CA2221460A1 - Thermoplastic molding material - Google Patents

Thermoplastic molding material

Info

Publication number
CA2221460A1
CA2221460A1 CA002221460A CA2221460A CA2221460A1 CA 2221460 A1 CA2221460 A1 CA 2221460A1 CA 002221460 A CA002221460 A CA 002221460A CA 2221460 A CA2221460 A CA 2221460A CA 2221460 A1 CA2221460 A1 CA 2221460A1
Authority
CA
Canada
Prior art keywords
block
under
proportion
bonds
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002221460A
Other languages
French (fr)
Other versions
CA2221460C (en
Inventor
Konrad Knoll
Hermann Gausepohl
Norbert Niessner
Paul Naegele
Wolfgang Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos Styrolution Europe GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2221460A1 publication Critical patent/CA2221460A1/en
Application granted granted Critical
Publication of CA2221460C publication Critical patent/CA2221460C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Rubber-elastic block copolymers of at least one hard block A consisting of styrene monomers and at least one elastomeric block (B/A) of styrene monomers and containing dienes, the glass temperature T g of block A being over 25 °C and that of block B/A is under 25 °C and the phase volume ratio between block A and block B/A being such that the proportion of the hard phase in the entire block copolymer is 1 to 40 vol %, and the proportion by weight of the diene is under 50 wt.%. The relative proportion of 1,2 bonds of the polydiene in relation to the sum of 1,2 and 1,4 cis/trans-bonds is under 15 %, process for their production by anionic polymerisation by means of lithium alkyl in a non-polar solvent in the presence of a soluble potassium salt and their use for the production of mouldings.
CA002221460A 1996-04-19 1997-04-03 Thermoplastic molding material Expired - Lifetime CA2221460C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19615533.9 1996-04-19
DE19615533A DE19615533A1 (en) 1996-04-19 1996-04-19 Thermoplastic molding compound
PCT/EP1997/001670 WO1997040079A1 (en) 1996-04-19 1997-04-03 Thermoplastic moulding compound

Publications (2)

Publication Number Publication Date
CA2221460A1 true CA2221460A1 (en) 1997-10-30
CA2221460C CA2221460C (en) 2006-07-11

Family

ID=7791776

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002221460A Expired - Lifetime CA2221460C (en) 1996-04-19 1997-04-03 Thermoplastic molding material

Country Status (9)

Country Link
US (1) US6197889B1 (en)
EP (1) EP0859803B1 (en)
JP (1) JP3953522B2 (en)
KR (1) KR100453662B1 (en)
CN (1) CN1143871C (en)
CA (1) CA2221460C (en)
DE (2) DE19615533A1 (en)
ES (1) ES2140974T3 (en)
WO (1) WO1997040079A1 (en)

