CA2150101A1 - Method and system for treatment of water and wastewater - Google Patents

Method and system for treatment of water and wastewater

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Publication number
CA2150101A1
CA2150101A1 CA 2150101 CA2150101A CA2150101A1 CA 2150101 A1 CA2150101 A1 CA 2150101A1 CA 2150101 CA2150101 CA 2150101 CA 2150101 A CA2150101 A CA 2150101A CA 2150101 A1 CA2150101 A1 CA 2150101A1
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CA
Canada
Prior art keywords
wastewater
cell
treatment
discharge cell
mixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA 2150101
Other languages
French (fr)
Inventor
Peter L. Timpany
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
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Publication of CA2150101A1 publication Critical patent/CA2150101A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/121Multistep treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/006Regulation methods for biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1263Sequencing batch reactors [SBR]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/308Biological phosphorus removal
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/22O2
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/44Time
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S210/00Liquid purification or separation
    • Y10S210/918Miscellaneous specific techniques
    • Y10S210/921Flow equalization or time controlled stages or cycles

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Microbiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Activated Sludge Processes (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

This substantially constant level biological wastewater treatment process and system enables efficient treatment of wastewater, combining the advantages and eliminating the disadvantages of both SBR and activated sludge processes. In the present case, wastewater continuously flows in one direction through a plurality of treatment cells hydraulically connected in series. The wastewater is subjected to biological treatment in at least one of the cells and settled in at least one last treatment and discharge cell, immediately prior to discharge from the system. In subsequent steps, the wastewater may continue to be fed into the system at the same location while the discharge from the last cell is temporarily closed, the mixing aeration device therein is turned on to re-suspend the settled mixed liquor suspended solids and provide additional treatment, a transfer pump therein is turned on to transfer the mixed liquor suspended solids and co-mingled partially treated wastewater back to a previous treatment cell, and at the completion of the transfer step the mixing aeration device is turned off to once again allow settling of biological solids prior to once again discharging treated wastewater on a continuing basis. Mixed liquor suspended solids flow in the same general direction as the wastewater but always receive at least partial transfer back to a prior treatment cell, settling and separation of the remaining solids from the wastewater prior to discharged of treated wastewater from the last cell. Preferred embodiments of the invention include continous discharge and essentially completely constant level operation by use of two discharge cells alternatively and treatment of soluble and particulate contaminants as well as biological removal of nitrogen and phosphorus.

Description

215~101 METHOD AND SYSTEM FOR TREATMENT OF WATER AND WASTEWATER
This invention relates to a method and a system for treatment of water and wastewater. More specifically, the method and system of the present invention are designed for the biological removal from wastewater of contamination in the form of solids and soluble organic material, and optionally the biological removal of nitrogen and phosphorus nutrients.
The biological treatment of sewage and other apparatuses for effecting such treatment are described in United States Patents Nos. 2,907,463, issued to D.J.N. Light et al on October 6, 1959; 3,964,998, issued to J.L. Bernard on June 22, 1976; 4,279,753 issued to N.E. Nielson et al on July 21, 1981; 4,430,224, issued to U. Fuchs on February 7, 1984; 4,468,327 issued to A.D. Brown on August 28, 1984;
4,522,722 issued to E.M. Nicholas on June 11, 1985;
4,663,044 issued to M.C. Goronszy on May 5, 1987; 4,798,673 issued to C. Huntington on January 17, 1989; 204,867,883, issued to G.T. Daigger on September 19, 1989; 4,948,510 issued to M.D. Todd et al. on August 14, 1990; 5,013,441 issued to M.C. Goronszy on May 7, 1991; and in Canadian Patents Nos. 997,488, issued to B.K. Tholander et al. on September 21, 1976 and 251,117,042, issued to M.L. Spector on January 26, 1982.
In general, suspended growth activated sludge SUB~ JTE SHEtI

. ~

WO95/09130 215 0 1~1 PCT/CA~1'0r~4~

processes and mcdifications thereto have recently been shown to be able to accomplish the objectives set out above, but the costs of specialized clarifiers required to settle and recycle biological solids is quite high. Moreover, the size, complexity and operating problems encountered with such systems make them unattractive to potential users. In addition, the basic activated sludge process often results in poor treatment because of the continuous flow through characteristics in the final clarifier and the resulting constant sludge management requirements.
As a consequence of the foregoing, duriny the past ten years improved final clarification and solids removal has been sought by using larger and improved but more complex and expensive designs for final clarifiers. Moreover, final effluent filtration is often necessary to reliably meet permitted environmental standards.
There has also been a recent revival of interest in the sequencing batch reactor (SBR) suspended growth activated sludge process because of the inherently more efficient 0 batch organic contaminants removal than is possible with the conventional continuous flow activated sludge process.
The SBR process uses the same vessel for batch aerated biological reaction and quiescent batch settling. Thus, the SBR process eliminates the major cost of dedicated ~inal ~5 clarifiers necessary for the conventional activated sludge S~JB~ 11 1 ~JTE SHEET

