CA1290393C - Manifold seal structure for fuel cell stack - Google Patents

Manifold seal structure for fuel cell stack

Info

Publication number
CA1290393C
CA1290393C CA000552783A CA552783A CA1290393C CA 1290393 C CA1290393 C CA 1290393C CA 000552783 A CA000552783 A CA 000552783A CA 552783 A CA552783 A CA 552783A CA 1290393 C CA1290393 C CA 1290393C
Authority
CA
Canada
Prior art keywords
openings
stack
manifold
gaskets
manifolds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA000552783A
Other languages
French (fr)
Inventor
William P. Collins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UTC Power Corp
Original Assignee
International Fuel Cells Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Fuel Cells Corp filed Critical International Fuel Cells Corp
Application granted granted Critical
Publication of CA1290393C publication Critical patent/CA1290393C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2484Details of groupings of fuel cells characterised by external manifolds
    • H01M8/2485Arrangements for sealing external manifolds; Arrangements for mounting external manifolds around a stack
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Gasket Seals (AREA)
  • Fuel Cell (AREA)

Abstract

Abstract Improved Manifold Seal Structure For Fuel Cell Stack The seal between the sides of a fuel cell stack and the gas manifolds is improved by adding a mechanical interlock between the adhesive sealing strip and the abutting surface of the manifolds. The adhesive is a material which can flow to some extent when under compression, and the mechanical interlock is formed providing small openings in the portion of the manifold which abuts the adhesive strip. When the manifolds are pressed against the adhesive strips, the latter will flow into and through the manifold openings to form buttons or ribs which mechanically interlock with the manifolds. These buttons or ribs increase the bond between the manifolds and adhesive, which previously relied solely on the adhesive nature of the adhesive.

Description

3~;~

Description Improved ManiEold Seal Structure For Fuel Cell Stack Technical Field This invention relates to an improved seal for use in mountinq qas mani~olds on fuel cell stacks.

Backqround Art Fuel cell stacks which utilize qaseous reactants conventionally are provided with oPposed pairs oE side manifolds which distribute the reactant gases to the cells in the stack, and which qather reactant exhaust gases ~rom the cells in the stack. In the larger commercial stacks, the maniEolds may take the form oE
large shells which abut the sides of the stack and are secured in place by some sort o~ Easteninq means. U.S.
Patent No. 4,3g5,009 granted August 17, 1982, is illustrative of such a commerical stack and manifold construction.
When this type o~ construction is used, care must be taken to seal the edqes oE the maniEold aqainst the stack so that the reactant qases and the exhaust gases will not escape into the amhient surroundinqs. This seal has been eEEected with elastomeric qaskets and also with elastomeric adhesive qaskets. The elastomeric qaskets rely on the com~ression Eorces o~
the mechanism which secures the manifold to the stack for their inteqrity. The elastomeric adhesive qaskets , .

~3V3~3 will provide a more stable seal because they rely on compression forces plus adhesion to the stack and to the manifold for their integrity.
This invention relates to an improvement in the elastomeric adhesive seal provided by the gaskets. The improved seal will disPlay better stability under pressure excursion conditions in the manifolds, i.e., when changes in manifold pressure occur quickly and with some degree of magnitude due to gas flow rate changes which occur in the system. These flow rate changes can result from intentional changes in operating conditions, such as, power o-utput variations, or they can result from unintentional phenomena, such as, flow passage restriction or blockage, or the like.
With the improved seal of this invention, there is formed a mechanical interlock between the sealing gasket and the manifold flange which engaqes the sealing qasket. The gasket used in this invention is preferably the adhesive elastomeric gasket oE the prior art, so that, as modified, the seal has the compression characteristic, the adhesion characteristic, and also a mechanical interlock characteristic. The mechanical interlock between the sealing gasket and the manifold flange is obtained by Eorminq discreet openings in the manifold Elange. These openings may be formed by drilling, millinq or the like. The aforesaid openings are Eormed on the manifold flange which abuts the sealing gasket and is compressed by the pressure of the securement means used to hold the manifolds against the stack. The sealing gaskets are, to a certain extent, inherently flowable when placed 33~33 \