Families Citing this family (94)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19638254A1 (en) * 1996-09-19 1998-03-26 Basf Ag Thermoplastic elastomers
DE19810141A1 (en) 1998-03-10 1999-09-16 Basf Ag Elastomeric polymer mixture with good tearing resistance and stiffness for fiber, film and molded article
DE19846529A1 (en) * 1998-10-09 2000-04-13 Basf Drucksysteme Gmbh Photopolymerizable printing forms for the production of relief printing plates for printing with UV-curable printing inks
DE19848683B4 (en) * 1998-10-22 2004-05-06 Basf Ag Laminated sheet
DE19914075A1 (en) * 1999-03-27 2000-09-28 Basf Ag Transparent high-impact styrene-butadiene block copolymers comprises at least two hard blocks and a soft block with a low 1,2-vinyl content for improved thermal stability
US6593430B1 (en) 1999-03-27 2003-07-15 Basf Aktiengesellschaft Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis
KR100370217B1 (en) * 2000-08-25 2003-01-29 삼성전자 주식회사 CRT coupling apparatus of projection television
US6462137B2 (en) * 2000-10-19 2002-10-08 China Petroleum And Chemical Corporation Star-block interpolymers and preparation of the same
US6987142B2 (en) 2002-02-07 2006-01-17 Kraton Polymers U.S. Llc Adhesives and sealants from controlled distribution block copolymers
US20030181584A1 (en) 2002-02-07 2003-09-25 Kraton Polymers U.S. Llc Elastomeric articles prepared from controlled distribution block copolymers
US20040138371A1 (en) * 2002-02-07 2004-07-15 St. Clair David John Gels from controlled distribution block copolymers
ATE392450T1 (en) * 2003-08-14 2008-05-15 Basf Se MIXTURE OF POLYESTER AND BLOCK COPOLYMERS FROM VINYL ROMATS AND CONJUGATED SERIES
JP2007506842A (en) 2003-09-23 2007-03-22 デイス−アナリティック コーポレーション NOVEL BLOCK COPOLYMER AND METHOD FOR PRODUCING THE SAME
US7232864B2 (en) * 2003-10-30 2007-06-19 Bening Robert C Coupled radial anionic polymers
ES2466640T3 (en) 2004-02-09 2014-06-10 Styrolution GmbH Molding masses of styrene polymers with matt surface
US7348076B2 (en) 2004-04-08 2008-03-25 Saint-Gobain Ceramics & Plastics, Inc. Single crystals and methods for fabricating same
US7717893B2 (en) * 2004-06-04 2010-05-18 The Procter & Gamble Company Absorbent articles comprising a slow recovery elastomer
US7905872B2 (en) * 2004-06-04 2011-03-15 The Procter & Gamble Company Absorbent articles comprising a slow recovery stretch laminate
DE102004029138A1 (en) * 2004-06-17 2005-12-29 Basf Ag Blends of styrene-butadiene block copolymers and polyolefins for transparent, elastic films
DE102004029132A1 (en) * 2004-06-17 2005-12-29 Basf Ag Blends of styrene-butadiene block copolymers and polyolefins for transparent, elastic films
DE102004055539A1 (en) 2004-11-17 2006-05-18 Basf Ag Masterbatch based on styrene-butadiene block copolymers
US8419701B2 (en) * 2005-01-10 2013-04-16 The Procter & Gamble Company Absorbent articles with stretch zones comprising slow recovery elastic materials
JP4611390B2 (en) 2005-01-26 2011-01-12 ザ プロクター アンド ギャンブル カンパニー Disposable pull-on diaper with elastic waist that has low resistance and recovers slowly
US20070026251A1 (en) * 2005-07-26 2007-02-01 Kraton Polymers U.S. Llc Flexible packaging laminate films including a block copolymer layer
US20070066753A1 (en) * 2005-09-16 2007-03-22 Ehrlich Martin L Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers
US20070078206A1 (en) * 2005-10-04 2007-04-05 Clair David J S Sound damping composition
US20070078194A1 (en) * 2005-10-04 2007-04-05 St Clair David J Flexographic printing plate and flexographic printing plate precursor composition for preparing same
US20070078205A1 (en) * 2005-10-04 2007-04-05 St Clair David J Hot melt adhesive composition having improved stability
US7582702B2 (en) 2006-03-24 2009-09-01 Kraton Polymers U.S. Llc Block copolymer compositons
US7592390B2 (en) * 2006-03-24 2009-09-22 Kraton Polymers U.S. Llc Hydrogenated block copolymer compositions
US7585916B2 (en) 2006-03-24 2009-09-08 Kraton Polymers Us Llc Block copolymer compositions
US7858693B2 (en) 2006-03-24 2010-12-28 Kratonpolymers U.S. Llc Unhydrogenated block copolymer compositions
WO2007127155A2 (en) * 2006-04-24 2007-11-08 Kraton Polymers U.S Llc Polymeric compositions and films formed therefrom
JP2010508055A (en) * 2006-11-02 2010-03-18 ザ プロクター アンド ギャンブル カンパニー Absorbent article with slowly recovering material handle
DK2144959T3 (en) 2007-04-11 2011-04-18 Basf Se Elastic particle foam based on polyolefin / styrene polymer blends
EP2195152B1 (en) 2007-09-28 2012-11-14 Styrolution GmbH Methods for producing flameproofed thermoplastic moulding compounds
JP5168460B2 (en) * 2007-09-28 2013-03-21 株式会社クラレ Block copolymer and method for producing the same
US8323257B2 (en) 2007-11-21 2012-12-04 The Procter & Gamble Company Absorbent articles comprising a slow recovery stretch laminate and method for making the same
ATE506484T1 (en) * 2007-12-13 2011-05-15 Basf Se THERMOPLASTIC LINOLEUM
JP2011513544A (en) * 2008-03-05 2011-04-28 ビーエーエスエフ ソシエタス・ヨーロピア A tough and rigid mixture of α-methylstyrene-acrylonitrile copolymer and block copolymer
JP5575669B2 (en) * 2008-03-13 2014-08-20 ビーエーエスエフ ソシエタス・ヨーロピア Method and dispersion for forming a metal layer on a substrate, and metallizable thermoplastic molding compound
CN101628959A (en) * 2008-07-15 2010-01-20 中国石油化工集团公司 Foamed styrene monomer-diolefin copolymer, and preparation method and application thereof
DK2384354T3 (en) 2008-12-30 2013-05-13 Basf Se ELASTIC PARTICLE FOAM PLASTIC BASED ON POLYOLEFINE / STYRENE POLYMER MIXTURES
WO2010100101A1 (en) 2009-03-05 2010-09-10 Basf Se Elastic particle foam material based on polyolefin/styrene polymer mixtures
JP5739814B2 (en) * 2009-09-29 2015-06-24 電気化学工業株式会社 Heat shrinkable laminated film
WO2011039292A1 (en) 2009-10-01 2011-04-07 Basf Se Method for producing functionalized expandable graphite intercalation compounds
WO2011039301A1 (en) 2009-10-01 2011-04-07 Basf Se Functionalized expandable graphite intercalation compounds
US8324309B2 (en) * 2010-04-27 2012-12-04 Kraton Polymers Us Llc High melt flow block copolymers for non-woven adhesives
US8697795B2 (en) 2010-08-25 2014-04-15 Konrad Knoll Thermoplastic linoleum
