CA2020485A1 - Multilayer containers and method of making same - Google Patents
Multilayer containers and method of making sameInfo
- Publication number
- CA2020485A1 CA2020485A1 CA002020485A CA2020485A CA2020485A1 CA 2020485 A1 CA2020485 A1 CA 2020485A1 CA 002020485 A CA002020485 A CA 002020485A CA 2020485 A CA2020485 A CA 2020485A CA 2020485 A1 CA2020485 A1 CA 2020485A1
- Authority
- CA
- Canada
- Prior art keywords
- layer
- polymer
- container
- polyamide
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1379—Contains vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31725—Of polyamide
- Y10T428/31728—Next to second layer of polyamide
- Y10T428/31732—At least one layer is nylon type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31928—Ester, halide or nitrile of addition polymer
Abstract
ABSTRACT
A plastic container having a plastic wall that includes two plastic layers bonded together without a separate adhesive layer, the two layers being a barrier layer and a support layer, the support layer being a blend of a polyolefin, a polymer having a polar group and a barrier polymer.
A plastic container having a plastic wall that includes two plastic layers bonded together without a separate adhesive layer, the two layers being a barrier layer and a support layer, the support layer being a blend of a polyolefin, a polymer having a polar group and a barrier polymer.
Description
~020~85 MULTILAYER CONTAINERS AND
METHOD OF MAKING SAME
The present invention relates to multilayer containers contalning at least two layers bonded 5 together without an adhesive. The invention also relates to method of making the containers without using an adhesive layer between the two walls of the containers.
BACKGROUND OF THE INVENTION
In the art, the usual method of making multilayer containers for food and chemical packaging involves bonding two walls of the containers together with a separate adhesive layer. Thus, an adhesive layer is normally used to bond a high barrier layer 15 such as nylon or a copolymer of ethylene and vinyl acetate to a plastic support layer of a polyolefin such as polyethylene or polypropylene or copolymers of ethylene and propylene.
The resulting structure has an extra layer 20 with extra cost and, for production, requires using a multilayer die head design.
It is desirable to provide a multilayer container having two walls which are bonded together without a separate adhesive layer between the layers.
OBJECTS OF THE INVENTION
It is an object of the present invention to provide a multilayer plastic container having at least two plastic layers that are bonded together without using an extra separate adhesive layer 30 between the walls.
It is an object of the present invention to provide a plastic container having two plastic walls (a support layer that is a polyolefin and a barrier layer such as nylon) without using a 202048~
separate layer and without the use of a multilayer die head design.
These and other objects will be apparent from the specification that follows and the appended 5 claims.
SUMMARY OF THE INVENTION
Broadly stated, the present invention provides a plastic container having at least two walls bonded together without a separate adhesive layer, the 10 one layer being a support layer that is a blend of a polyolefin and a polymer having a polar group (preferably a polymer containing the residue of maleic anhydride such as a maleic anhydride functionalized block copolymer of polystyrene and poly (ethylene/butylene), and 15 the other layer being a barrier layer such as polyamide or a copolymer of ethylene and vinyl alcohol.
The present invention provides a multilayer plastic container and a method of making the same, the container having mulcilayer walls having two plastic 20 walls or layers bonded together without a separate adhesive layer, one layer being a support layer that is a blend of ~A) a polyolefin, (B) a polymer with a polar group and (C) a copolymer of ethylene and vinyl alcohol; the other layer being a barrier layer 25 that is a copolymer of ethylene and vinyl alcohol.
The present invention also provides a plastic multiwall container with two plastic walls or layers bonded together without a separate adhesive layer, the container comprising:
1. a polyolefin support layer, the support layer being a blend of (A) polyolefin, (~) a polymer with a polar group, (C~ a polyamide, and 2. a polyamide barrier layer.
`8S
The present invention provides for a method of making the previously described multilayer plastic containers.
DETAILED ~ESCRIPTION
In the present invention, the multilayer process is simplified by modifying polyolefin support layer polymers such as polyethylenes, polypropylene and ethylene-propylene copo~ymers by adding another polymer containing a polar group so that a direct bonding to the barrier layer, e.g., amorphous or crystalline polyamide, or ethylene-vinyl alcohol copolymer, is achieved without the use of a separate adhesive layer.
