CA2473553A1 - Fuel cell oxygen removal and pre-conditioning system - Google Patents

Fuel cell oxygen removal and pre-conditioning system Download PDF

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Publication number
CA2473553A1
CA2473553A1 CA002473553A CA2473553A CA2473553A1 CA 2473553 A1 CA2473553 A1 CA 2473553A1 CA 002473553 A CA002473553 A CA 002473553A CA 2473553 A CA2473553 A CA 2473553A CA 2473553 A1 CA2473553 A1 CA 2473553A1
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CA
Canada
Prior art keywords
fuel
oxidant
fuel cell
delivered
anode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002473553A
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French (fr)
Other versions
CA2473553C (en
Inventor
Philip John Mitchell
Paul Leonard Adcock
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Intelligent Energy Ltd
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Individual
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Filing date
Publication date
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Publication of CA2473553A1 publication Critical patent/CA2473553A1/en
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Publication of CA2473553C publication Critical patent/CA2473553C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126Humidifying
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04014Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
    • H01M8/04022Heating by combustion
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04119Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
    • H01M8/04126Humidifying
    • H01M8/04141Humidifying by water containing exhaust gases
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M2008/1095Fuel cells with polymeric electrolytes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

A fuel cell having an anode, a cathode and an ion exchange membrane is supplied by hydrogen fuel through an anode fuel delivery conduit. A recirculation loop is provided to recycle gases in the fuel delivery conduit to a mixing point where a controlled flow rate of fuel is supplied and mixed therewith. Any oxidant species remaining in the fuel delivery conduit are thereby combusted in a controlled manner to avoid damage to the fuel cell membrane-electrode assembly. Small quantities of oxidant may be deliberately introduced into the fuel delivery conduit to generate water vapour and heat to pre-condition the fuel delivered to the anode. Such preconditioning assists in hydration control of the membrane, and temperature control of the membrane- electrode assembly for optimum fuel cell performance.

Claims (50)

