microwave energy transparent
2 - , , substrate, for example, a layer of paper or polymer film for ease of handling and/or to prevent contact between the microwave energy interactive material and the food item.
Upon sufficient exposure to microwave energy, the structure transforms from a substantially flattened, planar structure to a multi-dimensional structure having an irregular surface. In this transformed state, the structure is capable of providing some degree of thermal insulation between the food item and the microwave heating environment and, therefore, may be referred to as a "microwave energy interactive insulating structure", "microwave energy interactive insulating material", "insulating material", or "insulating structure".
In one particular aspect, the microwave energy interactive insulating structure comprises a layer of microwave energy interactive material supported on a first polymer film, a support layer joined to the layer of microwave energy interactive material, a second polymer film in a superposed relationship with the support layer such that the support layer is disposed between the layer of microwave energy interactive material and the second polymer film, and a tie layer joining the support layer to the second polymer film layer. The tie layer comprises a thermoplastic material. Upon sufficient exposure to microwave energy, the support layer and the second polymer film at least partially separate from one another to define at least one insulating void between the support layer and the second polymer film, for example, in the tie layer.
The tie layer may be formed in numerous ways and may have various configurations and/or compositions. In one example, tie layer is substantially continuous. In another example, the tie layer includes at least one area having a first bond strength and at least one area having a second bond strength greater than the first bond strength. In still another
Upon sufficient exposure to microwave energy, the structure transforms from a substantially flattened, planar structure to a multi-dimensional structure having an irregular surface. In this transformed state, the structure is capable of providing some degree of thermal insulation between the food item and the microwave heating environment and, therefore, may be referred to as a "microwave energy interactive insulating structure", "microwave energy interactive insulating material", "insulating material", or "insulating structure".
In one particular aspect, the microwave energy interactive insulating structure comprises a layer of microwave energy interactive material supported on a first polymer film, a support layer joined to the layer of microwave energy interactive material, a second polymer film in a superposed relationship with the support layer such that the support layer is disposed between the layer of microwave energy interactive material and the second polymer film, and a tie layer joining the support layer to the second polymer film layer. The tie layer comprises a thermoplastic material. Upon sufficient exposure to microwave energy, the support layer and the second polymer film at least partially separate from one another to define at least one insulating void between the support layer and the second polymer film, for example, in the tie layer.
The tie layer may be formed in numerous ways and may have various configurations and/or compositions. In one example, tie layer is substantially continuous. In another example, the tie layer includes at least one area having a first bond strength and at least one area having a second bond strength greater than the first bond strength. In still another
3 , CA 02621723 2008-02-15 . .
example, the tie layer comprises at least one material that does not soften at the softening temperature of the thermoplastic material. Such material may be thermoplastic and have a higher softening point or may be thermosetting, such that it has no softening point. In still another example, the thermoplastic material has an affinity for each of the support layer and the second polymer film, and the tie layer comprises at least one other material that has an affinity for at least one of the support layer and the second polymer film that differs from the respective affinity of the thermoplastic material.
In another aspect, a method of making a microwave energy interactive insulating structure includes joining a support layer to a susceptor film, and joining a polymer film to the support layer to define a bonded area, where the bonded area is adapted to at least partially weaken in response to heat. In one variation, joining the polymer film to the support layer defines a second bonded area adapted to remain intact in response to heat.
In one variation, joining the polymer film to the support layer comprises extruding a tie layer material onto the support layer and bringing the polymer film into contact with the tie layer material. If desired, the interior surface of the polymer film may be printed before joining the polymer film to the support layer.
In another variation, joining the polymer film to the support layer comprises applying a tie layer material between the polymer film and the support layer to form the bonded area of the structure, and the method further comprises passing the structure through a patterned nip assembly to define an area having a first bond strength and an area having a second bond strength greater than the first bond strength.
example, the tie layer comprises at least one material that does not soften at the softening temperature of the thermoplastic material. Such material may be thermoplastic and have a higher softening point or may be thermosetting, such that it has no softening point. In still another example, the thermoplastic material has an affinity for each of the support layer and the second polymer film, and the tie layer comprises at least one other material that has an affinity for at least one of the support layer and the second polymer film that differs from the respective affinity of the thermoplastic material.
In another aspect, a method of making a microwave energy interactive insulating structure includes joining a support layer to a susceptor film, and joining a polymer film to the support layer to define a bonded area, where the bonded area is adapted to at least partially weaken in response to heat. In one variation, joining the polymer film to the support layer defines a second bonded area adapted to remain intact in response to heat.
In one variation, joining the polymer film to the support layer comprises extruding a tie layer material onto the support layer and bringing the polymer film into contact with the tie layer material. If desired, the interior surface of the polymer film may be printed before joining the polymer film to the support layer.
In another variation, joining the polymer film to the support layer comprises applying a tie layer material between the polymer film and the support layer to form the bonded area of the structure, and the method further comprises passing the structure through a patterned nip assembly to define an area having a first bond strength and an area having a second bond strength greater than the first bond strength.
4 In still another variation, joining the polymer film to the support layer comprises forming a tie layer between the polymer film and the support layer, where the tie layer includes a first component that softens at a first softening temperature and a second component that does not soften at the softening temperature of the first component.
In yet another variation, joining the polymer film to the support layer comprises forming a tie layer between the polymer film and the support layer, where the tie layer includes a thermoplastic material having an affinity for each of the support layer and the polymer film, and at least one other material having an affinity for at least one of the support layer and the polymer film that differs from the respective affinity of the thermoplastic material.
According to one aspect of the present invention there is provided a microwave energy interactive structure comprising a support layer having a first side and a second side opposite one another; a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a substantially continuous tie layer, wherein the tie layer comprises a thermoplastic material, and a void forms within the tie layer in response to microwave energy.
According to a further aspect of the present invention there is provided a microwave energy interactive structure comprising a support layer having a first side and a second side opposite one another; a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of
In yet another variation, joining the polymer film to the support layer comprises forming a tie layer between the polymer film and the support layer, where the tie layer includes a thermoplastic material having an affinity for each of the support layer and the polymer film, and at least one other material having an affinity for at least one of the support layer and the polymer film that differs from the respective affinity of the thermoplastic material.
According to one aspect of the present invention there is provided a microwave energy interactive structure comprising a support layer having a first side and a second side opposite one another; a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a substantially continuous tie layer, wherein the tie layer comprises a thermoplastic material, and a void forms within the tie layer in response to microwave energy.
According to a further aspect of the present invention there is provided a microwave energy interactive structure comprising a support layer having a first side and a second side opposite one another; a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of
5 , , microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a tie layer, wherein the tie layer comprises a first polymer and a second polymer, and wherein a void forms within the tie layer proximate to the first polymer in response to microwave energy.
According to another aspect of the present invention there is provided a microwave energy interactive structure comprising a support layer having a first side and a second side opposite one another; a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer by a substantially continuous tie layer, the second polymer film being joined to the second side of the support layer to define areas having a first bond strength and areas having a second bond strength greater than the first bond strength, wherein voids form within the tie layer proximate to the areas having the first bond strength in response to microwave energy.
Various other aspects, features, and advantages of the present invention will become apparent from the following description and accompanying figures.
5a DESCRIPTION
Some aspects of the present disclosure may be understood further by referring to the figures. For simplicity, like numerals may be used to describe like features. It will be understood that while various exemplary embodiments are shown and described in detail herein, any of the features may be used in any combination, and that such combinations are contemplated by the invention.
FIG. 1A depicts a schematic cross-sectional view of an exemplary insulating structure or material 100. The insulating structure 100 includes a layer of microwave energy interactive material 105 supported on a first polymer film layer 110 or other substrate to collectively define a susceptor film or simply "susceptor" 115. A support layer or simply "support" 120, 5b . , . .
which may be a moisture-providing layer, is joined to the microwave energy interactive material 105 using a layer of adhesive 125 or other suitable material. A substantially continuous tie layer 135 joins the second polymer film layer 130 to the support layer 120.
While not wishing to be bound by theory, it is believed that upon sufficient exposure to microwave energy, the temperature of the microwave energy interactive material 105 increases, thereby causing water vapor to be released and/or generated by the support layer 120.
At the same time, the tie layer 135 tends to soften, thereby weakening the bond between the second polymer film layer 130 and the support layer 120.
Depending on the degree of softening of the tie layer 135, the local and overall bond strength of the tie layer 135, the accompanying loss of adhesion between the second polymer film 130 and the moisture-providing support layer 120, and various other factors, the water vapor (and any other gases) released and/or generated by the support layer 120 may exert a pressure on the tie layer 135 and/or the second polymer film 130, thereby creating one or more voids, cells, or bubbles (collectively "voids") 140 between the support layer 120 and the polymer film layer 130 (e.g., in or adjacent to the tie layer 135), as shown in FIG. 1B. As a result, the structure 100 may be transformed from a somewhat flattened structure into an irregular, multi-dimensional structure having a somewhat wrinkled or textured appearance. The somewhat random or unpredictable manner in which this occurs may cause the polymer film layer 130 to appear stretched in some areas and shrunken in others, thereby creating a somewhat wrinkled or textured appearance.
In this wrinkled or textured, multi-dimensional configuration, the insulating structure 100 may enhance the heating, browning, and/or
According to another aspect of the present invention there is provided a microwave energy interactive structure comprising a support layer having a first side and a second side opposite one another; a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer by a substantially continuous tie layer, the second polymer film being joined to the second side of the support layer to define areas having a first bond strength and areas having a second bond strength greater than the first bond strength, wherein voids form within the tie layer proximate to the areas having the first bond strength in response to microwave energy.
Various other aspects, features, and advantages of the present invention will become apparent from the following description and accompanying figures.
5a DESCRIPTION
Some aspects of the present disclosure may be understood further by referring to the figures. For simplicity, like numerals may be used to describe like features. It will be understood that while various exemplary embodiments are shown and described in detail herein, any of the features may be used in any combination, and that such combinations are contemplated by the invention.
FIG. 1A depicts a schematic cross-sectional view of an exemplary insulating structure or material 100. The insulating structure 100 includes a layer of microwave energy interactive material 105 supported on a first polymer film layer 110 or other substrate to collectively define a susceptor film or simply "susceptor" 115. A support layer or simply "support" 120, 5b . , . .
which may be a moisture-providing layer, is joined to the microwave energy interactive material 105 using a layer of adhesive 125 or other suitable material. A substantially continuous tie layer 135 joins the second polymer film layer 130 to the support layer 120.
While not wishing to be bound by theory, it is believed that upon sufficient exposure to microwave energy, the temperature of the microwave energy interactive material 105 increases, thereby causing water vapor to be released and/or generated by the support layer 120.
At the same time, the tie layer 135 tends to soften, thereby weakening the bond between the second polymer film layer 130 and the support layer 120.
Depending on the degree of softening of the tie layer 135, the local and overall bond strength of the tie layer 135, the accompanying loss of adhesion between the second polymer film 130 and the moisture-providing support layer 120, and various other factors, the water vapor (and any other gases) released and/or generated by the support layer 120 may exert a pressure on the tie layer 135 and/or the second polymer film 130, thereby creating one or more voids, cells, or bubbles (collectively "voids") 140 between the support layer 120 and the polymer film layer 130 (e.g., in or adjacent to the tie layer 135), as shown in FIG. 1B. As a result, the structure 100 may be transformed from a somewhat flattened structure into an irregular, multi-dimensional structure having a somewhat wrinkled or textured appearance. The somewhat random or unpredictable manner in which this occurs may cause the polymer film layer 130 to appear stretched in some areas and shrunken in others, thereby creating a somewhat wrinkled or textured appearance.
In this wrinkled or textured, multi-dimensional configuration, the insulating structure 100 may enhance the heating, browning, and/or
6 . .
crisping of a food item in a microwave oven. First, any water vapor, air, and other gases contained in the voids 140 may provide insulation between the food item and the ambient environment of the microwave oven, thereby increasing the amount of sensible heat that stays within or is transferred to the food item. Further, the wrinkling and/or deforming of the structure 100 may cause the structure to conform more closely to the surface of the food item, thereby placing the microwave energy interactive material 105 into closer proximity with the food item and enhancing the browning and/or crisping of the surface of the food item.