Polar polymers contain groups such as carboxylic, hydroxyl, amide, imide, ester, and acetalic. Suitable polymers with polar groups are copolymers of ethylene or propylene with vinyl alcohol or vinyl acetate or ethylene acrylate. A preferred polymer is made from maleic anhydride such as a maleic anhydride functionalized block copolymer polystyrene and polyethylene/butylene (or butadiene).
The following examples illustrate the invention.
High density polyethylene (HDPE), a polar gxoup containing polymer ~an 85/15 copolymer of ethylene and vinyl acetate), and a polyamide were mixed together in a single screw Brabender mixer in the ratio of 80:10:10. A sheet of such blend was pressed in a laboratory scale Carver Press at 450F.
This sheet was then put in contact with a sheet of polyamide alone in the press at ~50F and 25-30 psi for 2-~ minutes followed by quenching. In a control experiment, a sheet of HDPE and a sheet of polyamide 1616~
2~2048~
were kept in the press under similar conditions. No adhesion was found between the sheet of HDPE and polyamide while the sheet of the above described blend could not be pulled apart from the sheet of 5 polyamide.
In another experiment, one gallon containers were blown on a ML-4 blow molding machine with a gallon mold at 450F, with above described blend as the 10 outside layer and polyamide as the inside layer. A
good adhesion between these layers is observed.
Excellent results were obtained when polypropylene was used in place of polyethylene in the above Examples. Also good results were obtained when 15 a copolymer of ethylene and vinyl alcohol was used in place of the polyamide in the support layer and in the barrier layer.
Sheets were made as described in Example 1 20 except that Kraton G FG l901X thermoplastic rubber was used in place of the copolymer of ethylene and vinyl acetate. Substantial equivalent results were obtained when the polyamide in the blend was omitted and a blend of 90 HDPE, 10 Kraton FG rubber used.
In the present invention, the polyolefin support layer is a polymer of an olefin having two to four carbon atoms. The preferred polyolefin is polyethylene or polypropylene. The polyethylene can 30 be high density, low density, or linear low density polyethylene with high density polyethylene being preferred. Copolymers of ethylene and propylene are very useful, such copolymers containing about 80 or 85 20204~5 up to 95 weight percent ethylene or propylene.
Suitable polyethylenes, polypropylene and propylene based polymers are set forth in Jabarin U.S. patent No. 4,605,576 which is incorporated by reference.
Suitable barrier polymers include polyvinylidene chloride and nitrile polymers, although polyamides and copolymers of ethylene and vinyl alcohol (5 to 25 weight percent vinyl alcohol) are highly preferred.
Suitable polyamides are nylon, copolymers of adipic acid hexamethylene diamine (6, 6-nylon), and copolymers of adipic acid and polycaprolactam.
Suitable polar polymers are copolymers of ethylene, propylene, butylene, with monomers 15 containing polar groups (carboxylic, hydroxyl, amide, imide, ester, acetalic), such as vinyl acetate, alkyl (methyl, ethyl) acrylate, trimellitic anhydride, caprolactone, caprolactam, vinyl alcohol, adipic acid, maleic acid or maleic anhydride, sebacic acid, 20 glycerol, propane diol, and other polar group containing monomers that are generally 2 or 5 up to 20 or 25 weight percent of the total copolymer and preferably 5 or 10 up to 15 or 18 weight percent.
Kraton FG l901X Rubber is described in 25 Shell Chemical Company Technical Bulletin SC: 592-87.
As described therein, the rubber generally has about 2 weight percent of bond maleic anhydride therein. 5 ~t;
The Bulletin is incorporated by reference. _S J J
The bond maleic anhydride, or other 30 polar group in the polymer can be about 1/2 to 10 or 20 weight percent, the preferred functionality being about 1 or 2 to 5 or 8 weight percent.
METHOD OF MAKING SAME
The present invention relates to multilayer containers contalning at least two layers bonded 5 together without an adhesive. The invention also relates to method of making the containers without using an adhesive layer between the two walls of the containers.
BACKGROUND OF THE INVENTION
In the art, the usual method of making multilayer containers for food and chemical packaging involves bonding two walls of the containers together with a separate adhesive layer. Thus, an adhesive layer is normally used to bond a high barrier layer 15 such as nylon or a copolymer of ethylene and vinyl acetate to a plastic support layer of a polyolefin such as polyethylene or polypropylene or copolymers of ethylene and propylene.
