CA1316946C

CA1316946C - Process for the production of mono-olefins by the catalytic oxidative dehydrogenation of gaseous paraffinic hydrocarbons having two or more carbon atoms

Info

Publication number: CA1316946C
Application number: CA000590531A
Authority: CA
Inventors: Josephus Johannes Helena Maria Font Freide; Mark Julian Howard; Trevor Alan Lomas
Original assignee: BP PLC
Current assignee: PetroIneos Europe Ltd
Priority date: 1988-03-08
Filing date: 1989-02-09
Publication date: 1993-04-27
Anticipated expiration: 2010-04-27
Also published as: US4940826A; DE68921907D1; NZ227922A; EP0332289A2; US5105052A; MY104970A; JPH01272534A; AU615720B2; NO890862D0; CN1038271A; ZA891729B; DE68921907T2; NO890862L; AU2970489A; CN1026100C; EP0332289B1; NO179140B; EP0332289A3; JP2516676B2; NO179140C

Abstract

Case6861(2) ABSTRACT OF THE DISCLOSURE

A PROCESS FOR THE PRODUCTION OF MONO-OLEFINS BY THE CATALYTIC OXIDATIVEDEHYDROGENATION OF GASEOUS PARAFFINIC HYDROCARBONS HAVING TWO OR MORE
CARBON ATOMS

A process for preparing mono-olefins by catalytic oxidative dehydrogenation of eg ethane, propane or butanes is provided. The process employs a catalyst which is capable of supporting combustion beyond the normal fuel rich limit of flammability. Preferred catalysts are platinum group metals supported on a monolith eg platinum.

Description

Case 6861(2) 131~9~6 A PROCESS FOR THE PRODUCTION OF MONO-OLEFINS BY THE CATALYTIC
OXIDATIVE DEHYDROGENATION OF GASEOUS PARAFFINIC HYDROCARBONS
_ HAVING TWO OR MORE CARBON ATOMS

The present invention relates in general to the production of mono-olefins by the catalytic oxidative dehydrogenation of gaseous paraffinic hydrocarbons having 2 or more carbon atoms and in particular to the production of mono-olefins by the catalytic oxidative dehydrogenation of ethane, propana and butanes.
The prior art on the oxitative conversion of gaseaus paraffins to mono~olefins can be broadly divided into two groups, depending on the temperatures employed. At low temperature~, typically below 500C, oxidative dehydrogenation is generally a genuinely catalytic 10 process. This is exemplified by US-A-4524236 and EP-A-0189282. In the process of US-A-4,524236 ethane~oxygen mixtures are passed over catalysts comprising mixed oxides of molybdenum, vanadium, niobium and antimony (optionally incorporating a wide range of addltional metals). Reaction takes place at temperatures in the range from 350 15 to 400C to gi~e high selectivities to ethylene (i.e. 70%
selectivity to ethylene at 75Z ethane conversion). These catalysts produce only carbon oxides from higher paraffins. EP-A-0189282 disclose the use of a tin/phosphorus oxide catalyst in the production of mono-olefins from ethane, propane or butane in admixture with oxygen. Although reaction temperatures in the range 200 to 100C are disclosed, the working embodiment uses a temperature of only 550C.
At hi8her temp~ratures, for example temperatures greater than 500C, it is unlikely that reaction is entirely heterogeneous. At such temperatures thermal crac~ing and gas phase oxidations are .

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likely to assume increasing importance. An example of prior art relevant to the high temperature reaction is US-A-354117~ which discloses passin~ a paraffinic gas through an externally heated fluid bed of "fire resistant" particles containing from 0.5 to 20% wt of at least one of the m~tals copper, manganese or vanadium.
An oxygen-containing gas is injected into the fluid bed. The reaction temperature is from 650 to 900C and the process is at least partially autothermal. At a molar ratio of C2H6:02 of 2.6:1 and about 840~C about 90% of the ethane feed is converted to ethylene.
There are also a number of processes that do not involve catalysts at all. These are genuine high temperature autothermal cracking reactions and are exemplified by, for example, an article entitled "Autothermal Cracking for Ethylene Production" by 15 R.M. Deanesly in Petrol. Refiner, 29 (September, 1950), 217 and GB-A-794,157.
A desirable objective would be to convert ethane, propane or butanes in a single step to mono-oleflns.
Recently, the production of olefins together with carbon ~ 20 monoxide and hydrogen from gaseous paraffinic hydrocarbons, ; including ethane, by partial oxidation in spouted or fl~id bed reactors has been disclosed in, for example, our copending applications EP-A-0164864 and EP-A-0178853.
The pxesent invention provides a process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least t~o carbon atoms or a mixture thereof which process comprises partially combusting a mixture of the hydrocarbon(s) and a molecular oxygen-containing gas in contact with a catalyst capable of upportin~ combustion beyond the normal fuel rich limit of flammability.
As the gaseous paraffinic hydrocarbon there may suitably be used either ethane, propane or a butane, or a mixture of two or more thereof. A suitable feodstock hydrocarbon is a mi~ture of gaseous paraffinic hydrocarbons, principally comprising ethane resulting from the separation of methane from natural gas.