When exposure to microwave energy ceases, the softened tie layer 135 material cools and eventually solidifies with at least some of the previously formed voids 140 between the support layer 120 and the second polymer film layer 130 intact in the solidified structure. In some instances, the voids 140 may provide a surface for safe and comfortable handling of the heated food item and also may help to retain heat within the package to keep the food item warm. As a result, the insulating structures of the invention may be used to form multi-functional packages (e.g., sleeves, pouches, wrappers, etc.) and other constructs that can be used to store, heat, brown, crisp, transport, and contain a food item.
If desired, the structure 100 may be formed and/or processed to selectively strengthen or weaken the bond between the support layer 120 and the second polymer film 130 to promote a desired degree of void 140 formation in the tie layer 135. Such strengthening or weakening may be made to be inherent in the tie layer 135 or may be the result of processing the structure 100 to mechanically or chemically strengthen or weaken particular areas of the tie layer 135. As a result, the areas of the tie layer 135 having a greater bond strength 145 are more likely to remain intact
crisping of a food item in a microwave oven. First, any water vapor, air, and other gases contained in the voids 140 may provide insulation between the food item and the ambient environment of the microwave oven, thereby increasing the amount of sensible heat that stays within or is transferred to the food item. Further, the wrinkling and/or deforming of the structure 100 may cause the structure to conform more closely to the surface of the food item, thereby placing the microwave energy interactive material 105 into closer proximity with the food item and enhancing the browning and/or crisping of the surface of the food item.
When exposure to microwave energy ceases, the softened tie layer 135 material cools and eventually solidifies with at least some of the previously formed voids 140 between the support layer 120 and the second polymer film layer 130 intact in the solidified structure. In some instances, the voids 140 may provide a surface for safe and comfortable handling of the heated food item and also may help to retain heat within the package to keep the food item warm. As a result, the insulating structures of the invention may be used to form multi-functional packages (e.g., sleeves, pouches, wrappers, etc.) and other constructs that can be used to store, heat, brown, crisp, transport, and contain a food item.
If desired, the structure 100 may be formed and/or processed to selectively strengthen or weaken the bond between the support layer 120 and the second polymer film 130 to promote a desired degree of void 140 formation in the tie layer 135. Such strengthening or weakening may be made to be inherent in the tie layer 135 or may be the result of processing the structure 100 to mechanically or chemically strengthen or weaken particular areas of the tie layer 135. As a result, the areas of the tie layer 135 having a greater bond strength 145 are more likely to remain intact
7 , CA 02621723 2008-02-15 , .
than areas of the tie layer 135 having a weaker bond strength 145, as illustrated schematically in FIG. 1 B.
In one example, selected areas of the structure may be strengthened using a patterned nip assembly or other suitable apparatus that can be configured to create areas of no nip pressure, low nip pressure, medium nip pressure, and high nip pressure that result in areas having increasing degrees of bond strength. In this manner, the degree of void formation in the tie layer can be better controlled to meet the heating, browning, and/or crisping requirements for a particular food item and/or heating application.
In another example, areas of greater and lesser strength can be created by forming a tie layer with various components or materials having differing properties. For example, the tie layer may include materials having different softening points. As another example, the tie layer may include materials having different affinities for the support layer and/or second polymer layer. In such examples, voids may form in areas of the tie layer material having a lower softening point or lesser affinity, while voids may form at a higher temperature or later in the heating process in areas of the tie layer having a higher softening point or affinity, or may not form at all. Numerous other techniques for modifying the behavior of the tie layer are contemplated by the invention.
It will be evident that any of the various techniques described above may result in the formation of any size, shape, and configuration of voids in the tie layer. In each of various examples, each void independently may have a major linear dimension of from about 0.05 to about 0.1 in., from about 0.1 to about 0.25 in., from about 0.25 to about 3 in., for example, from about 0.25 to about 0.5 in., from about 0.5 to about 0.75 in., from about 0.75 to about 1 in., from about 1 to about 1.25 in., from
than areas of the tie layer 135 having a weaker bond strength 145, as illustrated schematically in FIG. 1 B.
In one example, selected areas of the structure may be strengthened using a patterned nip assembly or other suitable apparatus that can be configured to create areas of no nip pressure, low nip pressure, medium nip pressure, and high nip pressure that result in areas having increasing degrees of bond strength. In this manner, the degree of void formation in the tie layer can be better controlled to meet the heating, browning, and/or crisping requirements for a particular food item and/or heating application.
In another example, areas of greater and lesser strength can be created by forming a tie layer with various components or materials having differing properties. For example, the tie layer may include materials having different softening points. As another example, the tie layer may include materials having different affinities for the support layer and/or second polymer layer. In such examples, voids may form in areas of the tie layer material having a lower softening point or lesser affinity, while voids may form at a higher temperature or later in the heating process in areas of the tie layer having a higher softening point or affinity, or may not form at all. Numerous other techniques for modifying the behavior of the tie layer are contemplated by the invention.
It will be evident that any of the various techniques described above may result in the formation of any size, shape, and configuration of voids in the tie layer. In each of various examples, each void independently may have a major linear dimension of from about 0.05 to about 0.1 in., from about 0.1 to about 0.25 in., from about 0.25 to about 3 in., for example, from about 0.25 to about 0.5 in., from about 0.5 to about 0.75 in., from about 0.75 to about 1 in., from about 1 to about 1.25 in., from
8 , about 1.25 to about 1.5 in., from about 1.5 to about 1.75 in., from about 1.75 to about 2 in., from about 2 to about 2.25 in., from about 2.25 to about 2.5 in., from about 2.5 to about 2.75 in., from about 2.75 to about 3 in., from about 3 to about 4 in., from about 4 to about 5 in, from about 0.5 to about 1.5 in., from about 1 to about 3 in., or any other dimension.
It is contemplated that, for some heating applications, the amount of water vapor provided by the support layer may be insufficient to provide the desired degree of void formation. In such applications, it may be beneficial to include an additional source of water vapor with the structure, for example, an additional paper or paper-based layer.
Alternatively or additionally, one or more reagents may be used to generate a gas to promote formation of voids. Numerous examples of reagents that may be suitable for use with the present structure are provided in U.S. Patent Application Publication No. 2006/0289521A1, published on Dec. 28, 2006,. In one example, the reagents may comprise sodium bicarbonate (NaHCO3) and a suitable acid. When exposed to heat, the reagents react to produce carbon dioxide. As another example, the reagent may comprise a blowing agent. Examples of blowing agents that may be suitable include, but are not limited to, p-p'-oxybis(benzenesulphonylhydrazide), azodicarbonamide, and p-toluenesulfonylsemicarbazide. In another example, the reagent may comprise a hydrated mineral that releases water in response to heat.
However, numerous other reagents and released gases may be used.
By way of example, FIG. 2 schematically depicts a microwave energy interactive insulating structure 200 including a layer of microwave energy interactive material 205 supported on a first polymer film 210 to form a susceptor film 215. A support layer 220 is joined to the layer of
It is contemplated that, for some heating applications, the amount of water vapor provided by the support layer may be insufficient to provide the desired degree of void formation. In such applications, it may be beneficial to include an additional source of water vapor with the structure, for example, an additional paper or paper-based layer.
Alternatively or additionally, one or more reagents may be used to generate a gas to promote formation of voids. Numerous examples of reagents that may be suitable for use with the present structure are provided in U.S. Patent Application Publication No. 2006/0289521A1, published on Dec. 28, 2006,. In one example, the reagents may comprise sodium bicarbonate (NaHCO3) and a suitable acid. When exposed to heat, the reagents react to produce carbon dioxide. As another example, the reagent may comprise a blowing agent. Examples of blowing agents that may be suitable include, but are not limited to, p-p'-oxybis(benzenesulphonylhydrazide), azodicarbonamide, and p-toluenesulfonylsemicarbazide. In another example, the reagent may comprise a hydrated mineral that releases water in response to heat.
However, numerous other reagents and released gases may be used.
By way of example, FIG. 2 schematically depicts a microwave energy interactive insulating structure 200 including a layer of microwave energy interactive material 205 supported on a first polymer film 210 to form a susceptor film 215. A support layer 220 is joined to the layer of
9 microwave energy interactive material 205 using a layer of adhesive or other suitable material 225. One or more reagents 230, optionally within a carrier or coating, overlie at least a portion of the support layer 220. A
second polymer film 235 is joined releasably to the reagent layer 230 using a substantially continuous tie layer of adhesive, polymer, or other suitable thermoplastic material 240. After sufficient exposure to microwave energy, water vapor or other gases are released from or generated by the support layer 220 and the reagent layer 230. This expansion may occur within 1 to 15 seconds in an energized microwave oven, and in some instances, may occur within 2 to 10 seconds. The resulting gas applies pressure on the second polymer film 235 to form a plurality of insulating voids 245.
In another example (not shown), the support layer 220 may be omitted. Even without a paper or paperboard layer, the water vapor or other gas provided by the reagent may be sufficient both to form the insulating voids and to absorb any excess heat from the microwave energy interactive material. In still another example (not shown), the reagent layer 203 may lie between the layer of microwave energy interactive material 205 and the support layer 220. Numerous other examples are encompassed hereby.
If desired, multiple layers or sheets of insulating structures may be used to provide enhanced thermal insulation and, therefore, enhanced browning and/or crisping. The various sheets of similar and/or dissimilar insulating structures may be superposed in any configuration as needed or desired for a particular application. For example, the sheets may be arranged so that their respective susceptor film layers are facing away from each other, towards each other, or in any other manner. The sheets may remain separate or may be joined using any suitable process or technique, for example, thermal bonding, adhesive bonding, ultrasonic bonding or welding, mechanical fastening, or any combination thereof. If the greatest degree of wrinkling or deforming is desirable, it might be beneficial to use a discontinuous, patterned adhesive bond that will not restrict the expansion and flexing of the layers within each structure. In contrast, where structural stability is desirable, a continuous adhesive bond between sheets might provide the desired result.
Typically, the susceptor film serves as a food-contacting side or surface, while the polymer film adjacent to the tie layer serves as an outer surface of a package or other construct formed. In some instances, it may be desirable to print advertising, product information, heating instructions, or other indicia on the outer side of a package. Thus, if desired, the outer side or surface of the polymer film adjacent to the tie layer may be printed with such information (generally referred to as "printed matter"). Alternatively, the opposite side of the polymer film (i.e., the inner side or surface facing the support layer) may be reverse printed prior to being joined to the support layer. This advantageously provides optimal print clarity that cannot typically be achieved by printing directly onto the support, particularly when the support layer is formed from paper or any other material that commonly is prone to ink bleeding.
Any of the various layers of the structures and constructs encompassed by the invention may be formed from various materials, provided that the materials are substantially resistant to softening, scorching, combusting, or degrading at typical microwave oven heating temperatures, for example, at from about 250 F to about 425 F. The particular materials used may include microwave energy interactive materials, for example, those used to form susceptors and other microwave energy interactive elements, and microwave energy transparent or inactive materials, for example, those used to form the polymer film layers and support layer.
The microwave energy interactive material may be an electroconductive or semiconductive material, for example, a metal or a metal alloy provided as a metal foil; a vacuum deposited metal or metal alloy; or a metallic ink, an organic ink, an inorganic ink, a metallic paste, an organic paste, an inorganic paste, or any combination thereof.
Examples of metals and metal alloys that may be suitable for use with the present invention include, but are not limited to, aluminum, chromium, copper, inconel alloys (nickel-chromium-molybdenum alloy with niobium), iron, magnesium, nickel, stainless steel, tin, titanium, tungsten, and any combination or alloy thereof.