The resulting structure has an extra layer 20 with extra cost and, for production, requires using a multilayer die head design.
It is desirable to provide a multilayer container having two walls which are bonded together without a separate adhesive layer between the layers.
OBJECTS OF THE INVENTION
It is an object of the present invention to provide a multilayer plastic container having at least two plastic layers that are bonded together without using an extra separate adhesive layer 30 between the walls.
It is an object of the present invention to provide a plastic container having two plastic walls (a support layer that is a polyolefin and a barrier layer such as nylon) without using a 202048~
separate layer and without the use of a multilayer die head design.
These and other objects will be apparent from the specification that follows and the appended 5 claims.
SUMMARY OF THE INVENTION
Broadly stated, the present invention provides a plastic container having at least two walls bonded together without a separate adhesive layer, the 10 one layer being a support layer that is a blend of a polyolefin and a polymer having a polar group (preferably a polymer containing the residue of maleic anhydride such as a maleic anhydride functionalized block copolymer of polystyrene and poly (ethylene/butylene), and 15 the other layer being a barrier layer such as polyamide or a copolymer of ethylene and vinyl alcohol.
The present invention provides a multilayer plastic container and a method of making the same, the container having mulcilayer walls having two plastic 20 walls or layers bonded together without a separate adhesive layer, one layer being a support layer that is a blend of ~A) a polyolefin, (B) a polymer with a polar group and (C) a copolymer of ethylene and vinyl alcohol; the other layer being a barrier layer 25 that is a copolymer of ethylene and vinyl alcohol.
The present invention also provides a plastic multiwall container with two plastic walls or layers bonded together without a separate adhesive layer, the container comprising:
1. a polyolefin support layer, the support layer being a blend of (A) polyolefin, (~) a polymer with a polar group, (C~ a polyamide, and 2. a polyamide barrier layer.
`8S
The present invention provides for a method of making the previously described multilayer plastic containers.
DETAILED ~ESCRIPTION
In the present invention, the multilayer process is simplified by modifying polyolefin support layer polymers such as polyethylenes, polypropylene and ethylene-propylene copo~ymers by adding another polymer containing a polar group so that a direct bonding to the barrier layer, e.g., amorphous or crystalline polyamide, or ethylene-vinyl alcohol copolymer, is achieved without the use of a separate adhesive layer.
Polar polymers contain groups such as carboxylic, hydroxyl, amide, imide, ester, and acetalic. Suitable polymers with polar groups are copolymers of ethylene or propylene with vinyl alcohol or vinyl acetate or ethylene acrylate. A preferred polymer is made from maleic anhydride such as a maleic anhydride functionalized block copolymer polystyrene and polyethylene/butylene (or butadiene).
The following examples illustrate the invention.
High density polyethylene (HDPE), a polar gxoup containing polymer ~an 85/15 copolymer of ethylene and vinyl acetate), and a polyamide were mixed together in a single screw Brabender mixer in the ratio of 80:10:10. A sheet of such blend was pressed in a laboratory scale Carver Press at 450F.
This sheet was then put in contact with a sheet of polyamide alone in the press at ~50F and 25-30 psi for 2-~ minutes followed by quenching. In a control experiment, a sheet of HDPE and a sheet of polyamide 1616~
2~2048~
were kept in the press under similar conditions. No adhesion was found between the sheet of HDPE and polyamide while the sheet of the above described blend could not be pulled apart from the sheet of 5 polyamide.
In another experiment, one gallon containers were blown on a ML-4 blow molding machine with a gallon mold at 450F, with above described blend as the 10 outside layer and polyamide as the inside layer. A
good adhesion between these layers is observed.
Excellent results were obtained when polypropylene was used in place of polyethylene in the above Examples. Also good results were obtained when 15 a copolymer of ethylene and vinyl alcohol was used in place of the polyamide in the support layer and in the barrier layer.
Sheets were made as described in Example 1 20 except that Kraton G FG l901X thermoplastic rubber was used in place of the copolymer of ethylene and vinyl acetate. Substantial equivalent results were obtained when the polyamide in the blend was omitted and a blend of 90 HDPE, 10 Kraton FG rubber used.