13169~6 As the molecular oxygen-containing gas there may suitably be used either oxygen or air. It is preferred t:o use oxygen, optionally diluted with an inert gas, for example nitrogen. It is preferred to pre-mix the oxygen-containing gas and the paraffinic hydrocarbon prior to contact with the cataly~;t. Additionally, other feed components may be included if so desired to optimise process design. Examples of other suitable feed component~ include methane, hydrogen, carbon monoxide, carbon dioxide ancl water.
The preferred composition of the gaseous paraffinic hydrocarbon/molecular oxygen-containing gas mixture is from 5.0 to 9.0 times the stoichiometric ratio of hydrocarbon to oxygen for complete combustion to carbon dioxide and water, but these limits are extendible if desired. Typically, commercial reactors would be operated at pressure3 of approximately 1-5 bar above atmospheric.
A catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability is employed. Suitable catalysts comprise supported platinum group metals and mixtures thereof, for example supported platinum or palladium. Although a range of support materi~ls may be used, it is preferred to use an ~lumina as the support. The support material may be in the form of spheres or other granular shapes, but is preferably in the form of a monolith.
Monoliths are continuous multichannel ceramic structures, frequently of a honeycomb appearance. They are commercially available as similar materials are commonly u~ed as catalytic convertors in automobile exhausts. A preferred form of alumina-supported platinum catalyst is platinum/gamma-alumina spheres. A more preferred form of supported platinum catalyst is a platinum/monolith, for example a platinum/cordierite or mullite monolith. Cordierite has a material ~ composition of 2 NgO.2A1203.5SiO2 whilst mullite has a material ; 30 co~position of 3A1203 2SiO2. The catalyst ma~ suitably be prepared by impregnating the support with a solution of a soluble compound of the platinum group metal. Using a monolith catalyst, this may suitably be achieved by soaking the monolith in a solution of a soluble compound, for example a salt, of the metal, removing the monolith from the solution and drying, typically at about 120~C.

~L3~L~946 4 2~935-985 Using ~he simple soaking method it is difficult to achieve high, i.e. greater than about 0.15% me~al loadinys. Although such a metal loading is ~dequate for the performance of the invention, in certain circumstances higher loadings may be desirable. R hiyher loading may be achieved by ~ash coating the monolith prior to immersion in the solution of the catalytic metal compound with a material, for example alumina, capable of facilitating the retention of the metal compound. A combustion catalyst in the form of a metallic gauæe such as Pt/Rh may also be employed.
The catalyst in the form of spheres may be used as a solids recirculating bed, for example a fluid bed or a spouted bed.
A process for producing synthesis ~as, i.e. carbon monoxide/hydrogqn mixtures, from a reaction mixture comprising a saturated hydrocarbon and an ox~gen-containing gas in a spouted bed, the bed comprising material which is cataly~ically active for steam reforming reactions, is described in our copending EP-A-0164864. The process described in EP-A-0164864, may be modified by the use of a catalys~ cap~ble of supporting combustion beyond the normal fuel rich limit of flammability, Xor example a supported platinum group metal(s) as hereinbefore described, instead of the steam reforming catalyst and khe conditions modified in accordance with the process of the present invention to produce a mono-olefin as the princlpal product of the process.
In a preferred embodiment of the modified process of EP-A-016486~, hydrogen is co-fed to the process as described in our copending EP-A-0178853.

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1316~6 4a 22935 985 It is preferred to use the catalyst in a fixed bed. One reason for this preference is that it largely avoids the attrition problems generally encounterecl in moving bed operations.
In the context of fixed bed operation it is further preferred to use a monolith catalyst. Monolith catalysts are preferred over other forms of fixed bed catalysk because (13 they are capable of sustaining a very low pressure drop along the bed, thereby allowing large gas throughputs, (2) they present a hi~h surface area to the gaseous P~