Alternatively, the microwave energy interactive material may comprise a metal oxide. Examples of metal oxides that may be suitable for use with the present invention include, but are not limited to, oxides of aluminum, iron, and tin, used in conjunction with an electrically conductive material where needed. Another example of a metal oxide that may be suitable for use with the present invention is indium tin oxide (ITO). ITO can be used as a microwave energy interactive material to provide a heating effect, a shielding effect, a browning and/or crisping effect, or a combination thereof. For example, to form a susceptor, ITO
may be sputtered onto a clear polymer film. The sputtering process typically occurs at a lower temperature than the evaporative deposition process used for metal deposition. ITO has a more uniform crystal structure and, therefore, is clear at most coating thicknesses. Additionally, ITO can be used for either heating or field management effects. ITO also may have fewer defects than metals, thereby making thick coatings of , % CA 02621723 2008-02-15 , .
ITO more suitable for field management than thick coatings of metals, such as aluminum.
Alternatively, the microwave energy interactive material may comprise a suitable electroconductive, semiconductive, or non-conductive artificial dielectric or ferroelectric.
Artificial dielectrics comprise conductive, subdivided material in a polymer or other suitable matrix or binder, and may include flakes of an electroconductive metal, for example, aluminum.
The substrate typically comprises an electrical insulator, for example, a polymer film or other polymeric material. As used herein the terms "polymer", "polymer film", and "polymeric material" include, but are not limited to, homopolymers, copolymers, such as for example, block, graft, random, and alternating copolymers, terpolymers, etc. and blends and modifications thereof.
Furthermore, unless otherwise specifically limited, the term "polymer" shall include all possible geometrical configurations of the molecule. These configurations include, but are not limited to isotactic, syndiotactic, and random symmetries.
The thickness of the film typically may be from about 35 gauge to about 10 mil. In one aspect, the thickness of the film is from about 40 to about 80 gauge. In another aspect, the thickness of the film is from about 45 to about 50 gauge. In still another aspect, the thickness of the film is about 48 gauge. Examples of polymer films that may be suitable include, but are not limited to, polyolefins, polyesters, polyamides, polyimides, polysulfones, polyether ketones, cellophanes, or any combination thereof.
Other non-conducting substrate materials such as paper and paper laminates, metal oxides, silicates, cellulosics, or any combination thereof, also may be used.
In one example, the polymer film comprises polyethylene terephthalate (PET). Polyethylene terephthalate films are used in commercially available susceptors, for example, the QWIKWAVE Focus susceptor and the MICRORITE susceptor, both available from Graphic Packaging International (Marietta, Georgia). Examples of polyethylene terephthalate films that may be suitable for use as the substrate include, but are not limited to, MELINEX , commercially available from DuPont Teijan Films (Hopewell, Virginia), SKYROL, commercially available from SKC, Inc. (Covington, Georgia), BARRIALOX PET, available from bray Films (Front Royal, VA), and QU50 High Barrier Coated PET, available from bray Films (Front Royal, VA).
The polymer film may be selected to impart various properties to the microwave interactive web, for example, printability, heat resistance, or any other property. As one particular example, the polymer film may be selected to provide a water barrier, oxygen barrier, or a combination thereof. Such barrier film layers may be formed from a polymer film having barrier properties or from any other barrier layer or coating as desired. Suitable polymer films may include, but are not limited to, ethylene vinyl alcohol, barrier nylon, polyvinylidene chloride, barrier fluoropolymer, nylon 6, nylon 6,6, coextruded nylon 6/EVOH/nylon 6, silicon oxide coated film, barrier polyethylene terephthalate, or any combination thereof.
One example of a barrier film that may be suitable for use with the present invention is CAPRAN EMBLEM 1200M nylon 6, commercially available from Honeywell International (Pottsville, Pennsylvania). Another example of a barrier film that may be suitable is CAPRAN OXYSHIELD OBS
monoaxially oriented coextruded nylon 6/ethylene vinyl alcohol (EVOH)/nylon 6, also commercially available from Honeywell International.
Yet another example of a barrier film that may be suitable for use with the present invention is DARTEK N-201 nylon 6,6, commercially available from Enhance Packaging Technologies (Webster, New York). Additional examples include BARRIALOX PET, available from Toray Films (Front Royal, VA) and QU50 High Barrier Coated PET, available from bray Films (Front Royal, VA), referred to above.
Still other barrier films include silicon oxide coated films, such as those available from Sheldahl Films (Northfield, Minnesota). Thus, in one example, a susceptor may have a structure including a film, for example, polyethylene terephthalate, with a layer of silicon oxide coated onto the film, and ITO or other material deposited over the silicon oxide. If needed or desired, additional layers or coatings may be provided to shield the individual layers from damage during processing.
The barrier film may have an oxygen transmission rate (OTR) as measured using ASTM D3985 of less than about 20 cc/m2/day. In each of various particular examples, the barrier film may have an OTR of less than about 10 cc/m2/day, less than about 1 cc/m2/day, less than about 0.5 cc/m2/day, less than about 0.1 cc/m2/day, or any other suitable OTR or range of OTR's.
The barrier film may have a water vapor transmission rate (WVTR) of less than about 100 g/m2/day as measured using ASTM F1249. In each of various particular examples, the barrier film may have a WVTR of less than about 50 g/m2/clay, less than about 15 g/m2/day, less than about 1 g/m2/day, less than about 0.1 g/m2/day, less than about 0.05 g/m2/day, or any other suitable WVTR or range of WVTR's.
Other non-conducting substrate materials such as metal oxides, silicates, cellulosics, or any combination thereof, also may be used in accordance with the present invention.
Likewise, the second polymer film may be any suitable polymer film including, but not limited to, those described above. In one example, the second polymer film layer comprises polyethylene terephthalate. The second polymer film layer may have any suitable thickness, and in each of various examples, the second polymer film layer may have a thickness of from about 20 to about 70 gauge, from about 30 to about 60 gauge, from about 40 to about 50 gauge, from about 45 to about 55 gauge, or about 48 gauge. In one particular example, the second polymer film layer comprises polyethylene terephthalate having a thickness of about 48 gauge.
The microwave energy interactive material may be applied to the substrate in any suitable manner, and in some instances, the microwave energy interactive material is printed on, extruded onto, sputtered onto, evaporated on, or laminated to the substrate. The microwave energy interactive material may be applied to the substrate in any pattern, and using any technique, to achieve the desired heating effect of the food item. For example, the microwave energy interactive material may be provided as a continuous or discontinuous layer or coating including circles, loops, hexagons, islands, squares, rectangles, octagons, and so forth. Examples of various patterns and methods that may be suitable for use with the present invention are provided in U.S. Patent Nos. 6,765,182;
6,717,121; 6,677,563; 6,552,315; 6,455,827; 6,433,322; 6,410,290; 6,251,451;
6,204,492; 6,150,646; 6,114,679; 5,800,724; 5,759,418; 5,672,407; 5,628,921;
5,519,195; 5,420,517; 5,410,135; 5,354,973; 5,340,436; 5,266,386; 5,260,537;
5221,419; 5,213,902; 5,117,078; 5,039,364; 4,963,420; 4,936,935; 4,890,439;
4,775,771; 4,865,921; and Re. 34,683. Although particular examples of patterns of microwave energy interactive material are shown and described herein, it should be understood that other patterns of microwave energy interactive material are contemplated by the present invention.
The support layer typically may comprise any suitable moisture-containing layer. In some instances, the support layer is a dimensionally stable layer. However, where a reagent layer is used in conjunction with the support layer, the support layer may comprise any material, for example, a polymer film. In one example, the support layer comprises a paper or paper-based material generally having a basis weight of from about 15 to about 60 lbs/ream (lb/300 sq. ft.), for example, from about 20 to about 40 lbs/ream. In one particular example, the paper has a basis weight of about 25 lbs/ream.
The tie layer may comprise any suitable thermoplastic material that is capable of joining, bonding, or adhering two layers together. As used herein, the term "thermoplastic" refers to any polymeric or non-polymeric material that is capable of becoming soft and/or pliable when heated, without a substantial change of the inherent properties of the material. In some examples, the tie layer may comprise a thermoplastic polymer based on, for example, a polyolefin, a polyamide, a polyester; a thermoplastic elastomer; any combination or copolymer of such materials; or any other suitable material. In some particular examples, the tie layer may comprise polypropylene, polyethylene, low density polyethylene, or any combination or copolymer thereof.
The tie layer generally may have a softening temperature that is less than about 425 F. In each of various examples, one or more components of the tie layer may have a softening point of from about 75 F to about 100 F, from about 100 F to about 125 F, from about 125 F to about 150 F, from about 150 F to about 175 F, from about 175 F to about 200 F, from about 200 F to about 250 F, from about 250 F to about 275 F, from about 275 F to about 300 F, from about 300 F to about 325 F, from about 325 F
to about 350 F, from about 350 F to about 375 F, from about 375 F to about 400 F, from about 400 F to about 425 F, from about 100 F to about 400 F, from about 150 F to about 350 F, from about 200 F to about 300 F, or any other suitable range or combination of ranges of temperatures.
The tie layer may have any suitable basis weight and may be formed in any suitable manner. In one example, the tie layer has a basis weight or dry coat weight of from about 3 to about 18 lb/ream. In another example, the tie layer has a dry coat weight of from about 5 to about 15 lb/ream. In another example, the tie layer has a dry coat weight of from about 8 to about 12 lb/ream. However, other basis weights or dry coat weights are contemplated by the invention.
The particular process used to form the tie layer may vary depending on the particular application. Examples of processes that may be used include, but are not limited to, spraying, roll coating, extrusion lamination, or any other process.
If desired, one or more pigments or opacifying agents (generally referred to herein as "colorants") may be added to the tie layer to alter or enhance the appearance of the resulting structure. For example, one or more colorants may be added to the tie layer to mask the often grey appearance of the microwave energy interactive material that may be visible through the other side of the support layer. Examples of colorants that may be suitable for use in this manner include titanium dioxide (Ti02), carbon black, or any combination thereof.
The colorant may be added in any amount needed or desired for a particular application, generally from about 1 wt % to about 15 wt % of the tie layer. In each of various examples, the colorant may be added in an amount of from about 1 to about 5 wt %, from about 3 to about 7 wt %, from about 5 to about 10 wt %, from about 7 to about 12 wt %, or from about 10 to about 15 wt %. In each of various other examples, the colorant may be added in an amount of from about 1 to about 1.5 wt %, from about 1.5 to about 2 wt %, from about 2 to about 2.5 wt %, from about 2.5 to about 3 wt %, from about 3 to about 3.5 wt %, from about 3.5 to about 4 wt %, from about 4 to about 4.5 wt %, from about 4.5 to about 5 wt %, from about 5 to about 5.5 wt %, from about 5.5 to about 6 wt %, from about 6 to about 6.5 wt %, from about 6.5 to about 7 wt %, from about 7 to about 7.5 wt %, from about 7.5 to about 8 wt %, from about 8 to about 8.5 wt %, from about 8.5 to about 9 wt %, from about 9 to about 9.5 wt %, from about 9.5 to about 10 wt %, from about 10 to about 10.5 wt %, from about 10.5 to about 11 wt %, from about 11 to about 11.5 wt %, from about 11.5 to about 12 wt %, from about 12 to about 12.5 wt %, from about 12.5 to about 13 wt %, from about 13 to about 13.5 wt %, from about 13.5 to about 14 wt %, from about 14 to about 14.5 wt %, from about 14.5 to about 15 wt %, or any other suitable amount.
Various aspects of the invention may be illustrated further by way of the following examples, which are not to be construed as limiting in any manner.
Printed 48 gauge polyethylene terephthalate (PET) film was laminated to MICROFLEX Q susceptor material (described above) using BR-3482 water based adhesive applied (commercially available from Royal Adhesives, LLC) with a No. 8 Meyer rod. The laminated materials were allowed to dry at ambient conditions for about 24 hours. After drying, some of the samples were cut into 1" strips to evaluate the bond quality using a Dixie adhesion tester. The results are presented in Table 1.
