CA2186871A1 - Resin Composition for Hard Coating, Coated Product and Surface-Coated Vessel and Process for Producing Same - Google Patents

Resin Composition for Hard Coating, Coated Product and Surface-Coated Vessel and Process for Producing Same

Info

Publication number
CA2186871A1
CA2186871A1 CA2186871A CA2186871A CA2186871A1 CA 2186871 A1 CA2186871 A1 CA 2186871A1 CA 2186871 A CA2186871 A CA 2186871A CA 2186871 A CA2186871 A CA 2186871A CA 2186871 A1 CA2186871 A1 CA 2186871A1
Authority
CA
Canada
Prior art keywords
coated
group
meth
hard coating
resin composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2186871A
Other languages
French (fr)
Other versions
CA2186871C (en
Inventor
Hajime Inagaki
Koji Yoshii
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Hajime Inagaki
Koji Yoshii
Mitsui Petrochemical Industries, Ltd.
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hajime Inagaki, Koji Yoshii, Mitsui Petrochemical Industries, Ltd., Mitsui Chemicals, Inc. filed Critical Hajime Inagaki
Publication of CA2186871A1 publication Critical patent/CA2186871A1/en
Application granted granted Critical
Publication of CA2186871C publication Critical patent/CA2186871C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G06—COMPUTING; CALCULATING OR COUNTING
    • G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K7/00—Methods or arrangements for sensing record carriers, e.g. for reading patterns
    • G06K7/10—Methods or arrangements for sensing record carriers, e.g. for reading patterns by electromagnetic radiation, e.g. optical sensing; by corpuscular radiation
    • G06K7/10544—Methods or arrangements for sensing record carriers, e.g. for reading patterns by electromagnetic radiation, e.g. optical sensing; by corpuscular radiation by scanning of the records by radiation in the optical part of the electromagnetic spectrum
    • G06K7/10554—Moving beam scanning
    • G06K7/10594—Beam path
    • G06K7/10683—Arrangement of fixed elements
    • G06K7/10693—Arrangement of fixed elements for omnidirectional scanning
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106—Esters of polycondensation macromers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]

Abstract

A surface-coated vessel or a surface-coated product having a hard coating layer is obtained, by coating a 6ubstrate of, for example, resin product with a resin composition for hard coating which comprises (a) a poly[(meth)acryloyloxyalkyl] (iso)cyanurate represented by the following general formula (1) or (2):
... (1) ... (2) wherein X1, X2 and X3 are each an acryloyl group, methacryloyl group, hydrogen atom or an alkyl group, with a proviso that at least two of them are (meth)acryloyl groups, and R1, R2 and R3 are each an oxyalkylene group or a polyoxyalkylene group;
(b) a poly(meth)acrylated polyoxyalkane polyol;
(c) a photopolymerization initiator consisting of 2-methyl-1-[4-(methylthio)phenyl]-2-morpholino-1-propan-one;
(d) a photopolymerization initiator based on thioxanthone;

(e) a UV-absorber based on monohydroxybenzophenone;
(f) an organic solvent.
Such surface-coated coated products and vessels have a hard coat which is more excellent than that of the prior art especially in the curing characteristics, such as the rate of curing etc., as well as in the coating properties, such as surface hardness, fastness to scratch and abrasion, flexibility, surface gloss, heat resistance, fastness to solvents and to alkali, weather resistance and tight adhesion onto substrates, so that they can constitute reclamable coated products in a form of, for example, returnable bottles.
CA002186871A 1995-02-01 1996-01-29 Resin composition for hard coating, coated product and surface-coated vessel and process for producing same Expired - Fee Related CA2186871C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP15455/1995 1995-02-01
JP1545595 1995-02-01
JP1545495 1995-02-01
JP15454/1995 1995-02-01

Publications (2)

Publication Number Publication Date
CA2186871A1 true CA2186871A1 (en) 1996-08-08
CA2186871C CA2186871C (en) 1999-02-23

Family

ID=26351600

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002186871A Expired - Fee Related CA2186871C (en) 1995-02-01 1996-01-29 Resin composition for hard coating, coated product and surface-coated vessel and process for producing same

Country Status (6)