21501û1 process as well as improving upon solids removal performance.
However, the SBR process has several disddvantages, the principle one heing that it does not operate with a 5 constant level and continuous flow, but requires intermittent operation for cycles of fill, react, settle, decant and idle. Typical level fluctuations are 30% to 50%
of the maximum operating depth or as much as ~ to 10 feet of level fluctuations. The result is a much lower use to total volume ratio than the conventional activated sludge process.
Accordingly, the SBR process is generally not cost effective for flows greater than five to ten million gallons per day (MGD).
Another disadvantage of the SBR process is that significant head loss occurs from the influent to the final effluent, requiring additional energy and pumping costs.
Additionally, because the effluent flow is not continuous, flow equalization systems may be required to prevent peak loadings and adverse impacts on receiving waters.
~0Finally, the basic process and design limitations of the SBR process make it difficult to achieve the same high efficiency biological nutrient removal possible using the continuous flow activated sludge process, especially for weak or colder waters.
~5Several improvements have heen attempted tv overcome the SU~ UTE SHEE

W095/09130 21 S O 1~ PCT/CA94/OOS44 limitations of the conventional activated sludge process. A
continuous inflow, partitioned SBR process Patent ~o.
4,468,3~7 was issued to A.D. srown on August ~8, 1984, and c~clicall~ operated intermittent flow path sequential c~cle, multi-zoned recycle SBR process Patents ~ 4,663,044 and 5,013,~41 were issued to H.G. Goronszy on May 5, 1987 ~nd May 7, 1991, respectively. Significant level fluctuations, head losses and intermittent high flow rate discharges, however, still prevent these processes from overcoming all the limitations of the conventional SBR process.
Attempts have also been made over the years to overcome the level variation limitations of all SBR type processes and the cost of dedicated final clarifiers for the conventional activated sludge process. The Degremont S.A.
U.S. Patent No. 3,470,092 issued to J.J.P. Bernard on September 30, 1969 illustrates a first attempt to develop a new suspended growth activated sludge process utilizing the concepts of both batch treatment and continuous flow. This two cell process was partially interconnected at the water ~0 surface. The alternate cell feed concept was not effective because it did not achieve a high treatment efficiency, had a low aerator utilization factor, and required long detention times to operate resulting in e~pensive systems.
nion ~arbide U.S. Patent No. 4,179,366 issued to J.R.
~5 Kaelin on December 18, 1979 added a third bottom SUBs ~ JTE SHEET

21~01Q~ -WO95/09130 PCT/CA9~CC~l interconnected cell, hut also suffered from low treatment efficiency and ineffective ~hanyeover of untreated wastewater wastewater from the first cell to the third cell.
The processes disclosed by both patents also required significant level fluctuations in the treatment cells between operating cycles which made it difficult to control flows and operate fixed, level sensiti~e mechanical aeration systems.
Linde AG German Patent No. 3,147,920 issued on October 13, 1983 utilized the same three cell concept as U.S. Patent No. 4,179,366. Although this three cell process achieved a more constant level, and overcame some of the limitations of the prior art, the process failed because it relied on expensive and unreliable mechanical gates to separate the treatment cells at various cycle times, and because treatment efficiency and effectiveness was too low to be commercially useful.
VOR SA French Patent No. 255052~ issued on February 15, 1985, describes another constant level apparatus including three separate, identical basins. The process required a large, expensive treatment system because three independent basins were required, and only 1~3 of the total treatment volume was used for biological treatment at any time, and only 1~3 of the aeration equipment could he used at one time.

SUB~ 11 1 IJTE SHEET

~ 7,, ~
i 'i~ ' _ WO95109130 215 01 ~ ¦ PCT/CA~'C~

In spite of these attempts to improve on the performance and effectiveness of the SBR conventional activated sludge processes, they do not provide a higher treatment efficiency and hence they are not significantly most cost efective. Such attempts have either failed to totally achieve the desired benefits, or have new inherent disadvantages which result in little or not benefits compared to conventional methods.
All these attempts to develop constant level processes to improve on the conventional suspended growth activated sludge process, rely on the management control and recycle of mixed liquor suspended solids by back flushing or forward flushing through or around the treatment system by control of the timing and direction of wastewater flow into and through the treatment system. These methods vf solids management differ significantly from variable level SBR's, and also differ from the constant level conventional activated sludge process, which settles the mixed liquor suspended solids in a dedicated final clarifier to collect ~0 and recycle the resulting activated sludge back to the aeration basin.
In contrast, this present inventivn relies on biological solids management hy a novel substantially constant level wastewater treatment method and system in 5 which mixed liquor suspended solids are positively SUB~ ~ JTE SHEE

2ls~lal WO 95/09130 . ~ r~ PCT/CA94/00544 transferred alternatively from at least one last treatment dis~harge ~ell to a previous ~lydraulically connected treatment cell simultaneously with the ~o-mingled partially treated wastewater, while being subjected to mixing prior to each last cell sequentially functioniny nnce again as a quiescent clarifier for discharge of final treated effluent.
The novel treatment method and system makes it possible to achieve many worthwhile objectives to significantly increase the usefulness and lower the cost of wastewater treatment.
The principle object ~f the present invention similar to the objective of applicant's co-pending ~nited States Patent Application No. 07/963,~78, filed October 19, 1992, is to provide a method and a system which maintains the benefits of the sequencing batch reactor (SBR) process while eliminating the disadvantages.
Another object of the invention is to eliminate the disadvantages of prior art attempts to improve ~n SBR and conventional activated sludge processes by achieving ~0 greater utilization and effectiveness of the aeration systems, maintaining a constant level or requiring only small hydraulic level changes, and thus increasing the oxygen transfer efficiency of the aeration systems, and not exceeding aeration power per unit volume limitations as it 2S is common with some process designs to date, ma~ing possible SUB~ I I I UTE SHEET