Table 1 Ex. Printed PET Bond strength Printing/adhesion quality (g/in.) 1 Solid green 350-400 Poor; almost complete transfer of the backed by ink from the PET to the MICROFLEX Q
white susceptor material 2 Blue vignette 450-500 Very good; no ink transfer from PET to backed by the MICROFLEX Q susceptor material white 3 Process 500-800 Good; slight ink transfer to the pictorial MICROFLEX Q susceptor material backed by white 4 White only 100-125 Fair; some ink transfer to the MICROFLEX Q susceptor material Various samples then were evaluated for performance in a microwave oven. Each laminate was cut into a sample about 100 mm by 100 mm in size. The corners of each sample were taped to a piece of board stock to prevent the sample from folding over on itself in the microwave. Each sample was heated for 10 seconds in a 1000W
microwave oven with a 700m1 competing water load. The samples were visually judged for performance. As expected, each sample exhibited varying degrees of delamination and insulating void formation.
A 48 gauge metallized PET susceptor film was coated with a moisture-releasing reagent coating using two roll coating stations, as set forth in Table 2. Samples were prepared at 250 feet per minute (fpm) and 200 fpm.
t CA 02621723 2008-02-15 . .
Table 2 Coating station 1 Coating station 2 Approx. capacity (gal) 65 68 Basis 3 barrels, 300 lb 1.5 barrels, 150 lb MgHPhosphate MgHPhosphate hydrate hydrate _ Water 100 lbs (12 gal) 150 lbs (18 gal) Airflex 460 Adhesive 335 lbs (40 gal) 355 lbs (43 gal (Air Products) Mg H PO4*3H20 300 lbs (2.5 100 lb 150 lbs (2 100 lb (Jost Chemical) barrels) barrels) Hydrad C hydrated -0- 100 lbs (2 bags alumina filler (J.M. @50 lb) Huber) Michemlube 160 wax -0-12 lbs (1.5 gal) (Michelaman, Inc.) The resulting material was laminated to 20 lb/ream bleached Kraft paper using a solventless coater and a two part urethane adhesive. The paper side of the resulting structure was then laminated to a reverse printed 48 gauge PET film (printed with laminating inks) using a tie layer coating of 7 lbs/ream of a blend of 85% low density polyethylene and 15%
polypropylene.
Various properties of the resulting samples were measured. The results are presented in Table 3.
Table 3 Sample 1 Sample 2 Coating speed (fpm) 200 Reagent layer coat weight (113/ream) 14.7 13.1 % Moisture release in microwave oven after 6.65 7.77 3 sec % Shrinkage in microwave oven after 3 sec 78 Additionally, each sample was used to heat Healthy Choice tomato basil Panini sandwiches, raw pastry dough, and Hot Pockets pastry sandwiches in a household microwave oven. In each example, the experimental insulating structure achieved a greater degree of browning and/or crisping than a plain susceptor paper.
All directional references (e.g., upper, lower, upward, downward, left, right, leftward, rightward, top, bottom, above, below, vertical, horizontal, clockwise, and counterclockwise) are used only for identification purposes to aid the reader's understanding of the various embodiments of the present invention, and do not create limitations, particularly as to the position, orientation. Joinder references (e.g., joined, attached, coupled, connected, and the like) are to be construed broadly and may include intermediate members between a connection of elements and relative movement between elements. As such, joinder references do not necessarily imply that two elements are connected directly and in fixed relation to each other.
The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole.
second polymer film 235 is joined releasably to the reagent layer 230 using a substantially continuous tie layer of adhesive, polymer, or other suitable thermoplastic material 240. After sufficient exposure to microwave energy, water vapor or other gases are released from or generated by the support layer 220 and the reagent layer 230. This expansion may occur within 1 to 15 seconds in an energized microwave oven, and in some instances, may occur within 2 to 10 seconds. The resulting gas applies pressure on the second polymer film 235 to form a plurality of insulating voids 245.
In another example (not shown), the support layer 220 may be omitted. Even without a paper or paperboard layer, the water vapor or other gas provided by the reagent may be sufficient both to form the insulating voids and to absorb any excess heat from the microwave energy interactive material. In still another example (not shown), the reagent layer 203 may lie between the layer of microwave energy interactive material 205 and the support layer 220. Numerous other examples are encompassed hereby.
If desired, multiple layers or sheets of insulating structures may be used to provide enhanced thermal insulation and, therefore, enhanced browning and/or crisping. The various sheets of similar and/or dissimilar insulating structures may be superposed in any configuration as needed or desired for a particular application. For example, the sheets may be arranged so that their respective susceptor film layers are facing away from each other, towards each other, or in any other manner. The sheets may remain separate or may be joined using any suitable process or technique, for example, thermal bonding, adhesive bonding, ultrasonic bonding or welding, mechanical fastening, or any combination thereof. If the greatest degree of wrinkling or deforming is desirable, it might be beneficial to use a discontinuous, patterned adhesive bond that will not restrict the expansion and flexing of the layers within each structure. In contrast, where structural stability is desirable, a continuous adhesive bond between sheets might provide the desired result.
Typically, the susceptor film serves as a food-contacting side or surface, while the polymer film adjacent to the tie layer serves as an outer surface of a package or other construct formed. In some instances, it may be desirable to print advertising, product information, heating instructions, or other indicia on the outer side of a package. Thus, if desired, the outer side or surface of the polymer film adjacent to the tie layer may be printed with such information (generally referred to as "printed matter"). Alternatively, the opposite side of the polymer film (i.e., the inner side or surface facing the support layer) may be reverse printed prior to being joined to the support layer. This advantageously provides optimal print clarity that cannot typically be achieved by printing directly onto the support, particularly when the support layer is formed from paper or any other material that commonly is prone to ink bleeding.
Any of the various layers of the structures and constructs encompassed by the invention may be formed from various materials, provided that the materials are substantially resistant to softening, scorching, combusting, or degrading at typical microwave oven heating temperatures, for example, at from about 250 F to about 425 F. The particular materials used may include microwave energy interactive materials, for example, those used to form susceptors and other microwave energy interactive elements, and microwave energy transparent or inactive materials, for example, those used to form the polymer film layers and support layer.
The microwave energy interactive material may be an electroconductive or semiconductive material, for example, a metal or a metal alloy provided as a metal foil; a vacuum deposited metal or metal alloy; or a metallic ink, an organic ink, an inorganic ink, a metallic paste, an organic paste, an inorganic paste, or any combination thereof.
Examples of metals and metal alloys that may be suitable for use with the present invention include, but are not limited to, aluminum, chromium, copper, inconel alloys (nickel-chromium-molybdenum alloy with niobium), iron, magnesium, nickel, stainless steel, tin, titanium, tungsten, and any combination or alloy thereof.
Alternatively, the microwave energy interactive material may comprise a metal oxide. Examples of metal oxides that may be suitable for use with the present invention include, but are not limited to, oxides of aluminum, iron, and tin, used in conjunction with an electrically conductive material where needed. Another example of a metal oxide that may be suitable for use with the present invention is indium tin oxide (ITO). ITO can be used as a microwave energy interactive material to provide a heating effect, a shielding effect, a browning and/or crisping effect, or a combination thereof. For example, to form a susceptor, ITO
may be sputtered onto a clear polymer film. The sputtering process typically occurs at a lower temperature than the evaporative deposition process used for metal deposition. ITO has a more uniform crystal structure and, therefore, is clear at most coating thicknesses. Additionally, ITO can be used for either heating or field management effects. ITO also may have fewer defects than metals, thereby making thick coatings of , % CA 02621723 2008-02-15 , .
ITO more suitable for field management than thick coatings of metals, such as aluminum.
Alternatively, the microwave energy interactive material may comprise a suitable electroconductive, semiconductive, or non-conductive artificial dielectric or ferroelectric.
Artificial dielectrics comprise conductive, subdivided material in a polymer or other suitable matrix or binder, and may include flakes of an electroconductive metal, for example, aluminum.
The substrate typically comprises an electrical insulator, for example, a polymer film or other polymeric material. As used herein the terms "polymer", "polymer film", and "polymeric material" include, but are not limited to, homopolymers, copolymers, such as for example, block, graft, random, and alternating copolymers, terpolymers, etc. and blends and modifications thereof.
Furthermore, unless otherwise specifically limited, the term "polymer" shall include all possible geometrical configurations of the molecule. These configurations include, but are not limited to isotactic, syndiotactic, and random symmetries.
The thickness of the film typically may be from about 35 gauge to about 10 mil. In one aspect, the thickness of the film is from about 40 to about 80 gauge. In another aspect, the thickness of the film is from about 45 to about 50 gauge. In still another aspect, the thickness of the film is about 48 gauge. Examples of polymer films that may be suitable include, but are not limited to, polyolefins, polyesters, polyamides, polyimides, polysulfones, polyether ketones, cellophanes, or any combination thereof.
Other non-conducting substrate materials such as paper and paper laminates, metal oxides, silicates, cellulosics, or any combination thereof, also may be used.
In one example, the polymer film comprises polyethylene terephthalate (PET). Polyethylene terephthalate films are used in commercially available susceptors, for example, the QWIKWAVE Focus susceptor and the MICRORITE susceptor, both available from Graphic Packaging International (Marietta, Georgia). Examples of polyethylene terephthalate films that may be suitable for use as the substrate include, but are not limited to, MELINEX , commercially available from DuPont Teijan Films (Hopewell, Virginia), SKYROL, commercially available from SKC, Inc. (Covington, Georgia), BARRIALOX PET, available from bray Films (Front Royal, VA), and QU50 High Barrier Coated PET, available from bray Films (Front Royal, VA).
The polymer film may be selected to impart various properties to the microwave interactive web, for example, printability, heat resistance, or any other property. As one particular example, the polymer film may be selected to provide a water barrier, oxygen barrier, or a combination thereof. Such barrier film layers may be formed from a polymer film having barrier properties or from any other barrier layer or coating as desired. Suitable polymer films may include, but are not limited to, ethylene vinyl alcohol, barrier nylon, polyvinylidene chloride, barrier fluoropolymer, nylon 6, nylon 6,6, coextruded nylon 6/EVOH/nylon 6, silicon oxide coated film, barrier polyethylene terephthalate, or any combination thereof.
One example of a barrier film that may be suitable for use with the present invention is CAPRAN EMBLEM 1200M nylon 6, commercially available from Honeywell International (Pottsville, Pennsylvania). Another example of a barrier film that may be suitable is CAPRAN OXYSHIELD OBS
monoaxially oriented coextruded nylon 6/ethylene vinyl alcohol (EVOH)/nylon 6, also commercially available from Honeywell International.
Yet another example of a barrier film that may be suitable for use with the present invention is DARTEK N-201 nylon 6,6, commercially available from Enhance Packaging Technologies (Webster, New York). Additional examples include BARRIALOX PET, available from Toray Films (Front Royal, VA) and QU50 High Barrier Coated PET, available from bray Films (Front Royal, VA), referred to above.
Still other barrier films include silicon oxide coated films, such as those available from Sheldahl Films (Northfield, Minnesota). Thus, in one example, a susceptor may have a structure including a film, for example, polyethylene terephthalate, with a layer of silicon oxide coated onto the film, and ITO or other material deposited over the silicon oxide. If needed or desired, additional layers or coatings may be provided to shield the individual layers from damage during processing.
The barrier film may have an oxygen transmission rate (OTR) as measured using ASTM D3985 of less than about 20 cc/m2/day. In each of various particular examples, the barrier film may have an OTR of less than about 10 cc/m2/day, less than about 1 cc/m2/day, less than about 0.5 cc/m2/day, less than about 0.1 cc/m2/day, or any other suitable OTR or range of OTR's.
The barrier film may have a water vapor transmission rate (WVTR) of less than about 100 g/m2/day as measured using ASTM F1249. In each of various particular examples, the barrier film may have a WVTR of less than about 50 g/m2/clay, less than about 15 g/m2/day, less than about 1 g/m2/day, less than about 0.1 g/m2/day, less than about 0.05 g/m2/day, or any other suitable WVTR or range of WVTR's.