Country Link
US (2) US5693390A (en)
EP (1) EP0754736B1 (en)
BR (1) BR9603961A (en)
CA (1) CA2186871C (en)
DE (1) DE69610669T2 (en)
WO (1) WO1996023842A1 (en)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69637356T2 (en) * 1996-11-01 2008-10-30 Laboratoires Choisy Ltee, Louisville COATING OR SEALING COMPOSITION
US6312765B1 (en) * 1998-09-04 2001-11-06 Dukeplanning & Co., Inc. Method for repairing the coated surface of a vehicle
WO2000064597A1 (en) * 1999-04-28 2000-11-02 Ecolab Inc. Polymer surface coating made by coalescing polymer particulate with a coalescing agent
AU5149500A (en) * 1999-05-20 2000-12-12 Sport Court, Inc. Method and apparatus for coating a floor tile
ES2386297T3 (en) * 1999-07-22 2012-08-16 Diversey, Inc. Use of lubricant composition to lubricate a conveyor belt
US6427826B1 (en) 1999-11-17 2002-08-06 Ecolab Inc. Container, such as a food or beverage container, lubrication method
US6495494B1 (en) * 2000-06-16 2002-12-17 Ecolab Inc. Conveyor lubricant and method for transporting articles on a conveyor system
DE60017952T2 (en) 1999-08-16 2005-12-29 Ecolab Inc., St. Paul Method for lubricating containers transported on conveyor belt
US7384895B2 (en) * 1999-08-16 2008-06-10 Ecolab Inc. Conveyor lubricant, passivation of a thermoplastic container to stress cracking and thermoplastic stress crack inhibitor
DE19942534A1 (en) 1999-09-07 2001-03-08 Henkel Ecolab Gmbh & Co Ohg Lubricants containing fluorine
US7364033B2 (en) * 1999-11-17 2008-04-29 Ecolab Inc. Container, such as a food or beverage container, lubrication method
US6806240B1 (en) 2000-08-14 2004-10-19 Ecolab Inc. Conveyor lubricant, passivation of a thermoplastic container to stress cracking, and thermoplastics stress crack inhibitor
US6576298B2 (en) * 2000-09-07 2003-06-10 Ecolab Inc. Lubricant qualified for contact with a composition suitable for human consumption including a food, a conveyor lubrication method and an apparatus using droplets or a spray of liquid lubricant
US6509302B2 (en) 2000-12-20 2003-01-21 Ecolab Inc. Stable dispersion of liquid hydrophilic and oleophilic phases in a conveyor lubricant
US20040058089A1 (en) * 2001-10-10 2004-03-25 Sport Court, Inc. Floor tile coating method and system
US6562414B2 (en) 2001-10-10 2003-05-13 Sport Court, Inc. Method of coating polyolefin floor tile
US7364091B2 (en) 2003-12-19 2008-04-29 Scientific Games International, Inc. Embedded optical signatures in documents
US7748177B2 (en) 2004-02-25 2010-07-06 Connor Sport Court International, Inc. Modular tile with controlled deflection
US7849642B2 (en) 2004-03-12 2010-12-14 Connor Sport Court International, Inc. Tile with wide coupling configuration and method for the same
US8407951B2 (en) 2004-10-06 2013-04-02 Connor Sport Court International, Llc Modular synthetic floor tile configured for enhanced performance
US8397466B2 (en) 2004-10-06 2013-03-19 Connor Sport Court International, Llc Tile with multiple-level surface
KR20070084102A (en) 2004-10-28 2007-08-24 사이언티픽 게임스 인터내셔널, 아이엔씨. Lottery game played on a geometric figure using indicia with variable point values
JP2008526374A (en) 2005-01-07 2008-07-24 サイエンティフィック ゲイムズ インターナショナル インコーポレイテッド Lottery game using nostalgic game theme
US7662038B2 (en) 2005-01-07 2010-02-16 Scientific Games International, Inc. Multi-matrix lottery
US7824257B2 (en) 2005-01-11 2010-11-02 Scientific Games International, Inc. On-line lottery game in which supplemental lottery-selected indicia are available for purchase
US8262453B2 (en) 2005-02-09 2012-09-11 Scientific Games International, Inc. Combination lottery and raffle game
USD656250S1 (en) 2005-03-11 2012-03-20 Connor Sport Court International, Llc Tile with wide mouth coupling
US7745381B2 (en) 2005-03-15 2010-06-29 Ecolab Inc. Lubricant for conveying containers
US7741257B2 (en) 2005-03-15 2010-06-22 Ecolab Inc. Dry lubricant for conveying containers
US7874902B2 (en) 2005-03-23 2011-01-25 Scientific Games International. Inc. Computer-implemented simulated card game
US20060228506A1 (en) * 2005-04-11 2006-10-12 Lin A P Abrasion resistant composite material structure
EP1874418A1 (en) 2005-04-27 2008-01-09 Scientific Games International, Inc. Game apparatus
US7654529B2 (en) 2005-05-17 2010-02-02 Scientific Games International, Inc. Combination scratch ticket and on-line game ticket
US7727941B2 (en) * 2005-09-22 2010-06-01 Ecolab Inc. Silicone conveyor lubricant with stoichiometric amount of an acid
US7915206B2 (en) * 2005-09-22 2011-03-29 Ecolab Silicone lubricant with good wetting on PET surfaces
US7741255B2 (en) * 2006-06-23 2010-06-22 Ecolab Inc. Aqueous compositions useful in filling and conveying of beverage bottles wherein the compositions comprise hardness ions and have improved compatibility with pet
JP4986903B2 (en) * 2008-03-26 2012-07-25 株式会社トクヤマ Manufacturing method of plastic lens
GB2469498B (en) * 2009-04-16 2012-03-07 Cambridge Display Tech Ltd Polymer and polymerisation method
US9200107B2 (en) * 2009-10-26 2015-12-01 Ppg Industries Ohio, Inc. Coating compositions and methods for using the same as a spot blender
US8460081B2 (en) 2010-05-14 2013-06-11 Scientific Games International, Inc. Grid-based multi-lottery game and associated method
US8808080B2 (en) 2010-05-14 2014-08-19 Scientific Games International, Inc. Grid-based lottery game and associated method
BR112013006087B1 (en) 2010-09-24 2019-05-14 Ecolab Usa Inc. METHODS FOR LUBRICATING THE PASSAGE OF A CONTAINER ALONG A CARRIER.
EP2969864A4 (en) 2013-03-11 2016-08-31 Ecolab Usa Inc Lubrication of transfer plates using an oil or oil in water emulsions
CN116515327A (en) * 2018-07-02 2023-08-01 苏州科硕住宅科技有限公司 Nano ceramic composite coating, preparation method thereof and waterproof disc
CN113423513B (en) * 2019-02-06 2023-08-15 日产化学株式会社 Light-resistant hard coating curable composition
EP3892599A1 (en) * 2020-04-06 2021-10-13 Duravit Aktiengesellschaft Sanitary article