WO95/09130 215 01~1 PCTICA9~/00544 the use of a fixed level ~ischarge weir flow control systems and continuous flow in, through, ~nd out of a treatment system at all times.
Another object of the invention is to provide a process that is capable of achieving a high treatment efficiency and a system which is simple to design, construct, operate and maintain, while being more cost effective than either SBR or conventional activated sludge processes for either small or large flows up to 100 MGD or greater.
1 n Another object of the invention is to provide a low cost method and a treatment system facilitating biological nitrogen and~or phosphorus nutrient removal even for weak (e.g. dilute) or colder wastewaters as is possible, but at high costs, by use of advanced nutrient removal activated sludge processes.
Another another object of the invention is the use of a single basin for treatment to eliminate the inefficient land use, costs, and ~omplexity of treating wastewaters in a plurality of separate hydraulic structures as required by ~0 SBR and conventional activated sludge processes to date.
Another obje~t of the invention is to make possible a low cost modification of existing aerated basins or lagoons to convert them to a higher treatment efficiency activated sludge process style ~f treatment, either by use of "on-the-5 run" modifications or by simple éxpansion of th~ aerated-- 8 SUB~ I I I ~JTE SHEET

215~101 basins or lagoons.
Yet another object of the invention is to be able to operate at low or high food to micro-organism ratios and at low to high hydraulic retention times, depending on the sludge age and resulting waste sludge production rate selected hy a designer, as well as being able to operate for a specific system with ]ow food to micro-organism ratio variations and hence making possible optimized system process operations and minimum ~reated effluent variations.
A final object of the invention is to make possible the use of a single dedicated inlet location for introducing untreated wastewater into the treatment system like the conventional activated sludge process and to eliminate the operating complexity and cost of multiple controls and facilities needed to direct untreated wastewater to different treatment cells or hold back flows within the system at different time periods as is common with SBR type processes.
In accordance with one aspect, the invention relates to ~0 a method of biologically treating wastewater by a modified activated sludge process comprising the following steps:
feeding the wastewater at a dedicated single inlet position to a first treatment cell so the wastewater flows in the same direction through a plurality of treatment cells hydraulically ~5 connected in series; subjecting the wastewater to .~eration SUB~ ~ JTE SHEET