Other non-conducting substrate materials such as metal oxides, silicates, cellulosics, or any combination thereof, also may be used in accordance with the present invention.
Likewise, the second polymer film may be any suitable polymer film including, but not limited to, those described above. In one example, the second polymer film layer comprises polyethylene terephthalate. The second polymer film layer may have any suitable thickness, and in each of various examples, the second polymer film layer may have a thickness of from about 20 to about 70 gauge, from about 30 to about 60 gauge, from about 40 to about 50 gauge, from about 45 to about 55 gauge, or about 48 gauge. In one particular example, the second polymer film layer comprises polyethylene terephthalate having a thickness of about 48 gauge.
The microwave energy interactive material may be applied to the substrate in any suitable manner, and in some instances, the microwave energy interactive material is printed on, extruded onto, sputtered onto, evaporated on, or laminated to the substrate. The microwave energy interactive material may be applied to the substrate in any pattern, and using any technique, to achieve the desired heating effect of the food item. For example, the microwave energy interactive material may be provided as a continuous or discontinuous layer or coating including circles, loops, hexagons, islands, squares, rectangles, octagons, and so forth. Examples of various patterns and methods that may be suitable for use with the present invention are provided in U.S. Patent Nos. 6,765,182;
6,717,121; 6,677,563; 6,552,315; 6,455,827; 6,433,322; 6,410,290; 6,251,451;
6,204,492; 6,150,646; 6,114,679; 5,800,724; 5,759,418; 5,672,407; 5,628,921;
5,519,195; 5,420,517; 5,410,135; 5,354,973; 5,340,436; 5,266,386; 5,260,537;
5221,419; 5,213,902; 5,117,078; 5,039,364; 4,963,420; 4,936,935; 4,890,439;
4,775,771; 4,865,921; and Re. 34,683. Although particular examples of patterns of microwave energy interactive material are shown and described herein, it should be understood that other patterns of microwave energy interactive material are contemplated by the present invention.
The support layer typically may comprise any suitable moisture-containing layer. In some instances, the support layer is a dimensionally stable layer. However, where a reagent layer is used in conjunction with the support layer, the support layer may comprise any material, for example, a polymer film. In one example, the support layer comprises a paper or paper-based material generally having a basis weight of from about 15 to about 60 lbs/ream (lb/300 sq. ft.), for example, from about 20 to about 40 lbs/ream. In one particular example, the paper has a basis weight of about 25 lbs/ream.
The tie layer may comprise any suitable thermoplastic material that is capable of joining, bonding, or adhering two layers together. As used herein, the term "thermoplastic" refers to any polymeric or non-polymeric material that is capable of becoming soft and/or pliable when heated, without a substantial change of the inherent properties of the material. In some examples, the tie layer may comprise a thermoplastic polymer based on, for example, a polyolefin, a polyamide, a polyester; a thermoplastic elastomer; any combination or copolymer of such materials; or any other suitable material. In some particular examples, the tie layer may comprise polypropylene, polyethylene, low density polyethylene, or any combination or copolymer thereof.
The tie layer generally may have a softening temperature that is less than about 425 F. In each of various examples, one or more components of the tie layer may have a softening point of from about 75 F to about 100 F, from about 100 F to about 125 F, from about 125 F to about 150 F, from about 150 F to about 175 F, from about 175 F to about 200 F, from about 200 F to about 250 F, from about 250 F to about 275 F, from about 275 F to about 300 F, from about 300 F to about 325 F, from about 325 F
to about 350 F, from about 350 F to about 375 F, from about 375 F to about 400 F, from about 400 F to about 425 F, from about 100 F to about 400 F, from about 150 F to about 350 F, from about 200 F to about 300 F, or any other suitable range or combination of ranges of temperatures.
The tie layer may have any suitable basis weight and may be formed in any suitable manner. In one example, the tie layer has a basis weight or dry coat weight of from about 3 to about 18 lb/ream. In another example, the tie layer has a dry coat weight of from about 5 to about 15 lb/ream. In another example, the tie layer has a dry coat weight of from about 8 to about 12 lb/ream. However, other basis weights or dry coat weights are contemplated by the invention.
The particular process used to form the tie layer may vary depending on the particular application. Examples of processes that may be used include, but are not limited to, spraying, roll coating, extrusion lamination, or any other process.
If desired, one or more pigments or opacifying agents (generally referred to herein as "colorants") may be added to the tie layer to alter or enhance the appearance of the resulting structure. For example, one or more colorants may be added to the tie layer to mask the often grey appearance of the microwave energy interactive material that may be visible through the other side of the support layer. Examples of colorants that may be suitable for use in this manner include titanium dioxide (Ti02), carbon black, or any combination thereof.
The colorant may be added in any amount needed or desired for a particular application, generally from about 1 wt % to about 15 wt % of the tie layer. In each of various examples, the colorant may be added in an amount of from about 1 to about 5 wt %, from about 3 to about 7 wt %, from about 5 to about 10 wt %, from about 7 to about 12 wt %, or from about 10 to about 15 wt %. In each of various other examples, the colorant may be added in an amount of from about 1 to about 1.5 wt %, from about 1.5 to about 2 wt %, from about 2 to about 2.5 wt %, from about 2.5 to about 3 wt %, from about 3 to about 3.5 wt %, from about 3.5 to about 4 wt %, from about 4 to about 4.5 wt %, from about 4.5 to about 5 wt %, from about 5 to about 5.5 wt %, from about 5.5 to about 6 wt %, from about 6 to about 6.5 wt %, from about 6.5 to about 7 wt %, from about 7 to about 7.5 wt %, from about 7.5 to about 8 wt %, from about 8 to about 8.5 wt %, from about 8.5 to about 9 wt %, from about 9 to about 9.5 wt %, from about 9.5 to about 10 wt %, from about 10 to about 10.5 wt %, from about 10.5 to about 11 wt %, from about 11 to about 11.5 wt %, from about 11.5 to about 12 wt %, from about 12 to about 12.5 wt %, from about 12.5 to about 13 wt %, from about 13 to about 13.5 wt %, from about 13.5 to about 14 wt %, from about 14 to about 14.5 wt %, from about 14.5 to about 15 wt %, or any other suitable amount.
Various aspects of the invention may be illustrated further by way of the following examples, which are not to be construed as limiting in any manner.
Printed 48 gauge polyethylene terephthalate (PET) film was laminated to MICROFLEX Q susceptor material (described above) using BR-3482 water based adhesive applied (commercially available from Royal Adhesives, LLC) with a No. 8 Meyer rod. The laminated materials were allowed to dry at ambient conditions for about 24 hours. After drying, some of the samples were cut into 1" strips to evaluate the bond quality using a Dixie adhesion tester. The results are presented in Table 1.
Table 1 Ex. Printed PET Bond strength Printing/adhesion quality (g/in.) 1 Solid green 350-400 Poor; almost complete transfer of the backed by ink from the PET to the MICROFLEX Q
white susceptor material 2 Blue vignette 450-500 Very good; no ink transfer from PET to backed by the MICROFLEX Q susceptor material white 3 Process 500-800 Good; slight ink transfer to the pictorial MICROFLEX Q susceptor material backed by white 4 White only 100-125 Fair; some ink transfer to the MICROFLEX Q susceptor material Various samples then were evaluated for performance in a microwave oven. Each laminate was cut into a sample about 100 mm by 100 mm in size. The corners of each sample were taped to a piece of board stock to prevent the sample from folding over on itself in the microwave. Each sample was heated for 10 seconds in a 1000W
microwave oven with a 700m1 competing water load. The samples were visually judged for performance. As expected, each sample exhibited varying degrees of delamination and insulating void formation.
A 48 gauge metallized PET susceptor film was coated with a moisture-releasing reagent coating using two roll coating stations, as set forth in Table 2. Samples were prepared at 250 feet per minute (fpm) and 200 fpm.
t CA 02621723 2008-02-15 . .
Table 2 Coating station 1 Coating station 2 Approx. capacity (gal) 65 68 Basis 3 barrels, 300 lb 1.5 barrels, 150 lb MgHPhosphate MgHPhosphate hydrate hydrate _ Water 100 lbs (12 gal) 150 lbs (18 gal) Airflex 460 Adhesive 335 lbs (40 gal) 355 lbs (43 gal (Air Products) Mg H PO4*3H20 300 lbs (2.5 100 lb 150 lbs (2 100 lb (Jost Chemical) barrels) barrels) Hydrad C hydrated -0- 100 lbs (2 bags alumina filler (J.M. @50 lb) Huber) Michemlube 160 wax -0-12 lbs (1.5 gal) (Michelaman, Inc.) The resulting material was laminated to 20 lb/ream bleached Kraft paper using a solventless coater and a two part urethane adhesive. The paper side of the resulting structure was then laminated to a reverse printed 48 gauge PET film (printed with laminating inks) using a tie layer coating of 7 lbs/ream of a blend of 85% low density polyethylene and 15%
polypropylene.
Various properties of the resulting samples were measured. The results are presented in Table 3.
Table 3 Sample 1 Sample 2 Coating speed (fpm) 200 Reagent layer coat weight (113/ream) 14.7 13.1 % Moisture release in microwave oven after 6.65 7.77 3 sec % Shrinkage in microwave oven after 3 sec 78 Additionally, each sample was used to heat Healthy Choice tomato basil Panini sandwiches, raw pastry dough, and Hot Pockets pastry sandwiches in a household microwave oven. In each example, the experimental insulating structure achieved a greater degree of browning and/or crisping than a plain susceptor paper.
All directional references (e.g., upper, lower, upward, downward, left, right, leftward, rightward, top, bottom, above, below, vertical, horizontal, clockwise, and counterclockwise) are used only for identification purposes to aid the reader's understanding of the various embodiments of the present invention, and do not create limitations, particularly as to the position, orientation. Joinder references (e.g., joined, attached, coupled, connected, and the like) are to be construed broadly and may include intermediate members between a connection of elements and relative movement between elements. As such, joinder references do not necessarily imply that two elements are connected directly and in fixed relation to each other.
The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole.
Claims (44)
1. A microwave energy interactive structure comprising:
a support layer having a first side and a second side opposite one another;
a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a substantially continuous tie layer, wherein the tie layer comprises a thermoplastic material, and a void forms within the tie layer in response to microwave energy.
a support layer having a first side and a second side opposite one another;
a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a substantially continuous tie layer, wherein the tie layer comprises a thermoplastic material, and a void forms within the tie layer in response to microwave energy.
2. The structure of claim 1, wherein the susceptor film remains joined to the first side of the support layer when the void is formed in the tie layer.
3. The structure of claim 1 or 2, wherein the void is a thermal insulating void.
4. The structure of claim 3, wherein the thermal insulating void is a first thermal insulating void of a plurality of thermal insulating voids formed within the tie layer.
5. The structure of any one of claims 1 to 4, wherein the tie layer includes an area having a first bond strength, and an area having a second bond strength greater than the first bond strength, wherein the void forms proximate to the first area.
6. The structure of any one of claims 1 to 4, wherein the thermoplastic material has a softening temperature, and the tie layer comprises at least one other material that does not soften at the softening temperature of the thermoplastic material.
7. The structure of claim 6, wherein the thermoplastic material is a first thermoplastic material, and the other material is a second thermoplastic material having a softening temperature greater than the softening temperature of the first thermoplastic material, wherein the void forms proximate to the first thermoplastic material.
8. The structure of claim 6, wherein the other material is a thermoset material, and the void forms proximate to the thermoplastic material.
9. The structure of any one of claims 1 to 4, wherein the thermoplastic material has an affinity for each of the support layer and the second polymer film, and the tie layer comprises at least one other material that has an affinity for at least one of the support layer and the second polymer film that differs from the respective affinity of the thermoplastic material.