1. A fuel cell including an anode, a cathode, and an ion exchange membrane therebetween, and having a fuel delivery conduit for supplying fuel from a fuel source to an active surface area of the anode and further comprising means for effecting a controlled combustion of fuel and oxidant species within the fuel delivery conduit.
2. A fuel cell according to claim 1 in which the fuel delivery conduit comprises a fluid flow field plate forming part of the anode, having a fluid flow channel extending therethrough; a fuel delivery inlet coupled to one end of the fluid flow channel; and a fuel delivery outlet coupled another end of the fluid flow channel.
3. A fuel cell according to claim 2 in which the means for effecting a controlled combustion of fuel and oxidant species within the fuel delivery conduit comprises:
a recirculation conduit extending between the fuel delivery outlet and a mixing point in the fuel delivery inlet, and a fluid flow regulator for controllably varying the quantity of fuel delivered to the mixing point.
4. A fuel cell according to claim 3 in which the mixing point comprises a reaction chamber for reacting fuel from said fluid flow regulator with oxidant species from said recirculation conduit.
5. A fuel cell according to claim 4 in which the reaction chamber includes a catalyst material.
6. A fuel cell according to claim 3 in which the mixing point comprises a pre-mixing chamber for mixing fuel from said fluid flow regulator with oxidant species from said recirculation conduit.
7. A fuel cell according to any preceding claim in which the recirculation conduit is switchably connected to the fuel delivery outlet by way of a two way valve.
8. A fuel cell according to any preceding claim further including detection means for detecting a level of oxidant species present in at least part of the fuel delivery conduit.
9. A fuel cell according to claim 8 in which the detection means comprises means for testing an open circuit voltage across the anode and cathode of the fuel cell.
10. A fuel cell according to claim 3 further including control means for switching the fuel cell between a normal mode of operation in which a relatively high flow rate of fuel is delivered to the anode and oxidant is delivered to the cathode, and a recirculation mode in which a relatively low flow rate of fuel is delivered to the anode together with oxidant delivered via the recirculation conduit.
11. A fuel cell according to claim 3 further including control means for switching the fuel cell between a normal mode of operation in which a relatively high flow rate of fuel is delivered to the anode and oxidant is delivered to the cathode, and a recirculation mode in which a relatively low flow rate of fuel is delivered into fuel delivery conduit together with oxidant delivered via the recirculation conduit.
12. A fuel cell according to claim 2 in which the means for effecting a controlled combustion of fuel and oxidant species within the fuel delivery conduit comprises an oxidant supply conduit extending from an oxidant supply to a mixing point in the fuel delivery inlet.
13. A fuel cell according to claim 12 further including an oxidant flow regulator for controllably varying the quantity of oxidant delivered to the mixing point.
14. A fuel cell according to claim 13 in which the oxidant flow regulator comprises a valve coupling the oxidant supply conduit to a cathode oxidant delivery conduit.
15. A fuel cell according to claim 12 in which the mixing point comprises a reaction chamber for reacting fuel from said fluid flow regulator with oxidant species from said oxidant supply conduit.
16. A fuel cell according to claim 15 in which the reaction chamber includes a catalyst material.
17. A fuel cell according to claim 1 further including means for effecting a controlled combustion of fuel and oxidant species within a cathode fluid delivery conduit.
18. A fuel cell according to claim 17 in which the cathode fluid delivery conduit comprises a fluid flow field plate forming part of the cathode, having a fluid flow channel extending therethrough; an oxidant delivery inlet coupled to one end of the cathode fluid flow channel; and an exhaust outlet coupled to another end of the cathode fluid flow channel.
19. A fuel cell according to claim 18 in which said means for effecting a controlled combustion within a cathode comprises a fuel supply conduit extending from an fuel supply to a mixing point in the oxidant delivery inlet.
20. A fuel cell according to claim 19 in which the mixing point comprises a ,reaction chamber for reacting fuel from said fuel supply conduit with oxidant species from said oxidant supply.
21. A fuel cell system including:
a fuel cell having an anode, a cathode, and an ion exchange membrane therebetween;
a fuel delivery conduit comprising:
a fluid flow field plate forming part of the anode, having a fluid flow channel extending therethrough;
a fuel delivery inlet coupled to one end of the fluid flow channel; and a fuel delivery outlet coupled another end of the fluid flow channel;
the fuel cell system further comprising a recirculation conduit extending between the fuel delivery outlet and a mixing point in the fuel delivery inlet.
22. A fuel cell system according to claim 21 further including a fluid flow regulator for controllably varying the quantity of fuel delivered to the mixing point.
23. A fuel cell system according to claim 21 or claim 22 in which the mixing point comprises a reaction chamber for reacting fuel from said fluid flow regulator with oxidant species from said recirculation conduit.
24. A fuel cell system according to claim 21 or claim 22 in which the mixing point comprises a pre-mixing chamber for mixing fuel from said fluid flow regulator with oxidant species from said recirculation conduit.
25. A fuel cell system according to claim 21 in which the recirculation conduit is switchably connected to the fuel delivery outlet by way of a two way valve.
26. A fuel cell system according to claim 21 further including detection means for detecting a level of oxidant species present in at least part of the fuel delivery conduit.
27. A fuel cell according to claim 26 in which the detection means comprises means for testing an open circuit voltage across the anode and cathode of the fuel cell.
28. A fuel cell system according to claim 21 further including control means for switching the fuel cell between a normal mode of operation in which a relatively high flow rate of fuel is delivered to the anode and oxidant is delivered to the cathode, and a recirculation mode in which a relatively low flow rate of fuel is delivered to the anode together with oxidant delivered via the recirculation conduit.
29. A fuel cell system according to claim 21 further including control means for switching the fuel cell between a normal mode of operation in which a relatively high flow rate of fuel is delivered to the anode and oxidant is delivered to the cathode, and a recirculation mode in which a relatively low flow rate of fuel is delivered into fuel delivery conduit together with oxidant delivered via the recirculation conduit.
30. A fuel cell system including:

a fuel cell having an anode, a cathode, and an ion exchange membrane therebetween;
a fuel delivery conduit for delivering preconditioned fuel to the anode comprising:
a reaction chamber for reacting fuel and oxidant;
a fuel supply inlet for delivering fuel to the reaction chamber;
an oxidant supply inlet for supplying oxidant to the reaction chamber; and a reaction chamber outlet connected to the anode;
the reaction chamber being adapted so that at least a part of the fuel supply delivered thereto to is reacted with the oxidant supplied thereto to precondition the fuel being delivered to the anode.
31. A fuel cell system according to claim 30 further including control means for controllably varying the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of humidification of the fuel stream delivered to the anode.
32. A fuel cell system according to claim 30 further including control means for controllably varying the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of pre-heat of the fuel stream delivered to the anode.
33. A fuel cell system including:
a fuel cell having an anode, a cathode, and an ion exchange membrane therebetween;
an oxidant delivery conduit for delivering preconditioned oxidant to the cathode comprising:

a reaction chamber for reacting fuel and oxidant;

a fuel supply inlet for delivering fuel to the reaction chamber;
an oxidant supply inlet for supplying oxidant to the reaction chamber; and a reaction chamber outlet connected to the cathode;
the reaction chamber being adapted so that at least a part of the oxidant supply delivered thereto to is reacted with the fuel supplied thereto to precondition the oxidant being delivered to the cathode.
34. A fuel cell system according to claim 33 further including control means for controllably varying the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of humidification of the oxidant stream delivered to the cathode.
35. A fuel cell system according to claim 33 further including control means for controllably varying the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of pre-heat of the oxidant stream delivered to the cathode.
36. Apparatus substantially as described herein with reference to the accompanying drawings.
37. A method of operating a fuel cell having an anode, a cathode, and an ion exchange membrane therebetween, comprising the steps of:
supplying fuel from a fuel source to an active surface area of the anode by way of a fuel delivery conduit; and effecting a controlled combustion of fuel and oxidant species within the fuel delivery conduit.
38. The method of claim 37 further including the step of recirculating fluid within the fluid delivery conduit to a mixing point upstream of the active surface area of the anode.
39. The method of claim 38 further including the step of consuming oxidant species at the mixing point, in a reaction chamber.
40. The method of claim 38 or claim 39 further including the step of controllably varying the quantity of fuel delivered to the mixing point.
41. The method of any one of claims 37 to 40 further including the step of detecting a level of oxidant species present in at least part of the fuel delivery conduit.
42. The method of claim 38 further including the steps of switching the fuel cell between a normal mode of operation in which a relatively high flow rate of fuel is delivered to the anode and oxidant is delivered to the cathode, and a recirculation mode in which a relatively low flow rate of fuel is delivered to the anode together with oxidant delivered in the recirculated fluid.
43. The method of claim 38 further including the steps of switching the fuel cell between a normal mode of operation in which a relatively high flow rate of fuel is delivered to the anode and oxidant is delivered to the cathode, and a recirculation mode in which a relatively low flow rate of fuel is delivered into the fuel delivery conduit together with oxidant delivered in the recirculation fluid.
44. A method of operating a fuel cell having an anode, a cathode, and an ion exchange membrane therebetween, comprising the steps of:

supplying fuel from a fuel source to an active surface area of the anode by way of a fuel delivery conduit; and reacting fuel and oxidant in a reaction chamber upstream of the anode to precondition the fuel being delivered to the anode
45. The method of claim 44 further including the step of controlling the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of humidification of the fuel stream delivered to the anode.
46. The method of claim 44 further including the step of controlling the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of pre-heat of the fuel stream delivered to the anode.
47. A method of operating a fuel cell having an anode, a cathode, and an ion exchange membrane therebetween, comprising the steps of:
supplying oxidant from an oxidant source to an active surface area of a cathode by way of an oxidant delivery conduit; and reacting fuel and oxidant in a reaction chamber upstream of the cathode to preconditioned the oxidant being delivered to the cathode.
48. The method of claim 47 further including the step of controlling the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of humidification of the oxidant stream delivered to the cathode.
49. The method of claim 47 further including the step of controlling the flow rate of one or both of the fuel and oxidant in order to achieve a predetermined degree of pre-heat of the oxidant stream delivered to the cathode.
50. A method substantially as described herein with reference to the accompanying drawings.
CA2473553A 2002-01-18 2003-01-15 Fuel cell oxygen removal and pre-conditioning system Expired - Fee Related CA2473553C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0201114A GB2412784B (en) 2002-01-18 2002-01-18 Fuel cell oxygen removal and pre-conditioning system
GB0201114.6 2002-01-18
PCT/GB2003/000169 WO2003063278A2 (en) 2002-01-18 2003-01-15 Fuel cell oxygen removal and pre-conditioning system