CN103154357B (en) 2010-08-25 2015-04-01 巴斯夫股份公司 Thermoplastic molding compound, method for producing same, and use thereof
US9394414B2 (en) 2010-09-29 2016-07-19 Kraton Polymers U.S. Llc Elastic, moisture-vapor permeable films, their preparation and their use
WO2012049264A2 (en) 2010-10-15 2012-04-19 Basf Se Method for producing flame-proofed thermoplastic molding compounds
EP2632964B1 (en) * 2010-10-27 2015-05-06 Styrolution Europe GmbH Elastomeric block copolymers with a star-shaped molecular architecture, said star-shaped molecular architecture having at least two different star arms
US8835560B2 (en) 2010-10-27 2014-09-16 Styrolution GmbH Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms in the star
US9017305B2 (en) 2010-11-12 2015-04-28 The Procter Gamble Company Elastomeric compositions that resist force loss and disintegration
JP5859563B2 (en) 2010-12-23 2016-02-10 スタイロリューション・ヨーロッパ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Thermoplastic elastomer composition and method for producing the same
WO2012089574A1 (en) 2010-12-28 2012-07-05 Basf Se Foam board based on styrene polymer-polyolefin mixtures
US9080050B2 (en) 2011-03-02 2015-07-14 Basf Se Use of vinylaromatic-diene copolymers in lactam compositions
KR101859244B1 (en) * 2011-03-02 2018-05-18 바스프 에스이 Use of vinylaromatic-diene copolymers in lactam compositions
EP2537872B1 (en) 2011-06-22 2015-08-12 Trinseo Europe GmbH High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof
PL2537871T3 (en) 2011-06-22 2019-03-29 Trinseo Europe Gmbh High styrene high vinyl styrene-butadiene rubber with narrow molecular weight distribution and methods for preparation thereof
US20140100310A1 (en) 2012-10-08 2014-04-10 Teknor Apex Company Thermoplastic elastomer compositions having biorenewable content
EP2813524A1 (en) 2013-06-10 2014-12-17 Basf Se Phosphorylated polymers
WO2015067817A1 (en) 2013-11-11 2015-05-14 Styrolution Group Gmbh Blends of styrene butadiene copolymers with poly(lactic acid)
EP3068834B1 (en) 2013-11-12 2017-07-19 INEOS Styrolution Group GmbH Polymer compositions based on smma
EP3092269A4 (en) * 2014-01-10 2017-09-27 CommScope Connectivity Belgium BVBA Thermoplastic gel compositions and their methods of making
US10559778B2 (en) * 2014-01-29 2020-02-11 Zeon Corporation Composite gas barrier laminate and method for producing same
EP3105290B1 (en) 2014-02-10 2019-10-23 INEOS Styrolution Group GmbH Styrene methyl methacrylate copolymers (smma) as compatibilizing agents
EP3105288B1 (en) * 2014-02-11 2020-04-08 INEOS Styrolution Group GmbH Blends of thermoplastic elastomers based on styrene (s-tpe) and polyolefins
US9156978B1 (en) 2014-06-06 2015-10-13 Teknor Apex Company Low softener halogen free flame retardant styrenic block copolymer-based thermoplastic elastomer compositions
US10131779B2 (en) 2014-09-03 2018-11-20 Ineos Styrolution Group Gmbh Blends of styrene-butadiene copolymers
BE1022422B1 (en) 2014-09-23 2016-03-25 Avore Nv METHOD FOR REMOVING ORGANIC POLLUTANTS FROM WATER
BE1022987B1 (en) 2015-03-10 2016-10-27 Avore Nv METHOD FOR REMOVING ORGANIC POLLUTANTS FROM WATER
US9540475B2 (en) 2015-03-12 2017-01-10 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers for tubing applications
US9598524B1 (en) 2015-09-18 2017-03-21 Chevron Phillips Chemical Company Lp Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications
US9441090B1 (en) 2015-03-12 2016-09-13 Chevron Phillips Chemical Company Lp Methods for controlling hardness of styrene-butadiene block copolymers
WO2016146729A1 (en) 2015-03-18 2016-09-22 Styrolution Group Gmbh Impact modified styrenic polymers with improved environmental stress crack resistance properties
US9416212B1 (en) * 2015-08-17 2016-08-16 The Goodyear Tire & Rubber Company Pneumatic tire with block copolymer
US9738781B2 (en) 2015-09-03 2017-08-22 Ineos Styrolution Group Gmbh Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications
EP3359593B1 (en) 2015-10-09 2019-12-11 INEOS Styrolution Group GmbH Electrically insulating thermally conductive polymer resin composition based on styrenics with balanced properties
EP3359595B1 (en) 2015-10-09 2019-12-11 INEOS Styrolution Group GmbH Thermally conductive polymer resin composition based on styrenics with low density
WO2017060343A1 (en) 2015-10-09 2017-04-13 Ineos Styrolution Group Gmbh Electrically conducting thermally conductive polymer resin composition based on styrenics with balanced properties
US10023676B2 (en) 2016-02-24 2018-07-17 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
US9828455B2 (en) 2016-02-24 2017-11-28 Ineos Styrolution Group Gmbh Styrene-butadiene block copolymers with an internal butadiene block for tubing applications
ES2882143T3 (en) 2016-04-21 2021-12-01 Ineos Styrolution Group Gmbh ABS molding composition that has improved cracking and chemical resistance and wear
ES2804255T3 (en) * 2016-06-29 2021-02-05 Ineos Styrolution Group Gmbh Polymeric composition comprising at least one vinyl aromatic diene block copolymer and specific amounts of oil
US10839979B2 (en) 2016-07-08 2020-11-17 Teknor Apex Company Cable with flame retardant multi-layer covering
US11891503B2 (en) 2017-03-16 2024-02-06 Ineos Styrolution Group Gmbh Non-sticky, soft and transparent styrenic thermoplastic elastomers
JP7170654B2 (en) 2017-03-16 2022-11-14 イネオス・スタイロリューション・グループ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング A very soft, non-sticky and transparent styrenic thermoplastic elastomer composition
JP7178373B2 (en) 2017-06-19 2022-11-25 イネオス・スタイロリューション・グループ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング Vinyl aromatic/diene-block copolymers with excellent sensory properties
EP3752561B1 (en) 2018-02-16 2023-05-24 INEOS Styrolution Group GmbH High heat resistant abs molding composition
CN111819313A (en) 2018-03-06 2020-10-23 巴斯夫欧洲公司 Filament based on a core material comprising a fibrous filler
US20220332872A1 (en) 2019-08-21 2022-10-20 Ineos Styrolution Group Gmbh Abs molding composition for sheet extrusion and thermoforming with high escr, high color and thermal stability and low tendency to delamination
KR20220113734A (en) 2019-12-04 2022-08-16 이네오스 스티롤루션 그룹 게엠베하 Recycled material containing ultra-high quality thermoplastics