WO95/09130 215 010 i PCT/CA94/00544 mixing and hiological treatment ln at least one cell;
settling the mixed liquor suspended ~olids in the wastewater and discharge of treated wastewater from at least one ~last) treatment discharge cell while the aeration mixing mean.s is turned off so that the settled mixed liquor suspended solids remains in the treatment systems; transferring mixed liquor suspended solids and cv-mingled partially treated wastewater back to at least one previous cell to provide biological treatment therein while the discharge from the treatment discharge ~ell is t~losed and the aeration mixing means therein is turned on to re-suspend the settled mixed liquor suspended solids; and at the completion of the solids transfer step recommencing discharge of treated wastewater from the (last) discharge cell after final (batch) wastewater polishing treatment hy aeration mixing and pre-settling of mixed liquor suspended solids has been completed. The method includes recycle of partially treated wastewater and biolc.gical solids contained in the mixed liquor suspended solids and a method of controlling the ~0 schedule of treated wastewater being discharged from the system in a fixed pattern selected to achieve the treatment objectives. Achieving a substantially constant water level is possible by using only one last cell for lvng hydraulic retention time systems. ~ method of achieving a ~5 substantially constant level o~ operation with the invention SUB~ ~ JTE SHEE r 215~
WO95/09130 '~ PCT/CA94/00544 for even short hydraulic retention time ~ystems includes controlling the flow out cf two (last) treatment discharge cells, ~oth of which are hydraulically connected to the first ~ell, so that they discharge alternatively.
In accordance with a second aspect, the invention relates to a system for biological treatment of wastewater comprising at least two cells or zones in a basin wherein one (first) cell is a feed cell pro~ided with inlet means for introducing wastewater; all cells are hydraulically connected in series from the feed ~ell to the discharge cell(s), and are typically pro~7ided with aeration mixing means ~o biological treatment and mixing can be provided to the wastewater in all cells; at least one (last) treatment discharge cell is provided with on-off control means for its aeration mixing means, outlet flow control means for discharging treated wastewater out of the treatment system after the aeration mixing means is shut off to allow pre-settling of mixed liquor suspended ~olids, .~nd ~ transfer means to transfer mixed .liquor suspended 501ids and ~0 partially treated wastewater hack to a prior treatment cell while said aeration mixing means is turned ~n; and the entire treatment system may be operated automatically by providing a central flow control means to direct the flow through and out of the treatment hasin and to control the ~5 on-off schedule for said aeration mixing means, said WO95/09130 21 5 01 J I ~ PCT/CA9~.~^C~1 discharge flow control means and said transfer means to transfer mixed liquor suspended solids and partially treated wastewater back to the previous cell. Two or more last cells.
are provided for short hydl-aulic retention time systems in order to achieve substantially constant level operation.
The invention will be described in greater detail, with reference to the accompanying drawings, which illustrate preferred embodiments of the system of the present invention, and wherein:
Figure la is a schematic flow diagram of a two cell long hydraulic retention time system for providing biological treatment of wastewater solids and soluble organic material in accordance with the present invention;
Figure lb is a schematic flow diagram of a three cell system for long or short hydraulic retention times to provide biological treatment of wastewater solids and soluble organic material in accordance with the present invention;
Figure lc is a schematic flow (~liagram of a four cell system with two mirror image Figure la embodiments operating on an integrated basis in accordance with the present invention;
Figure ~ is a schematic flow diagram of a four cell system for providing a higher treatment efficiency for ~5 difficult to treat wastewater in accordance with the present SUB~ 1 1 I LITE SHE~, 21501~1 .~ .; `
WOs5/09130 ~ Y,~ PCT/CA94/00~44 invention;
Figure 3 is a schematic flow diagram of a si~ cell system suitable for ~lso providing nitrogen removal in accordance with the present invention;
Figure 4 is a schematic flow diagram of ~ si~ cell system suitable for also providing biological phosphorus as well as nitrogen removal in accordance with the present invention.
~eferring to Figure la, the most basic embodiment of the present invention includes two cells or ~ones in one basin capable of ~eceiving constant inflow ~nd maintaining a substantially constant operating level for long hydraulic retention time systems. The untreated wastewater may be continuously introduced into Cell 1 via inlet pipe 2 at inlet 3 and flow continually out of Cell 1 through free hydraulic connection(s) at 31 to treatment discharge cell 20. The treatment discharge cell ?O iS hydraulically and may be alway~ unhinderedly and freely connected to cell 1 at 31. Cell 0 also is preverably less than one-half and ~0 typically ~S-40-O or less of the volume of the total treatment system. To obtain the most effective ~peration of cell 20, the hydraulic connection 31 may be multiple openings or an opening across the entire width of cell 20 near the top or bottom water level as used in conventional 5 ~larifier influent (~istribution sy~tems. Similarl~T, - ~3 -SU~ 11 1 I_ITE SHEET
2 15 01 0 i PCTJCA94/00544 discharge low control means ~l would c~ptimallv removetreated wastewater across the entire width of cell 20. The treated wastewater is discharged on a continuing basis through flow control means 1l vi~ outlet pipe 42 except for brief solids transfer and settling periods as discussed below. Flow ~ontrol means 41 can be provided hy flow control weir means as disclosed in applicant's co-pending United States patent application serial number 07f963,479, filed October l9, 1992, fixed level weirs and commercially available discharge flow control means or lonventional control val~-es connected to discharge pipe ~. Because the inventi~n operates at a substantially constant level the use of ronventional fixed level weirs and flow control valves can be utilized, which reduces the capital cost and improves operations by requiring less mo~ing equipment than necessary for variable level SBR decanters. The aeration mixing means 51 in cell l typically supplies the majoritv of the oxygen and mixing necessary to achieve comp1ete biological treatment of the wastewater by contact of the untreated wastewater with the mixed liquor suspended solids recycled from cell 20. The aeration mixing means 51 in eell operates continuously which makes possible higher aerator utilization than possib~e with SBR systems. The aeration mixing means 58 in cell 20 is shut off during discharge of ~ treated wastewater out of the system by outlet pipe 42. In SUB~ UTE SHEE

~- 2 1 5 0 ~ ;d' 1, WO95/09130 ~`~ PCT/CA94/00544 ~rder to achieve maximum wastewater -treatment efficiency, the discharge out of cell ?O ~f partially treated wastewater received from cell l through 31 can be prevented by control of the length of time of discharge out of 41 and ~S so the -1 lag time ~etween the input and output of flow received in cell 20 is not exceeded. If lower treatment efficiency is acceptable, naturally said lag time can be exceeded as appropriate within the system operating limitations.
When the mixed liquor suspended solids from ~ell accumulate by settling in cell ~0 sufficiently to require removal, the following operating steps are used: the discharge flow control rneans 41 is closed for a short period and the aeration mixing means 58 turned on by the central control unit (not shown). A variety of commercially availa~le, programmable logic controllers (PLC's) can be used to control all operating steps of the process similar to the control units used for conventional SBR processes.
After re-suspension of the mixed liquor suspended solids, a portion of the mixed liquor suspended solids in ~0 cell 0 and co-mingled partially treated wastewater are pumped through pipe 70 by solids transfer pump 71 back to cell l at inlet 7~. This partial solids transfer ensures continuing high biological solids in cell l and sufficient biological solids remaining in cell ~0 for additional ~5 polishing of ~artially trea~ed wastewater transferred into SUB~ 11 1 UTE SHEEl-WO95/09130 2 1~ PCTICA~ G5~1 cell 20 from cell l prior to once again discharging treated wastewater out of cell ~0 by opening flow control means 11.
The rate and duration of flow by transfer pump 71 is also selected to ensure that the accumulation of mixed liquor S suspended solids in cell ~0 is not too high to prevent effective treatment cycles to achieve a substantially constant water level as discussed below. An essential part of this step of the process is the mixing ,~ccomplished by aeration mixing means 58. It is noted that for some applications with low cxygen demand in the final cell 20, the use of just mixing means in cell 20 is possible (e.g.
aeration may be eliminated and just mixing means used to re-suspend the mixed liquor suspended solids).
When sufficient mixed liquor suspended solids have been transferred out of cell ~0 back to cell l, solids transfer pump 71 is shut off by the central control unit, and aeration mixing means 58 remains on for a brief period if required to provide final hatch polishing treatment for the partially t7-eated wastewater in cell ~0. At the ~ompletion ~0 of this final polishing treatment step in cell ~0, the aeration mixing means 58 is shut off ~y the control unit, and ~ell ~0 mixed liquor suspended solids are provided a predetermined pre-settling time prior to reopening of flow control means 41 and treated wastewater once again is 5 discharged on a continuing basis out ~f the treatment system SUB~ I ~ I LJTF SHEET