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2038208B (en) * 1978-11-20 1983-05-11 Yoshino Kogyosho Co Ltd Saturated polyester bottle-shaped container with hard coating and method of fabricating the same
US4515836A (en) * 1982-07-16 1985-05-07 Nordson Corporation Process for coating substrates with aqueous polymer dispersions
JPS5925840A (en) * 1982-08-05 1984-02-09 Mitsui Petrochem Ind Ltd Curable resin composition for coating
JPS607931A (en) * 1983-06-24 1985-01-16 Suriibondo:Kk Preparation of microcapsule
US5145885A (en) * 1983-08-15 1992-09-08 Ciba-Geigy Corporation Photopolymerizable compositions containing aminoaryl ketone photoinitiators
JP3084690B2 (en) * 1991-03-15 2000-09-04 ジェイエスアール株式会社 Method for producing polymer

Also Published As

Publication number Publication date
EP0754736A4 (en) 1997-09-24
US5693390A (en) 1997-12-02
CA2186871C (en) 1999-02-23
DE69610669D1 (en) 2000-11-23
DE69610669T2 (en) 2001-05-03
US5789459A (en) 1998-08-04
EP0754736A1 (en) 1997-01-22
MX9604202A (en) 1997-12-31
WO1996023842A1 (en) 1996-08-08
BR9603961A (en) 1997-10-07
EP0754736B1 (en) 2000-10-18

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