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3507934A (en) 1965-12-20 1970-04-21 Shell Oil Co Block copolymer compositions having improved processability
US3639517A (en) 1969-09-22 1972-02-01 Phillips Petroleum Co Resinous branched block copolymers
JPS5810410B2 (en) * 1973-08-17 1983-02-25 住友化学工業株式会社 The best way to get started
US4122134A (en) 1974-02-13 1978-10-24 Sumitomo Chemical Company, Limited Method for producing transparent block copolymer resin
DE2550226C2 (en) 1975-11-08 1984-12-13 Basf Ag, 6700 Ludwigshafen Branched block copolymers and process for their preparation
US4167545A (en) 1975-11-08 1979-09-11 Basf Aktiengesellschaft Branched block copolymers and their manufacture
JPS5679147A (en) * 1979-11-30 1981-06-29 Asahi Chem Ind Co Ltd Impact-resistant resin composition
JPH0615596B2 (en) * 1984-03-23 1994-03-02 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Branched block copolymer and method for producing the same
JP2612588B2 (en) * 1988-04-04 1997-05-21 日本エラストマー株式会社 Thermoplastic elastomer for asphalt modification
US5256736A (en) * 1991-05-08 1993-10-26 Phillips Petroleum Company Tapered block copolymers of conjugated dienes and monovinylarenes
JP3468246B2 (en) * 1992-12-17 2003-11-17 日本エラストマー株式会社 Block copolymer for asphalt modification
JP3418420B2 (en) * 1993-02-03 2003-06-23 日本エラストマー株式会社 Thermoplastic copolymer for asphalt modification
JP3112607B2 (en) * 1993-09-28 2000-11-27 電気化学工業株式会社 Block copolymer and heat shrinkable film thereof
US5385994A (en) * 1993-10-22 1995-01-31 Bridgestone Corporation 2,5-substituted tetrahydrofurans as anionic initiator modifiers
CA2134026C (en) * 1993-11-15 1998-06-09 William J. Trepka Tapered block copolymers of monovinylarenes and conjugated dienes
JP3335747B2 (en) * 1994-02-21 2002-10-21 旭化成株式会社 Production method of block copolymer
DE4420952A1 (en) * 1994-06-17 1995-12-21 Basf Ag Thermoplastic elastomer