10. The structure of any one of claims 1 to 9, wherein the thermoplastic material comprises a polymer.
11. The structure of claim 10, wherein the polymer is selected from the group consisting of a polyolefin, a polyamide, a polyester, a thermoplastic elastomer, any copolymer thereof, and any combination thereof.
12. The structure of claim 10, wherein the polymer is selected from the group consisting of polypropylene, polyethylene, low density polyethylene, any copolymer thereof, and combination thereof.
13. The structure of any one of claims 1 to 12, wherein the tie layer further comprises a colorant in an amount of from about 1 wt % to about 15 wt % of the tie layer.
14. The structure of claim 13, wherein the colorant is selected from the group consisting of titanium dioxide, carbon black, and any combination thereof.
15. The structure of any one of claims 1 to 14, wherein the support layer is a moisture-providing layer.
16. The structure of claim 15, wherein the support layer comprises paper, paperboard, or any combination thereof.
17. The structure of any one of claims 1 to 16, further comprising a reagent layer including at least one reagent that generates a gas in response to heat.
18. The structure of claim 17, wherein the reagent layer is disposed between the support layer and the second polymer film.
19. The structure of claim 17, wherein the reagent layer is disposed between the layer of microwave energy interactive material and the support layer.
20. The structure of any one of claims 1 to 19, wherein the second polymer film includes a first side facing the support layer and a second side opposite the first side, and the first side of the second polymer film includes printed matter.
21. A method of making the structure of any one of claims 1 to 20, the method comprising:
joining the layer of microwave energy interactive material of the susceptor film to the first side of the support layer with the substantially continuous layer of adhesive; and joining the second polymer film to the second side of the support layer.
joining the layer of microwave energy interactive material of the susceptor film to the first side of the support layer with the substantially continuous layer of adhesive; and joining the second polymer film to the second side of the support layer.
22. The method of claim 21, wherein joining the second polymer film to the second side of the support layer comprises extruding the tie layer onto the second side of the support layer, and bringing the second side of the second polymer film into contact with the tie layer.
23. The method of claim 22, wherein the method further comprises passing the structure susceptor film, support layer, tie layer, and second polymer film through a patterned nip assembly to define an area having a first bond strength and an area having a second bond strength greater than the first bond strength, wherein the void forms proximate to the area having the first bond strength.
24. The method of claim 21, wherein joining the second polymer film to the second side of the support layer comprises forming the tie layer between the second polymer film and the second side of the support layer.
25. The method of claim 24, wherein the method further comprises passing the susceptor film, support layer, tie layer, and second polymer film through a patterned nip assembly to define an area having a first bond strength and an area having a second bond strength greater than the first bond strength, wherein the void forms proximate to the area having the first bond strength.
26. The method of any one of claims 21 to 25, wherein the second polymer film includes a first surface facing the support layer and a second surface opposite the first surface, and the method further comprises printing the first surface of the second polymer film before joining the second polymer film to the support layer.
27. A microwave energy interactive structure comprising:
a support layer having a first side and a second side opposite one another;
a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a tie layer, wherein the tie layer comprises a first polymer and a second polymer, and wherein a void forms within the tie layer proximate to the first polymer in response to microwave energy.
a support layer having a first side and a second side opposite one another;
a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer, the second polymer film being joined to the second side of the support layer by a tie layer, wherein the tie layer comprises a first polymer and a second polymer, and wherein a void forms within the tie layer proximate to the first polymer in response to microwave energy.
28. The structure of claim 27, wherein the first polymer and the second polymer each have a softening temperature, and the softening temperature of the first polymer is less than the softening temperature of the second polymer.
29. The structure of claim 27 or 28, wherein the first polymer is a thermoplastic polymer, and the second polymer is a thermoset polymer.
30. The structure of claim 27, wherein the first polymer and the second polymer each have an affinity for each of the support layer and the second polymer film, and the affinity of the first polymer for at least one of the support layer and the second polymer film differs from the respective affinity of the second polymer for the at least one of the support layer and the second polymer film.
31. The structure of any one of claims 28 to 30, wherein the susceptor film remains joined to the first side of the support layer when the void is formed within the tie layer.
32. The structure of any one of claims 27 to 31, wherein the void is a first void of a plurality of voids formed within the tie layer.
33. The structure of any one of claims 27 to 32, wherein the support layer comprises moisture.
34. The structure of any one of claims 27 to 33, wherein the support layer comprises at least one of paper, paperboard, or a polymer film.
35. A microwave energy interactive structure comprising:
a support layer having a first side and a second side opposite one another;
a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer by a substantially continuous tie layer, the second polymer film being joined to the second side of the support layer to define areas having a first bond strength and areas having a second bond strength greater than the first bond strength, wherein voids form within the tie layer proximate to the areas having the first bond strength in response to microwave energy.
a support layer having a first side and a second side opposite one another;
a susceptor film joined to the first side of the support layer, the susceptor film comprising a layer of microwave energy interactive material supported on a first polymer film, wherein the susceptor film is joined to the first side of the support layer so that the layer of microwave energy interactive material is positioned between the first polymer film and the first side of the support layer; and a second polymer film joined to the second side of the support layer by a substantially continuous tie layer, the second polymer film being joined to the second side of the support layer to define areas having a first bond strength and areas having a second bond strength greater than the first bond strength, wherein voids form within the tie layer proximate to the areas having the first bond strength in response to microwave energy.
36. The structure of claim 35, wherein the areas having the second bond strength are defined by applying pressure to the susceptor film, support layer, tie layer, and second polymer film.
37. The structure of claim 35 or 36, wherein the susceptor film remains joined to the first side of the support layer when the voids are formed in the tie layer.
38. The structure of any one of claims 35 to 37, wherein the support layer comprises moisture.
39. The structure of any one of claims 35 to 38, wherein the support layer comprises at least one of paper, paperboard, or a polymer film.
40. A method of making the structure of any one of claims 35 to 39, the method comprising:
joining the layer of microwave energy interactive material of the susceptor film to the first side of the support layer with the substantially continuous layer of adhesive; and joining the second polymer film to the second side of the support layer.
joining the layer of microwave energy interactive material of the susceptor film to the first side of the support layer with the substantially continuous layer of adhesive; and joining the second polymer film to the second side of the support layer.
41. The method of claim 40, wherein joining the second polymer film to the second side of the support layer comprises extruding the tie layer onto the second side of the support layer, and bringing the second side of the second polymer film into contact with the tie layer.
42. The method of claim 41, wherein the method further comprises passing the structure susceptor film, support layer, tie layer, and second polymer film through a patterned nip assembly to define the areas having the first bond strength and the areas having the second bond strength.
43. The method of claim 40, wherein joining the second polymer film to the second side of the support layer comprises forming the tie layer between the second polymer film and the second side of the support layer.
44. The method of claim 43, wherein the method further comprises passing the susceptor film, support layer, tie layer, and second polymer film through a patterned nip assembly to define the areas having the first bond strength and the areas having the second bond strength.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US89005607P | 2007-02-15 | 2007-02-15 | |
US60/890,056 | 2007-02-15 | ||
US90390407P | 2007-02-28 | 2007-02-28 | |
US60/903,904 | 2007-02-28 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2621723A1 CA2621723A1 (en) | 2008-08-15 |
CA2621723C true CA2621723C (en) | 2014-05-20 |
Family
ID=39687928
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2621723A Expired - Fee Related CA2621723C (en) | 2007-02-15 | 2008-02-15 | Microwave energy interactive insulating structure |
Country Status (2)
Country | Link |
---|---|
US (1) | US9073689B2 (en) |
CA (1) | CA2621723C (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2870030C (en) | 2002-02-08 | 2015-08-18 | Graphic Packaging International, Inc. | Insulating microwave interactive packaging |
CN1918044B (en) | 2004-02-09 | 2013-11-06 | 印刷包装国际公司 | Microwave cooking packages |
US9073689B2 (en) | 2007-02-15 | 2015-07-07 | Graphic Packaging International, Inc. | Microwave energy interactive insulating structure |
FR2942431B1 (en) * | 2009-02-20 | 2011-03-11 | Faurecia Sieges Automobile | VEHICLE SEAT, METHOD OF MANUFACTURING SUCH A VEHICLE SEAT AND MACHINE FOR CARRYING OUT THE MANUFACTURING METHOD. |
EP2398847A4 (en) * | 2009-02-23 | 2014-04-16 | Graphic Packaging Int Inc | Low crystallinity susceptor films |
US9284108B2 (en) | 2009-02-23 | 2016-03-15 | Graphic Packaging International, Inc. | Plasma treated susceptor films |
US20110011854A1 (en) * | 2009-02-23 | 2011-01-20 | Middleton Scott W | Low crystallinity susceptor films |
US20100213192A1 (en) * | 2009-02-23 | 2010-08-26 | Middleton Scott W | Plasma Treated Susceptor Films |
CA2894294C (en) * | 2009-07-30 | 2018-06-12 | Scott W. Middleton | Low crystallinity susceptor films |
US10251223B2 (en) * | 2015-05-20 | 2019-04-02 | Illinois Tool Works Inc. | Apparatus for providing customizable heat zones in an oven |
MX2018013418A (en) | 2016-06-03 | 2019-02-28 | Graphic Packaging Int Llc | Microwave packaging material. |