under compression, thus, the gasket material will extrude into and flow through the flange openings as a result of the compressive forces imposed upon the gasket by the manifolds. The gaskets will thus form integral rivet-like mechanical interlocks with the manifold at each of the openings. These mechanical interlocks can only be broken if the gaskets were forced by pressure -to flow back out of the openings, or if the gaskets were torn at the rivet-like con-nectors. It is thus readily apparent that the seal formed in accordance with this invention will be more resistant to pressure-induced failure.
It is therefore an object of this invention to provide an improved seal between a fuel cell stack -and associated gas manifolds mounted on the stack.
It is a further object of this invention to provide a seal of the character described wherein an adhesive sealing gaske-t is extruded through restricted openings in manifold flanges to form in-tegral rivet-like connections between the gasket and the manifold.
In accordance with the invention there is provided an electrochemical cell stack assembly comprising:
(a) a s-tack of electrochemical cells adapted to use gaseous reactants in an electrochemical reaction, said stack having side walls through which the gaseous reactants are admitted to -the cells;
(b) a plurality of gas manifolds mounted on said staclc adjacent said side walls, each of said manifoLds having edge sealing flanges thereon;

~Z9~)3~33 .
- 3a -(c) a plurality of sealing gaskets sandwiched be-tween said manifold edge sealing flanges and said s-tack side wall to seal the mani-fo]d interior from ambient surroundings;
(d) each of said manifold edge sealing flanges having a plurality of openings formed therein; and ~e) means for pressing said manifold edge seal-ing flanges against said sealing gaskets sufficiently to cause localized portions of said gaskets to extrude into said manifold sealing flange openings to form protruding interlocks between said gaskets and said sealing flanges which resist lateral move-ment of said manifolds relative to said gaskets.
These and other objects and advantages will become rnore readily apparatent from the following detailed description of a preferred embodiment of the invention when taken in conjunction with -the accompanying drawings.
Brief Description of Drawings Fig. 1 is a fragmented horizontal sectional view of a corner of a fuel cell stack employing the sealing structure of this invention;

~9~393 Fig. 2 is a fragmented perspective view of a gas manifold used with the stack of Fiq. l showinq the sealing flange and several varieties of openings that can be used to effect the seal of this invention;
Fig. 3 is a sectional view taken along line 3-3 of Fig. 2 showinq details of the flanqe openings: and Fig. 4 is a ~raqmented horizontal sectional view of the seal showinq the inteqral rivet-like connection found between the qasket and manifold flange.

~est Mode for Carryinq Out the Invention Referring now to the drawings r there is shown in Fig. 1 a sectional view of a corner of a fuel cell stack formed in accordance with this invention. The stack, denoted qenerally bv the numeral 2, includes the component plates 4 and the gas manifolds 6 and 8. It will be understood that the plates 4 are rectanqularly shaped and there are four manifolds in total, one on each side of the stack 2. Certain ones oE the plates 4 have qrooves lO which open into the manifolds 8 and through which a qaseous reactant is delivered to the reacting zones of the stack 2. It will be also understood that similar qrooves open into the manifold 6 from other of the Plates 4 to deliver the other gaseous reactants to the reactinq zones of the stack 2.
The manifolds 6 and 8 may be pressed against the stack 2 as for exam~le, hy bands 12 which encircle the manifolds 6 and 8 and the stack 2. Alternatively, tie rods could he used. Each manifold has side walls l4 which merge into outwardly extendinq sealinq flanqes 16 havinq upturned free ends 18. Sandwiched bewteen the ~.%~03~3 flanges 16 and the plates 14 are gasket strips 20. The gasket strips are formed from Gore-Tex~, a PTF~
material which possesses some flow capabilities under pressure, and which is coated with a fluorocarbon polymer adhesive for this application. Gore-Tex~ is a trademark for a flowable polytetrafluoroeth~lene material having a fibrous texture which is manufactured by W. L. Gore and Associates, Inc., Elkton, Maryland.
This material is described in V.S. Patent Nos.
3,953,566 and 4,187,390. It will be understood that the strips 12 force the manifolds 6 and 8 toward the plates 4 so that the gasket strips 2n are compressed between the plates 4 and the manifold sealing flanges 16.
It will be noted from Fig. 2 that the manifold sealing flanqes 16 have openings therein midway between the edges of the sealing flanges 16. The openings may take several different shapes, as, for example, they may be circular as at 22, or they may be relatively short elonqated slots, as at 24, or even longer slots 26. The preferred shape of the sealing flange openings is circular. It will be noted in Fiq. 3 that the sealing flange openings 22 are formed with chamfers 28 on their inside and outside ends.
Referring to Fig. 4, the interlock between the sealing gaslcet 20 and the sealing ~lange 16 is shown.
When the manifold is pressed against the sides of the stack, the sealinq flange 16 is forced against the gasket 20. The portions of the gasket 20 adjacent the openings 22 will be forced through the openings 22 to form integral rivet-like interlocks with the sealing ~9~)~393 flange 16. The interlocks 30 will each include a reduced neck Portion 32 which merqes into the main body of the gasket 20, and an expanded head portion 34 which flows outwardly somewhat from the openinqs 22 to overlie the surface of the sealing flanqe 1~ remote from the qasket 2n. The chamfers 2~ on the openinqs 22, 24 and 26 will impart a radius to the corners of the interlock neck 32 to increase strenqth and reduce the likelihood of corner fracture.
lo It will be appreciated that manY pressure variations which occur within the manifolds will impinge the gasket 20 at 21 wherehy the qaskets 20 could shift laterally. The interlocks 30 between the gasket 20 and the manifold ~ ~rovide added stahility to the gasket-manifold combination and resist lateral movement of the qasket with respect to the manifolfl.
It will be appreciatefl that the interlock between qasket and manifold is simple to produce and requires very little alteration of existing systems, whereby the latter can readily be retrofitted to enjoy the benefits of the invention.
Since many changes and variations of the disclosed embodiments of the invention may be made without departing from the inventive concept, it is not intended to limit the invention otherwise than as required by the appended claims.