OE wo 95/09130 2 1 5 A, via 42.
The above steps are repeated in recurring cycles toprovide continuous wastewater treatment as directed by the central control unit at regular time or flow ~7O1ume intervals or when biological solids fl-o~ cell 1 have accumulated sufficiently in cell ~0 to require removal ~y transfer back to cell 1.
The means to achieve a substantially constant level operation and minimize the head loss of wastewater flowing through the system for this embodiment is to use a high rate of solids transfer and flow through pump 71 so the duration of zero discharge through flow control means 41 is minimized. Typical transfer flow rates would be 3 to 6 or more times the average flow into the treatment system and discharge out of 41 would occur typically 70-80% of the time for this embodiment.
Achieving a substantially constant operating level for Figure la embodiment of the invention is most effective for long hydraulic retention time systems. Level variations of ~0 less than 1 foot are desirable, and preferably less than 3 -6 inches and optimally less than 1 - 2 inches in order to achieve the most efficient oxygen transfer rates, effective use of fixed mounted aerators and also mixed liquor suspended solids settling in the last cell durin~ the long ~5 treated wastewater discharge peri~ds of up to 90~ ~,f the SUB~ 11 1 ~JTE SHEET

`f''"~ " ,. C,',.~
WO95/09130 2 1 5 O` i 0 i PCTICA94/00544 time each day. Substantially, constant operatiny levels are possible compared with typicall~ 5 - 10 feet for SBR
processes. However, for relatively short hydraulic retention time systems, e.g. retention times of less than approximately ~4 hours, substantially constant level operation is not easily achieved by the basic embodiment of the invention as illustrated in Figure la.
The means to essentially eliminate significant operating level fluctuations for any hydraulic retention time and also virtually eliminate the head loss of wastewater passing through the treatment system is to use a second treatment discharge cell as shown in ~igure lb with a similar hydraulic connection means 131 and 132 to the treatment discharge cells 1 0 and 121 respectively, a~ for cell 20 connection to cell 1 at ~1 in Figure la. Figure lb has similar aeration mixing, solids transfer and discharge flow control means as for the embodiment of Figure la. The second treatment discharge cell 121 operates with solids transfer ~t 180 through pump 181 and discharge to cell 101 at 182, and has identical operating steps as used for cell 20 2n in Figure la, except said second treatment discharge cell 121 discharges treated effluent through flow control means 141. The result of this second preferred embodiment is d continuous flow into the system inlet 102 ~nd essentially e~ual flow out of the total treatment system through outlet 5 115 at ~ll times fc)r long or short hydraulic retention time SUB~ JTE SltEET

~` 21501~1 WO95/09130 ~ PCT/CA94/00544 't i':~ .
systems. Another ~enefit of this embodiment is by use oftwo lower flow rate transfer pumps 171, 181 working alternatively from the two last cells 1 0, 121, respectively, the rate of transfer of biological solids back to the pre~ious cell 101 would be more consistent and hence the food to micro-organism ratio in prior cells 101 would also be more consistent. In combination these two factors result in a more controlled process unlike SBR variable process conditions and thus makes possible optimized treatment system design, operation, and consistently high treatment efficiency.
All vther operations means ~f Figure lb system and operating methods used are similar to the equivalent means and system methods of Figure la. Each equivalent means of operation is designated by the same number as that used in Figure la plus 100 i.e. 2 is 102, 3 is 103 etc., and for Figure 3, 2 is 302, ~03 is 303, etc. and for Figure 4, 2 is 402, and 3 is ~03, etc.
Continuous discharge and constant operating level can ~0 also be achieved for long or short hydraulic detention time systems by using two ~or more) identical Figure la complete systems operating in parallel, as shown in Figure lc. The treatment system means in Figure lc mirror image of Figure la embodiment are designated as cell 1', as for cell 1 in Figure la, aeration mixing means 58' as for 58 in Figure 1~ cell 1, SUB~ ~ JTE SHEET

WO95/09130 2 1 ~ O 1 ~ 1 PCT~CA~ c~1 aeration mi~ing means 58 respectively and so vn, for those components performing the same functions. The result of this third preferred embodiment is that each side of the system would operate with no flow out of one of the treatment discharge cells 20 or 20' during operation of the other parallel system's treatment discharge cell ~0', ~0, respectively. To obtain maximum utilization of the aeration mixing means of this third preferred embodiment, untreated wastewater may ~e introduced constantly into each first cell and the solids may he transferred at least in part, from the last cells ?~ and ~0' to feed cells 1' and 1 respectively, through recycle system 83, 84, 85 and recycle system 83', 84', 85~, respectively, instead of only to the feed cells hydraulically connected in series to each discharge cell.
Alternatively, a common wall valved hydraulic connection (not shown) between cell 1 and cell 1' can be used to maintain a constant untreated wastewater flow into cells 1 and 1'. This third embodiment also has the benefit of ~acilitating the operation of one parallel system independentl~- during ~0 inspection or maintenance down time on the other yarallel system. Using parallel systems would also make it possible to ~ontrol the flow through the identical parallel embodiments of the invention hy use vf flow control means on the influent to each system instead of controlling the flow out of each system. This flow ~ontrol method is suited for certain - 2~ -SUB~ 1 1 1 UTE SHEE~

.