WO2020112034A2 (en) * | 2018-11-27 | 2020-06-04 | Scg Packaging Public Company Limited | Susceptor film structure for packaging used with microwave ovens and packaging comprising the said susceptor film structure |
Family Cites Families (174)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3098583A (en) * | 1961-08-28 | 1963-07-23 | Olin Mathieson | Carton lock |
US3439428A (en) * | 1964-11-20 | 1969-04-22 | Cooper Ind Inc | Plastic measuring tapes and methods of making such tapes |
US3595468A (en) * | 1969-06-06 | 1971-07-27 | Dow Chemical Co | Opening device |
US3601252A (en) | 1969-08-01 | 1971-08-24 | Kleer Vu Ind Inc | Burst pack |
US3967998A (en) * | 1972-08-18 | 1976-07-06 | E. I. Du Pont De Nemours And Company | Polyethylene terephthalate/paperboard laminate and method of making it, container blank formed from such laminate and container formed from such blank, and cooking method using such container |
US3973045A (en) | 1973-05-14 | 1976-08-03 | The Pillsbury Company | Popcorn package for microwave popping |
US4013798A (en) * | 1973-11-21 | 1977-03-22 | Teckton, Inc. | Selectively ventable food package and micro-wave shielding device |
US4132811A (en) * | 1974-05-30 | 1979-01-02 | The Pillsbury Company | Food package for assuring uniform distribution of microwave energy and process for heating food |
US4268738A (en) * | 1977-09-28 | 1981-05-19 | The Procter & Gamble Company | Microwave energy moderator |
US4267420A (en) * | 1978-05-30 | 1981-05-12 | General Mills, Inc. | Packaged food item and method for achieving microwave browning thereof |
US4196331A (en) * | 1978-07-17 | 1980-04-01 | The Procter & Gamble Company | Microwave energy cooking bag |
US4283427A (en) | 1978-12-19 | 1981-08-11 | The Pillsbury Company | Microwave heating package, method and susceptor composition |
US4220684A (en) | 1979-03-12 | 1980-09-02 | Mobil Oil Corporation | Coextruded laminar thermoplastic bags |
US4825025A (en) * | 1979-03-16 | 1989-04-25 | James River Corporation | Food receptacle for microwave cooking |
US4641005A (en) * | 1979-03-16 | 1987-02-03 | James River Corporation | Food receptacle for microwave cooking |
US4267955A (en) * | 1979-07-25 | 1981-05-19 | Diamond International Corporation | Quickly erected scoop-type carton and layout for cutting |
US4260060A (en) * | 1979-09-17 | 1981-04-07 | Champion International Corporation | Food carton for microwave heating |
US4286136A (en) | 1979-12-10 | 1981-08-25 | Mason Jr Stanley I | Cooking container for more efficient cooking in a microwave oven |
US4461031A (en) * | 1981-03-10 | 1984-07-17 | Bagcraft Corporation Of America | Tubular bag and method of making the same |
US4691374A (en) | 1983-08-11 | 1987-09-01 | Golden Valley Microwave Foods Inc. | Cooking bag with diagonal gusset seals |
US4571337A (en) * | 1984-05-10 | 1986-02-18 | Hunt-Wesson Foods, Inc. | Container and popcorn ingredient for microwave use |
US4574174A (en) * | 1984-05-21 | 1986-03-04 | Mcgonigle Thomas P | Convenience dinner container and method |
US4873101A (en) | 1985-09-26 | 1989-10-10 | Minnesota Mining And Manufacturing Company | Microwave food package and grease absorbent pad therefor |
US4848931A (en) * | 1985-11-20 | 1989-07-18 | Toyo Aluminium Kabushiki Kaisha | Packaging sheet and containers and pouches using the sheet |
JPH0532288Y2 (en) | 1986-04-07 | 1993-08-18 | ||
US4777053A (en) | 1986-06-02 | 1988-10-11 | General Mills, Inc. | Microwave heating package |
US4786513A (en) | 1986-12-05 | 1988-11-22 | Conagra, Inc. | Package for sliced bacon adapted for microwave cooking |
GB2207589A (en) | 1987-07-28 | 1989-02-01 | Mardon Son & Hall Limited | Microwave cooking |
US4745249A (en) * | 1987-02-19 | 1988-05-17 | Mrs. Paul's Kitchens Inc. | Package and method for microwave heating of a food product |
USRE34683E (en) | 1987-03-10 | 1994-08-02 | James River Corporation Of Virginia | Control of microwave interactive heating by patterned deactivation |
US4883936A (en) | 1988-09-01 | 1989-11-28 | James River Corporation | Control of microwave interactive heating by patterned deactivation |
US4865921A (en) | 1987-03-10 | 1989-09-12 | James Riker Corporation Of Virginia | Microwave interactive laminate |
US4968865A (en) | 1987-06-01 | 1990-11-06 | General Mills, Inc. | Ceramic gels with salt for microwave heating susceptor |
US5041295A (en) | 1987-07-06 | 1991-08-20 | The Pillsbury Company | Package for crisping the surface of food products in a microwave oven |
DE3861747D1 (en) * | 1987-07-11 | 1991-03-14 | Frisco Findus Ag | PACKAGING WITH LID FOR EDIBLE GOODS. |
US4775771A (en) | 1987-07-30 | 1988-10-04 | James River Corporation | Sleeve for crisping and browning of foods in a microwave oven and package and method utilizing same |
EP0302712B1 (en) | 1987-08-04 | 1996-11-13 | Asahi Kasei Kogyo Kabushiki Kaisha | Novel copolycarbonate |
AU609187B2 (en) | 1987-10-15 | 1991-04-26 | Minnesota Mining And Manufacturing Company | Microwave absorbing composite |
US5006684A (en) * | 1987-11-10 | 1991-04-09 | The Pillsbury Company | Apparatus for heating a food item in a microwave oven having heater regions in combination with a reflective lattice structure |
US4894247A (en) * | 1987-12-11 | 1990-01-16 | E. I. Du Pont De Nemours And Company | Fibrous microwave susceptor package |
US4933193A (en) * | 1987-12-11 | 1990-06-12 | E. I. Du Pont De Nemours And Company | Microwave cooking package |
US5084601A (en) * | 1988-03-15 | 1992-01-28 | Golden Valley Microwave Foods Inc. | Microwave receptive heating sheets and packages containing them |
US5177332A (en) * | 1988-04-29 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Microwave energy susceptible conformable laminate packaging materials |
CA1292934C (en) | 1988-05-20 | 1991-12-10 | Donald G. Beckett | Microwave heating material |
US4970360A (en) | 1988-11-04 | 1990-11-13 | The Pillsbury Company | Susceptor for heating foods in a microwave oven having metallized layer deposited on paper |
US5003142A (en) * | 1988-06-03 | 1991-03-26 | E. I. Du Pont De Nemours And Company | Easy opening microwave pouch |
US4911938A (en) * | 1988-08-22 | 1990-03-27 | E. I. Du Pont De Nemours And Company | Conformable wrap susceptor with releasable seal for microwave cooking |
US5410135A (en) * | 1988-09-01 | 1995-04-25 | James River Paper Company, Inc. | Self limiting microwave heaters |
US4943456A (en) * | 1988-09-01 | 1990-07-24 | James River Corporation Of Virginia | Microwave reactive heater |
US4851632A (en) * | 1988-09-16 | 1989-07-25 | E. I. Du Pont De Nemours And Company | Insulated frame package for microwave cooking |
US4890439A (en) * | 1988-11-09 | 1990-01-02 | James River Corporation | Flexible disposable material for forming a food container for microwave cooking |
US5239153A (en) | 1988-11-28 | 1993-08-24 | Beckett Industries Inc. | Differential thermal heating in microwave oven packages |
GB8827759D0 (en) | 1988-11-28 | 1988-12-29 | Beckett D E | Selective microwave heating material-ii |
US5519195A (en) * | 1989-02-09 | 1996-05-21 | Beckett Technologies Corp. | Methods and devices used in the microwave heating of foods and other materials |
US4914266A (en) * | 1989-03-22 | 1990-04-03 | Westvaco Corporation | Press applied susceptor for controlled microwave heating |
US4950859A (en) | 1989-03-27 | 1990-08-21 | Anderson Alan R | Bag for containing edibles during microwave cooking |
CA2011740A1 (en) * | 1989-04-07 | 1990-10-07 | Glen Connell | Microwave heatable materials |
US4959120A (en) | 1989-06-21 | 1990-09-25 | Golden Valley Microwave Foods, Inc. | Demetallization of metal films |
US4973810A (en) | 1989-07-03 | 1990-11-27 | General Mills, Inc. | Microwave method of popping popcorn and package therefor |
US5164562A (en) | 1989-08-02 | 1992-11-17 | Westvaco Corporation | Composite susceptor packaging material |
US4962293A (en) | 1989-09-18 | 1990-10-09 | Dunmore Corporation | Microwave susceptor film to control the temperature of cooking foods |
US5241150A (en) | 1989-10-02 | 1993-08-31 | Minnesota Mining And Manufacturing Company | Microwave food package |
CA2025130A1 (en) | 1989-10-02 | 1991-04-03 | Joseph F. Garvey | Microwave food package |
US5053594A (en) | 1989-11-09 | 1991-10-01 | Rich-Seapak Processing Corporation | Cook and serve food package for the storing and heating by microwave energy of a food item |
WO1991007861A1 (en) | 1989-11-22 | 1991-05-30 | General Mills, Inc. | Microwave bread article and method |
US4970358A (en) | 1989-12-22 | 1990-11-13 | Golden Valley Microwave Foods Inc. | Microwave susceptor with attenuator for heat control |
US5124519A (en) * | 1990-01-23 | 1992-06-23 | International Paper Company | Absorbent microwave susceptor composite and related method of manufacture |
CA2009207A1 (en) * | 1990-02-02 | 1991-08-02 | D. Gregory Beckett | Controlled heating of foodstuffs by microwave energy |
US5630959A (en) * | 1990-02-26 | 1997-05-20 | Vesture Corporation | Microwavable heating pad for warming food and method |
US5008024A (en) * | 1990-03-22 | 1991-04-16 | Golden Valley Microwave Foods Inc. | Microwave corn popping package |
US5180894A (en) * | 1990-06-19 | 1993-01-19 | International Paper Company | Tube from microwave susceptor package |
US5081330A (en) * | 1990-07-11 | 1992-01-14 | Golden Valley Microwave Foods Inc. | Package with microwave induced insulation chambers |
US5077455A (en) | 1990-08-13 | 1991-12-31 | The Stouffer Corporation | Easy open microwave susceptor sleeve for pizza and the like |
US5044777A (en) | 1990-10-26 | 1991-09-03 | Golden Valley Microwave Foods Inc. | Flat-faced package for improving the microwave popping of corn |
EP0558655A1 (en) | 1990-11-29 | 1993-09-08 | Minnesota Mining And Manufacturing Company | Microwave hot melt adhesive package and dispenser |
US5298708A (en) * | 1991-02-07 | 1994-03-29 | Minnesota Mining And Manufacturing Company | Microwave-active tape having a cured polyolefin pressure-sensitive adhesive layer |
CA2041062C (en) | 1991-02-14 | 2000-11-28 | D. Gregory Beckett | Demetallizing procedure |
US5266386A (en) | 1991-02-14 | 1993-11-30 | Beckett Industries Inc. | Demetallizing procedure |
US5628921A (en) * | 1991-02-14 | 1997-05-13 | Beckett Technologies Corp. | Demetallizing procedure |
US5221419A (en) * | 1991-02-19 | 1993-06-22 | Beckett Industries Inc. | Method for forming laminate for microwave oven package |
US5213902A (en) * | 1991-02-19 | 1993-05-25 | Beckett Industries Inc. | Microwave oven package |
US5157817A (en) * | 1991-03-13 | 1992-10-27 | Wilbert Inc. | Plastic lined concrete structure |
US5260536A (en) | 1991-05-01 | 1993-11-09 | Peery William W | Heat retaining napkin |
US5230914A (en) | 1991-05-02 | 1993-07-27 | Luigino's, Inc. | Metal foil food package for microwave cooking |
US5260537A (en) | 1991-06-17 | 1993-11-09 | Beckett Industries Inc. | Microwave heating structure |
US5294765A (en) * | 1991-06-26 | 1994-03-15 | Hunt-Wesson, Inc. | Perforated susceptor for microwave cooking |
US5340649A (en) | 1991-07-03 | 1994-08-23 | Minnesota Mining And Manufacturing | Microwaveable adhesive article and method of use |
US5256846A (en) | 1991-09-05 | 1993-10-26 | Advanced Dielectric Technologies, Inc. | Microwaveable barrier films |
US5217768A (en) * | 1991-09-05 | 1993-06-08 | Advanced Dielectric Technologies | Adhesiveless susceptor films and packaging structures |
US5405663A (en) * | 1991-11-12 | 1995-04-11 | Hunt-Wesson, Inc. | Microwave package laminate with extrusion bonded susceptor |
GB9201932D0 (en) | 1992-01-29 | 1992-03-18 | Beckett Ind Inc | Novel microwave heating structure |
US5317118A (en) * | 1992-02-05 | 1994-05-31 | Golden Valley Microwave Foods Inc. | Package with microwave induced insulation chambers |