Claims (6)

1. An electrochemical cell stack assembly comprising:
(a) a stack of electrochemical cells adapted to use gaseous reactants in an electrochemical reaction, said stack having side walls through which the gaseous reactants are admitted to the cells;
(b) a plurality of gas manifolds mounted on said stack adjacent said side walls, each of said manifolds having edge sealing flanges thereon;
(c) a plurality of sealing gaskets sandwiched between said manifold edge sealing flanges and said stack side wall to seal the mani-fold interior from ambient surroundings;
(d) each of said manifold edge sealing flanges having a plurality of openings formed therein; and (e) means for pressing said manifold edge seal-ing flanges against said sealing gaskets sufficiently to cause localized portions of said gaskets to extrude into said manifold sealing flange openings to form protruding interlocks between said gaskets and said sealing flanges which resist lateral move-ment of said manifolds relative to said gaskets.
2. The stack assembly of claim 1 wherein said protruding interlocks include reduced diameter neck portions disposed within the confines of said open-ings, and expanded head portions which overlie portions of said flanges remote from said gaskets and surrounding said openings.
3. The stack assembly of claim 2 wherein said openings include chamfered edges which produce radiused corners on said neck portions of said pro-truding interlocks.
4. The stack assembly of claim 3 wherein said openings are round.
5. The stack assembly of claim 3 wherein said openings are elongated slots.
6. The stack assembly of claim 1 wherein said gaskets are formed from adhesive-coated PTFE.
CA000552783A 1986-12-03 1987-11-25 Manifold seal structure for fuel cell stack Expired - Lifetime CA1290393C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/938,483 US4738905A (en) 1986-12-03 1986-12-03 Manifold seal structure for fuel cell stack
US938,483 1986-12-03

Publications (1)

Publication Number Publication Date
CA1290393C true CA1290393C (en) 1991-10-08

Family

ID=25471511

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000552783A Expired - Lifetime CA1290393C (en) 1986-12-03 1987-11-25 Manifold seal structure for fuel cell stack

Country Status (2)

Country Link
US (1) US4738905A (en)
CA (1) CA1290393C (en)

Families Citing this family (30)