~' 21t~ 01~ 1 appli.cations, however, has reduced aerator utilization factors and ].ess precise discharge timin~ as a result of slowly reducing flo~s out of discharge ~ells after t.he influent flow is diverted.
Another use of the invention which would be capable of continuous flow and constant operating level wou3.d be to utilize at least two large, equal sized treatmer,t discharge cells, operated identically as cells 120 and 121 above, and to feed untreated wastewater into a very small common hydraulically connected first feed cell. Such a use of the invention would not be most t~ost effe~tive, however, ~ecause of the inefficiencies of utilizing onl- about 50% of the aeration mixing means at one time. Such inefficienci~s could be largely eliminated, however, by use of a say 4 or more equal sized treatment discharge cells each used alternatively like cells 1~0 and 121, resulting in approximately 7S% or more aeration mi~ing means utilization at one time.
The system illustrated in ~igure 2 is similar to the system of Figure 1~, except that two cells 201 and 202 are provided with continuously operating aeration mixing means ~51 and 25~ respectively and have hydraulic connection means 231, 232 and 233 to allow wastewater to flow unhinderea through the system to the (last) treatment discharge cells ~5 220 and ~ 1. This configuration of the invention makes SUB~ I I I UTE SHEET

WO95/09130 2 i 5 0 1~ PCT/CAg4/00544 possible similar operation as that illustrated in Fiyure lb but provides for a higher degree of treatment efficiency by improved plug flow characteristics if necessary based on specific - wastewater characteristics and treatment 5 objectives. If even higher degrees of treatment efficiency are required and even further plug flow characteristics would be helpful, several additional treatment cells can be provided in series with cells 201 and 02.
The system illustrated in ~igure 3 provides for removal of soluble and particulate contaminants but also makes possible hi~h efficiency nitrogen removal by adapting conventional ~ctivated sludge nitrogen removal process concepts to achieve the specific additional benefits available by use of this invention. The principles of operation of this embodiment are similar to those illustrated in ~igure lb and Figure 2, except that transfer of mixed liquor suspended solids and co-mingled partially treated nitrified wastewater from cell 320 bac~ tc~ prior treatmen~, cells can be provided with preferably two solids 0 transfer pumps. The 371 and 37~ transfer pumps in ~igure 3 transfer mixed liquor suspended solids and co-mingled partially treated wastewater in whatever ratio is required from cell ?20 back to the first two cells 301 and 302 respectively, wherein the aeration means is turned off or ?5 reduced as r~quired for the aeration rnixing means 351 and SUB~ I ~ I UTE SHEET

~ 2150~1 WO95/09130 ~ ; PCT/CA9q~

352 respective~y. The resulting mixing means 351 and 352 thus provide little if any dissolved oxygen thus achieving anoxic conditions of typically not more than 0.5 mg/1 of ~issolved oxygen making possible biological dentrification of the wastewater in treatment cells 301 and 302 respectively. Alternatively, separate aeration means and mixing means can be provided in both these cells and used separately as required to achieve mixing and the dissolved oxygen concentration as required from time to time for optimized process operations. A lower degree of dentrification and process control can be achieved hy eliminating recycle ~olids transfer pump 374 and/or treatment cell 302. Likewise for certain high nitrogen wastewaters, and for the requirement of higher degree of treatment efficiency, additional dentrification cells may be added beyond the two cells 301 and 302, and the aeration means and mixing means in subsequent treatment cells may be operated sequentially for improved dentrification.
As for previous embodiments of the invention; a ~0 constant operating level and essentially zero head loss and constant inlet flow at 30~ and outlet flow at 345 can be achieved as shown in Figure 3 embodiment by providing a second ~last) treatment discharge cell 321 in addition to cell 3~n and operating in a similar manner dS for ~igure lb and Figure ~ embodiments. A mirror image independently SUB~ ~ JTE SHEET

WO95/09130 215 O 1~ 1 PCT/CA~

operated parallel systen can also ~e used as in Figure lc embodiment above to achieve a fully constant vperating level.
The system and operation of Figure ~ embodiment is similar to Figure ~ embodiment and operation except th~t Figure 4 embodiment provides a preferred embodiment of the invention which also achieves ~iological removal of phosphorus in addition to the removal of nitrogen, and treatment of soluble and particulate contaminants. Advanced activated sludge biological phosphorus removal process technologies, such a~ the University of Cape Town (11~T) process or the Modified l'~T (~UCT~ process, utilize pre-treatment anaerobic contact cell~s) having ~ dissolved oxygen concentration of typically less than 0.1 mg~1, in series with anoxic dentrification cell(s) having a dissolved oxygen concentration of typically less than 0.5 mgtl prior to aerobic treatment, nitrification, settling of mixed liquor suspended solids in dedicated clarifiers and return of the activated sludge to the anoxic cell(s) and a recycle ~0 from ano~ic cell(s) to the first anaerobic cell. This invention also can make improved, more cost effective use of these or other biological phosphorus removal technology concepts as illustrated in the Figure ~ em~odiment as follows: mixed liquor suspended solids transfer pump 474 ~5 recycles solids and co-mingled nitrified partially treated ~ ~ . 2 ~ ~0 ~
WO95/09130 - ~ PCT/CA~SJ~C~

wastewater from cel1 ~20 at 473 t~ achie~7e dentrification in anoxic cell 102, which is maintained ~, a dissolved o~ygen concentration typically of less than 0.5 mg/]. Pump 477 provides for recycle of mixed liquor suspended solids and co-mingled dentrified partially treated wastewater from ano~ic cell 4n2 at 476 to anaerobic cell 10l at 478 to optimize the operation of cell 401, which is maintained at dissolved oxygen con~entrations of typically less than 0.l mg/l. If ~reater treatment efficiency is required more cells can be used to incr*ase the number of anaerobic, anoxic or even aerobic treatment cells dS required. In addition selected ~ell aeration means and mixing means can be operated sequentially instead of continuously as required to improve the treatment efficiency of nutrient removal for l~ all embodiments of the invention.
Similar to the embodiments of the invention shown in Figures lb, ? and 3, the system as shown in the Figure 4 embodiment can achieve a fully constant operating level and essentially zero head loss throuyh the treatment system by providing a second (last) treatment discharge cell 42l to operate alternatively to cell 420 when no discharge is occurring through outlet flow control device 441. Other alternatives can also be used to achieve these objectives as discussed above.
For all embodiments of the invention, the necessary SUB~ I ~ I ~JTE SHEt I

WO95/09130 21~ O I O ~ PCT/CA94/00544 removal ~r wasting of excess solids can be accomplished by pumping of mixed liquor suspended solids from an intermediate aerobic cell prior to the last cell(s) at a ~ontinuous rate as required to achieve the treatment system's desired sludge age. .~lternatively, if pre-thickened settled sludge wasting is desired, intermittent wasting of excess solids can be achieved by pumping settled mixed liquor suspended solids from the (last) treatment discharge cell(s) during settling and solids ~ccumulation steps utilizing conventional sludge collection systems.
The result of use of tlle solids transfer pump(s) and the hydraulic connection means between th~ cells of all embodiments of the invention is a dynamic bi~logical solids inventory and wastewater flow pattern that circulates around and through each system, but the concentrations of solids and wastewater patterns can be predicted in advance using conventional mass balance and flow simulation methods. Using these methods in combination with conventional process l~inetic models makes poxsible solids management and accurate ~0 design predictions of treatment efficiency for any pre-characterized wastewaters treatable . with conventional activated sludge processes.
The net result of t.he present invention is a process and treatment system capable of achieving the most effective S food to micro-organism ratio ranges in all treatment cells, SUB~ JTE SHE~

' 2lsal0~
WO95/09130 - ~ PCTtCA94/00544 hence ~ consistentl~ high treatment efficiency in ~ single basin, with ~ continuous flow single inlet, and constant or substantiall- constant discharge flow capahilities at typical medium operating depths of 10 - 30 feet. The system can productively utilize essentially all of the available land area and treatment systems volume 100% of the time, maintaining the process treatment benefits and eliminate the disadvantages of both the SBR and the conventional activated sludge processes. Finally the invention can reduce the capital cost and simplify operations of conventional treatment systems by eliminating separate dedicated clarification systems for the convéntional activated sludge process and ~-ariable level flow control decanters for SBRs.
These objectives can be met while maintaining substantially constant operating level with virtually no significant hydraulic head loss through the system, which is not possible with SBRs or even conventional activated sludge systems because of secondary clarifier head losses.
The present invention also makes possiblé ~conomical ~0 high efficiency biolo~ical removal of nutrients even for dilute or ~ool wastewaters. This often cannot be reliable achieved by SBR processes, which attempt to provide all treatment steps sequentially in one cell instead of using ~eparate high ~fficienc~ dedicated anaerobic and anoxic ~5 cells with optimized recycles. The present invention also SUB~ 11 1 JTE SHEET

WO95109130 2 1 5 0 1 0 i PCrrCA~

accomplishes high efficienc~- nutrient removal without the use of the e:~tra large dedicated final clarifiers typically required for conventional high efficiency activated sludge nutrient removal process systems.
The present invention also makes possible the retrofit of existing aerated basins or lagoons to a higher treatment efficiency acti~-ated sludge style of treatment by making possible virtually no head loss through the system and installation of retrofit baffles "on-the-run" to create the treatment discharge cells as specified for this invention without the necessity of shutting (lown the existing aerated basins or lagoons.
Finally, the present invention has been shown to be capable of achieving higher aerator utilization ratios and diffuser oxygen transfer efficiency than possible with the SBR
variable level process. ~lso possible are higher efficiency of aeration power use which does not exceed limiting power per unit volume factors. The system has been shown to be cost effective for low or high strength wastes, and for both small ~0 or large flows at low or high hydraulic retention times and low or high food to micro-organism ratios.
Although the invention has been described as being intended for biological wastewater treatment systems, it will be ~ppreciated that the invention could be used for ~5 ~ther water ~r wastewater treatment applications such as SUB~ 11 1 ~ITE SHEE~

~ - 215 01 ~ ~
WO9S/09130 - PCT/CAg4/00544 chemical flocculation an~ settling ~r anaerobic removal of contaminants, e.g. the anaerobic contact process as well as other ~iological, chemical, or other processes reyuiring reacti~n or treatment ~ontact time with mi~ing or aeration followed by gravity (larification of solids prior to recycle of solids and co-mingled treated or partially treated fluid during mixing of the final treatment cell to complete the process cycle. Having thus provided a general cliscussion, described the overall method and system in detail and illustrated the invention with typical examples and simple schematics of how to utilize the invention, it is now evident that effective solutions have }:)een provided ~y the invention over operating and high cost problems of prior art. It is therefore to be understood that no undue lS restrictions are to be imposed by reason of the specific embodiments of the invention as illustrated and discussed herein.

~0 _ ~9 _ SUB~ 1~ 1 ~lTE SHEET

Claims (9)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A method of treating water containing contaminants, comprising of the steps of:
a) providing at least two hydraulically connected treatment cells;
b) introducing untreated water into at least the first of the at least two treatment cells for which said first cell is hydraulically connected to each treatment discharge cell;
c) causing flow of water through the at least two cells;
d) maintaining the level of water in at least the treatment discharge cell(s) at a substantially constant level;
e) treating the water in each of the at least two cells;
f) periodically mixing the water in each discharge cell so that previous settled solids will he resuspended;
g) returning a portion of the water in each discharge cell back to a previous cell while discharge cell waters are being mixed in the previous mixing step;
h) discharging treated water from said discharge cell(s) alternatively and only in the absence of water being mixed in the previous mixing step;

i) providing a central control for regulating the performance of the previous steps.
2. A method of treating water containing contaminants as defined in claim 1, further comprising the step of freely connecting said hydraulically connected treatment cells.
3. A method of continuously treating wastewater having soluble and particulate contaminants, comprising the steps of:
a) providing a first inlet cell for receiving and treating untreated wastewater;
b) providing a first treatment discharge cell for final treatment and discharge of treated wastewater received from said first inlet cell;
c) hydraulically connecting said first inlet cell with each treatment discharge cell;
d) maintaining the level of wastewater substantially constant in at least all treatment discharge cells;
e) introducing untreated wastewater into said first inlet cell;
f) treating the wastewater by aerating and mixing the wastewater in said first cell for oxygenating and mixing mixed liquor suspended solids in said first inlet cell;
g) periodically aerating and mixing wastewater in each treatment discharge cell for providing oxygen for additional treatment of partially treated wastewater and for resuspending and mixing the mixed liquor suspended solids;

h) transferring back a portion of the wastewater in each treatment discharge cell to a previous cell during the steps of aerating and mixing treatment discharge cell wastewater;
i) discharging wastewater from said discharge cell(s) only in the absence of wastewater being mixed in said discharge cell(s); and j) providing a central control for regulating the performance of the previous steps.
4. A method of treating wastewater containing contaminants as defined in claim 3, further comprising the step of freely connecting said hydraulically connected treatment cells.
5. A method of treating wastewater as defined in claim 4, further comprising the steps of;
a) providing a second treatment discharge cell;
b) aerating and mixing wastewater in said second treatment discharge cell substantially concurrently with the stopping of aerating and mixing water in said first treatment discharge cell; and c) supplying wastewater from said first inlet cell to said second treatment discharge cell as well as continuing to supply wastewater from said first inlet cell to said first treatment discharge cell.
6. A method of treating wastewater as defined in claim 5, further comprising the steps of:

a) providing at least one additional treatment discharge cell;
b) supplying wastewater from said first inlet cell to each said additional treatment discharge cell as well as continuing to supply wastewater from said first inlet cell to said first treatment discharge cell.
7. A system for continuously treating wastewater having soluble and particulate contaminants, comprising:
a) a first inlet cell for receiving and treating untreated wastewater;
b) a first treatment discharge cell for final treatment and discharge of treated wastewater received from said first inlet cell;
c) said first inlet cell being hydraulically connected with all treatment discharge cells;
d) means for maintaining the level of wastewater in at least all treatment discharge cell(s) substantially constant;
e) means for introducing untreated wastewater into said first inlet cell;
f) means for aerating and mixing the wastewater in said first inlet cell for oxygenating and mixing mixed liquor suspended solids in said first inlet cell;
g) means for periodically aerating and mixing wastewater in each treatment discharge cell for providing oxygen for additional treatment of partially treated wastewater and for resuspending and mixing the mixed liquor suspended solids therein;
h) means for transferring back a portion of the wastewater in each treatment discharge cell to a prior cell during mixing of treatment discharge cell wastewater;
i) means for discharging treated wastewater out of each treatment discharge cell only in the absence of wastewater being mixed in each said discharge cell; and j) central control means for regulating the operation of the system.
8. A system of treating wastewater containing contaminants as defined in claim 7, wherein said first inlet cell is provided a means to be freely connected with all said hydraulically connected treatment cells.
9. A system for continuously treating wastewater as defined in claim 8, further comprising:
a) at least one additional treatment discharge cell;
and b) means for controlling the alternate discharge of treated wastewater out of said first and said at least one additional treatment discharge cell.
CA 2150101 1993-09-30 1994-09-30 Method and system for treatment of water and wastewater Abandoned CA2150101A1 (en)

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US5902484A (en) 1999-05-11
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WO1995009130A1 (en) 1995-04-06
AU1102395A (en) 1995-04-18
CN1115178A (en) 1996-01-17

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