US5189272A (en) * | 1992-02-06 | 1993-02-23 | General Mills, Inc. | Bag utilizing a microwave susceptor and non-heated flaps |
US5231268A (en) | 1992-03-04 | 1993-07-27 | Westvaco Corporation | Printed microwave susceptor |
US5357086A (en) | 1992-03-16 | 1994-10-18 | Golden Valley Microwave Foods Inc. | Microwave corn popping package |
US5389767A (en) * | 1993-01-11 | 1995-02-14 | Dobry; Reuven | Microwave susceptor elements and materials |
US5338921A (en) | 1993-02-16 | 1994-08-16 | Universal Packaging Corporation | Method of distributing heat in food containers adapted for microwave cooking and novel container structure |
US6090706A (en) | 1993-06-28 | 2000-07-18 | Applied Materials, Inc. | Preconditioning process for treating deposition chamber prior to deposition of tungsten silicide coating on active substrates therein |
US5424517A (en) * | 1993-10-27 | 1995-06-13 | James River Paper Company, Inc. | Microwave impedance matching film for microwave cooking |
US5932680A (en) | 1993-11-16 | 1999-08-03 | Henkel Kommanditgesellschaft Auf Aktien | Moisture-curing polyurethane hot-melt adhesive |
US5484984A (en) | 1994-03-04 | 1996-01-16 | Gics & Vermee, L.P. | Ovenable food package including a base with depending leg member and a plurality of raised portions and associated food packages |
PT797604E (en) | 1994-05-25 | 2000-05-31 | Henkel Kgaa | POLYURETHANE FUSING TAIL THAT STRESSES THROUGH HUMIDITY ACTION |
US5510132A (en) | 1994-06-07 | 1996-04-23 | Conagra, Inc. | Method for cooking a food item in microwave heating package having end flaps for elevating and venting the package |
US5514854A (en) * | 1994-08-23 | 1996-05-07 | Epic Associates, Ltd. | Gusseted microwave popcorn bag with susceptor |
US5565125A (en) | 1994-10-24 | 1996-10-15 | Westvaco Corporation | Printed microwave susceptor with improved thermal and migration protection |
US5489766A (en) * | 1994-10-24 | 1996-02-06 | Advanced Deposition Technologies, Inc. | Food bag for microwave cooking with fused susceptor |
US5773801A (en) * | 1995-02-15 | 1998-06-30 | Golden Valley Microwave Foods, Inc. | Microwave cooking construction for popping corn |
WO1997003893A1 (en) * | 1995-07-21 | 1997-02-06 | Pethick & Money Limited | Wrapper and method of its manufacture |
BR9610417A (en) | 1995-08-18 | 1999-12-21 | Pethick & Money Ltd | "improvements in or related to packaging for goods articles" |
DE69634455T2 (en) | 1995-09-18 | 2006-02-02 | Graphic Packaging International, Inc., Golden | Microwaveable container |
US5690853A (en) | 1995-09-27 | 1997-11-25 | Golden Valley Microwave Foods, Inc. | Treatments for microwave popcorn packaging and products |
US5753895A (en) | 1996-01-16 | 1998-05-19 | Golden Valley Microwave Foods, Inc. | Microwave popcorn package with adhesive pattern |
US5759422A (en) * | 1996-02-14 | 1998-06-02 | Fort James Corporation | Patterned metal foil laminate and method for making same |
US5800724A (en) | 1996-02-14 | 1998-09-01 | Fort James Corporation | Patterned metal foil laminate and method for making same |
WO1998008752A2 (en) | 1996-08-26 | 1998-03-05 | Fort James Corporation | Microwavable package |
EP0921992B1 (en) | 1996-08-26 | 2001-11-21 | Graphic Packaging Corporation | Microwavable container |
US5916470A (en) * | 1997-01-10 | 1999-06-29 | Aladdin Industries, Llc | Microwaveable heat retentive receptacle |
DE69819419T2 (en) | 1997-01-29 | 2004-10-07 | Graphic Packaging Corp | MICROWAVE OVEN WITH SEVERAL HEATING ELEMENTS ARRANGED IN A LOOP |
US5780824A (en) | 1997-02-07 | 1998-07-14 | Lulirama International, Inc. | Expandable and self-venting novelty container for cooking microwavable popcorn |
CA2251282C (en) | 1997-02-12 | 2002-06-25 | Fort James Corporation | Patterned microwave oven susceptor |
GB2331291A (en) | 1997-11-18 | 1999-05-19 | Rapid Action Packaging Ltd | Containers for foodstuffs |
US6414290B1 (en) | 1998-03-19 | 2002-07-02 | Graphic Packaging Corporation | Patterned microwave susceptor |
US6060096A (en) * | 1998-04-14 | 2000-05-09 | Conagra, Inc. | Microwaveable bag having stand-up, wide mouth, features; and, method |
GB2339756B (en) * | 1998-07-17 | 2002-07-17 | Pethick & Money Ltd | Improvements in or relating to food packages with attached wrapping material |
US6005234A (en) | 1998-07-30 | 1999-12-21 | Weaver Popcorn Company | Microwave popcorn bag with cross mitre arrangement |
US6137098A (en) | 1998-09-28 | 2000-10-24 | Weaver Popcorn Company, Inc. | Microwave popcorn bag with continuous susceptor arrangement |
US6488973B1 (en) * | 1998-10-05 | 2002-12-03 | Food Talk, Inc. | Method of making a cooking pouch containing a raw protein portion, a raw or blanched vegetable portion and a sauce |
US6414288B1 (en) | 1999-02-22 | 2002-07-02 | The Procter & Gamble Company | Microwave packaging kit for improved cooking performance |
US6303914B1 (en) | 1999-02-22 | 2001-10-16 | The Procter & Gamble Company | Microwave packaging with improved divider |
US6303913B1 (en) | 1999-02-22 | 2001-10-16 | The Procter & Gamble Company | Microwave packaging with improved orientation feature |
US6093920A (en) | 1999-07-28 | 2000-07-25 | Beckwith; Darla L. | Method of microwave heating of food |
US6436457B1 (en) | 1999-06-01 | 2002-08-20 | Mojocoffee Co. | Microwave coffee roasting devices |
EP1059245B1 (en) | 1999-06-11 | 2002-09-18 | Societe Des Produits Nestle S.A. | Container and method for heating rapidly and evenly frozen foods in microwave oven |
US6359272B1 (en) * | 1999-06-11 | 2002-03-19 | Schwan's Sales Enterprises, Inc. | Microwave package and support tray with features for uniform crust heating |
US6204492B1 (en) * | 1999-09-20 | 2001-03-20 | Graphic Packaging Corporation | Abuse-tolerant metallic packaging materials for microwave cooking |
US6433322B2 (en) * | 1999-09-20 | 2002-08-13 | Graphic Packaging Corporation | Abuse-tolerant metallic packaging materials for microwave cooking |
US6501059B1 (en) | 1999-09-27 | 2002-12-31 | Roy Lee Mast | Heavy-metal microwave formations and methods |
JP4467683B2 (en) | 1999-11-16 | 2010-05-26 | 大日本印刷株式会社 | Packaging container for microwave oven heating |
GB0023927D0 (en) * | 2000-09-29 | 2000-11-15 | Dupont Teijin Films Us Ltd | Multilayer polymeric film |
US7108911B2 (en) * | 2000-11-02 | 2006-09-19 | 3M Innovative Properties Company | Adhesive composition and adhesive sheet |
US20040130788A1 (en) | 2001-02-02 | 2004-07-08 | Kazuhiko Minami | Optical filter and filter for touch panel type display |
DE10138298A1 (en) | 2001-08-10 | 2003-02-27 | Basf Ag | Thermoplastic polyurethanes |
GB0121623D0 (en) * | 2001-09-07 | 2001-10-31 | Eatwell U K Ltd | Packaging |
US6717121B2 (en) * | 2001-09-28 | 2004-04-06 | Graphic Packaging International, Inc. | Patterned microwave susceptor element and microwave container incorporating same |
US6683289B2 (en) * | 2001-10-29 | 2004-01-27 | Mars Incorporated | Hand-held food package |
US6744028B2 (en) * | 2001-10-29 | 2004-06-01 | Mars Incorporated | Semi-rigid hand-held food package |
US6677563B2 (en) * | 2001-12-14 | 2004-01-13 | Graphic Packaging Corporation | Abuse-tolerant metallic pattern arrays for microwave packaging materials |
US7323669B2 (en) | 2002-02-08 | 2008-01-29 | Graphic Packaging International, Inc. | Microwave interactive flexible packaging |
CA2870030C (en) * | 2002-02-08 | 2015-08-18 | Graphic Packaging International, Inc. | Insulating microwave interactive packaging |
US20030206997A1 (en) | 2002-05-01 | 2003-11-06 | Schwan's Sales Enterprises, Inc. | Susceptor sleeve for food products |
US20040173607A1 (en) | 2003-01-03 | 2004-09-09 | Blankenbeckler Nicole L. | Article containing microwave susceptor material |
US20050267245A1 (en) | 2003-03-18 | 2005-12-01 | Sandusky Donald A | Alloy blends of polyurethane and rubber |
US7038182B2 (en) * | 2003-06-27 | 2006-05-02 | Robert C. Young | Microwave oven cooking process |
MY139350A (en) | 2003-09-26 | 2009-09-30 | Invista Tech Sarl | Alloy blends of polyurethane and latex rubber |
JP2007512187A (en) * | 2003-10-14 | 2007-05-17 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Multi-compartment package with temperature-dependent fragile seal |
CA2544652A1 (en) * | 2003-11-03 | 2005-05-19 | Steamway Franchise Sales, Inc. | Microwave cooking container with separate compartments for crisping and steaming |
ATE415360T1 (en) * | 2004-01-08 | 2008-12-15 | Food Talk Inc | FLEXIBLE MICROWAVE COOKING BAG CONTAINING A RAW FROZEN PROTEIN PORTION AND PRODUCTION METHOD |
CN1918044B (en) | 2004-02-09 | 2013-11-06 | 印刷包装国际公司 | Microwave cooking packages |
US8026464B2 (en) | 2004-03-01 | 2011-09-27 | Nestec S.A. | Multi-purpose food preparation kit |
US20060049190A1 (en) * | 2004-08-25 | 2006-03-09 | Middleton Scott W | Absorbent microwave interactive packaging |
CN101027723A (en) * | 2004-09-24 | 2007-08-29 | 松下电器产业株式会社 | Multilayer information recording medium and production method therefor, and photosensitive adhesive sheet |
US20060096978A1 (en) * | 2004-11-10 | 2006-05-11 | Graphic Packaging International, Inc | Insulated packages for microwaveable foods |
CA2592641C (en) * | 2005-01-14 | 2013-11-19 | Graphic Packaging International, Inc. | Package for browning and crisping dough-based foods in a microwave oven |
ES2586441T3 (en) | 2005-04-14 | 2016-10-14 | Graphic Packaging International, Inc. | Interactive insulating material with expandable microwave energy lasting |
US7592385B2 (en) * | 2005-05-06 | 2009-09-22 | Oatey Company | Universal solvent cement |
ES2751955T3 (en) * | 2005-06-17 | 2020-04-02 | Graphic Packaging Int Llc | Susceptors that can balance tension and effectiveness |
US7812293B2 (en) | 2006-03-14 | 2010-10-12 | Pliant Corporation | Freezable/microwavable packaging films and venting packages |
US9073689B2 (en) | 2007-02-15 | 2015-07-07 | Graphic Packaging International, Inc. | Microwave energy interactive insulating structure |
DE102007015083A1 (en) | 2007-03-29 | 2008-10-02 | Clariant International Limited | Flame-retardant adhesives and sealants |
ES2348625T3 (en) | 2007-05-11 | 2010-12-09 | Sika Technology Ag | LAYERED COMPOSITE BODIES JOINTED THROUGH A POLYURETHANE HOT MELT GLUE, AS WELL AS A PROCEDURE FOR GLUING PLASTICS WITH PLASTIFIER CONTENT. |
EP2185442A2 (en) * | 2007-08-31 | 2010-05-19 | Sara Lee Corporation | Microwaveable package for food products |
US20090242550A1 (en) | 2008-03-27 | 2009-10-01 | Schneider Lee M | Self-Venting Microwave Heating Package |
US8759730B2 (en) * | 2008-09-22 | 2014-06-24 | H.J. Heinz Company | Microwaveable carton having multiple focused susceptors |
US20100260900A1 (en) | 2009-03-17 | 2010-10-14 | Sara Lee Corporation | Microwaveable product |
-
2008
- 2008-02-15 US US12/070,091 patent/US9073689B2/en active Active
- 2008-02-15 CA CA2621723A patent/CA2621723C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2621723A1 (en) | 2008-08-15 |
US9073689B2 (en) | 2015-07-07 |
US20080197128A1 (en) | 2008-08-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2621723C (en) | Microwave energy interactive insulating structure | |
EP2018333B1 (en) | Microwave energy interactive heating sheet | |
EP2325106B1 (en) | Heat stabilized microwave energy interactive insulating material | |
US8178822B2 (en) | Variable serving size insulated packaging | |
EP2059457B1 (en) | Microwave heating package with thermoset coating | |
US9114913B2 (en) | Multi-compartment microwave heating package | |
CA2676047A1 (en) | Microwave energy interactive insulating sheet and system | |
US20080041925A1 (en) | Construct for heating multiple food items in a microwave oven |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20210215 |