Also Published As

Publication number Publication date
CN1143871C (en) 2004-03-31
EP0859803A1 (en) 1998-08-26
CA2221460C (en) 2006-07-11
JP3953522B2 (en) 2007-08-08
JPH11508317A (en) 1999-07-21
KR19990023020A (en) 1999-03-25
DE19615533A1 (en) 1997-10-23
ES2140974T3 (en) 2000-03-01
US6197889B1 (en) 2001-03-06
DE59700794D1 (en) 2000-01-05
EP0859803B1 (en) 1999-12-01
WO1997040079A1 (en) 1997-10-30
KR100453662B1 (en) 2005-02-24
CN1189170A (en) 1998-07-29

Similar Documents

Publication Publication Date Title
CA2221460A1 (en) Thermoplastic molding material
EP0667359A4 (en) Olefin copolymers and process for producing the same.
SG50421A1 (en) Process for the manufacture of a composition comprising a vinylaromatic polymer and a rubber
CA2028410A1 (en) Tapered block styrene/butadiene copolymers
AU5193893A (en) Process for the preparation of thermoplastic elastomeric block copolymers derived from conjugated dienes and methyl methacrylate, with improved heat resistance, and products obtained
EP0818478A4 (en) Styrene-isoprene-butadiene copolymer rubber and process for the production thereof
MY121636A (en) Process for the preparation of polymer particles.
CA2052387A1 (en) Tapered block styrene/butadiene copolymers
IE811283L (en) Thermoformable polymer blend composition
JPS5740513A (en) Production of impact-resistant polystyrene
GB1480443A (en) Thermoplastic block polymers
AU7306996A (en) Water-redispersible pulverulent composition of film-forming polymers
AU7683587A (en) Abc block copolymers based on butadiene and isoprene, process for their preparation and their use
AU617172B2 (en) Process for making 1,3-dioxane derivatives
MX9802675A (en) Branched block ethylene polymers, their preparation and compositions comprising the same.
IE39599L (en) Graft polymers and compositions of high impact strength
EP0814095A3 (en) Process for producing a shaped product
CA2219708A1 (en) Synthesis of macrocyclic polymers with group iia and iib metal cyclic organometallic initiators
AU7306896A (en) Water-redispersible pulverulent compositon of film-forming polymers
CA2180809A1 (en) A process for low temperature heat sealing of polyethylene
CA1038097A (en) Method of preparing block polymers
EP0471998A3 (en) Branched block copolymer, process for its preparation and use therefor
CA2055229A1 (en) Thermoplastic compositions based on a polyolefine and a vinyl aromatic polymer
MY133396A (en) Process for the manufacture of impact resistant modified polymers
GR3025270T3 (en) Elastosols, preparation, use and products thereof.

Legal Events

Date Code Title Description
EEER Examination request