Publications (2)

Publication Number Publication Date
CA2473553A1 true CA2473553A1 (en) 2003-07-31
CA2473553C CA2473553C (en) 2011-03-15

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA2473553A Expired - Fee Related CA2473553C (en) 2002-01-18 2003-01-15 Fuel cell oxygen removal and pre-conditioning system

Country Status (15)

Country Link
US (1) US7785746B2 (en)
EP (1) EP1504484B1 (en)
JP (1) JP4840896B2 (en)
AT (1) ATE357748T1 (en)
AU (1) AU2003201682A1 (en)
BR (1) BR0302671A (en)
CA (1) CA2473553C (en)
DE (1) DE60312677T2 (en)
ES (1) ES2299684T3 (en)
GB (1) GB2412784B (en)
MX (1) MXPA04006981A (en)
NO (1) NO336082B1 (en)
RU (1) RU2310255C2 (en)
WO (1) WO2003063278A2 (en)
ZA (1) ZA200405663B (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2382455B (en) * 2001-11-07 2004-10-13 Intelligent Energy Ltd Fuel cell fluid flow field plates
GB2412784B (en) 2002-01-18 2006-08-23 Intelligent Energy Ltd Fuel cell oxygen removal and pre-conditioning system
GB2390738B (en) * 2002-07-09 2005-05-11 Intelligent Energy Ltd Fuel cell direct water injection
GB2401986B (en) * 2003-05-17 2005-11-09 Intelligent Energy Ltd Improvements in fuel utilisation in electrochemical fuel cells
DE10340982A1 (en) * 2003-09-05 2005-03-31 Volkswagen Ag Fuel cell, e.g. for vehicle, is supplied by compressor with air from a preheater system that is connected to the cathode
US20050112454A1 (en) * 2003-11-25 2005-05-26 Victor Gurin Alkaline electrolyte fuel cells with improved hydrogen-oxygen supply system
GB2409763B (en) 2003-12-31 2007-01-17 Intelligent Energy Ltd Water management in fuel cells
GB2413002B (en) * 2004-04-08 2006-12-06 Intelligent Energy Ltd Fuel cell gas distribution
DE102004024847A1 (en) * 2004-05-13 2005-12-08 Volkswagen Ag High-temperature fuel cell unit starting method for vehicle, involves accomplishing conditioning of unit with warming up phase, pressure increase phase and power increase phase, before normal operation of unit
TWM262846U (en) * 2004-08-31 2005-04-21 Antig Tech Co Ltd Semi-active fuel cell device
GB2422716B (en) * 2005-01-26 2007-08-22 Intelligent Energy Ltd Multi-layer fuel cell diffuser
JP2007123833A (en) * 2005-09-30 2007-05-17 National Institute Of Advanced Industrial & Technology Method for activating solid acid salt, and large-capacity capacitor and fuel cell using same
JP4997763B2 (en) * 2005-12-28 2012-08-08 日産自動車株式会社 Fuel cell system
GB2434845B (en) * 2006-02-01 2010-10-13 Intelligent Energy Ltd Variable compressibility gaskets
GB2435711B (en) 2006-03-03 2011-01-12 Intelligent Energy Ltd Rehydration of fuel cells
JP5024721B2 (en) * 2006-05-10 2012-09-12 トヨタ自動車株式会社 Fuel cell system and circulation ratio calculation method thereof
US20100040914A1 (en) * 2006-12-29 2010-02-18 Sitaram Ramaswamy Fuel-cascaded fuel cell stacks with decoupled power outputs
US20080299423A1 (en) * 2007-05-30 2008-12-04 Laven Arne Fuel cell systems with maintenance hydration
JP5261999B2 (en) * 2007-07-03 2013-08-14 富士電機株式会社 Fuel cell power generator
JP2009266588A (en) * 2008-04-24 2009-11-12 Mitsubishi Heavy Ind Ltd Fuel battery module
NL2002071C (en) 2008-10-07 2010-04-08 Univ Delft Tech ELECTRODEM COMPARTMENT FOR ELECTROCHEMICAL CELL, THAT FRESH SYSTEM, AND AN EMULSION TO BE USED THEREOF.
NL2004746C2 (en) * 2010-05-19 2011-11-22 Epyon B V Charging system for electric vehicles.
US8673510B2 (en) 2010-10-11 2014-03-18 Dcns Sa Systems and methods for maintaining hydrogen-selective membranes during periods of inactivity
WO2018046990A1 (en) 2016-09-07 2018-03-15 Intelligent Energy Limited Ground stations and methods for pem fuel cell powered unmanned aerial vehicles
GB2582359B (en) 2019-03-21 2022-01-19 Intelligent Energy Ltd Fuel cell startup/shutdown degradation mitigation by removal of oxygen ad/absorption media
US11618676B2 (en) 2020-10-23 2023-04-04 H2 Powertech, Llc Systems and methods for increasing the hydrogen permeance of hydrogen-separation membranes in situ
EP4141998A1 (en) * 2021-08-26 2023-03-01 Technische Universität Braunschweig Method for operating a fuel cell, computer program and fuel cell system
DE102021213726A1 (en) 2021-12-02 2023-06-07 Robert Bosch Gesellschaft mit beschränkter Haftung Process for conditioning a fuel cell unit

Family Cites Families (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2408897A1 (en) 1977-11-15 1979-06-08 Cii Honeywell Bull TAKE-OFF TIME PROCESS OF A PLATFORM INCLUDING AT LEAST ONE READ / WRITE TRANSDUCER OF AN INFORMATION MEDIUM, A PLATFORM RESULTING FROM THE EXECUTION OF THE PROCESS, AND PROCESS FOR MANUFACTURING SUCH A PLATFORM
US4537839A (en) * 1982-11-23 1985-08-27 Johnson Matthey Public Limited Company Fuel cell and method of purging a fuel cell
JPS61233976A (en) * 1985-04-10 1986-10-18 Fuji Electric Co Ltd Fuel cell facility
JPS61233977A (en) * 1985-04-10 1986-10-18 Fuji Electric Co Ltd Gas replacement of fuel cell
JPS62283564A (en) * 1986-05-31 1987-12-09 Toshiba Corp Generating system for fuel cell
US4755439A (en) * 1987-03-25 1988-07-05 International Fuel Cells Corporation Fuel cell configuration for contaminated fuel gases and method of using the same
JPH01117277A (en) * 1987-10-30 1989-05-10 Ube Ind Ltd Fuel cell equipment having purging gas manufacturing apparatus
JPH01124962A (en) * 1987-11-10 1989-05-17 Fuji Electric Co Ltd Alkaline electrolyte fuel cell system
JP2752987B2 (en) * 1988-06-01 1998-05-18 株式会社東芝 Phosphoric acid fuel cell power plant
JP3070769B2 (en) * 1990-12-28 2000-07-31 アイシン・エィ・ダブリュ株式会社 Method for activating fuel electrode of methanol fuel cell
JPH0589899A (en) * 1991-09-27 1993-04-09 Hitachi Ltd Internal reforming type fused carbonate fuel cell and operation thereof
ES2094273T3 (en) 1991-12-24 1997-01-16 Toshiba Kk ENERGY PRODUCTION FACILITY INCLUDING FUEL ELEMENTS.
JP3499199B2 (en) * 1992-01-27 2004-02-23 株式会社東芝 Fuel cell power plant
JP3375200B2 (en) * 1993-06-18 2003-02-10 田中貴金属工業株式会社 Polymer solid electrolyte composition
JP3608872B2 (en) * 1995-05-10 2005-01-12 東北電力株式会社 Fuel cell power generation system
US6376113B1 (en) * 1998-11-12 2002-04-23 Idatech, Llc Integrated fuel cell system
JP3182373B2 (en) * 1997-06-27 2001-07-03 富士通テン株式会社 Microcomputer device
JP3741178B2 (en) 1997-07-18 2006-02-01 株式会社ニコン X-ray reduction exposure apparatus and X-ray projection exposure method
JP3706462B2 (en) * 1997-07-23 2005-10-12 三洋電機株式会社 Polymer electrolyte fuel cell
US5928805A (en) * 1997-11-20 1999-07-27 Siemens Westinghouse Power Corporation Cover and startup gas supply system for solid oxide fuel cell generator
US6007931A (en) 1998-06-24 1999-12-28 International Fuel Cells Corporation Mass and heat recovery system for a fuel cell power plant
DE19983564T1 (en) 1998-09-30 2001-07-26 Hitachi Ltd Fuel cell system and vehicle using it
AT407315B (en) 1998-11-23 2001-02-26 Vaillant Gmbh CHP POWER PLANT
JP4457421B2 (en) 1998-12-24 2010-04-28 トヨタ自動車株式会社 Fuel cell system
JP3956542B2 (en) 1999-07-09 2007-08-08 日産自動車株式会社 Fuel cell system
US6383670B1 (en) 1999-10-06 2002-05-07 Idatech, Llc System and method for controlling the operation of a fuel processing system
US6416891B1 (en) * 1999-11-22 2002-07-09 Utc Fuel Cells, Llc Operating system for a direct antifreeze cooled fuel cell power plant
NL1013876C2 (en) * 1999-12-17 2001-07-03 Stichting Energie Low temperature fuel cell assembly as well as a method of operating it.
US6465118B1 (en) 2000-01-03 2002-10-15 Idatech, Llc System and method for recovering thermal energy from a fuel processing system
KR100339795B1 (en) * 2000-01-25 2002-06-07 박호군 Direct Internal Reforming Molten Carbonate Fuel Cell with Membrane for Intercepting Carbonate Vapor
JP4781500B2 (en) * 2000-03-24 2011-09-28 本田技研工業株式会社 Fuel supply device for fuel cell
US6706429B1 (en) * 2000-06-13 2004-03-16 Hydrogenics Corporation Catalytic humidifier and heater, primarily for humidification of the oxidant stream for a fuel cell
US6558827B1 (en) * 2001-02-26 2003-05-06 Utc Fuel Cells, Llc High fuel utilization in a fuel cell
GB2382455B (en) 2001-11-07 2004-10-13 Intelligent Energy Ltd Fuel cell fluid flow field plates
GB2412784B (en) 2002-01-18 2006-08-23 Intelligent Energy Ltd Fuel cell oxygen removal and pre-conditioning system
GB2387959B (en) 2002-03-28 2005-02-09 Intelligent Energy Ltd Fuel cell compression assembly
GB2390738B (en) 2002-07-09 2005-05-11 Intelligent Energy Ltd Fuel cell direct water injection
GB2396688B (en) 2002-11-22 2006-06-28 Intelligent Energy Ltd Thermal energy management in electrochemical fuel cells
GB2401986B (en) 2003-05-17 2005-11-09 Intelligent Energy Ltd Improvements in fuel utilisation in electrochemical fuel cells
GB2409763B (en) 2003-12-31 2007-01-17 Intelligent Energy Ltd Water management in fuel cells
GB2413002B (en) 2004-04-08 2006-12-06 Intelligent Energy Ltd Fuel cell gas distribution
GB2422716B (en) 2005-01-26 2007-08-22 Intelligent Energy Ltd Multi-layer fuel cell diffuser
GB2422717B (en) 2005-02-01 2007-11-14 Intelligent Energy Ltd Detachable fuel cell power unit for vehicle applications
GB2434845B (en) 2006-02-01 2010-10-13 Intelligent Energy Ltd Variable compressibility gaskets

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DE60312677D1 (en) 2007-05-03
DE60312677T2 (en) 2007-12-06
ATE357748T1 (en) 2007-04-15
AU2003201682A1 (en) 2003-09-02
WO2003063278A2 (en) 2003-07-31
GB2412784B (en) 2006-08-23
RU2310255C2 (en) 2007-11-10
NO20034135D0 (en) 2003-09-17
JP2005516349A (en) 2005-06-02
US20050106445A1 (en) 2005-05-19
EP1504484A2 (en) 2005-02-09
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