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US4877499A (en) * 1984-11-05 1989-10-31 The Dow Chemical Company Membrane unit for electrolytic cell
US4892632A (en) * 1988-09-26 1990-01-09 The Dow Chemical Company Combination seal member and membrane holder for an electrolytic cell
US4940518A (en) * 1988-09-26 1990-07-10 The Dow Chemical Company Combination seal member and membrane holder for a filter press type electrolytic cell
US4898653A (en) * 1988-09-26 1990-02-06 The Dow Chemical Company Combination electrolysis cell seal member and membrane tentering means
US4915803A (en) * 1988-09-26 1990-04-10 The Dow Chemical Company Combination seal and frame cover member for a filter press type electrolytic cell
US4886586A (en) * 1988-09-26 1989-12-12 The Dow Chemical Company Combination electrolysis cell seal member and membrane tentering means for a filter press type electrolytic cell
US4978590A (en) * 1989-09-11 1990-12-18 The United States Of America As Represented By The Department Of Energy Dry compliant seal for phosphoric acid fuel cell
US5246065A (en) * 1990-12-21 1993-09-21 Cadillac Rubber & Plastics, Inc. Heat exchanger tank incorporating an overmolded gasket
US5160474A (en) * 1990-12-21 1992-11-03 Cadillac Rubber & Plastics, Inc. Overmolded gasket, heat exchanger tank incorporating the same and method for making the same
US5354625A (en) * 1992-03-16 1994-10-11 Aer Energy Resources, Inc. Metal-air power supply and air-manager system, and metal-air cell for use therein
US5721064A (en) * 1993-04-30 1998-02-24 Aer Energy Resources Inc. Air manager system for reducing gas concentrations in a metal-air battery
US5560999A (en) * 1993-04-30 1996-10-01 Aer Energy Resources, Inc. Air manager system for recirculating reactant air in a metal-air battery
US5460897A (en) * 1994-03-18 1995-10-24 Allied Signal Inc. Solid oxide fuel cell stacking assembly
JP2863083B2 (en) * 1994-04-01 1999-03-03 矢崎総業株式会社 Waterproof stopper for connector
DE4425186C1 (en) * 1994-07-16 1996-03-07 Mtu Friedrichshafen Gmbh Fuel cell arrangement and method for operating a fuel cell arrangement
US5622117A (en) * 1995-06-06 1997-04-22 Salco Products, Inc. Hatch cover having a removable gasket
US5873468A (en) * 1995-11-16 1999-02-23 Sumitomo Sitix Corporation Thin-plate supporting container with filter means
US6106962A (en) * 1997-09-24 2000-08-22 Aer Energy Resources Inc. Air manager control using cell voltage as auto-reference
US6017649A (en) * 1998-02-12 2000-01-25 M-C Power Corporation Multiple step fuel cell seal
US6050199A (en) * 1998-03-27 2000-04-18 Zeftek, Inc. Hatch cover sealing device
US6355371B1 (en) 1999-08-27 2002-03-12 Plug Power Inc. Profiled fuel cell flow plate gasket
US6261711B1 (en) 1999-09-14 2001-07-17 Plug Power Inc. Sealing system for fuel cells
GB2387959C (en) * 2002-03-28 2005-02-09 Intelligent Energy Ltd Fuel cell compression assembly
US7112384B2 (en) * 2003-07-15 2006-09-26 Utc Fuel Cells, Llc Fuel cell manifold seal with rigid inner layer
EP1705738A1 (en) * 2005-03-21 2006-09-27 Sulzer Hexis AG High temperature fuel cells and multi-component housing installation for a cell stack
JP2006298242A (en) * 2005-04-22 2006-11-02 Asteer Co Ltd Filler cap
US8652589B2 (en) * 2008-01-25 2014-02-18 Oerlikon Trading Ag, Truebbach Permeation barrier layer
WO2009149314A2 (en) * 2008-06-06 2009-12-10 Fuelcell Energy, Inc. Modular fuel cell stack assembly including anode gas oxidizer and integrated external manifolds for use in fuel cell stack modules
US8883365B2 (en) * 2010-02-22 2014-11-11 GM Global Technology Operations LLC Fuel cell stack discrete header
KR20140099925A (en) * 2011-11-28 2014-08-13 클리어엣지 파워 코포레이션 Fuel cell seal retainer assembly

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US4212929A (en) * 1979-04-06 1980-07-15 The United States Of America As Represented By The United States Department Of Energy Fuel cell manifold sealing system
US4345009A (en) * 1979-08-17 1982-08-17 United Technologies Corporation Fuel cell stack compressive loading system
US4374185A (en) * 1981-05-14 1983-02-15 United Technologies Corporation High temperature, high pressure chemical resistant seal material
JPS59214164A (en) * 1983-05-19 1984-12-04 Mitsubishi Electric Corp Layer-built fuel cell
DE3427626C1 (en) * 1984-07-26 1985-10-17 TRW United-Carr GmbH, 6000 Frankfurt Sealing cover
JPS6130968U (en) * 1984-07-28 1986-02-25 株式会社 富士電機総合研究所 fuel cell stack

Also Published As

Publication number Publication date
US4738905A (en) 1988-04-19

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