In the present invention, the polyolefin support layer is a polymer of an olefin having two to four carbon atoms. The preferred polyolefin is polyethylene or polypropylene. The polyethylene can 30 be high density, low density, or linear low density polyethylene with high density polyethylene being preferred. Copolymers of ethylene and propylene are very useful, such copolymers containing about 80 or 85 20204~5 up to 95 weight percent ethylene or propylene.
Suitable polyethylenes, polypropylene and propylene based polymers are set forth in Jabarin U.S. patent No. 4,605,576 which is incorporated by reference.
Suitable barrier polymers include polyvinylidene chloride and nitrile polymers, although polyamides and copolymers of ethylene and vinyl alcohol (5 to 25 weight percent vinyl alcohol) are highly preferred.
Suitable polyamides are nylon, copolymers of adipic acid hexamethylene diamine (6, 6-nylon), and copolymers of adipic acid and polycaprolactam.
Suitable polar polymers are copolymers of ethylene, propylene, butylene, with monomers 15 containing polar groups (carboxylic, hydroxyl, amide, imide, ester, acetalic), such as vinyl acetate, alkyl (methyl, ethyl) acrylate, trimellitic anhydride, caprolactone, caprolactam, vinyl alcohol, adipic acid, maleic acid or maleic anhydride, sebacic acid, 20 glycerol, propane diol, and other polar group containing monomers that are generally 2 or 5 up to 20 or 25 weight percent of the total copolymer and preferably 5 or 10 up to 15 or 18 weight percent.
Kraton FG l901X Rubber is described in 25 Shell Chemical Company Technical Bulletin SC: 592-87.
As described therein, the rubber generally has about 2 weight percent of bond maleic anhydride therein. 5 ~t;
The Bulletin is incorporated by reference. _S J J
The bond maleic anhydride, or other 30 polar group in the polymer can be about 1/2 to 10 or 20 weight percent, the preferred functionality being about 1 or 2 to 5 or 8 weight percent.
Claims (11)
1. A container having a wall with at least two layers bonded together without a separate adhesive layer, one layer being a support layer that is a blend of a polyolefin and a polymer having a polar group, and the other layer being a barrier layer that is a polyamide or a copolymer of ethylene and vinyl alcohol.
2. A container as defined in claim 1 in which the polar group is derived from maleic anhydride.
3. A container as defined in claim 1 in which the polymer with a polar group is a maleic anhydride functionalized block copolymer of styrene and ethylene/butylene.
4. A container as defined in claim 1 in which the polyolefin is polyethylene or polypropylene, the barrier polymer is polyamide and polyamide is also included in the blend in the support layer.
5. A container as defined in claim 4 in which the polymer having a polar group is a polymer formed with maleic anhydride.
6. A container having a wall with two layers bonded together without a separate adhesive layer, one layer being a polymer blend of (A) a polyolefin, (B) a polymer having a polar group, and (C) a polyamide; and the other layer being a polyamide.
7. A container having a wall with two layers bonded together without a separate adhesive layer, one layer being a polymer blend of (A) a polyolefin, (B) a polymer with a polar group, and (C) a copolymer of ethylene and vinyl alcohol; and the other layer being a copolymer of ethylene and vinyl alcohol.
8. A container as defined in claim 6 in which the polymer blend has about 60 to 90 weight percent polyolefin, about 5 to 20 weight percent of a polymer having a polar group, and about 5 to 20 weight percent of a polyamide.
9. A container having a wall with two layers bonded together without a separate adhesive layer, one layer being a polymer blend of (A) high density polyethylene, (B) polyethylene vinyl acetate, and (C) nylon; and the other layer being nylon.
10. A container having a wall with two layers bonded together without a separate adhesive layer, the layers comprising (1) a support layer that is a blend of (A) a polyolefin, (B) a polymer with a polar group, (C) a barrier polymer that is a polyamide or a copolymer of ethylene and vinyl alcohol;
and (2) a barrier layer that is a polyamide or a copolymer of ethylene and vinyl alcohol.
and (2) a barrier layer that is a polyamide or a copolymer of ethylene and vinyl alcohol.