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combustion mlxture, (3) they are particularly free from attrition problems, (4) they can result in very low levels of soot formation and as a result require less frequent de-coking and ~5) they are available in various cell sizes and shapes and their preparation by the soaking technique is relatively simple.
The elevated temperature employed in the process of th0 invention may suitably be in the range from 500 to 1200C, though temperatures in the upper part of this range, for example 800 to 1000C are preferred.
It is preferred but not essential to co-feed hydrogen gas. ~y so doing the yields of and selectivities to desirable products can be improved. It is also preferred but not essential to preheat the feed gas, a suitable temperature being in the range 300 to 500C.
In a preferred embodiment the present invention provides a process for the production of ethylene from ethane which process comprises contacting a mixture comprising ethane and oxygen in an ethane to oxygen molar ratio of 1~7 to 2.1 with a platinum- or palladium-containing monolith fixed bed catalyst.
In addition to ethylene, small amounts of higher olefins, acetylenes, aromatics and carbon oxides, i.e. carbon monoxide and carbon dioxide are co-produced.
The proces~ of the invention will now be further illustrated by reference to the following Examples.
Example A - PreDaration of P /cordierite monolith A cordierite monolith (ex CORNING) was soa~ed in a solution of [(NH3)4Pt]C12.H20. After 2 weeks the Pt impregnated monolith was removed from the solution, allowPd to drain and dried in air at 120C. The platinum loading, as determined by X-ray Fluorescence Spectroscopy was about 0.1% w/w.
Example 1 The ~t-loaded monolith (approximately 38 mm diameter x 51 mm length) was placed at the bottom of a quartz, 51 mm diameter, ~ reactor with a baffle placed beneath it. The baffle ensured that : the incoming flow of feed gas became evenly distributed through all cells in the monolith. ~thane, oxygen, hydrogen and nitrogen were , . . .

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preheat of the feed gases was required to effect autothermal operation, substantial heat generation being provided by the highly exothermic combustion of hydrogen/oxygen. Details of th~ molar proportions of the feed, th0 flow rates and the results obtained are given in Table 1.

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Exampl_ 2 Into a 51 mm diameter quartz reactor was placed a catalyst in the form of previously calcined Pt/gamma-alumina spheres (2 mm diameter), supported on a coarse silica sintered disc.
Ethane, hydrogen, oxygen and nitrogen were passed over the catalyst in the molar proportions and under the conditions shown in Table 2. Also tabulated in Table 2 are the experimental results.
No soot formation was obssrved.

In the following example, 0.5% Pt/Pd loaded al~ina spheres (1.7 mm diameter) were placed into a quart~ reactor (25 mm diameter). The catalyst was supported on a course silica sintered disc.
The appropriate paraffinic feedstock, ethane, propane or butane, or mixtures thereof, was co-fed with oxygen and nitrogen over the catalyst in the proportions and under the conditions shown in the following tables (3~4). Methane and hydrogen were also co-fed in some experiments.
The tables also show the experimental results, in which selectivities have been calculated on a soot free basis. Minimal soot formation was observed.
Example 4 In the following example, the monolith or gauze was placed in a quartz reactor (25 mm diameter) and the catalyst was supported on a course silica disc.
Ethane, hydrogen, o~ygen and nitrogen were co-fed over the catalyst in the molar proportions and under the conditions shown in the following tables (7-9).
; Tables 7 to 9 also show experimental results in which selectivities have been calculated on a soot-free basis. No soot formation was observed.

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Claims

1. A process for the production of mono-olefins from a gaseous paraffinic hydrocarbon having at least two carbon atoms or a mixture thereof which process comprises partially combusting mixture of the hydrocarbon or hydrocarbons and a molecular oxygen-containing gas in a composition of from 5 to 9 times the stoichiometric ratio of hydrocarbon to oxygen for complete combustion to carbon dioxide and water, in contact with a combustion catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability.

2. A process according to claim 1, wherein the catalyst is a supported platinum group metal or a mixture thereof.

3. A process according to claim 2, wherein the platinum group metal is either platinum or palladium.

4. A process according to either claim 2 or 3, wherein the support is an alumina.

5. A process according to claim 2, wherein the support is a monolith.

6. A process according to claim 2, wherein the catalyst is platinum/gamma-alumina spheres.

7. A process according to claim 2, wherein the catalyst is platinum/cordierite monolith.

8. A process according to claim 5, wherein the catalyst is platinum/mullite monolith.

9. A process according to claim 1, wherein the catalyst is a metallic gauze containing a platinum group metal.

10. A process according to claim 1, wherein the gaseous paraffinic hydrocarbon is ethane, propane, butane or a mixture thereof.

11. A process according to claim 10, wherein the molecular oxygen-containing gas is oxygen.

12. A process according to claim 1, wherein hydrogen is co-fed.

13. A process according to claim 1, wherein the catalyst is in the form of a fixed bed.

14. A process according to claim 1, wherein the mixture is partially combusted at a temperature in the range from 500 to 1200°C.

15. A process according to claim 14, wherein the temperature is in the range from 800 to 1000°C.

16. A process for the production of ethylene from ethane which process comprises contacting a mixture comprising ethane and oxygen in an ethane to oxygen molar ratio of 1.7 to 2.1 with a platinum- or palladium-containing monolith fixed bed catalyst.