11. A method of making a plastic container with a plastic wall having two plastic layers bonded together without a separate adhesive layer, the method comprising heating (1) a support layer that is a blend of (A) a polyolefin, (B) a polymer having a polar group, and optionally, (C) a barrier polymer that is a polyamide or a copolymer of ethylene and vinyl alcohol; and (2) a barrier layer that is a barrier polymer as defined as an optional ingredient in the blend of the support layer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/377,392 | 1989-07-10 | ||
| US07/377,392 US5011720A (en) | 1989-07-10 | 1989-07-10 | Multilayer containers and method of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2020485A1 true CA2020485A1 (en) | 1991-01-11 |
Family
ID=23488938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002020485A Abandoned CA2020485A1 (en) | 1989-07-10 | 1990-07-05 | Multilayer containers and method of making same |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5011720A (en) |
| EP (1) | EP0407880B1 (en) |
| AT (1) | ATE179931T1 (en) |
| AU (1) | AU612080B2 (en) |
| CA (1) | CA2020485A1 (en) |
| DE (1) | DE69033102T2 (en) |
| DK (1) | DK0407880T3 (en) |
| ES (1) | ES2132060T3 (en) |
| GR (1) | GR3030847T3 (en) |
| ZA (1) | ZA905398B (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4001126C1 (en) * | 1989-11-20 | 1990-12-13 | Technoform Caprano + Brunnhofer Kg, 3501 Fuldabrueck, De | |
| SE468635B (en) * | 1991-01-09 | 1993-02-22 | Tetra Alfa Holdings | PACKAGING MATERIAL FOR USE OF THE MATERIAL FOR PREPARATION OF CONTAINERS WITH GOOD OXYGEN PROPERTY CHARACTERISTICS |
| SE469376B (en) * | 1992-02-07 | 1993-06-28 | Tetra Laval Holdings & Finance | PACKAGING LAMINATE, INCLUDING A GAS AND AROMBARRIAR LAYER CONTAINING SILICONE, WAS TAKEN TO MANUFACTURING THE LAMINATE AND THE LAMINATE PACKAGING CONTAINER |
| ZA931680B (en) * | 1992-03-30 | 1993-10-05 | Grace W R & Co | Medical solution tubing |
| WO1995023697A1 (en) * | 1994-03-02 | 1995-09-08 | Minnesota Mining And Manufacturing Company | Heat sealable films |
| US6054529A (en) * | 1997-04-08 | 2000-04-25 | The Procter & Gamble Co. | Blends of and methods of blending EVOH polymers and ethylene based polymers having improved environmental stress cracking or environmental fatigue resistance, and products therefrom |
| FR2776228B1 (en) * | 1998-03-20 | 2000-05-19 | Solvay | MULTILAYER HOLLOW BODY IN THERMOPLASTIC MATERIAL |
| US6677013B1 (en) | 1998-04-17 | 2004-01-13 | Pechiney Emballage Flexible Europe | Transparent multilayer polypropylene container with barrier protection |
| US20040005475A1 (en) * | 1998-04-17 | 2004-01-08 | Curie Kevin James | Transparent multilayer polypropylene container with barrier protection |
| WO2000063085A1 (en) * | 1999-04-16 | 2000-10-26 | Pechiney Plastic Packaging, Inc. | Transparent multilayer polypropylene container with barrier protection |
| BR0213758A (en) * | 2001-10-24 | 2004-10-19 | Pechiney Emballage Flexible Eu | Polypropylene Container and Process for Manufacturing |
| US20050221036A1 (en) * | 2004-04-01 | 2005-10-06 | The Coca-Cola Company | Polyester composition with enhanced gas barrier, articles made therewith, and methods |
| US8381928B2 (en) | 2004-06-04 | 2013-02-26 | Ti Group Automotive Systems, L.L.C. | Multilayer fuel tank with a seam having an overlay for reducing vapor permeation |
| US8545952B2 (en) * | 2005-06-07 | 2013-10-01 | The Coca-Cola Company | Polyester container with enhanced gas barrier and method |
| US7820258B2 (en) * | 2005-10-05 | 2010-10-26 | The Coca-Cola Company | Container and composition for enhanced gas barrier properties |
| US20070160788A1 (en) * | 2006-01-11 | 2007-07-12 | Wurtzel Kenneth C | Multilayer container with barrier protection |
| US7790077B2 (en) * | 2006-09-15 | 2010-09-07 | The Coca-Cola Company | Pressurized tooling for injection molding and method of using |
| US8124202B2 (en) * | 2006-09-15 | 2012-02-28 | The Coca-Cola Company | Multilayer container for enhanced gas barrier properties |
| ATE461031T1 (en) | 2007-01-23 | 2010-04-15 | Borealis Tech Oy | USE OF ANHYDRIDE FUNCTIONALIZED POLYMER TO WIDE THE PROCESSING WINDOW OF POLYPROPYLENE |
| TW201917018A (en) * | 2017-10-25 | 2019-05-01 | 美商陶氏全球科技有限責任公司 | Tile containing primer coated substrates with good adhesion |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3857754A (en) * | 1971-06-18 | 1974-12-31 | Toyo Seikan Kaisha Ltd | Resinous compositions having improved processability and gas permeation resistance and molded structures thereof |
| US4058647A (en) * | 1975-02-27 | 1977-11-15 | Mitsubishi Petrochemical Co., Ltd. | Process for preparing laminated resin product |
| US4254169A (en) * | 1978-12-28 | 1981-03-03 | American Can Company | Multi-layer barrier film |
| JPS5655413A (en) * | 1979-10-12 | 1981-05-16 | Toa Nenryo Kogyo Kk | Modified elastomer and laminate thereof |
| US4397916A (en) * | 1980-02-29 | 1983-08-09 | Mitsui Petrochemical Industries, Ltd. | Laminated multilayer structure |
| US4511610A (en) * | 1982-10-14 | 1985-04-16 | Toyo Seikan Kaisha Ltd. | Multi-layer drawn plastic vessel |
| US4605576B1 (en) | 1984-10-22 | 1999-08-24 | Owens Brockway Plastic Prod | Multilayer plastic article |
| JPS62184817A (en) * | 1986-02-10 | 1987-08-13 | Toyo Seikan Kaisha Ltd | Compression molded product with multi-layer construction and manufacture and device thereof |
| EP0266982B1 (en) * | 1986-10-30 | 1994-04-27 | Mitsui Petrochemical Industries, Ltd. | Laminated and molded article prepared therefrom |
| JPH0645225B2 (en) * | 1986-11-01 | 1994-06-15 | 日本合成化学工業株式会社 | Laminated structure |
| US4894291A (en) * | 1988-01-28 | 1990-01-16 | Rampart Packaging Inc. | Increased regrind usage in coextruded structures |
-
1989
- 1989-07-10 US US07/377,392 patent/US5011720A/en not_active Expired - Lifetime
-
1990
- 1990-07-03 AU AU58659/90A patent/AU612080B2/en not_active Ceased
- 1990-07-04 AT AT90112755T patent/ATE179931T1/en not_active IP Right Cessation
- 1990-07-04 DE DE69033102T patent/DE69033102T2/en not_active Expired - Fee Related
- 1990-07-04 DK DK90112755T patent/DK0407880T3/en active
- 1990-07-04 ES ES90112755T patent/ES2132060T3/en not_active Expired - Lifetime
- 1990-07-04 EP EP90112755A patent/EP0407880B1/en not_active Expired - Lifetime
- 1990-07-05 CA CA002020485A patent/CA2020485A1/en not_active Abandoned
- 1990-07-10 ZA ZA905398A patent/ZA905398B/en unknown
-
1999
- 1999-07-26 GR GR990401931T patent/GR3030847T3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0407880A3 (en) | 1991-09-18 |
| ATE179931T1 (en) | 1999-05-15 |
| EP0407880B1 (en) | 1999-05-12 |
| US5011720A (en) | 1991-04-30 |
| EP0407880A2 (en) | 1991-01-16 |
| ZA905398B (en) | 1991-05-29 |
| ES2132060T3 (en) | 1999-08-16 |
| GR3030847T3 (en) | 1999-11-30 |
| DE69033102T2 (en) | 1999-12-23 |
| AU612080B2 (en) | 1991-06-27 |
| DK0407880T3 (en) | 1999-11-01 |
| DE69033102D1 (en) | 1999-06-17 |
| AU5865990A (en) | 1991-02-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |